EP0780649A1 - A method and installation for the removal of nitrogen from natural gas - Google Patents

A method and installation for the removal of nitrogen from natural gas Download PDF

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Publication number
EP0780649A1
EP0780649A1 EP96203555A EP96203555A EP0780649A1 EP 0780649 A1 EP0780649 A1 EP 0780649A1 EP 96203555 A EP96203555 A EP 96203555A EP 96203555 A EP96203555 A EP 96203555A EP 0780649 A1 EP0780649 A1 EP 0780649A1
Authority
EP
European Patent Office
Prior art keywords
nitrogen
natural gas
heat exchanger
installation
liquid oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96203555A
Other languages
German (de)
French (fr)
Other versions
EP0780649B1 (en
Inventor
Karel Dirk Scheffer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nv Hoek Loos
Original Assignee
HOEK MACH ZUURSTOFF
WA Hoeks Machine en Zuurstoffabriek NV
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Publication date
Application filed by HOEK MACH ZUURSTOFF, WA Hoeks Machine en Zuurstoffabriek NV filed Critical HOEK MACH ZUURSTOFF
Publication of EP0780649A1 publication Critical patent/EP0780649A1/en
Application granted granted Critical
Publication of EP0780649B1 publication Critical patent/EP0780649B1/en
Anticipated expiration legal-status Critical
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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/066—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/0605—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the feed stream
    • F25J3/061—Natural gas or substitute natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/0635—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/50—Oxygen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/90—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
    • F25J2270/904—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration by liquid or gaseous cryogen in an open loop

Definitions

  • the present invention relates to a method and installation for the removal of nitrogen from natural gas.
  • Nitrogen is not wanted in natural gas because nitrogen does not contribute to a higher flame temperature, on the contrary, nitrogen is ballast; therefore nitrogen needs to be removed from natural gas.
  • nitrogen is known to bind to oxygen, forming toxic NO x compounds.
  • the object of the invention is the removal of nitrogen from natural gas and the use of pure oxygen, resulting in increased efficiency.
  • the nitrogen present in the natural gas has to be removed before the natural gas enters the combustion process.
  • the present invention provides a method and installation.
  • the method for the removal of nitrogen from natural gas by means of cryocondensation according to the invention is characterized in that liquid oxygen is used as the cooling means.
  • cryocondensation of hydrocarbons is carried out using cold nitrogen as cooling means.
  • the method according to the invention is particularly suitable for the removal of nitrogen from natural gas having a nitrogen content of about 14% by volume.
  • the general idea of the invention is that the liquid oxygen is boiled off in a cryocondensation unit, causing the hydrocarbons to condense. After heating, the condensed hydrocarbons, together with the gaseous oxygen that has developed, can be used in the combustion process.
  • the liquid oxygen is fed to a heat exchanger where the nitrogen-rich natural gas is condensed and the residual gaseous nitrogen is discharged while after being warmed up, the nitrogen-free condensed hydrocarbons as well as the gaseous oxygen, are led to a burner.
  • the natural gas to be treated is preferably precooled in a heat exchanger to about -80°C before cooling with liquid oxygen to about -165°C.
  • the method according to the invention provides the following advantages:
  • the present invention relates to an installation for the removal of nitrogen from natural gas, characterized in that the installation (1) is provided with a storage tank (2) for liquid oxygen, which tank (2) is connected by means of a pipe (5) with the heat exchanger (3) for the condensation of the natural gas which, via pipe (7) and heat exchanger (3) is linked to the heat exchanger (4), from which the nitrogen-free condensed natural gas via a pipe (6), after being heated in the heat exchanger (4), arrives via pipe (13) in the burner (12), while liquid oxygen from heat exchanger (3) enters via pipe (9) the heat exchanger (11) to be fed in the gaseous phase via pipe (10) to burner (12) and gaseous nitrogen is removed from the heat exchanger (3) via pipe (8).
  • the installation according to the invention is indicated by reference number (1).
  • the installation (1) according to the invention is provided with a storage tank (2) for liquid oxygen.
  • the installation is further provided with heat exchangers (3,4, and 11).
  • Natural gas for instance from Groningen, having a nitrogen content of 14% by volume is fed via the mains to the heat exchanger (4) in which the natural gas is cooled to -80°C.
  • the thus cooled natural gas is led to the heat exchanger (3) in order to be further cooled with the aid of liquid oxygen to -160°C to -165°C, which liquid oxygen is led from the storage tank (2) into the heat exchanger via pipe (5) and tap (14).
  • the hydrocarbons condensed in the heat exchanger (3) are fed into the heat exchanger (4), where the liquid hydrocarbons become gaseous and in that form are transported via pipe (13) to, for instance, the burner (12) of a melting furnace.
  • oxygen coming from the heat exchanger (3) in liquid form is led via pipe (9) and tap (16) to the burner (12) in the heat exchanger (11).
  • cold gaseous oxygen is further heated to ambient temperature.
  • the gaseous oxygen is united with the hydrocarbons in burner (12) of the melting furnace.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The invention relates to a method for the removal of nitrogen from natural gas by means of cryocondensation. According to the invention liquid oxygen is used as the cooling means.
Usually the natural gas has a nitrogen content of about 14% by volume.
The invention further relates to an installation for the removal of nitrogen from natural gas.

