Classifications

• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
  • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
  • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
  • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
  • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
  • D04H1/4326—Condensation or reaction polymers
  • D04H1/435—Polyesters
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
  • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
  • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
  • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
  • D04H1/43835—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
  • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
  • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
  • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
  • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
  • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
  • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
  • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
  • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
  • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
  • D04H1/43825—Composite fibres
  • D04H1/43828—Composite fibres sheath-core
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
  • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
  • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
  • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
  • D04H1/43825—Composite fibres
  • D04H1/43832—Composite fibres side-by-side

Definitions

• This invention is concerned with improvements in and relating to bonded polyester fiberfill batts, sometimes referred to as battings, especially such improved batts with desirable aesthetic and serviceable qualities, and to articles incorporating such improved batts.
• a process for preparing a bonded batt comprising forming a blend of polyester fiberfill, in amount by weight about 70 to about 96%, intimately mixed with a binder fiber, preferably a bicomponent binder fiber, having binder material of melting point lower than the softening point of the polyester fiberfill, in amount by weight about 4 to about 30%, preparing a continuous batt from said blend, said batt having an upper face and a lower face, advancing said batt through one or more spray zones, whereby both faces of the batt are sprayed with resin, in total amount about 10 to about 30% of the weight of the sprayed batt, including the resin, said resin being selected to provide, after curing, a cured resin having a glass transition temperature (Tg) of about 0 degrees Celsius or less, heating the sprayed batt in an oven to cure the resin and soften the binder material,
• Tg glass transition temperature
• a bonded batt with upper and lower faces, said batt comprising polyester fiberfill of denier per filament greater than 0.2 and not more than 1, in amount about 75 to about 96%, and bonded throughout with lower melting binder material, complementally in amount about 4 to 25%, said amounts being calculated on the basis weight of the batt, said batt having a wash durability (WD, as defined) of at least 4, and a bending stiffness (B, as defined) of about 40 cN/cm 2 or less, wherein at least one of said faces is sealed with a resin having a glass transition temperature (Tg) of about 0 deg Celsius or less, in amount about 0.02 to about 0.35 oz/yd 2 (0.7 to 12 g/m 2 ), preferably about 0.1 to about 0.25 oz/yd 2 (3.4 to 8.5 g/m 2 ), calculated with regard to said face of the batt, whereby the sealing rating (SR, as defined) of said face is at least 4, said bonded batt having been prepared without the
• metric units such as dtex, and denier are used herein, 1 dtex being the same as 0.9 denier per filament (dpf).
• the present invention provides fiberfill batts, such as are needed for use in premium apparel, by first preparing a homogeneous blend of polyester fiberfill (75-96% by weight of the blend) and a suitable binder fiber (4-25% by weight of the blend). This blend is converted on a card or garnet to a web which may then be layered or cross lapped to form a batting to whose upper (and preferably serially also to whose lower) face is applied a suitable latex (e.g., a colloidal dispersion of acrylic polymers and/or copolymers in water, discussed in more detail hereinafter), e.g., by spraying.
• a suitable latex e.g., a colloidal dispersion of acrylic polymers and/or copolymers in water, discussed in more detail hereinafter
• the sprayed batting is heated, e.g., conveniently by being passed through a heated oven to dry the coating(s) and to polymerize the polymeric component(s) to high molecular weight, and to activate the binder fiber. This may be conveniently done, for example, in three passes through such an oven, two to serially dry and partially cure each such coating, after it has been applied to any face, and a final pass to supplement the other(s).
• the resins that may be used herein are termed variously, by different manufacturers, as “soft” or “medium”, or even “very soft”, but are characterized by having second order glass transition temperatures (Tg) of about 0 C or less. They provide both softness and drapability to the batt when used in, e.g., apparel, while acting as barrier to fiber leakage from the batt.
