Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D33/00—Details of, or accessories for, sacks or bags
  • B65D33/16—End- or aperture-closing arrangements or devices
  • B65D33/34—End- or aperture-closing arrangements or devices with special means for indicating unauthorised opening
• • G—PHYSICS
  • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
  • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
  • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
  • G09F3/02—Forms or constructions
  • G09F3/0291—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
  • G09F3/0292—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time tamper indicating labels
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D2401/00—Tamper-indicating means

Definitions

• This invention relates generally to tamper-evident closures and, more particularly, a closure in the form of a tape or label that indicates a forced opening, cooling below a particular temperature, and/or heating above a particular temperature.
• Tamper-evident closures for containers such as bags, envelopes, packages, etc. and tamper-evident tapes and labels for use with bags, envelopes, and other packages have been available for several years. Generally, if these existing closures are forced open, the visual appearance of the closure changes so as to provide an indication that the contents of the container have been accessed.
• Containers fabricated having tamper-evident closures are commonly used in industries in which the contents of the containers must be maintained in tight security, for example, in the banking industry. In certain instances package manufacturers employ prefabricated closures in the form of a tape or label to provide a tamper-evident closure on their packaging. Tamper-evident closures in the form of tapes or labels are also often used by everyday consumers who want to ensure that their packages are securely sealed and will evidence tampering if it occurs.
• a bag commonly used in banking and other industries is a bag, pouch or envelope (generally referred to herein as a bag) formed of a plastic material such as polyethylene.
• the opening in this type of bag is commonly closed with a pressure-sensitive adhesive located on one side of the bag.
• a peelback strip covering the free side of the adhesive is removed, and the exposed surface of the adhesive is then pressed against the opposite side of the bag.
• the pressure-sensitive adhesive and/or other parts of the bag will distort and break apart, so as to provide an indication that the bag has been opened, possibly without authorization.
• Closures for a bag of this type have been formed with layers in addition to the pressure-sensitive adhesive to provide a clearer indication of when the closure is forced open.
• U.S. Patent No. 5,060,848 to F.R. Ewan describes a tamper evident seal that uses a layer of nitrocellulose or acrylic ink that breaks apart in a selected pattern when the seal is forced open. The layer of ink is adhered to a polyester panel that is part of the seal. Before applying the ink the plastic panel is masked with a desired pattern of a silicon oil releasant material, which normally causes the ink to break apart in the masked pattern when the seal is forced open. Also, to ensure that the ink layer adheres to the silicon oil releasant material and polyester panel, a primer is applied over the silicon oil releasant, and the ink is then applied over the primer.
• bags of this type are generally expensive to manufacture, use hazardous materials, and are not easily recycled.
• the polyester panel disclosed in U.S. Patent No. 5,060,848 to F.R Ewan is not easily recycled, and the primer required is hazardous.
• thieves have devised a scheme to gain access to the contents of bags of this type without detection.
• the scheme devised involves spraying a liquid refrigerant onto the adhesive to freeze the adhesive down to its glass transition temperature, generally at about -10°F. At this temperature, the adhesive becomes brittle and loses its adhesive qualities, i.e., tack.
• the thief is then able to open the bag and remove certain contents.
• the thief allows the adhesive to warm back to room temperature, at which point the adhesive regains its tack and then simply recloses the bag by applying pressure, all without any evidence of tampering.
• Thieves have also devised a scheme to gain access to the contents of bags of this type without detection by heating the adhesive to a temperature at which the adhesive softens. The thief is then able to open the bag and remove certain contents. The thief can reseal the bag while the adhesive is still soft by applying pressure, all without any evidence of tampering.
• Tamper-evident closures for plastic bags have been formed to combat the problem of refrigerant tampering. Such closures provide an indication that the bag was opened, whether or not a refrigerant is first applied.
• These closures include multiple adhesive and nonadhesive layers that have differing strengths so that when the closure is forced open, one or more of the layers is permanently altered, even if a refrigerant is first applied.
• U.S. Patent No. 4,834,552 to K.R. Makowka describes a tamper-evident seal for a plastic envelope. The tamper-evident seal comprises two paper layers and an adhesive layer.
• One of the paper layers is bonded to a closure flap on the back wall of the envelope, the other paper layer is bonded to the front wall of the envelope, and the adhesive layer is applied to the free side of one of the paper layers.
• the closure flap is folded over the envelope opening, and the adhesive layer is pressed onto the paper layer that has a free side.
• the adhesive seeps into the interstices of the paper layers to form a mechanical-type lock with the paper layers.
• the strength of this mechanical-type lock is apparently greater than the internal strength of the paper layers, even if a refrigerant is first applied, so that the paper layers break apart when the seal is forced open.
• closures such as the seal disclosed in the Makowka patent have several shortcomings. These closures do not provide any evidence of refrigerant tampering unless the closure is actually forced open. Thus, if a thief begins to attempt to open a bag by applying a refrigerant, but his efforts are somehow thwarted before he is able to force the bag open, the thief's tampering will go undetected. Even if these closures are forced open, they do not always satisfactorily provide evidence of such tampering. Any delamination of one of the paper layers can only be detected by close inspection; the delamination is not bold and distinct as would be desired.
• closures Once the closure is forced open, it is possible to use additional adhesive/glue to reclose the closure, without any readily visible evidence that the closure was ever opened.
• these closures generally have high production costs.
• the closure described in the Makowka patent requires two paper layers, which must both be bonded to the envelope during its production.
• the bag and closure taught by the Makowka patent is not readily recyclable.