Description

  • The present invention relates to a method and installation for the removal of nitrogen from natural gas.
  • Nitrogen is not wanted in natural gas because nitrogen does not contribute to a higher flame temperature, on the contrary, nitrogen is ballast; therefore nitrogen needs to be removed from natural gas.
  • Moreover, at high flame temperatures nitrogen is known to bind to oxygen, forming toxic NOx compounds.
  • These reasons also make it clear that for the combustion process nitrogen is a most undesirable gas.
  • It is generally known that oxyfuel is a much applied process, in which during the combustion process pure oxygen is used instead of air with the aim to improve the efficiency of ovens. It goes without saying that here also the nitrogen present in the air (about 79% by volume) is merely ballast which, apart from the disadvantages just mentioned, leads to heat loss because nitrogen is blown into the atmosphere as warmed up gas.
  • The object of the invention is the removal of nitrogen from natural gas and the use of pure oxygen, resulting in increased efficiency.
  • To this end the nitrogen present in the natural gas has to be removed before the natural gas enters the combustion process.
  • To this end the present invention provides a method and installation.
  • The method for the removal of nitrogen from natural gas by means of cryocondensation according to the invention is characterized in that liquid oxygen is used as the cooling means.
  • According to the prior art cryocondensation of hydrocarbons is carried out using cold nitrogen as cooling means.
  • According to the present invention the disadvantages mentioned above are effectively removed.
  • It has been shown that the method according to the invention is particularly suitable for the removal of nitrogen from natural gas having a nitrogen content of about 14% by volume.
  • Basically the general idea of the invention is that the liquid oxygen is boiled off in a cryocondensation unit, causing the hydrocarbons to condense. After heating, the condensed hydrocarbons, together with the gaseous oxygen that has developed, can be used in the combustion process.
  • According to a favourable embodiment of the present invention, the liquid oxygen is fed to a heat exchanger where the nitrogen-rich natural gas is condensed and the residual gaseous nitrogen is discharged while after being warmed up, the nitrogen-free condensed hydrocarbons as well as the gaseous oxygen, are led to a burner.
  • The natural gas to be treated is preferably precooled in a heat exchanger to about -80°C before cooling with liquid oxygen to about -165°C.
  • In comparison to the prior art, the method according to the invention provides the following advantages:
    • 1) The toxic NOx compounds are reduced to a minimum.
    • 2) A highly calorific natural gas is obtained from a natural gas of low calorific value such as, for instance, natural gas from the North Sea.
    • 3) A natural gas is obtained having a greater combustion efficiency, which natural gas is particularly suitable for use in melting furnaces in the glass industry, ceramic industry, steel industry and non-ferro industry.
  • Further, the present invention relates to an installation for the removal of nitrogen from natural gas, characterized in that the installation (1) is provided with a storage tank (2) for liquid oxygen, which tank (2) is connected by means of a pipe (5) with the heat exchanger (3) for the condensation of the natural gas which, via pipe (7) and heat exchanger (3) is linked to the heat exchanger (4), from which the nitrogen-free condensed natural gas via a pipe (6), after being heated in the heat exchanger (4), arrives via pipe (13) in the burner (12), while liquid oxygen from heat exchanger (3) enters via pipe (9) the heat exchanger (11) to be fed in the gaseous phase via pipe (10) to burner (12) and gaseous nitrogen is removed from the heat exchanger (3) via pipe (8).
  • The invention will now be further elucidated with reference to the drawing which illustrates a preferred embodiment of the installation in accordance with the invention.
  • In the drawing the installation according to the invention is indicated by reference number (1). The installation (1) according to the invention is provided with a storage tank (2) for liquid oxygen.
  • The installation is further provided with heat exchangers (3,4, and 11).
  • Natural gas, for instance from Groningen, having a nitrogen content of 14% by volume is fed via the mains to the heat exchanger (4) in which the natural gas is cooled to -80°C. Via valve (15) the thus cooled natural gas is led to the heat exchanger (3) in order to be further cooled with the aid of liquid oxygen to -160°C to -165°C, which liquid oxygen is led from the storage tank (2) into the heat exchanger via pipe (5) and tap (14). Via pipe (6) the hydrocarbons condensed in the heat exchanger (3) are fed into the heat exchanger (4), where the liquid hydrocarbons become gaseous and in that form are transported via pipe (13) to, for instance, the burner (12) of a melting furnace.
  • Further, oxygen coming from the heat exchanger (3) in liquid form is led via pipe (9) and tap (16) to the burner (12) in the heat exchanger (11). In the heat exchanger (11) cold gaseous oxygen is further heated to ambient temperature. Via pipe (10) the gaseous oxygen is united with the hydrocarbons in burner (12) of the melting furnace.
  • It goes without saying that other embodiments of the method and installation according to the invention are possible without departing from the underlying principle. Naturally any such variants are comprised in the present invention.

