EP0789069A3 - Additive containing multifunctional lubricating oil and engine oil compositions - Google Patents

Additive containing multifunctional lubricating oil and engine oil compositions Download PDF

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Publication number
EP0789069A3
EP0789069A3 EP95119299A EP95119299A EP0789069A3 EP 0789069 A3 EP0789069 A3 EP 0789069A3 EP 95119299 A EP95119299 A EP 95119299A EP 95119299 A EP95119299 A EP 95119299A EP 0789069 A3 EP0789069 A3 EP 0789069A3
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EP
European Patent Office
Prior art keywords
derivative
usual
acid
polymer
dispersant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP95119299A
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German (de)
French (fr)
Other versions
EP0789069A2 (en
EP0789069B1 (en
Inventor
Janos Auer
Jeno Baladincz
Laszlo Dr. Bartha
Eva Bobest
Gyula Dr. Deak
Ferenc Dr. Dénes
Jeno Dr. Hancsok
Janos Kis
Margit Lenti
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VESZPREMI EGYETEM
Mol Magyar Olaj es Gazipari Rt
Original Assignee
VESZPREMI EGYETEM
Mol Magyar Olaj es Gazipari Rt
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Publication of EP0789069A2 publication Critical patent/EP0789069A2/en
Publication of EP0789069A3 publication Critical patent/EP0789069A3/en
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Publication of EP0789069B1 publication Critical patent/EP0789069B1/en
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M167/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04Hydroxy compounds
    • C10M129/10Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
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    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26Carboxylic acids; Salts thereof
    • C10M129/28Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26Carboxylic acids; Salts thereof
    • C10M129/28Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/42Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms polycarboxylic
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    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/86Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of 30 or more atoms
    • C10M129/95Esters
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    • C10M133/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/12Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
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    • C10M133/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/38Heterocyclic nitrogen compounds
    • C10M133/44Five-membered ring containing nitrogen and carbon only
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    • C10M133/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/52Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
    • C10M133/56Amides; Imides
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    • C10M135/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/02Sulfurised compounds
    • C10M135/06Esters, e.g. fats
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    • C10M135/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/12Thio-acids; Thiocyanates; Derivatives thereof
    • C10M135/14Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond
    • C10M135/18Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiocarbamic type, e.g. containing the groups
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    • C10M135/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/32Heterocyclic sulfur, selenium or tellurium compounds
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    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • C10M137/10Thio derivatives
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    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
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    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/02Polyethene
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    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/04Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing propene
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    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/12Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing conjugated diene
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    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/06Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of a saturated carboxylic or carbonic acid
    • C10M145/08Vinyl esters of a saturated carboxylic or carbonic acid
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    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/12Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
    • C10M145/14Acrylate; Methacrylate
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    • C10M149/00Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/06Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
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    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
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    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/24Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
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    • C10M2205/022Ethene
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    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024Propene
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    • C10N2010/04Groups 2 or 12
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    • C10N2040/251Alcohol-fuelled engines
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/255Gasoline engines
    • C10N2040/28Rotary engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Processing Of Solid Wastes (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Saccharide Compounds (AREA)
  • Lubrication Of Internal Combustion Engines (AREA)

Abstract

Multifunctional engine oil composition consists of a base oil and an additive package (1.5-55 weight %) comprises: (A) 10-100 wt.% polyfunctional, ash-free detergent-dispersant additive or its oily solution comprising polymer components which are produced by reacting a polyolefin derivative, preferably a PIB derivative, injected with dicarboxylic acid (anhydride) and non-acidic comonomers with ethylenic double bond, and having an average molecular weight of 800, with compound containing amino, imino or hydroxyl groups, the polyolefin chain in the polymer component carrying 1.6-20 acid derivatives, the amount of the molecules with more than one acid derivative being at least 25 wt.%, and the derivative being an imide, amide or ester amide derivative, and 0-90 wt.% usual alkenyl succinic acid derivative; (B) usual dispersant-detergent with different base number and metal content, antioxidant, friction reducer, wear inhibitor, corrosion inhibitor, defoamer and flow point reducer; and (C) usual viscosity (index) improving polymer. Weight ratio of A:B:C is 15-85: 15-85: 0-70.
EP95119299A 1995-09-25 1995-12-07 Additive containing multigrade lubricating oil and engine oil composition Expired - Lifetime EP0789069B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
HU9502797A HU213255B (en) 1995-09-25 1995-09-25 Multiple- stage engineoil and lubricant composition and additive-pocket
HU9502797 1995-09-25