• closures which provide evidence of heat tampering are also needed.
• the tape or label should be easy to close, and the evidence of tampering provided should be readily visible, i.e., bold and distinct.
• the tape or label providing these features should also be relatively inexpensive and easy to recycle and include only nonhazardous materials. As explained in the following, the present invention provides a tape and label that meets these criteria.
• a bag closure that provides evidence of refrigerant tampering.
• the bag closure is sensitive to being cooled below a particular "breakdown temperature," so that if a refrigerant is applied, the visual appearance of the closure permanently changes, regardless of whether the closure is opened.
• the closure includes an adhesive layer and a delaminating layer that visibly delaminates when the closure is cooled below the breakdown temperature.
• the bag includes a back and front wall that are joined at their peripheral side and bottom edges. The opening of the bag is formed by the upper ends of the back and front walls, and the closure is located at this opening.
• one surface of the delaminating layer is bonded to a closure flap formed at the upper end of the bag front wall.
• the opposite surface of the delaminating layer is adhered to one surface of the adhesive layer, and the opposite surface of the adhesive layer is adhered to the bag back wall.
• the bag is formed so that one surface of the adhesive layer is adhered to the bag back wall and the opposite surface of the adhesive layer is covered with a peel-back strip. To close the closure, the peel-back strip is removed and the free surface of the adhesive layer is pressed against the delaminating layer.
• the delaminating layer delaminates from the front wall prior to the adhesive layer losing its tack which occurs when the adhesive layer reaches its glass transition temperature.
• an indication of refrigerant tampering is provided before the refrigerant allows the closure to be easily opened.
• the delaminating layer delaminates regardless of whether the closure is actually opened, so that the closure provides evidence of the mere application of a refrigerant.
• the delaminating layer delaminates whenever the closure is opened, so as to provide an indication that the contents of the bag have been accessed.
• the delaminating layer comprises a layer of ink that is applied to the closure flap on the bag front wall.
• the adhesive layer comprises a pres.sure-sensitive adhesive and the closure flap comprises a plastic material.
• the closure flap, ink and pressure-sensitive adhesive are chosen so that when the temperature of the closure is above the glass transition temperature of the adhesive, the bond (i.e., affinity) between the ink layer and the adhesive layer is at least as strong as (and preferably stronger than) the bond between the ink layer and the closure flap.
• the ink layer delaminates when the closure is forced open.
• the adhesive layer and the closure flap are chosen such that, when cooled, the closure flap and the adhesive layer shrink at different rates.
• both the ink and closure flap have contrasting colors so that delamination of the ink can be easily seen.
• the closure flap comprises a polyethylene plastic and the ink is water based.
• the ink is in direct contact with the closure flap without any intervening primer or releasant, and the closure flap is not pretreated (e.g., by corona discharge) .
• a process for manufacturing this bag closure is also provided by the invention.
• the previously described delaminating layer of the bag closure includes two layers of ink.
• a patterned layer of clear ink is applied directly to the closure flap without any intervening primer or releasant, or pretreating of the closure flap.
• the clear ink can be applied in a pattern to form a series of "stop signs.”
• the closure flap is treated, e.g., with a corona discharge process, so that the ink more readily adheres to the closure flap.
• a uniform layer of colored ink is applied over the patterned layer of clear ink and ink-free portions of the closure flap.
• the two ink layers are sandwiched between the adhesive and the closure flap, which is preferably a polyethylene plastic. If the closure flap is quickly "frozen” or forced open, the clear ink, and the colored ink positioned over the clear ink delaminates from the closure flap. The colored ink in between the clear ink pattern remains on the closure flap, so that the pattern of the clear ink appears.
• a tamper evident tape or label formed similarly to the tamper-evident closure described above is provided.
• a polyethylene plastic layer is used to form the tape or label backing.
• a layer of ink is applied to the plastic layer, and a layer of pressure-sensitive adhesive is then applied over the ink.
• the tape or label is secured by pressing the adhesive layer onto the desired surface.
• a bag closure that provides evidence of heat tampering is also provided.
• the bag closure is sensitive to being heated above a particular activation temperature, so that if heat is applied, the visual appearance of the closure permanently changes, regardless of whether the closure is opened.
• the closure includes a thermally activatable or thermochromic ink layer that visibly changes when the closure is heated at or above the activation temperature of the ink.
• the thermally activatable ink layer can be applied uniformly or in a pattern, for example, so that upon activation, the ink forms a series of "stop signs."
• a uniform coating of a standard ink can be used to provide a background contrast, and a layer of the thermally activatable ink can be applied in a pattern, such as the above-referenced series of "stop signs" over the layer of standard ink.
• the standard ink and the thermally activatable ink are the same color.
• the thermally activatable ink layer is used in combination with any of the tamper evident closures described above.
• this invention provides a tape or label that can be used as a bag closure that provides evidence of the mere application of a refrigerant, and/or the mere application of heat, regardless of whether the closure is actually forced open. Furthermore, if the closure is forced open, whether or not a refrigerant and/or heat is first applied, the tape or label provides a permanent indication that the closure was opened.
• the tapes and labels and corresponding manufacturing process provided by this invention present a cost savings over existing tapes and labels since they include a minimal number of layers which are inexpensive to form. The materials used are inexpensive and nonhazardous. Furthermore, because the tape and labels are preferably formed of a polyethylene plastic, they are easily recycled.