Claims (5)

  1. A method for the removal of nitrogen from natural gas by means of cryocondensation, characterized in that liquid oxygen is used as the cooling means.
  2. A method in accordance with claim 1, characterized in that the natural gas has a nitrogen content of about 14% by volume.
  3. A method in accordance with claim 1 or 2, characterized in that the liquid oxygen is fed to a heat exchanger where the nitrogen-rich natural gas is condensed and the residual gaseous nitrogen is discharged while after being warmed up, the nitrogen-free condensed hydrocarbons as well as the gaseous oxygen, are led to a burner.
  4. A method in accordance with claims 1-3, characterized in that the natural gas is first precooled in a heat exchanger to about -80°C before cooling with liquid oxygen to about -165°C.
  5. An installation for the removal of nitrogen from natural gas, characterized in that the installation 1 is provided with a storage tank 2 for liquid oxygen, which tank 2 is connected by means of a pipe 5 with the heat exchanger 3 for the condensation of the natural gas which, via pipe 7 and heat exchanger 3 is linked to the heat exchanger 4, from which the nitrogen-free condensed natural gas via a pipe 6, after being heated in the heat exchanger 4, arrives via pipe 13 in the burner 12, while liquid oxygen from heat exchanger 3 enters via pipe 9 the heat exchanger 11 to be fed in the gaseous phase via pipe 10 to burner 12 and gaseous nitrogen is removed from the heat exchanger 3 via pipe 8.
EP96203555A 1995-12-20 1996-12-16 A method and installation for the removal of nitrogen from natural gas Expired - Lifetime EP0780649B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL1001940 1995-12-20
NL1001940A NL1001940C2 (en) 1995-12-20 1995-12-20 Method and device for removing nitrogen from natural gas.

