EP0690780B1 - Three-dimensional object production process - Google Patents
Three-dimensional object production process Download PDFInfo
- Publication number
- EP0690780B1 EP0690780B1 EP94912502A EP94912502A EP0690780B1 EP 0690780 B1 EP0690780 B1 EP 0690780B1 EP 94912502 A EP94912502 A EP 94912502A EP 94912502 A EP94912502 A EP 94912502A EP 0690780 B1 EP0690780 B1 EP 0690780B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- process according
- layer
- subregions
- solidified
- region
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/40—Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/59—Processes in which a partial cure is involved
Definitions
- the present invention relates to a method for manufacturing a three-dimensional object according to the generic term of Claim 1.
- EP-A-0 429 196 describes a method according to the preamble of Claim 1 known. Avoiding the occurrence of delay and deformation in the formed object is however in the in described in this document achieved by a layer is exposed in such a way that a boundary vector is exposed and the interior by means of different Techniques is partially exposed.
- WO 92/20505 also describes a method for manufacturing of a three-dimensional object.
- WO 92/08200 also describes a method according to the preamble of claim 1 known. Stages by successive Layers are created on the surface through special techniques of additional exposure of the step area balanced.
- the invention is further illustrated by an embodiment explained with reference to the figure, which is in schematic Representation of a section through part of the object shows in a layer plane.
- FIG. 1 A partial view of an example of a selected layer is shown in the figure on the basis of which the invention The procedure should first be described in principle.
- line 1 the contour of the to be manufactured Object in the layer.
- the area of the layer is grid-like in a variety of square or rectangular Individual areas or voxels i, j .... i + 6, j + 6 with one Side length from 0.1 to 5mm, preferably 0.5 to 2mm, divided.
- the coordinate data of contour 1 and the individual Individual areas are available in a computer that receives the radiation the shift controls. A comparison is made in the computer the contour data with the coordinate data of the individual areas.
- this individual area becomes a core area 2 assigned; however, it is found that a single area, for example the individual area i, j, of the contour 1 is cut, then this single area becomes an envelope area 3 assigned. This results in a narrower Envelope area 3, which along the contour line 1 with a on average approximately corresponding to the side length of the individual areas Width extends.
- the calculation is preferably carried out exclusively in the computer the core area 2; the envelope area 3 is then through Subtraction of the individual areas of core area 2 from the whole body calculated.
- the core area 2 all individual areas are marked which are fully inside the Body section, i.e. the contour line 1.
- the individual areas are assigned to Shell or core, however, not just two-dimensional, like Explained in principle above, but three-dimensionally, in order to defined thickness of the envelope area 3 in all three spatial directions to obtain.
- contour line 1 corresponds to a contour surface and when calculating the core area all individual areas marked that fully inside this contour area lie.
- Each individual area i, j contains in addition to the Information about the current shift including the corresponding one Information about previous shifts.
- the predetermined number depends on the desired number Shell thickness and the spatial distance between the individual areas; with layer thicknesses of 0.1mm and a shell thickness of 0.5mm For example, this number is 5.
- the same consideration also applies to subsequent layers: it only those individual areas are included in the core that in a given number of subsequent layers also belong to the core or would belong to it.
- the individual areas in the core area 2 only along closed Solidify lines, so that hollow structures such as Honeycomb structures result in which are still liquid or powdery material is included, which after the Solidification of the object either drained or by post-hardening is solidified.
- This method is particularly suitable to avoid thermal expansion, for example for melting molds, and also for direct production of molds.
- the inverted object is converted into a enveloping cuboid. This creates a negative form on the one in the manner described above Disassembly into shell and core is made.
- the radiation is carried out in such a way that that there is a high degree of polymerization and thus a high Strength with low tendency to warp results.
- the envelope area 3 there is high accuracy and quality of the surface on the contour 1. This is done the radiation or solidification in the envelope area 3 all over either in the form of side by side Hatching lines or one or more side by side Contour lines, i.e. the contour 1 for example as Polyline following line groups. Also a combination of these line types in a layer or in one on top of the other Layering is possible.
- the radiation in the core area 2 and in the envelope area 3 one single layer can be simultaneously or in succession by appropriate control using a single or also several light beams or laser beams take place, whereby the layer thickness in core area 2 and envelope area 3 is equal to.
- a number N of layers of the envelope region 3 solidify, where N is an integer.
- the material in the core area 2 initially remains liquid or powdery with a layer thickness that is N times the layer thickness of the Envelope area 3 corresponds. With the Nth layer too this thick layer of the core area by correspondingly intense Irradiation solidified. This can save time for the production of the core and thus for the production of the object can be significantly reduced.
- the core is not fully solidified, it is advantageous to provide openings in the shell through which the Core remaining liquid or powdery material after the solidification of the object can flow off. For example so that in every nth layer Breakthroughs of the envelope area 3 are provided, so are large enough to allow material to flow out, but do not affect the surface quality.