• FIGURES 1A and IB are pictorial views of a bag including a tamper-evident seal formed in accordance with the invention
• FIGURE 2A is a side cross-sectional view of the bag shown in FIGURES 1A and IB, and FIGURE 2B is a side cross-sectional view of the bag with the seal closed;
• FIGURE 3 is a front view of the bag illustrating the visual appearance of the seal when closed;
• FIGURE 4A is a pictorial view of the seal illustrating how the seal visually distorts if the seal is forced open
• FIGURE 4B is a pictorial view illustrating how the visual distortion remains, even if the seal is reclosed;
• FIGURE 5 is a front view of the bag illustrating the visual distortion of the seal that occurs when the seal is cooled below a particular temperature
• FIGURES 6A-6D are top views of a plastic strip formed in accordance with a further embodiment of the present invention, and FIGURE 6E is a side cross-sectional view of the plastic strip shown in FIGURES 6A-6D;
• FIGURE 7 is a side cross-sectional view of a bag with a tamper-evident seal including the plastic strip shown in FIGURES 6A-6E in accordance with the invention
• FIGURE 8A is a front view of the bag shown in FIGURE 7, illustrating the visual appearance of the seal when a portion of the seal is forced open;
• FIGURE 8B is an end cross-sectional view of the seal in FIGURE 8A, illustrating the delamination of the portion of the seal that is forced open;
• FIGURE 9A is a side cross-sectional view of a bag including a tamper-evident tape formed in accordance with a further aspect of the present invention
• FIGURE 9B is a side cross-sectional view of a bag with the tamper-evident tape sealing the bag closed;
• FIGURE 10 is a pictorial view of a roll of tamper-evident tape formed in accordance with the present invention.
• FIGURE 11 is a side view of a section of a roll of tamper-evident tape formed in accordance with the present invention.
• FIGURES 1A and IB illustrate a bag 10 that incorporates a seal 12 formed at the opening 14 of bag 10.
• the bag includes a front wall 16 and a back wall 18 that are joined together at the bottom and side edges to form an enclosure having opening 14 at the upper ends of front wall 16 and back wall 18.
• Seal 12 is included to close opening 14 and to provide visual evidence of any forced opening of seal 12.
• seal 12 will visually distort if the opening of the bag is cooled below a particular "breakdown temperature," e.g., by the application of a refrigerant.
• Seal 12 includes a plastic strip 20, a layer of ink 22, and a layer of adhesive 24.
• the bottom end of plastic strip 20 is attached to the inner surface of the upper end of front wall 16.
• Ink layer 22 is printed on the inner surface of plastic strip 20. While ink layer 22 is represented by a grid of lines in the figures, ink layer 22 is preferably a uniform layer of ink.
• adhesive layer 24 is preferably applied to the inner surface of the upper end of back wall 18. The free surface of adhesive layer 24 is covered with a peel-back strip 26. To seal the opening of the bag closed, peel-back strip 26 is removed from adhesive layer 24, and plastic strip 20 is pressed onto adhesive layer 24, which is a pressure sensitive adhesive. Thus, when seal 12 is closed, ink layer 22 is sandwiched between adhesive layer 24 and plastic strip 20.
• FIGURES 2A and 2B The location of the various layers of seal 12 can be seen more definitely in the side cross-sectional views in FIGURES 2A and 2B.
• Plastic strip 20 is attached at its lower end 28 to the inner surface of the upper end of front wall 16, and ink layer 22 is printed on the inner surface of plastic strip 20.
• Adhesive layer 24 is applied to the inner surface of the upper end of back wall 18, and the free surface of adhesive layer 24 is covered with peel-back strip 26.
• FIGURE 2B illustrates the alignment of seal 12 after peel-back strip 26 is removed and the seal is pressed closed. Plastic strip 20 is pressed onto adhesive layer 24 so that ink layer 22 adheres to adhesive layer 24.
• adhesive layer 24 preferably extends approximately an eighth of an inch below the bottom edge of plastic strip 20, so that when seal 12 is closed, a portion of adhesive layer 24 adheres directly to front wall 16. This helps prevent loose contents within the bag from partially opening seal 12 as the contents bump against the seal. Without a portion of adhesive layer 24 adhering to front wall 16, contents within the bag could falsely activate the tamper evidencing means of seal 12.
• back wall 18 includes a detachable identification tab 30 formed by perforating the upper end of back wall 18. As shown in FIGURES 1A and IB, the perforations allow identification tab 30 to be easily removed.
• identifying text or numbers are printed on identification tab 30 and matching identifying text or numbers are printed on either front wall 16 or back wall 18 of the bag. When the bag is sealed closed, identification tab 30 can be removed and used as a receipt .
• Plastic strip 20 is partially transparent so that ink layer 22 can be seen from the outer side of plastic strip 20 before seal 12 is closed, as shown in FIGURE 1A, and after seal 12 is closed, as shown in FIGURE 3, which is a front view of the bag with seal 12 closed.
• objects that are in direct contact with the inner surface of plastic strip 20 can be seen from the outer side of plastic strip 20.
• an object is positioned near the inner surface side of plastic strip 20, but not in direct contact with the inner surface of plastic strip 20, the object can barely be seen, if at all, from the outer side of plastic strip 20.
• ink layer 22 when ink layer 22 is printed on the inner surface of plastic strip 20, the ink can be seen from the outer surface of plastic strip 20, as shown in FIGURE 1A and FIGURE 3.
• FIGURE 4A if .seal 12 is forced open, a substantial portion of the ink remains adhered to adhesive layer 24 and accordingly delaminates from plastic strip 20. When this occurs, the ink is no longer visible from the outer side of plastic strip 20.
• the visual distortion of the ink is still visibly apparent, as illustrated in FIGURE 4B, because the ink does not re-adhere to plastic strip 20.