Publications (2)

Publication Number Publication Date
EP0780649A1 true EP0780649A1 (en) 1997-06-25
EP0780649B1 EP0780649B1 (en) 2001-07-04

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EP96203555A Expired - Lifetime EP0780649B1 (en) 1995-12-20 1996-12-16 A method and installation for the removal of nitrogen from natural gas

Country Status (5)

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EP (1) EP0780649B1 (en)
AT (1) ATE202840T1 (en)
DE (1) DE69613664T2 (en)
NL (1) NL1001940C2 (en)
PL (1) PL317602A1 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10006695B2 (en) 2012-08-27 2018-06-26 1304338 Alberta Ltd. Method of producing and distributing liquid natural gas
US10077937B2 (en) 2013-04-15 2018-09-18 1304338 Alberta Ltd. Method to produce LNG
US10288347B2 (en) 2014-08-15 2019-05-14 1304338 Alberta Ltd. Method of removing carbon dioxide during liquid natural gas production from natural gas at gas pressure letdown stations
US10571187B2 (en) 2012-03-21 2020-02-25 1304338 Alberta Ltd Temperature controlled method to liquefy gas and a production plant using the method
US10634426B2 (en) 2011-12-20 2020-04-28 1304338 Alberta Ltd Method to produce liquefied natural gas (LNG) at midstream natural gas liquids (NGLs) recovery plants
US10852058B2 (en) 2012-12-04 2020-12-01 1304338 Alberta Ltd. Method to produce LNG at gas pressure letdown stations in natural gas transmission pipeline systems
US11097220B2 (en) 2015-09-16 2021-08-24 1304338 Alberta Ltd. Method of preparing natural gas to produce liquid natural gas (LNG)
US11486636B2 (en) 2012-05-11 2022-11-01 1304338 Alberta Ltd Method to recover LPG and condensates from refineries fuel gas streams

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5036671A (en) * 1990-02-06 1991-08-06 Liquid Air Engineering Company Method of liquefying natural gas
US5390499A (en) * 1993-10-27 1995-02-21 Liquid Carbonic Corporation Process to increase natural gas methane content

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5036671A (en) * 1990-02-06 1991-08-06 Liquid Air Engineering Company Method of liquefying natural gas
US5390499A (en) * 1993-10-27 1995-02-21 Liquid Carbonic Corporation Process to increase natural gas methane content

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10634426B2 (en) 2011-12-20 2020-04-28 1304338 Alberta Ltd Method to produce liquefied natural gas (LNG) at midstream natural gas liquids (NGLs) recovery plants
US10571187B2 (en) 2012-03-21 2020-02-25 1304338 Alberta Ltd Temperature controlled method to liquefy gas and a production plant using the method
US11486636B2 (en) 2012-05-11 2022-11-01 1304338 Alberta Ltd Method to recover LPG and condensates from refineries fuel gas streams
US10006695B2 (en) 2012-08-27 2018-06-26 1304338 Alberta Ltd. Method of producing and distributing liquid natural gas
US10852058B2 (en) 2012-12-04 2020-12-01 1304338 Alberta Ltd. Method to produce LNG at gas pressure letdown stations in natural gas transmission pipeline systems
US10077937B2 (en) 2013-04-15 2018-09-18 1304338 Alberta Ltd. Method to produce LNG
US10288347B2 (en) 2014-08-15 2019-05-14 1304338 Alberta Ltd. Method of removing carbon dioxide during liquid natural gas production from natural gas at gas pressure letdown stations
US11097220B2 (en) 2015-09-16 2021-08-24 1304338 Alberta Ltd. Method of preparing natural gas to produce liquid natural gas (LNG)
US11173445B2 (en) 2015-09-16 2021-11-16 1304338 Alberta Ltd. Method of preparing natural gas at a gas pressure reduction stations to produce liquid natural gas (LNG)

Also Published As

Publication number Publication date
EP0780649B1 (en) 2001-07-04
DE69613664T2 (en) 2002-05-29
PL317602A1 (en) 1997-06-23
NL1001940C2 (en) 1997-06-24
DE69613664D1 (en) 2001-08-09
ATE202840T1 (en) 2001-07-15

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