EP0691399A3 - Aqueous liquid detergent compositions containing deflocculating polymers - Google Patents

Aqueous liquid detergent compositions containing deflocculating polymers Download PDF

Info

Publication number
EP0691399A3
EP0691399A3 EP95201843A EP95201843A EP0691399A3 EP 0691399 A3 EP0691399 A3 EP 0691399A3 EP 95201843 A EP95201843 A EP 95201843A EP 95201843 A EP95201843 A EP 95201843A EP 0691399 A3 EP0691399 A3 EP 0691399A3
Authority
EP
European Patent Office
Prior art keywords
detergent
detergent compositions
polymer
weight
surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP95201843A
Other languages
German (de)
French (fr)
Other versions
EP0691399B1 (en
EP0691399A2 (en
Inventor
Stephen Thomas Repinec Jr
Marianne Zappone
Robert Langley Fuller
Santhana Vaidyanathan Krishnan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Publication of EP0691399A2 publication Critical patent/EP0691399A2/en
Publication of EP0691399A3 publication Critical patent/EP0691399A3/en
Application granted granted Critical
Publication of EP0691399B1 publication Critical patent/EP0691399B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0026Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides for concentrated, structured liquid detergent compositions in the form of lamellar surfactant droplets dispersed in an aqueous electrolytic continuous phase comprising a mixture of: a) from about 10 to about 45% by weight of a surfactant; b) at least one detergent builder; c) from about 0.01 to about 5% by weight of a deflocculating polymer composition having a weight average molecular weight in the range of from about 1500 to about 50,000 and containing polymer chains of the structure P-SR, wherein P represents a polymer chain segment of a hydrophilic polymer and SR represents a mercapto end-cap group, R being an organic hydrophobic radical containing from about 4 to 28 carbon atoms; and d) water. The presence of the deflocculating polymer in the composition both stabilizes the detergent composition and retards the propensity of the lamellar droplets dispersed in the aqueous phase to flocculate, particularly where the droplets occupy a higher volume ratio as the result of high concentrations of surfactant present in the detergent. The invention also provides both phosphate built and non-phosphate built detergent compositions having a viscosity in the range of from about 500 to 20,000 cps, more preferably from about 2,000 to 10,000 cps, having improved flowability and stability.
EP95201843A 1994-07-06 1995-07-05 Aqueous liquid detergent compositions containing deflocculating polymers Expired - Lifetime EP0691399B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US27129994A 1994-07-06 1994-07-06
US271299 1994-07-06

Publications (3)

Publication Number Publication Date
EP0691399A2 EP0691399A2 (en) 1996-01-10
EP0691399A3 true EP0691399A3 (en) 1996-05-22
EP0691399B1 EP0691399B1 (en) 2000-12-13

Family

ID=23034999

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95201843A Expired - Lifetime EP0691399B1 (en) 1994-07-06 1995-07-05 Aqueous liquid detergent compositions containing deflocculating polymers

Country Status (6)

Country Link
EP (1) EP0691399B1 (en)
AT (1) ATE198082T1 (en)
AU (1) AU688033B2 (en)
DE (1) DE69519605D1 (en)
NZ (1) NZ272459A (en)
ZA (1) ZA955191B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5602092A (en) * 1994-07-06 1997-02-11 Colgate-Palmolive Company Concentrated aqueous liquid detergent compositions containing deflocculating polymers
EP0776965A3 (en) 1995-11-30 1999-02-03 Unilever N.V. Polymer compositions
DE19752165A1 (en) 1997-11-26 1999-05-27 Henkel Kgaa Thickened liquid detergent composition(s)
DE19752163A1 (en) 1997-11-26 1999-05-27 Henkel Kgaa Thickened liquid detergent composition(s)
US6458752B1 (en) * 1999-03-23 2002-10-01 National Starch And Chemical Investment Holding Corporation Powder laundry detergent having enhanced soils suspending properties
IL162227A0 (en) 2001-12-21 2005-11-20 Rhodia Stable surfactant compositions for suspending components
BRPI0809314A2 (en) 2007-03-23 2014-10-14 Rhodia STRUCTURED SURFACE COMPOSITIONS