• the ink is printed onto plastic strip 20 while wet, i.e., in a liquid state. The ink then dries. Once dried, if the ink is delaminated from plastic strip 20, the ink no longer adheres to the inner surface of plastic strip 20. As a result, even when plastic strip 20 is re-pressed against adhesive layer 24, the ink remains sufficiently separated from plastic strip 20 so that the ink cannot be clearly seen through the outer side of plastic strip 20.
• portion 32 of seal 12 is forced open and then re-closed. As illustrated in FIGURE 4B, portion 32 that was forced open is visibly distorted, in sharp contrast to the portion 34 of seal 12 that was not opened.
• ink layer 22 In order for ink layer 22 to delaminate from plastic strip 20 when the seal is forced open, it is necessary that the bond between the ink and plastic strip 20 be relatively weak i.e., weak relative to the bond between adhesive layer 24 and ink layer 22. Because the bond between the ink and plastic strip 20 is relatively weak, if adhesive layer 24 merely adhered to ink layer 22, the overall strength of seal 12 would be relatively weak. Adhesive layer 24 would simply release from plastic strip 20 whenever ink layer 22 delaminated from plastic strip 20. This could cause the seal to inadvertently open during handling and shipping of the bag, which would be highly undesirable. To avoid this potential problem, ink layer 22 is sufficiently thin so that there are voids in ink layer 22.
• seal 12 when seal 12 is pressed closed, portions of adhesive layer 24 adhere to the inner surface of plastic strip 20 through the voids in the ink.
• the affinity between the adhesive and the plastic strip is sufficiently high so that the strength of seal 12 is acceptably strong.
• seal 12 generally does not open unless it is intentionally forced open by pulling plastic strip 20 away from back wall 18.
• seal 12 is sensitive to cooling so that if the seal is cooled below a particular "breakdown temperature," e.g., -10°F, the seal visibly distorts in a manner similar to when the seal is forced open.
• breakdown temperature e.g., -10°F
• ink layer 22 delaminates from plastic strip 20 so that the ink can no longer be clearly seen when viewing the outer side of plastic strip 20.
• the mechanism for the delamination of the ink is differential rates of shrinking of adhesive layer 24 and plastic strip 20.
• plastic strip 20 and adhesive layer 24 are chosen so that they shrink at different rates when cooled. In a preferred embodiment, the adhesive shrinks more and at a greater rate than plastic strip 20.
• ink layer 22 which is sandwiched between the plastic strip and the adhesive, is pulled away from the plastic strip. As a result, the ink is no longer clearly visible through the outer side of plastic strip 20.
• seal 12 provides visual evidence of cooling because a common technique used by thieves to gain access to plastic bags sealed with a pressure sensitive adhesive is to "freeze" the bag with a refrigerant, as previously described herein. Seals that combat this form of tampering have been introduced. However, as previously described herein, these prior art seals do not provide evidence of mere "freezing.” Rather, the prior art seals simply provide evidence of a forced opening of the bag, whether or not the bag is first "frozen.” In sharp contrast, seal 12 provided by the present invention provides a permanent visual indication if the seal is cooled below the breakdown temperature, regardless of whether or not the seal is actually forced open.
• seal 12 provided by the present invention cannot be opened without ink layer 22 visibly delaminating, whether or not the seal is first "frozen.” This is ensured by choosing a pressure sensitive adhesive for adhesive layer 24 that has a relatively low glass transition temperature. When a pressure sensitive adhesive is cooled to its glass transition temperature, the adhesive loses its adhesive properties, i.e., its adhesive tack. The adhesive is chosen so that its glass transition temperature is lower than the breakdown temperature of seal 12, at which temperature ink layer 22 delaminates from plastic strip 20. As a result, as the seal is progressively cooled, ink layer 22 at least partially delaminates from plastic strip 20 before the glass transition temperature of the pressure sensitive adhesive is reached.
• the ink delaminates before the seal is sufficiently “frozen” to allow the seal to be opened without any significant force. It is important that the breakdown temperature of seal 12 be greater, i.e., at a higher temperature, than the glass transition temperature of the pressure sensitive adhesive, to ensure that the seal cannot be opened without detection. If, in contrast, the glass transition temperature is above the seal's breakdown temperature, a refrigerant could be used to cool the seal to the adhesive's glass transition temperature, at which point the adhesive would lose its adhesive tack and release from the upper end of back wall 18 and/or ink layer 22 and plastic strip 20. The bag could then be opened, and then after warming to room temperature be reclosed. As long as the temperature of the bag is kept above the breakdown temperature, no visual indication of tampering would exist.
• Adhesive layer 24 and plastic strip 20 are also preferably chosen so that they expand at different relative rates when warmed, i.e., the plastic strip and adhesive layer have different thermal coefficients of expansion. In one preferred embodiment, the adhesive expands more and at a greater rate than plastic strip 20. As a result, if, after the seal is "frozen” below the breakdown temperature, a portion of ink layer 22 has not delaminated from plastic strip 20, the ink will further delaminate upon warming of seal 12. This further ensures that the delamination is sufficient to provide a significant visual indication of "freezing.”
• the embodiment of seal 12 shown in FIGURES 1 and 2 is one preferred embodiment of the invention.
• FIGURES 9A and 9B illustrate a second embodiment.
• the second embodiment includes many of the same component parts as the first preferred embodiment; accordingly, like components are referred to with the same reference numerals, except that the reference numerals are double primed.
