EP0721451A1 - Acylated sulphonamides as insecticides and acaricides - Google Patents
Acylated sulphonamides as insecticides and acaricidesInfo
- Publication number
- EP0721451A1 EP0721451A1 EP94928366A EP94928366A EP0721451A1 EP 0721451 A1 EP0721451 A1 EP 0721451A1 EP 94928366 A EP94928366 A EP 94928366A EP 94928366 A EP94928366 A EP 94928366A EP 0721451 A1 EP0721451 A1 EP 0721451A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- formula
- alkyl
- compound
- group
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
- C07D295/26—Sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C307/00—Amides of sulfuric acids, i.e. compounds having singly-bound oxygen atoms of sulfate groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C307/04—Diamides of sulfuric acids
- C07C307/06—Diamides of sulfuric acids having nitrogen atoms of the sulfamide groups bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/50—Compounds containing any of the groups, X being a hetero atom, Y being any atom
- C07C311/51—Y being a hydrogen or a carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Definitions
- haloalkyl - as a group per se and as a structural unit of other groups and compounds, such as haloalkoxy - are methyl mono- to tri-substituted by fluorine, chlorine and/or by bromine, such as CHF 2 , CF 3 or CH 2 C1; ethyl mono- to penta- substituted by fluorine, chlorine and/or by bromine, such as CH 2 CF 3 , CF 2 CF 3 , CF 2 CC1 3 , CF 2 CHC1 2 , CF 2 CHF 2 , CF 2 CFC1 2 , CH 2 CH 2 C1, CF 2 CHBr 2 , CF 2 CHC1F, CF 2 CHBrF or CC1FCHC1F; propyl or isopropyl mono- to hepta-substituted by fluorine, chlorine and/or by bromine, such as CH 2 CHBrCH 2 Br, CF 2 CHFCF 3 , CH 2
- X is fluorine
- Suitable inert solvents for the reaction of compounds IV with difluorocarbene or chloro- fluorocarbene are, for example, aromatic, aliphatic and alicyclic hydrocarbons and halogenated hydrocarbons, such as benzene, toluene, xylene, mesitylene, tetralin, chloro- benzene, dichlorobenzene, bromobenzene, petroleum ether, hexane, cyclohexane, dichloromethane, trichloromethane, tetrachloromethane, dichloroethane, trichloroethene or tetrachloroethene; esters, such as ethyl acetate; ethers, such as diethyl ether, dipropyl ether, diisopropyl ether, dibutyl ether, tert-butyl methyl ether, ethylene glycol monomethyl ether,
- halogen substituents can be introduced into the alkyl radical R.
- the invention relates to all those forms of the process according to which a compound obtainable as starting material or intermediate at any stage of the process is used as starting material and all or some of the remaining steps are carried out, or a starting material is used in the form of a derivative or a salt and/or its racemates or antipodes or, especially, is formed under the reaction conditions.
- Haematopinus spp. Linognathus spp., Pediculus spp., Pemphigus spp. and Phylloxera spp.; of the order Mallophaga, for example,
- Scirtothrips aurantii of the order Heteroptera, for example,
- Aspidiotus spp. Bemisia tabaci, Ceroplaster spp., Chrysomphalus aonidium,
- Erythroneura spp. Gascardia spp., Laodelphax spp., Lecanium corni, Lepidosaphes spp.,
- Macrosiphus spp. Myzus spp., Nephotettix spp., Nilaparvata spp., Paratoria spp.,
- Hoplocampa spp. Lasius spp., Monomorium pharaonis, Neodiprion spp., Solenopsis spp. and Vespa spp.; of the order Diptera, for example,
- the solid carriers used are normally natural mineral fillers such as calcite, talcum, kaolin, montmorillonite or attapulgite.
- Suitable granulated adsorptive carriers are porous types, such as pumice, broken brick, sepiolite or bentonite; and suitable nonsorbent carriers are calcite or sand.
- suitable nonsorbent carriers are calcite or sand.
- a great number of granulated materials of inorganic or organic nature can be used, especially dolomite or pulverised plant residues.
- Suitable soaps are the alkali metal salts, alkaline earth metal salts and unsubstituted or substituted ammonium salts of higher fatty acids (C 10 -C 22 ), e.g. the sodium or potassium salts of oleic or stearic acid or of natural fatty acid mixtures which can be obtained e.g. from coconut oil or tall oil; mention may also be made of fatty acid methyltaurin salts. More frequently, however, synthetic surfactants are used, especially fatty sulfonates, fatty sulfates, sulfonated benzimidazole derivatives or alkyl- arylsulfonates.