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3839405A (en) * 1966-05-05 1974-10-01 Uniroyal Inc Alkyl sulfide terminated oligomers
JPH01310730A (en) * 1988-06-10 1989-12-14 Kao Corp Dispersant and detergent containing it
WO1991009109A1 (en) * 1989-12-12 1991-06-27 Unilever N.V. Liquid detergents
EP0623670A2 (en) * 1993-05-07 1994-11-09 ALBRIGHT & WILSON UK LIMITED Aqueous based surfactant compositions

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS588010A (en) * 1981-07-08 1983-01-18 Eisai Co Ltd Ubidecarenone-containing ribosome
US4715969A (en) 1984-12-24 1987-12-29 Colgate Palmolive Co. Controlling viscosity of fabric softening heavy duty liquid detergent containing bentonite
IN165509B (en) 1984-12-24 1989-11-04 Colgate Palmolive Co
GB8718217D0 (en) 1987-07-31 1987-09-09 Unilever Plc Liquid detergent compositions
GB8813978D0 (en) 1988-06-13 1988-07-20 Unilever Plc Liquid detergents
GB8813966D0 (en) 1988-06-13 1988-07-20 Nat Starch Chem Corp Process for manufacture of polymers

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3839405A (en) * 1966-05-05 1974-10-01 Uniroyal Inc Alkyl sulfide terminated oligomers
JPH01310730A (en) * 1988-06-10 1989-12-14 Kao Corp Dispersant and detergent containing it
WO1991009109A1 (en) * 1989-12-12 1991-06-27 Unilever N.V. Liquid detergents
EP0623670A2 (en) * 1993-05-07 1994-11-09 ALBRIGHT & WILSON UK LIMITED Aqueous based surfactant compositions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 9005, Derwent World Patents Index; Class A97, AN 90-033259, XP002000114 *

Also Published As

Publication number Publication date
ATE198082T1 (en) 2000-12-15
DE69519605D1 (en) 2001-01-18
NZ272459A (en) 1997-06-24
ZA955191B (en) 1996-12-23
AU2320395A (en) 1996-01-18
EP0691399B1 (en) 2000-12-13
AU688033B2 (en) 1998-03-05
EP0691399A2 (en) 1996-01-10

Similar Documents

Publication Publication Date Title
RO115539B1 (en) Concentrated liquid aqueous detergent compositions and process for preparing the same
GB2279080B (en) Concentrated aqueous based surfactant compositions
ATE159036T1 (en) COPOLYMERS BASED ON N-ALKYLACRYLAMIDE, THEIR PRODUCTION AND THEIR USE AS THICKENERS IN SHAMPOO COMPOSITIONS
AR029158A1 (en) COMPOSITION AND METHOD TO IMPROVE THE STABILITY OF THE VISCOSITY OF WATER COMPOSITIONS
CA2226564A1 (en) Concentrated, stable fabric softening compositions with low organic solvent level
ZA955191B (en) Aqueous liquid detergent compositions containing deflocculating polymers
CA2250909A1 (en) Fabric softener compositions
MA23734A1 (en) DETEGENT COMPOSITIONS COMPRISING A CATIONIC SURFACTANT AND METHOD FOR MANUFACTURING THE SAME
MX9704132A (en) Granular detergent compositions containing deflocculating polymers.
CO4290455A1 (en) AQUEOUS LIQUID COMPOSITIONS DETERGENTS CONTAINING DEFLOCULATING POLYMERS
CA2284756A1 (en) Detergent composition
TH19869A (en) Water-based detergent mixtures with non-clumping polymers
TH19869B (en) Water-based detergent mixtures with non-clumping polymers
TH30659A (en) Polymeric substances
TH5866A (en) Liquid detergent mixtures
TH8637B (en) Liquid detergent mixtures

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI NL PT SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI NL PT SE

17P Request for examination filed

Effective date: 19961114

17Q First examination report despatched

Effective date: 19990329

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY

Effective date: 20001213

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20001213

Ref country code: LI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20001213

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRE;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.SCRIBED TIME-LIMIT

Effective date: 20001213

Ref country code: GR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20001213

Ref country code: FR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20001213

Ref country code: ES

Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY

Effective date: 20001213

Ref country code: CH

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20001213

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20001213

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20001213

REF Corresponds to:

Ref document number: 198082

Country of ref document: AT

Date of ref document: 20001215

Kind code of ref document: T

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REF Corresponds to:

Ref document number: 69519605

Country of ref document: DE

Date of ref document: 20010118

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20010313

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20010313

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20010314

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
EN Fr: translation not filed
REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20010705

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20010705

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20010705

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A