• adhesive layer 24" is applied to the inner surface of ink layer 22" instead of to the inner surface of the back wall 18".
• the free surface of adhesive layer 24" is covered with peel-back strip 26".
• the other structural aspects of seal 12" are the same as seal 12 in FIGURES 1 and 2.
• peel-back strip 26" is removed and the free surface of adhesive layer 24" is pressed against the inner surface of back wall 18" . If the seal is forced open or "frozen,” ink layer 22" visually delaminates, as described with respect to the first embodiment shown in FIGURES 1 and 2.
• FIGURES 9A and 9B is an alternative embodiment
• the first embodiment shown in FIGURES 1 and 2 is preferred because adhesive 24 adheres more strongly to back wall 18 when applied hot, as described in more detail below, as opposed to adhesive layer 24" of the second embodiment that is pressed against back wall 18" to close seal 12".
• FIGURE 2A if front wall 16 is formed of the same material as plastic strip 30, front wall 16 can be extended to the same height as back wall 18. Plastic strip 30 would then be eliminated and ink layer 22 would be printed on the inner surface of the upper end of front wall 16.
• front wall 16 could be extended beyond the height of back wall 18, so that a fold-over closure flap is formed by the upper end of front wall 16.
• Adhesive layer 26 would then be applied to the outer surface of back wall 18, and the closure flap would be folded over the opening of the bag onto the adhesive on the outer surface of back wall 18.
• the seal provided by the present invention can be formed as a tape or label 40, as shown in FIGURES 10 and 11.
• the structure of tape 40 is essentially the same as the structure of seal 12" of the second embodiment shown in FIGURES 9A and 9B.
• Tape 40 includes a flexible, plastic backing 42, a layer of ink 44 printed on plastic backing 42, and a layer of adhesive 46 applied to the free surface of ink layer 44.
• Plastic backing 42 is analogous to plastic strip 20" in FIGURES 9A and 9B, and ink layer 44 is sandwiched between plastic backing 42 and adhesive layer 46.
• the free surface of adhesive layer 46 is covered with a peel-back strip 48.
• peel-back strip 48 is removed from a section of the tape then adhesive layer 48 is pressed onto the object to form a seal.
• ink layer 44 delaminates from plastic backing 42, to provide a visual indication of tampering.
• Roll of tape 40 can be used in various applications to form seals on surfaces of containers such as bags and envelopes.
• tape 40 could be used to seal an envelope.
• the tape could also be used to seal closed the opening of a bag as previously described herein.
• bag 10 shown in FIGURE 2A could be formed without seal 12, so that the bag simply consists of back wall 18 and front wall 16.
• Front wall 16 could be extended up beyond back wall 18, so that the upper end of front wall 16 forms a closure flap that can be folded over opening 14 onto the outer surface of back wall 18.
• the closure flap could then be secured onto back wall 18 with tape 40 by overlapping the tape over the closure flap and back wall 18.
• bag 10 shown in FIGURE 2A could be formed without seal 12 and then the upper portion of back wall 18 could be folded over the upper end of front wall 16 to contact the outer surface of front wall 16.
• the closure flap could then be secured onto front wall 16 with tape 40 by overlapping the tape over the closure flap and front wall 16.
• tape 40 can be printed on, for example, on plastic backing 42 to provide a label or other type of indicating means.
• the seal provided by the present invention is preferably constructed of relatively simple, inexpensive, and nonhazardous materials.
• the seal is preferably manufactured on a continuous line system, using conventional equipment including printers and handling machines.
• plastic strip 20 is preferably formed of a high density polyethylene or other polyolefin such as polypropylene.
• Plastic strips 20 are preferably formed of polyethylene, as opposed to some other plastic such as polyester, so that the strips can be easily recycled.
• plastic strip 20 is colored so as to contrast with the color of the ink of ink layer 22. For example, if the ink is blue, the plastic strip could be yellow.
• the plastic strip can be formed using an extrusion process as is commonly done in the plastics industry.
• polyethylene pellets are melted and then extruded.
• color pigment e.g., yellow pigment
• the polyethylene sheets are formed of a thickness of approximately 2.3 mils.
• the polyethylene sheets are cut into approximately 1.125 inch strips, and then cut to length, to form plastic strips 20.
• the ink of ink layer 22 is preferably a water-based ink that has a Ph of 7.5 to 8.2, such as Universal Reflex Blue sold by CPI Inks, Inc. However, other inks such as a solvent-based ink could be used.
• the ink is printed on the inner surface of plastic strip 20.
• the ink is preferably printed on the polyethylene sheets before the sheets are cut to form plastic strips 20.
• the pattern of ink does not have to be very exact; in fact, in one preferred embodiment the ink is printed as a uniform layer.
• inexpensive printing techniques can be used.
• a flexographic press that includes a photo polymer print roller can be used to print the ink even if a particular pattern is desired.
• the advantage of using a flexographic press is that the photo polymer roller for creating the print pattern is relatively inexpensive to manufacture.
• a rotogravure printer which includes steel printing plates and is much more expensive, has generally been used to hold more exact registration and produce more precise characters on the walls of plastic bags.
• the thickness of the ink layer is important.
• Ink layer 22 must be sufficiently thin so that there are microscopic voids in the ink through which adhesive layer 24 can migrate and therefore adhere to plastic strip 20. If ink layer 22 is too thick, adhesive layer 24 will not migrate through the ink layer and adhere to the inner surface of plastic strip 20. Instead, the adhesive layer will only adhere to ink layer 22, which would result in a seal that is too weak. It is also important that the ink have a relatively weak bond or adhesion to the inner surface of plastic strip 20, so that ink layer 22 delaminates from plastic strip 20 if the seal is forced open or "frozen.”
