EP0716675A1 - Rotary heating chamber for waste with internal tubing - Google Patents
Rotary heating chamber for waste with internal tubingInfo
- Publication number
- EP0716675A1 EP0716675A1 EP94924203A EP94924203A EP0716675A1 EP 0716675 A1 EP0716675 A1 EP 0716675A1 EP 94924203 A EP94924203 A EP 94924203A EP 94924203 A EP94924203 A EP 94924203A EP 0716675 A1 EP0716675 A1 EP 0716675A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- support
- heating chamber
- chamber according
- heating
- ivb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000010438 heat treatment Methods 0.000 title claims abstract description 71
- 239000002699 waste material Substances 0.000 title claims abstract description 24
- 239000011343 solid material Substances 0.000 claims abstract description 8
- 241001104043 Syringa Species 0.000 claims description 3
- 235000004338 Syringa vulgaris Nutrition 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 238000003763 carbonization Methods 0.000 abstract description 15
- 238000007665 sagging Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 15
- 238000000197 pyrolysis Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000284 resting effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000246 remedial effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
- C10B47/28—Other processes
- C10B47/30—Other processes in rotary ovens or retorts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2205/00—Waste feed arrangements
- F23G2205/12—Waste feed arrangements using conveyors
- F23G2205/121—Screw conveyor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2900/00—Special features of, or arrangements for incinerators
- F23G2900/50201—Waste pyrolysis, gasification or cracking by indirect heat transfer
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2900/00—Special features of, or arrangements for incinerators
- F23G2900/52001—Rotary drums with co-current flows of waste and gas
Definitions
- the invention relates to a heating chamber for solid material which can be rotated about its longitudinal direction, in particular to a smoldering drum for waste, with a number of heating pipes located in the interior, each with one end on a first end plate and the other end on one second end plate are attached.
- the heating chamber is used in particular as a smoldering drum for waste for the purpose of thermal waste disposal, preferably according to the smoldering-burning method.
- the so-called smoldering-burning method has become known in the field of waste disposal.
- the method and a plant for thermal waste disposal operating according to it are described, for example, in EP-A-0 302 310.
- the essential components of the plant for thermal waste disposal using the smoldering process include a smoldering chamber (pyrolysis reactor) and a high-temperature combustion chamber.
- the smoldering chamber converts the waste fed in via a waste transport device into smoldering gases and pyrolysis residues.
- the carbonization gases and the pyrolysis residues are then fed to the burner of the high-temperature combustion chamber after suitable processing.
- Molten slag is produced in the high-temperature combustion chamber, which is removed via a fume hood and which, after cooling, is in a glass-like form.
- the resulting flue gas is fed to a chimney as an outlet via a flue gas line.
- a waste heat generator as a cooling device
- a dust filter system as a cooling device
- a flue gas cleaning system are installed.
- a rotating, relatively long smoldering drum is generally used, which has a large number of parallel heating pipes on the inside, on which the waste is largely heated in the absence of air.
- the smoldering drum rotates about its longitudinal axis.
- the longitudinal axis is preferably slightly inclined with respect to the horizontal, so that the solid carbonization material collects at the outlet of the carbonization drum and can be discharged from there via a discharge pipe.
- the waste is lifted up through the heating pipes and falls down again.
- the transport of the solid material dust, lumps of carbon (coke), stones, bottles, metal, ceramic parts, etc.
- the smoldering drum should be built relatively long. This means that the heating pipes lying in the interior must also have a corresponding length. Depending on the material of these heating tubes and their length, it can now occur that they sag in the interior, unless remedial action is taken. During the rotary movement of the smoldering drum, this leads to alternating loads, so that there can be a risk that the heating pipes will be torn out of their end holder. Such a danger can exist in particular in the case of heating pipes which are 20 to 30 meters long or even more.
- the invention is based on the consideration that at least one simple support point, but preferably at least two support points in the interior, should be provided for supporting the heating pipes.
- a support point is in the form of a bracket or
- the object of the invention is therefore to design a heating chamber for solid material of the type mentioned that can be rotated about its longitudinal direction in such a way that the heating pipes are supported without significantly impairing the passage of the solid material and the carbonization gases.