• the final batts may have a basis weight of 1.5 to 12 oz/yd 2 (50 to 400 g/m 2 ) and a thickness of 0.07 to 0.20 inch/oz/yd 2 (0.05 to 0.15 mm/g/m 2 ).
• the batts of this invention are prepared from a blend of polyester fiberfill and binder fibers, and the fibers in the face(s) are sealed by a suitably soft-type resin coating.
• the polyester fiberfill may all be slickened, e.g., as described herein, or may be a blend of slickened and unslickened fibers.
• the fiberfill may be solid, hollow, or a blend of solid and hollow fibers and is not limited to any type of fiber cross section, i.e., it may be of cruciform, trilobal, Y-shaped, dog bone, scalloped oval, and other non-circular cross sections as well as round.
• the fiberfill has a denier per filament (dpf) within the range of 0.2 to 10, with a dpf of about 1.65 being very useful, and constitutes about 70 to 96% by weight of the blend.
• dpf denier per filament
• subdenier fibers give good sealing in the face(s) of the bonded batt, so are often preferred in such face(s).
• the individual fibers are provided with crimp by conventional means and typically exhibit from 5 to 15 crimps per inch (cpi) and have a length within the range of 3/4 to 3 inches.
• the binder fibers constitute from about 4 to 30% by weight of the batt and may be of the sheath/core (s/c), side/side (s/s), or monocomponent types.
• binder fibers are described in, e.g., "Nonwovens World", March/April, 1990, page 37.
• the initial dpf of suitable binder fibers in the blend is typically within the range of 2 to 15 with a dpf of 4 being commonly used.
• Useful binder fibers include those disclosed in the aforementioned U. S. Patents to Scott, Pamm, Frankosky, and Marcus, together with those shown in Harris et al U. S. Patent No. 4,732,809; Taniguchi et al U. S.
• Preferred binder fibers include the commercially-available "Melty 4080" (Unitika Co., Japan) and the “ES” and “EA" polyolefins (Chisso Corporation, Japan).
• the cured resin coatings on both faces of the batt may conveniently constitute about 10 to 30% by weight of the final bonded batt, with 12 to 25% being preferred for 1.65 dpf (1.83 dtex), where lesser amounts of resin tend to reduce wash durability and sealing rating while greater amounts tend to increase stiffness and reduce insulating efficiency. If only one face of the batt is so sealed, only half as much resin need be applied. When low fiber deniers (about 1 dpf or less) are used, less resin coating is needed to achieve fiber leakage control. Moreover, the amount of resin in the surface(s) need not depend on the basis weight of the batting, and so, for heavier battings, the total resin add-on may be as little as 3%, even for slickened fiberfill batts. For entirely dry (unslickened) fibers, less resin is needed than when slickened fiberfill is used.
• a suitable resin for coating has a Tg of about 0 C or less.
• the useful resins are obtained from commercially-available acrylic and vinyl latex compositions among which are included, e.g., Rhoplex E-32 (Rohm and Haas Co.), TR-934 (Rohm and Haas Co.), X-4280J (Kanebo, Japan), these Hycar® latex compositions of B. F.
• Preparation of the batts is generally begun by conventional opening and blending of the polyester fiberfill and binder fiber, followed by carding or garnetting to make a web.
• This web can be layered with other webs from a train of cards or garnets, or it can be cross lapped and combined with other webs to form an unbonded batting.
• This batting is then sprayed with the latex composition on one or both sides of the batting and is fed to the oven for curing of the resin and bonding of the binder fibers.
• the oven treatment is conducted at 150-190 C for 2 to 5 minutes, and may be conveniently done in three passes of the batt, as previously noted.
• the batts exhibit the basis weight and thickness ranges previously indicated.
• the batts of this invention exhibit desirable levels of thermal resistance or insulation, commonly reported as CLO ratings (see Hwang U.S. Patent No. 4,514,455). Batts of this invention desirably exhibit a CLO value of at least about 0.36 CLO/oz/yd 2 (0.01 CLO/g/m 2 ) and preferably 0.48 CLO/oz/yd 2 (0.014 CLO/g/m 2 ) or higher.
• the components and processes described herein should be selected to provide the batts of this invention. Care must be taken to select combinations that do so provide.
• the slickener on the fiber and the latex applied to the batt should be selected so as to adhere sufficiently, so that the final batt may exhibit, for example, sufficient wash durability.
• Wash durability of the batts of this invention is evaluated by the procedures of ASTM D-4770-88. In the Examples, the panels were 24 inches x 24 inches in size. Durability ratings are reported for measurements made according to paragraph 8.6.1. Batts of the invention exhibit a rating of 3 or higher (paragraph 8.5 scale).
• Fiber leakage or percolation through shell fabric is measured as a sealing rating ("SR") by the method described in LeVan U. S. Patent No. 4,869,771 (after 3 wash cycles), a sealing rating (SR) of 5 being excellent and a sealing rating (SR) of 1 being poor.
• the batts of this invention exhibit a sealing rating (SR) of 3 or higher (after 3 wash cycles).