• the structure and manufacturing process of the seal embodiment shown in FIGURES 1 and 2 do not involve any pretreating, such as with a corona discharge or a silicon releasant, of the inner surface of plastic strip 20. That is, the ink is applied without any intervening adhesion promoting material or pretreating, and without any intervening adhesion suppression material . Accordingly, this embodiment of the seal is very inexpensive to manufacture.
• the inner surface of plastic strip 20 is not pretreated with a corona discharge process, because a relatively weak adhesion between the ink and plastic strip is desired.
• a water-based ink is preferably used, which has a relatively weak adhesion with polyethylene, no releasants such as silicone are required.
• ink layer 22 is preferably printed onto the inner surface of plastic strip 20 in a single coat, which involves printing wet ink onto plastic strip 20.
• the single coat of ink is uniform, i.e., a flood coat. While it is important that ink layer 22 is sufficiently thin so that there are voids in ink layer 22, there is a lower limit on how thin the ink should be. If ink layer 22 is extremely thin, there will not be a sufficient visual color contrast in the seal when ink layer 22 delaminates from plastic strip 20.
• an appropriate ink thickness is obtained by using a water-based ink that has a viscosity reading of 20 to 30 seconds with a # 3 Zahn cup, and printing the ink on plastic strip 20 with a flexographic printer. After the wet ink is printed o plastic strip 20, the ink is thoroughly dried, for example, by using heat guns.
• plastic strip 20 It is also possible to print a particular pattern of ink e.g., a grid pattern, onto plastic strip 20.
• a particular pattern of ink e.g., a grid pattern
• two coats of ink could be printed onto plastic strip 20.
• the first coat of ink would be a flood coat that is uniform, and the second coat of ink would be applied in a grid pattern over the flood coat.
• plastic strip 20 is preferably secured to the inner surface of front wall 16 by a heat seal, e.g., a running heat sealer, as is commonly done to seal together plastic materials such as polyethylene.
• plastic strip 20 can also be attached in other ways, e.g., using an adhesive or glue.
• Plastic strip 20 is preferably secured to the inner surface, as opposed to the outer surface, of front wall 16 so that it is relatively easy to visually detect any slits or cuts made near plastic strip 20. While it is certainly possible to adhere plastic strip 20 to the outer surface of front wall 16, if this done, a slit, e.g., made using a razor blade, could be made under plastic strip 20 where plastic strip 20 is sealed to front wall 16.
• front wall 16 and back wall 18 are preferably formed of a plastic material, such as polyethylene.
• a plastic material such as polyethylene.
• Common extrusion techniques can be used to form the back and front walls.
• the side edges of the back and front walls are preferably joined together by a heat seal.
• the bottom ends of the back and front walls are preferably formed of a single sheet of plastic that is folded to form the bottom end, as shown in FIGURE 2A.
• two separate sheets of plastic could be used to form the back and front walls, in which case, the bottom ends of the walls would be joined together with a heat seal. Because the walls of the bag and plastic strip 20 are all preferably formed of polyethylene, the bag is recyclable.
• adhesive layer 24 is applied to the inner surface of back wall 18, as shown in FIGURE 2A.
• the free surface of adhesive layer 24 is covered with peel-back strip 26.
• peel-back strip 26 is removed and the free surface of adhesive layer 24 is pressed against ink layer 22 as shown in FIGURES 2A and 2B.
• no intervening materials are applied to the inner surface of back wall 18 or the inner surface of ink layer 22.
• adhesive layer 24 is in direct contact with the inner surface of back wall 18 and the inner surface of ink layer 22, as shown in FIGURES 2B.
• adhesive layer 24 is formed of a pressure sensitive adhesive that is rubber-based, has a relatively high liquid tactifier content, and is applied as a hot melt using an extrusion process.
• the adhesive must have a low glass transition temperature and simultaneously a relatively high internal cohesive strength. As previously described, it is important that the adhesive have a glass transition temperature that is below the breakdown temperature of the seal.
• the adhesive has a glass transition temperature that is below -10°F. In addition to the requirement that the glass transition temperature be below -10°F, the adhesive preferably has the following characteristics: 180° peel strength of 7.9 lbs.
• the adhesive is clear so that ink layer 22 can be seen through back wall 18 and adhesive layer 24 when seal 12 is closed.
• the basic ingredients of the adhesive include a rubber base of synthetic block polymers with a liquid tactifier added to provide the specified viscosity.
• An adhesive having the preceding characteristics can be manufactured by various adhesive producers, including Swift Adhesives Co. and Eco elt, Inc.
• the adhesive is melted and extruded onto the inner surface of back wall 18.
• Peel-back strip 26 is then placed over the free surface of the adhesive.
• the peel-back strip is formed of high density polyethylene, and the surface of the peel-back strip that is in contact with the adhesive is coated with silicon so that the peel-back strip easily releases from the adhesive.
• the adhesive cools, a pressure sensitive adhesive is formed.
• tape 40 is formed of the same materials as in the same process as seal 12" shown in FIGURES 9A and 9B.
• FIGURES 6A-E illustrate an alternative ink composition/pattern and manufacturing process for plastic strips 20 and 20" shown in FIGURES 2A and 9A.
• a seal incorporating the plastic strip 20' shown in FIGURES 6A-E has the benefits of being more difficult to force open and providing a more visible indication of a forced opening than the previously described embodiments.