- each support point is subdivided into p> 2 spaced partial supports, each with a console arrangement, each console arrangement comprising a plurality of support consoles lying in the same plane.
- Figure 1 shows a smoldering plant with a smoldering chamber for waste, which can be used in the smoldering process, in a basic sectional representation
- FIG. 3 shows a view of the console arrangement I of FIG. 2;
- FIG. 4 shows a view of the console arrangement II from FIG. 2;
- FIG. 5 is a view of the console arrangement III of Figure 2;
- Figure 9 shows a heating tube attachment in a support bracket.
- solid waste A is introduced centrally into a pyrolysis reactor or a smoldering chamber 8 via a feed or feed device 2 and a screw 4, which is driven by a motor 6 and is arranged in a feed tube 7.
- the smoldering chamber 8 is an internally heatable smoldering or pyrolysis drum which can be rotated about its longitudinal axis 10 and which can have a length of 15 to 30 m, which operates at 300 to 600 ° C., which is operated largely with the exclusion of oxygen and which, in addition to volatile smoldering gas s produces a largely solid pyrolysis residue.
- a multiplicity for example 50 to 200
- heating tubes 12 aligned parallel to one another, of which only four are shown in FIG. 1 and are arranged in the interior 13.
- Outlet chamber 16 arranged.
- the longitudinal axis 10 of the smoldering drum 8 is preferably inclined with respect to the horizontal, so that the outlet at the "hot" end on the right is lower than the inlet for waste A shown on the left.
- a discharge device 18 is connected downstream of the pyrolysis drum 8 on the output or discharge side via a rotating central discharge tube 17, said discharge device being provided with a carbonization gas discharge nozzle 20 for the discharge of the carbonization gas and with a pyrolysis residue outlet 22 for the discharge of the solid pyrolyzation residue f is provided.
- a carbonization line connected to the carbonization gas outlet 20 can be connected to the burner of a high-temperature combustion chamber.
- the rotary movement of the smoldering drum 8 about its longitudinal axis 10 is brought about by a drive 24 in the form of a gear which is connected to a motor 26.
- the drive means 24, 26 work, for example, on a toothed ring which is connected to the catch the smoldering drum 8 is attached.
- the bearings of the smoldering drum 8 are designated 27.
- the heating tubes 12 are each fixed at one end to a first end plate 28 and at the other end to a second end plate 30.
- the attachment to the end plates 28, 30 is such that there is preferably an easy interchangeability of the heating tubes 12.
- the end of the heating pipes 12 projects through an opening from the interior 13 to the left into the outlet chamber 16 or to the right into the inlet chamber 14.
- the axis of the heating tubes 12 is oriented perpendicular to the surface of the end plates 28, 30.
- the individual heating tubes 12 are subjected to high thermal and mechanical stresses, and that the end plates 28, 30, which could also be referred to as tube plates or drum tube sheets, rotate along the longitudinal axis 10 of the carbonization drum 8.
- the first support point X is one third (1/3 1) and the second support point Y is two thirds (2/3 1) of the total length 1 of
- Each of the console arrangements I, II, III (compare FIGS. 3 to 5) contains a plurality of support or support consoles located in the same plane in the form of rounded perforated plates made of metal, for example made of steel. These are designated in FIGS. 3 to 5 with the reference symbols la, Ib, Ic, Id and Ha, Ilb, IIc, Ild and purple, Illb, IIIc and Illd.
- the second bracket arrangement II according to FIG. 4 has the support brackets Ha, Ilb, IIc and Ild which are rotatably offset in the same plane.
- two opposite support brackets Ha, IIc and Ilb, Ild each have the same rounded configuration.
- the third bracket arrangement III comprises the four support brackets lilac, Illb, IIIc and Illd lying in one plane, rotatably offset from one another and spaced apart.
- the two support brackets purple, IIIc and Illb, Illd respectively, which are fastened opposite each other on the inner wall 33, are designed in the same way.