• SR sealing rating
• Table 2 Example 3
• sealing values are additionally reported after one wash (1W) as well as after 3 washes (3W) and compared with initial values before any washing (NEW).
• the batts of this invention exhibit a bending stiffness ("B" being the sum of values determined for MD and XD samples from the batt) of 80 cN/cm. 2 or less, a lower bending stiffness being preferred.
• BW Basis Weight, i.e., to the amount of polyester filberfill and binder fiber only, (i.e., without the added resin sprayed onto the faces to improve the sealing).
• Samples A, B, C and D were prepared from a commercially-available blend of polyester fibers consisting of 37.5% of slickened 1.65 dpf (finished with a silicone slickener), 37.5% of dry 1.65 dpf (without any silicone slickener), and 25% binder fiber.
• the blend was processed on conventional card and cross-lapper equipment similar to the equipment as described in Example 1 of U.S. Patent No. 5,225,242.
• the resulting battings were fed through a triple-pass oven maintained at about 165 C.
• the battings (except for A) were sprayed with equivalent amounts of a soft resin (glass transition temperature (Tg) equals -10 deg C) on each side such that the total resin add-on was as stated in the Table, based on "BW", the basis weight of the fiber in the batting at this stage which was about 4.5 oz/yd 2 (150 g/m 2 ).
• Tg glass transition temperature
• BW basis weight of the fiber in the batting at this stage which was about 4.5 oz/yd 2 (150 g/m 2 ).
• One side of the batting was sprayed with resin before entering the first pass and the other side was sprayed before entering the second pass.
• the entire batting was exposed to adequate time at a temperature sufficiently high to assure complete cure of the resin and set of the binder fiber (1 minute after the batt has reached 165 C has generally been sufficient).
• the battings were then calendered in a separate operation which served to seal the surfaces and reduce loft.
• the battings were also tested for fiber leakage by encasing in a fabric with a yarn count of 104 X 84, and a Frazier air permeability rating of 13.2 cu ft/min at a pressure drop of 0.5 inches of water.
• Samples E and F were the same as Samples A and D, respectively, except these were tested in a fabric with a yarn count of 102 x 84 and a Frazier rating of 48. Since 0.7 dpf battings were also tested in a more permeable fabric than for Samples A-D, results on Samples E and F (1.65 dpf) are included in the Table to bridge the data between Samples A-D and G-Q. Sample E, without resin, failed when new because of the openness of the fabric, but after three wash cycles had become sufficiently matted that it improved its leakage performance. Sample F's Sealing Value was 5 initially and provided a satisfactory Sealing Rating, i.e., after 3 wash cycles).
• Samples G, H, I and J were prepared from a blend of about 85 pounds of dry polyester fibers (0.7 dpf, 0.78 dtex, 1.5 inch cut, 12 cpi, without any special slickening finish) and 15 pounds of binder fiber. These samples were resin-sprayed, calendered and tested as for samples E and F.
• Samples K and L were prepared from a blend of about 55 pounds of similar 0.7 dpf slick fiber, finished with a silicone slickener, 27 pounds of dry (unslickened) 0.7 dpf fiber, and 18 pounds of binder fiber. These samples were not calendered, as indicated by the double asterisks in the Table, but gave good sealing ratings.
• Samples M, O, P and Q were similarly prepared from the same kind of blend as K and L, but were made to higher basis weights, as shown, and also showed good sealing ratings, despite lower (less than 10%) resin add-on and despite not being calendered, because of use of low dpf fiber. N was calendered (unlike the others). A comparison of these results shows that calendering was not needed to improve the sealing rating (when the subdenier fibers were used with the soft resin).
• Samples G through L were all tested for fiber leakage using the 48 Frazier fabric.
• samples K-M and O-Q are all according to the invention, whereas the others show comparisons, some without any resin sprayed on, some with regular denier fiberfill and whose sealing ratings are not adequate after washing, and some which were calendered.

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• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Dispersion Chemistry (AREA)
• General Chemical & Material Sciences (AREA)
• Nonwoven Fabrics (AREA)
• Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
• Laminated Bodies (AREA)

Applications Claiming Priority (3)

Publications (2)

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• 1994
  • 1994-06-10 TW TW083105305A patent/TW305889B/zh active
  • 1994-06-29 KR KR1019950706044A patent/KR100215684B1/ko not_active Expired - Fee Related
  • 1994-06-29 CN CN94193052A patent/CN1062922C/zh not_active Expired - Fee Related
  • 1994-06-29 WO PCT/US1994/007076 patent/WO1995001475A1/en active IP Right Grant
  • 1994-06-29 EP EP94920307A patent/EP0708852B1/en not_active Expired - Lifetime
  • 1994-06-29 DE DE69409115T patent/DE69409115T2/de not_active Expired - Lifetime
  • 1994-06-29 JP JP7503556A patent/JPH08512105A/ja not_active Ceased

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