- compositions according to the invention are also suitable for protecting plant propagation material, e.g. seed material, such as fruit, tubers or grains, or plant cuttings, from animal pests.
- the propagation material can be treated with the formulation before planting: seed, for example, can be dressed before being sown.
- the compounds of the invention can also be applied to grains (coating), either by impregnating the grains with a liquid formulation or by coating them with a solid formulation.
- the formulation can also be applied to the planting site when the propagation material is being planted, for example to the seed furrow during sowing.
- the invention relates also to those methods of treating plant propagation material and to the plant propagation material thus treated.
- Example F2 Solutions a) b) c) d) compound No. 1.3 80 % 10 % 5 % 95 % ethylene glycol monomethyl ether 20 % - polyethylene glycol
- the active ingredient is dissolved in dichloromethane, the solution is sprayed onto the carrier mixture, and the solvent is evaporated off in vacuo.
- the active ingredient is mixed with the adjuvants, and the mixture is ground, moistened with water, extruded and granulated, and the granules are then dried in a stream of air.
- Example F9 Coated granules compound No. 1.9 3 % polyethylene glycol (mol. wt. 200) 3 % kaolin 94 %
- Example B l Action against Nilaparvata lugens
- No. 1.2 is more than 80 % effective.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH291293 | 1993-09-28 | ||
CH2912/93 | 1993-09-28 | ||
PCT/EP1994/003104 WO1995009151A1 (en) | 1993-09-28 | 1994-09-16 | Acylated sulphonamides as insecticides and acaricides |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0721451A1 true EP0721451A1 (en) | 1996-07-17 |
Family
ID=4244418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94928366A Withdrawn EP0721451A1 (en) | 1993-09-28 | 1994-09-16 | Acylated sulphonamides as insecticides and acaricides |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0721451A1 (tr) |
JP (1) | JPH09504508A (tr) |
AU (1) | AU7782694A (tr) |
IL (1) | IL110991A0 (tr) |
TR (1) | TR28509A (tr) |
WO (1) | WO1995009151A1 (tr) |
ZA (1) | ZA947518B (tr) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2426277C (en) * | 2000-10-18 | 2010-11-30 | Takeda Chemical Industries, Ltd. | Process for preparation of optically active sulfonamides and intermediates for their synthesis |
AR037097A1 (es) | 2001-10-05 | 2004-10-20 | Novartis Ag | Compuestos acilsulfonamidas, composiciones farmaceuticas y el uso de dichos compuestos para la preparacion de un medicamento |
WO2005110413A2 (en) | 2004-05-19 | 2005-11-24 | Solvay Pharmaceuticals Gmbh | Medicaments containing n-sulfamoyl-n'-arylpiperazines for the prophylaxis or treatment of obesity and related conditions |
EA200801432A1 (ru) * | 2005-12-01 | 2008-12-30 | Басф Се | Способ получения сульфонамидов |
TWI482771B (zh) * | 2009-05-04 | 2015-05-01 | Du Pont | 磺醯胺殺線蟲劑 |
WO2016069637A1 (en) * | 2014-10-28 | 2016-05-06 | The Regents Of The University Of California | Sulfonamides that activate aba receptors |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3740840A1 (de) * | 1987-11-27 | 1989-06-08 | Schering Ag | 2,2-difluorcyclopropylethanderivate, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
YU128891A (sh) * | 1990-07-27 | 1994-06-10 | Ciba Geigy Ag. | Derivati karboksimetilciklopropana |
-
1994
- 1994-09-16 WO PCT/EP1994/003104 patent/WO1995009151A1/en not_active Application Discontinuation
- 1994-09-16 JP JP7504777A patent/JPH09504508A/ja active Pending
- 1994-09-16 EP EP94928366A patent/EP0721451A1/en not_active Withdrawn
- 1994-09-16 AU AU77826/94A patent/AU7782694A/en not_active Abandoned
- 1994-09-18 IL IL11099194A patent/IL110991A0/xx unknown
- 1994-09-27 TR TR00978/94A patent/TR28509A/tr unknown
- 1994-09-27 ZA ZA947518A patent/ZA947518B/xx unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9509151A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO1995009151A1 (en) | 1995-04-06 |
TR28509A (tr) | 1996-09-02 |
ZA947518B (en) | 1995-03-28 |
AU7782694A (en) | 1995-04-18 |
JPH09504508A (ja) | 1997-05-06 |
IL110991A0 (en) | 1994-11-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19960212 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE ES FR GB GR IT LI NL PT |
|
17Q | First examination report despatched |
Effective date: 19970220 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: NOVARTIS AG |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19970903 |