- Support brackets la to Id of Figure 3 is offset from the plane of the support brackets Ha to Ild of Figure 4 by the distance a in the longitudinal direction. The same applies to the level of the support brackets purple to Illd according to Figure 5; here too the distance is again a.
- the heating tubes 12 can be arranged in a configuration as shown in FIG. 2 and in FIGS. 3 to 5. Then there are a plurality of peripherally arranged heating tubes 12 and a plurality of heating tubes 12 arranged approximately radially (along curved lines) for heating the more centrally located waste. The curvature depends on the rotation of the smoldering drum 8, which is indicated by an arrow 35.
- Each console arrangement I, II and III in turn comprises four support consoles la to Id, Ha to Ild and lilac to Illd, respectively, lying in the same plane.
- a different configuration of the heating tubes 12 is selected than in Figure 2.
- the view VV (see FIG. 1) again shows the arrangement of all ⁇ cher heating tubes 12 and support brackets la to Illd, which are each assigned to groups of these heating tubes 12.
- Support brackets that are adjacent in the circumferential direction also have a different outer circumference here.
- the support brackets la to Illd are square here. It is noteworthy that - seen in the direction of rotation of arrow 35 - the support bracket la is followed by the purple support bracket and this is followed by the support bracket Ha. This means that between the two console arrangements I and II waste A has a considerable amount of free space for passage. Here, too, it becomes clear that the area projected according to the viewing direction V-V on each partial support has lost relatively little of its transport performance by introducing the individual support brackets Ia to Illd.
- each support point X and Y is staggered.
- each support point X, Y has a group of three console arrangements I, II, III. This staggering keeps the resistance, which opposes the transport of the waste in the heating drum 12, within reasonable limits.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Processing Of Solid Wastes (AREA)
- Gasification And Melting Of Waste (AREA)
- Muffle Furnaces And Rotary Kilns (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Incineration Of Waste (AREA)
- Drying Of Solid Materials (AREA)
- Details Of Heat-Exchange And Heat-Transfer (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Coke Industry (AREA)
- Refuse Collection And Transfer (AREA)
- Crushing And Pulverization Processes (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4329871 | 1993-09-03 | ||
DE4329871A DE4329871A1 (en) | 1993-09-03 | 1993-09-03 | Pipe-rotatable heating chamber for waste |
PCT/DE1994/000974 WO1995006697A1 (en) | 1993-09-03 | 1994-08-23 | Rotary heating chamber for waste with internal tubing |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0716675A1 true EP0716675A1 (en) | 1996-06-19 |
EP0716675B1 EP0716675B1 (en) | 1999-06-09 |
Family
ID=6496812
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94924203A Expired - Lifetime EP0716675B1 (en) | 1993-09-03 | 1994-08-23 | Rotary heating chamber for waste with internal tubing |
Country Status (16)
Country | Link |
---|---|
US (1) | US5688117A (en) |
EP (1) | EP0716675B1 (en) |
JP (1) | JP2813065B2 (en) |
KR (1) | KR100304304B1 (en) |
CN (1) | CN1053000C (en) |
AT (1) | ATE181100T1 (en) |