Publications (3)

Publication Number Publication Date
EP0789069A2 EP0789069A2 (en) 1997-08-13
EP0789069A3 true EP0789069A3 (en) 1998-05-13
EP0789069B1 EP0789069B1 (en) 2007-06-20

Family

ID=10987244

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95119299A Expired - Lifetime EP0789069B1 (en) 1995-09-25 1995-12-07 Additive containing multigrade lubricating oil and engine oil composition

Country Status (14)

Country Link
EP (1) EP0789069B1 (en)
AT (1) ATE365202T1 (en)
CZ (1) CZ294327B6 (en)
DE (1) DE59511080D1 (en)
EE (1) EE9500079A (en)
ES (1) ES2289741T3 (en)
HR (1) HRP950611B1 (en)
HU (1) HU213255B (en)
PL (1) PL179150B1 (en)
RO (1) RO119233B1 (en)
RS (1) RS49806B (en)
RU (1) RU2161179C2 (en)
SK (1) SK284909B6 (en)
UA (1) UA43339C2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4143417A4 (en) 2020-07-02 2024-01-10 Halliburton Energy Services, Inc. Seal bag for seal of an electric submersible pump
US11708838B2 (en) 2020-07-02 2023-07-25 Halliburton Energy Services, Inc. Chemical sequestration of wellbore fluids in electric submersible pump systems
RU2769603C1 (en) * 2021-03-17 2022-04-04 Федеральное государственное бюджетное образовательное учреждение высшего образования «Тамбовский государственный технический университет» (ФГБОУ ВО «ТГТУ») Non-drying composition for protecting steel products

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0657475A1 (en) * 1993-12-13 1995-06-14 Chevron Chemical Company Polymeric dispersants having polyalkylene and succinic groups
EP0658572A1 (en) * 1993-12-16 1995-06-21 Mol Magyar Olaj Es Gazipari Reszvenytarsasag Ashless detergent-dispersant polymeric additive mixtures and process for their manufacture
US5445657A (en) * 1993-06-16 1995-08-29 Institut Francais Du Petrole Polyfunctional polyisobutenes, their preparation, their formulation and their use
EP0677572A2 (en) * 1994-04-15 1995-10-18 Mol Magyar Olaj Es Gazipari Reszvenytarsasag Detergent-dipersant additive for lubricating oils of internal combustion engines and its preparation process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5445657A (en) * 1993-06-16 1995-08-29 Institut Francais Du Petrole Polyfunctional polyisobutenes, their preparation, their formulation and their use
EP0657475A1 (en) * 1993-12-13 1995-06-14 Chevron Chemical Company Polymeric dispersants having polyalkylene and succinic groups
EP0658572A1 (en) * 1993-12-16 1995-06-21 Mol Magyar Olaj Es Gazipari Reszvenytarsasag Ashless detergent-dispersant polymeric additive mixtures and process for their manufacture
EP0677572A2 (en) * 1994-04-15 1995-10-18 Mol Magyar Olaj Es Gazipari Reszvenytarsasag Detergent-dipersant additive for lubricating oils of internal combustion engines and its preparation process

Also Published As

Publication number Publication date
HRP950611B1 (en) 2008-08-31
YU80395A (en) 1998-07-10
ES2289741T3 (en) 2008-02-01
RS49806B (en) 2008-08-07
DE59511080D1 (en) 2007-08-02
CZ341095A3 (en) 1998-04-15
RU2161179C2 (en) 2000-12-27
HRP950611A2 (en) 1998-02-28
CZ294327B6 (en) 2004-11-10
HU213255B (en) 1997-05-28
EP0789069A2 (en) 1997-08-13
PL312098A1 (en) 1997-04-01
UA43339C2 (en) 2001-12-17
ATE365202T1 (en) 2007-07-15
EE9500079A (en) 1997-04-15
SK284909B6 (en) 2006-02-02
RO119233B1 (en) 2004-06-30
SK162995A3 (en) 1997-07-09
EP0789069B1 (en) 2007-06-20
PL179150B1 (en) 2000-07-31
HU9502797D0 (en) 1995-11-28

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