- the particular advantage of the described method lies in that through the superimposed envelope areas 3 a relatively stable shell is made that it allowed the core area by means of a default minimizing technique without losing stability of the object suffers. For example, it's only because of this Cover possible on the connecting webs between the individual Dispense with cells or hollow structures in the core area. Furthermore, the manufacturing time is significantly reduced that at the core, which covers the vast majority of the Object volume forms, is only partially solidified.
Abstract
Description
Die vorliegende Erfindung betrifft ein verfahren zum Herstellen eines dreidimensionalen Objekts nach dem Oberbegriff des Anspruchs 1.The present invention relates to a method for manufacturing a three-dimensional object according to the generic term of Claim 1.
Ein derartiges verfahren ist aus der EP 0 171 069 A bekannt. Bei einem derartigen Verfahren kann zwar eine gute Oberfläche erhalten werden, es tritt aber das Problem auf, daß eine Maßhaltigkeit des Objekts wegen der Verformung der einzelnen Schichten aufgrund von Schrumpfung des Materials nicht gewährleistet ist. Auch ist die Herstellungszeit lang.Such a method is known from EP 0 171 069 A. With such a method, a good surface can be used can be obtained, but the problem arises that a Dimensional accuracy of the object due to the deformation of the individual Layers not guaranteed due to material shrinkage is. The manufacturing time is also long.
Aus der EP 0 362 982 A ist es bekannt, zur Reduzierung der Verformungen entweder zunächst einzelne Streifen zu verfestigen, die mit benachbarten und darunterliegenden Streifen nur über eine Stützkonstruktion verbunden sind, oder die Schicht nur bereichsweise zu verfestigen, wobei im Objekt Spalten zwischen den Bereichen entstehen. In beiden Fällen kann jedoch keine hohe Oberflächenqualität erhalten werden. From EP 0 362 982 A it is known to reduce the Deformation either initially to individual strips solidify that with neighboring and underlying Stripes are connected only via a support structure, or to solidify the layer only in areas, whereby in the object Columns arise between the areas. In both cases however, high surface quality cannot be obtained.
Aus der EP-A-0 429 196 ist ein Verfahren nach dem Oberbegriff des Patentanspruches 1 bekannt. Das Vermeiden des Auftretens von Verzug und Verformung in dem gebildeten Objekt wird jedoch bei dem in dieser Druckschrift beschriebenen Verfahren dadurch erreicht, indem die Belichtung einer Schicht derart erfolgt, daß ein Begrenzungsvektor belichtet wird und das Innere mittels unterschiedlicher Techniken jeweils teilweise belichtet wird.EP-A-0 429 196 describes a method according to the preamble of Claim 1 known. Avoiding the occurrence of delay and deformation in the formed object is however in the in described in this document achieved by a layer is exposed in such a way that a boundary vector is exposed and the interior by means of different Techniques is partially exposed.
Aus der WO 92/20505 ist ebenfalls ein Verfahren zum Herstellen eines dreidimensionalen Objektes bekannt.WO 92/20505 also describes a method for manufacturing of a three-dimensional object.
Aus der WO 92/08200 ist ebenfalls ein Verfahren nach dem Oberbegriff des Patentanspruches 1 bekannt. Stufen, die durch aufeinanderfolgende Schichten an der Oberfläche erzeugt werden, werden durch spezielle Techniken der zusätzlichen Belichtung des Stufenbereiches ausgeglichen. WO 92/08200 also describes a method according to the preamble of claim 1 known. Stages by successive Layers are created on the surface through special techniques of additional exposure of the step area balanced.
Es ist Aufgabe der Erfindung, ein Verfahren der oben genannten Art derart zu verbessern, daß eine geringe Verformung des Objekts bei gleichzeitiger hoher Oberflächenqualität erhalten wird. Ferner soll die Genauigkeit der Oberfläche erhöht und der Materialverbrauch sowie die Bauzeit verringert werden.It is an object of the invention, a method of the above Art to improve such that a small deformation of the Object with high surface quality at the same time becomes. Furthermore, the accuracy of the surface should be increased and material consumption and construction time are reduced.
Diese Aufgabe wird erfindungsgemäß durch ein Verfahren mit den Merkmalen des Anspruchs 1 gelöst. Weiterbildungen sind in den abhängigen Ansprüchen gekennzeichnet. This object is achieved by a method with solved the features of claim 1. Further training is in the dependent claims.
Die Erfindung wird im weiteren anhand eines Ausführungsbeispiels unter Bezug auf die Figur erläutert, die in schematischer Darstellung einen Schnitt durch einen Teil des Objekts in einer Schichtebene zeigt.The invention is further illustrated by an embodiment explained with reference to the figure, which is in schematic Representation of a section through part of the object shows in a layer plane.