CA (1) | CA2170904A1 (en) |
CZ (1) | CZ283714B6 (en) |
DE (2) | DE4329871A1 (en) |
DK (1) | DK0716675T3 (en) |
ES (1) | ES2133568T3 (en) |
HU (1) | HU218441B (en) |
PL (1) | PL313145A1 (en) |
RU (1) | RU2103316C1 (en) |
SK (1) | SK282115B6 (en) |
WO (1) | WO1995006697A1 (en) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040208875A1 (en) * | 1995-03-15 | 2004-10-21 | Queen's University At Kingston | Method for treating amyloidosis |
DE4429908A1 (en) * | 1994-08-23 | 1996-02-29 | Siemens Ag | Heating chamber for solid goods equipped with heating pipes |
US5997288A (en) * | 1997-04-18 | 1999-12-07 | Robert J. Adams | Apparatus for thermal removal of surface and inherent moisture and limiting rehydration in high moisture coals |
DE19726150C1 (en) * | 1997-06-19 | 1998-11-05 | Siemens Ag | Rotary waste pyrolysis drum |
SG68092A1 (en) | 1998-02-20 | 1999-10-19 | Meidensha Electric Mfg Co Ltd | Process and system for treating material containing noxious components |
US20020077278A1 (en) * | 2000-06-05 | 2002-06-20 | Yong V. Wee | Use of glatiramer acetate (copolymer 1) in the treatment of central nervous system disorders |
LV14040B (en) * | 2009-09-18 | 2009-12-20 | Intec Group, Sia | Reactor for pyrolysis of biomass |
CN102274845B (en) * | 2010-06-12 | 2015-03-18 | 上海中科岸达节能产品科技有限公司 | Municipal refuse low-temperature oxygen-free carbonization system equipment and low-temperature oxygen-free carbonization revolving furnace therefor |
CN101985558B (en) * | 2010-08-19 | 2012-01-04 | 西峡龙成特种材料有限公司 | Coal decomposing equipment |
CN103697732B (en) * | 2013-12-25 | 2015-10-28 | 南宁广发重工集团有限公司 | A kind of planetary cooler cooling cylinder |
CN104017592A (en) * | 2014-05-27 | 2014-09-03 | 中国重型机械研究院股份公司 | Multitube heating rotary pulverized coal pyrolysis system |
CN104910939A (en) * | 2015-05-24 | 2015-09-16 | 三门峡化工机械有限公司 | Internal heat rotary kiln coal dry distillation device |
CN107202325B (en) * | 2016-03-16 | 2020-10-27 | 浙江金锅环保科技有限公司 | Rotary controllable pyrolysis carbonization kiln |
CN106285809A (en) * | 2016-09-12 | 2017-01-04 | 新疆广汇中化能源技术开发有限公司 | Rotatable radiation bed system |
CN106281382A (en) * | 2016-09-12 | 2017-01-04 | 新疆广汇中化能源技术开发有限公司 | Rotatable radiation bed |
CN106281381A (en) * | 2016-09-12 | 2017-01-04 | 新疆广汇中化能源技术开发有限公司 | Rotatable radiation bed |
CN113801671A (en) * | 2016-12-12 | 2021-12-17 | 朱书红 | Material heating device |
CN107033963A (en) * | 2017-05-31 | 2017-08-11 | 河南龙成煤高效技术应用有限公司 | A kind of pyrolytic process of coal device |
KR101828844B1 (en) | 2017-07-12 | 2018-02-13 | (주)에스제이인더스트리 | Carbonized fuel manufacturing system |
CN111763523A (en) * | 2020-06-09 | 2020-10-13 | 华中科技大学 | Rotary continuous pyrolysis reaction furnace and pyrolysis method for molten salt heat exchange |
CN113172079A (en) * | 2021-05-08 | 2021-07-27 | 南开大学 | Urban and rural organic solid waste rapid heat treatment device and application |
CN114166019A (en) * | 2021-11-10 | 2022-03-11 | 湖南德景源科技有限公司 | Powder material sintering furnace |
CN115628607A (en) * | 2022-10-18 | 2023-01-20 | 攀钢集团钛业有限责任公司 | Indirect heat exchange device for drying wet 20-titanium concentrate |
CN116768508B (en) * | 2023-05-18 | 2024-01-02 | 宿迁德威新材料有限公司 | Raw material preheating device for silicate cement wallboard production |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1108715B (en) * | 1959-09-10 | 1961-06-15 | Basf Ag | Pipe support for pipe bundles of heat exchangers |