• the drawback of the embodiment shown in FIGURES 6A-E is that the resulting seal does not evidence refrigerant tampering as effectively as the previously described embodiments.
• the ink/plastic strip embodiment shown in the top views in FIGURES 6A-D and the side cross-sectional view in FIGURE 6E includes a plastic strip 20', a patterned layer of clear ink 60 (e.g., ink extender) , and a uniform layer of colored ink 62.
• Plastic strip 20' is preferably formed of a high density polyethylene, as previously described plastic strip 20.
• plastic strip 20' is colored, e.g., yellow.
• Patterned layer of clear ink 60 is printed, e.g., using a flexographic press, onto an untreated surface of plastic strip 20' .
• Clear ink 60 should have a weak affinity to untreated polyethylene and should be able to withstand a corona discharge process as described in the following.
• ink 60 is a water-based ink as previously described, except that ink 60 contains no pigment so that the ink is clear.
• colorless, water-based ink extender manufactured by CPI Inks, Inc. sold under the name Universal Flex Extender can be used.
• a solvent-based ink extender could also be used.
• Ink 60 is printed in a selected pattern, so that the majority of the surface of plastic strip 20' is free of clear ink 60.
• clear ink 60 is printed as a series of "stop signs. "
• the surface of plastic strip 20' on which clear ink 60 is applied is treated with a corona discharge process to roughen and increase the surface energy of plastic strip 20', as illustrated pictorially by line dashes 64.
• a corona discharge treater set to a strength of approximately 43 to 50 dynes is used.
• the corona discharge process is used so that colored ink 62 adheres well to plastic strip 20' .
• colored ink 62 is printed as a uniform layer over plastic strip 20', so as to cover the entire surface of plastic strip 20' .
• FIGURE 7 is a side cross-sectional view of a bag 10' incorporating plastic strip 20' to form a seal 12' .
• seal 12' is closed, colored ink layer 62 is sandwiched between adhesive layer 24 and plastic strip 20' .
• colored ink 62 forms a strong adhesion with those portions of plastic strip 20' not covered with clear ink 60.
• colored ink 62 will not delaminate from plastic strip 20', except along the pattern where clear ink 60 was applied, as shown in FIGURE 8B.
• Colored ink 62 does not delaminate from plastic strip 20' because colored ink 62 adheres more strongly to the treated portions of plastic strip 20' than to adhesive 24.
• clear ink 60 was applied to the untreated surface of plastic strip 20', clear ink 60 does not adhere very well to plastic strip 20' .
• colored ink 62 and clear ink 60 delaminate from plastic strip 20' along the pattern of clear ink 60 when an attempt is made to force the seal open.
• Colored ink 62 is chosen to have a color that contrasts with the color of plastic strip 20' .
• plastic strip 20' is yellow and colored ink 62 is blue.
• colored ink 62 is water-based, as is the case for previously described ink layer 22. Because the color of colored ink 62 contrasts with the color of plastic strip 20', the pattern in which clear ink 60 was applied boldly appears when an attempt is made to force open the seal . For example, as indicated in FIGURE 8A, when a portion 66 of seal 12' is forced open, the "stop sign" pattern appears, whereas an untampered portion 68 of seal 12' appears uniformly opaque.
• FIGURE 8B is an end cross-sectional view of portion 66 shown in FIGURE 8A.
• seal 12' illustrated in FIGURE 8 is much more difficult to open. After being closed, if seal 12' is quickly “frozen” with a refrigerant, some "stop signs" will appear as a result of clear ink 60 delaminating from plastic strip 20' due to the differential shrink rates between plastic strip 20' and adhesive 24' . However, because colored ink 62 adheres strongly to the majority of the surface of plastic strip 20', colored ink 62 provides structural support that prevents the differential shrink rates from delaminating clear ink 60 as readily as ink layer 22 in the previously described embodiments.
• seal 12' are the same as for previously described seal 12 and 12" shown in FIGURES 2A and 9A.
• both clear ink 60 and colored ink 62 are preferably water-based with a viscosity reading of 20 to 30 seconds with a #3 Zahn cup, and the inks are preferably applied using a flexographic printer.
• a bag closure that provides evidence of heat tampering is also provided.
• the bag closure is sensitive to being heated above a particular activation temperature, so that if heat is applied, the visual appearance of the closure permanently changes, regardless of whether the closure is opened.
• a "heat activatable, " or “thermochromic, " ink layer is used in the closure of the invention.
• heat activatable or “thermochromic” ink refers to inks which, upon the application of heat, exhibit a visible, permanent color change.
• thermochromic inks Any of the types of thermochromic inks known in the art can be used.
• a thermochromic ink which permanently visually changes when heated to a temperature of at least about 140°F, more preferably at least about 150°F, or higher.
• This activation temperature range is desirable because typically the adhesives described above for use with the closures of the invention soften sufficiently at a temperature between about 140°F and about 180°F to enable a person to open the closure.
• a particularly preferred ink is available from Midwest Coatings Inc. of St. Louis, Missouri, and is described in more detail below.
• the time required to effect the color change can vary as heating conditions vary, i.e., the activation temperature of the ink system used, the temperature applied to the seal, how long heat is applied, and the like.
• heating conditions vary, i.e., the activation temperature of the ink system used, the temperature applied to the seal, how long heat is applied, and the like.
• the visible color change can take place more slowly than when higher activating temperatures are used.
• thermochromic ink can be used in the tamper-evident closures of the invention in various ways.
• the thermochromic ink is applied to an outer surface of plastic strip 20, on a surface opposite ink layer 22.