DE3412583A1 (en) * | 1984-04-04 | 1985-10-24 | KPA Kiener Pyrolyse Gesellschaft für thermische Abfallverwertung mbH, 7000 Stuttgart | SMOKE DRUM FOR SUSPENSIONING WASTE |
JPS6159197A (en) * | 1984-08-30 | 1986-03-26 | Ishikawajima Harima Heavy Ind Co Ltd | Pipe bundle section support structure of heat exchanger |
DE3702318C1 (en) * | 1987-01-27 | 1988-01-28 | Gutehoffnungshuette Man | Rotary drum for the carbonisation of wastes with exclusion of air |
US4734166A (en) * | 1987-02-05 | 1988-03-29 | Angelo Ii James F | Furnace for the selective incineration or carbonization of waste materials |
DE3811820A1 (en) * | 1987-08-03 | 1989-02-16 | Siemens Ag | METHOD AND SYSTEM FOR THERMAL WASTE DISPOSAL |
US4881947A (en) * | 1988-06-28 | 1989-11-21 | Parker Thomas H | High efficiency gasifier with recycle system |
US5078836A (en) * | 1989-07-21 | 1992-01-07 | Hogan Jim S | Method and apparatus for retorting material |
US5082534A (en) * | 1990-03-14 | 1992-01-21 | Wayne Technology, Inc. | Pyrolytic conversion system |
ATE157695T1 (en) * | 1992-04-13 | 1997-09-15 | Siemens Ag | SWEET DEVICE |
-
1993
- 1993-09-03 DE DE4329871A patent/DE4329871A1/en not_active Withdrawn
-
1994
- 1994-08-23 DK DK94924203T patent/DK0716675T3/en active
- 1994-08-23 ES ES94924203T patent/ES2133568T3/en not_active Expired - Lifetime
- 1994-08-23 JP JP7507865A patent/JP2813065B2/en not_active Expired - Fee Related
- 1994-08-23 KR KR1019960701065A patent/KR100304304B1/en not_active IP Right Cessation
- 1994-08-23 PL PL94313145A patent/PL313145A1/en unknown
- 1994-08-23 SK SK278-96A patent/SK282115B6/en unknown
- 1994-08-23 AT AT94924203T patent/ATE181100T1/en not_active IP Right Cessation
- 1994-08-23 CA CA002170904A patent/CA2170904A1/en not_active Abandoned
- 1994-08-23 DE DE59408396T patent/DE59408396D1/en not_active Expired - Fee Related
- 1994-08-23 WO PCT/DE1994/000974 patent/WO1995006697A1/en active IP Right Grant
- 1994-08-23 EP EP94924203A patent/EP0716675B1/en not_active Expired - Lifetime
- 1994-08-23 RU RU96107101/25A patent/RU2103316C1/en not_active IP Right Cessation
- 1994-08-23 CZ CZ96533A patent/CZ283714B6/en not_active IP Right Cessation
- 1994-08-23 CN CN94193275A patent/CN1053000C/en not_active Expired - Fee Related
- 1994-08-23 HU HU9600525A patent/HU218441B/en not_active IP Right Cessation
-
1996
- 1996-03-04 US US08/606,482 patent/US5688117A/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO9506697A1 * |
Also Published As
Publication number | Publication date |
---|---|
CZ283714B6 (en) | 1998-06-17 |
CZ53396A3 (en) | 1996-06-12 |
ATE181100T1 (en) | 1999-06-15 |
KR960704996A (en) | 1996-10-09 |
CN1053000C (en) | 2000-05-31 |
KR100304304B1 (en) | 2001-11-22 |
RU2103316C1 (en) | 1998-01-27 |
EP0716675B1 (en) | 1999-06-09 |
HU9600525D0 (en) | 1996-04-29 |
HU218441B (en) | 2000-08-28 |
DE59408396D1 (en) | 1999-07-15 |
WO1995006697A1 (en) | 1995-03-09 |
ES2133568T3 (en) | 1999-09-16 |
JPH08510789A (en) | 1996-11-12 |
DK0716675T3 (en) | 2000-01-17 |
CN1130393A (en) | 1996-09-04 |
DE4329871A1 (en) | 1995-03-09 |
CA2170904A1 (en) | 1995-03-09 |
JP2813065B2 (en) | 1998-10-22 |
US5688117A (en) | 1997-11-18 |
HUT72952A (en) | 1996-06-28 |
PL313145A1 (en) | 1996-06-10 |
SK282115B6 (en) | 2001-11-06 |
SK27896A3 (en) | 1997-06-04 |
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Legal Events
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