• the plastic layer 20 is printed using standard techniques, as described above, for example, .using a flexographic press including a photo polymer roller printed.
• the thermochromic ink can be printed onto the outer surface of plastic strip 20 before or after the ink layer 22 is printed thereon.
• thermochromic ink layer can be applied as a substantially uniform coating on a surface of the plastic strip 20, or applied in a pattern, for example, so that upon activation, the ink forms a series of "stop signs.”
• the thermochromic ink is then dried using conventional equipment, such as heat guns. Of course, the thermochromic ink is dried at a temperature below its activation temperature.
• thermochromic ink When dry, the thermochromic ink is a specific color. However, when heated to its activation temperature, dye compounds in the thermochromic ink can undergo a chemical reaction. As the dye compounds react, the color of the dye compounds changes, which results in a change in the color of the ink. In the example given below, the thermochromic ink initially appears white, similar to a standard white ink which is not thermally activatable. Once activated, the thermochromic ink turns from white to a reddish-purple color. The present invention is not, however, limited to this particular color format. The thermochromic ink can provide a permanent visual indication if the seal is heated at or above the activation temperature, regardless of whether or not the seal is actually forced open.
• a standard, non-thermochromic ink such as a conventional alcohol based ink
• a layer of thermochromic ink is then applied in a pattern, such as the above-referenced series of "stop signs" over the layer of standard ink.
• the standard, non-thermochromic ink and the thermochromic ink are the same color initially, such as white. If the closure is subsequently heated, the thermochromic ink visibly changes so as to form a series of contrasting reddish "stop signs" against the standard ink layer.
• an industry standard water based clear overcoat layer is applied over at least a portion of the strip to protect the thermochromic ink from scuffing.
• the thermochromic ink layer is used in combination with seal 12, i.e., which includes an ink layer 22, and in which the plastic strip 20 and the adhesive layer 24 exhibit differential shrinking and expansion rates.
• seal 12 i.e., which includes an ink layer 22, and in which the plastic strip 20 and the adhesive layer 24 exhibit differential shrinking and expansion rates.
• the thermochromic ink layer can be used for security purposes with various other seals which include an adhesive bonding layer and a plastic strip as a support for the thermochromic ink layer which do not include ink layer 22.
• the thermochromic ink layer can be printed on either the inner or outer surface of a plastic strip. The free surface of the adhesive layer can be covered with a peel-back strip.
• thermochromic ink layer can be used without regard to specific differential shrinking rates of the plastic support strip and the adhesive layer upon cooling, or differential expansion rates thereof upon warming.
• thermochromic ink layer can also be provided as a component of a seal in the form of a tape or label 40, as shown in FIGURES 10 and 11.
• the structure of tape 40 which includes the thermochromic ink layer is essentially the same as described above.
• thermochromic ink formulation is as follows.
• Solution "A” is prepared as follows.
• a carrier for the dye compounds is prepared by mixing 85% water and 15% polyvinyl alcohol (PVOH) . This mixture can be strained, for example, using a 25 micron filter.
• a mixture is then prepared with the following: 60% PVOH; 39.6% of a conventional leuco dye (well known in the industry) ; 0.1% Nopko-W dispersing agent (industry standard) ; 0.1% Surfonol TG wetting agent (industry standard) ; and 0.2% defoamer (industry standard) .
• Solution “B” is then prepared by first formulating a carrier as described above including 85% water and 15% PVOH. A mixture is then prepared comprising: 60% PVOH; 39.6% bisphenol-A activator; 0.1% Nopko-W dispersing agent (industry standard) ; 0.1% Surfonol TG wetting agent (industry standard) ; and 0.2% defoamer (industry standard) . The final formulation is prepared by mixing 1 part Solution “A” to 4 parts Solution “B".
• the bisphenol A activator can initiate a chemical reaction within the structure of the leuco dye compound, thus altering its structure and producing a color change.
• This particular formulation has an activation temperature of about 155°F.
• the ink is initially white when dry and changes color to a bright red or reddish purple when heated to its activation temperature or higher to provide a permanent visible color change.
• thermochromic dye compounds and thermochromic dye compound activators other than leuco dyes and bisphenol A, respectively, can also be used in accordance with this aspect of the invention.
• polyvinyl alcohol is a preferred carrier because its use can provide a desired degree of flexibility to the ink layer, which is particularly advantageous in continuous in-line application to plastic substrates.
• other carriers can also be used.
• the particle size of the ink formulation is sufficiently small to provide smooth consistent application of the ink to a substrate surface. Further, it is preferred that the thermochromic ink formulation not be cut or mixed with other inks or solutions, and that the equipment used to produce the seals of the invention is clean.

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• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Physics & Mathematics (AREA)
• General Physics & Mathematics (AREA)
• Theoretical Computer Science (AREA)
• Bag Frames (AREA)
• Laminated Bodies (AREA)
• Closures For Containers (AREA)
• Orthopedics, Nursing, And Contraception (AREA)

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• 1995
  • 1995-08-02 NZ NZ291083A patent/NZ291083A/en not_active IP Right Cessation
  • 1995-08-02 WO PCT/US1995/009803 patent/WO1996004177A2/en active IP Right Grant
  • 1995-08-02 DE DE69513291T patent/DE69513291T2/de not_active Expired - Fee Related
  • 1995-08-02 AU AU32106/95A patent/AU697919B2/en not_active Ceased
  • 1995-08-02 CA CA002196606A patent/CA2196606C/en not_active Expired - Lifetime
  • 1995-08-02 EP EP95928278A patent/EP0773889B1/de not_active Expired - Lifetime

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