Das erfindungsgemäße Verfahren arbeitet nach dem unter dem Begriff "Stereographie" oder "Stereolithographie" bekannten Verfahren, wie es beispielsweise in der EP-A-0 171 069 dargestellt ist. Hierbei wird auf einen Träger bzw. eine bereits verfestigte Schicht eine Schicht eines flüssigen oder pulverförmigen Materials aufgetragen und durch Bestrahlen mit einem gerichteten Lichtstrahl, beispielsweise einem Laser, an dem Objekt entsprechenden Stellen verfestigt. Durch entsprechendes Verfestigen einer Vielzahl von Schichten wird das Objekt schichtweise erstellt. Zur genaueren Beschreibung dieses Verfahrens wird auf die genannte EP-A-0 171 069 Bezug genommen, die insoweit Teil dieser Anmeldung sein soll.The inventive method works according to the The term "stereography" or "stereolithography" is known Processes as described, for example, in EP-A-0 171 069 is. This is done on a carrier or one already solidified layer a layer of a liquid or powdered material applied and by irradiation with a directed light beam, for example a laser places corresponding to the object. By doing so Solidify a multitude of layers of the object created in layers. For a more detailed description of this The method is referred to the aforementioned EP-A-0 171 069, which should be part of this application.
Eine Teilansicht einer beispielhaft herausgegriffenen Schicht
ist in der Figur dargestellt, anhand der das erfindungsgemäße
Verfahren zunächst im Prinzip beschrieben werden soll. In der
Figur bezeichnet die Linie 1 die Kontur des herzustellenden
Objekts in der Schicht. Die Fläche der Schicht ist
rasterförmig in eine Vielzahl von quadratischen oder rechteckigen
Einzelbereichen bzw. Voxels i,j....i+6,j+6 mit einer
Seitenlänge von 0.1 bis 5mm, vorzugsweise 0.5 bis 2mm, aufgeteilt.
Die Koordinatendaten der Kontur 1 sowie der einzelnen
Einzelbereiche liegen in einem Rechner vor, der die Bestrahlung
der Schicht steuert. Im Rechner erfolgt ein Vergleich
der Konturdaten mit den Koordinatendaten der Einzelbereiche.
Stellt der Rechner fest, daß ein Einzelbereich, beispielsweise
der Einzelbereich i+1,j, vollständig innerhalb der Kontur
1 liegt, dann wird dieser Einzelbereich einem Kernbereich
2 zugeordnet; wird dagegen festgestellt, daß ein Einzelbereich,
beispielsweise der Einzelbereich i,j, von der Kontur 1
geschnitten wird, dann wird dieser Einzelbereich einem Hüllbereich
3 zugeordnet. Damit ergibt sich ein schmaler
Hüllbereich 3, der sich entlang der Konturlinie 1 mit einer
im Mittel etwa der Seitenlänge der Einzelbereiche entsprechenden
Breite erstreckt.A partial view of an example of a selected layer
is shown in the figure on the basis of which the invention
The procedure should first be described in principle. In the
Figure denotes line 1 the contour of the to be manufactured
Object in the layer. The area of the layer is
grid-like in a variety of square or rectangular
Individual areas or voxels i, j .... i + 6, j + 6 with one
Side length from 0.1 to 5mm, preferably 0.5 to 2mm, divided.
The coordinate data of contour 1 and the individual
Individual areas are available in a computer that receives the radiation
the shift controls. A comparison is made in the computer
the contour data with the coordinate data of the individual areas.
If the computer determines that a single area, for example
the individual area i + 1, j, completely within the contour
1, then this individual area becomes a
Vorzugsweise erfolgt im Rechner ausschließlich die Berechnung
des Kernbereiches 2; der Hüllbereich 3 wird danach durch
Subtraktion der Einzelbereiche des Kernbereiches 2 vom Gesamtkörper
berechnet. Bei der Berechnung des Kernbereiches 2
werden alle Einzelbereiche markiert, die voll im Innern des
Körperschnittes, also der Konturlinie 1, liegen.The calculation is preferably carried out exclusively in the computer
the
Im Einzelnen erfolgt die Zuordnung der Einzelbereiche zur
Hülle oder zum Kern allerdings nicht nur zweidimensional, wie
oben im Prinzip erläutert, sondern dreidimensional, um eine
definierte Dicke des Hüllbereichs 3 in allen drei Raumrichtungen
zu erhalten.The individual areas are assigned to
Shell or core, however, not just two-dimensional, like
Explained in principle above, but three-dimensionally, in order to
defined thickness of the
In diesem Fall entspricht der Konturlinie 1 eine Konturfläche und bei der Berechnung des Kerngebietes werden alle Einzelbereiche markiert, die voll im Inneren dieser Konturfläche liegen. Jeder Einzelbereich i,j beinhaltet dabei neben der Information über die aktuelle Schicht auch die entsprechende Information der vorangegangenen Schichten. Hierbei werden nur diejenigen Einzelbereiche als zum Kern gehörend markiert, die in einer vorbestimmten Anzahl von vorausgehenden Schichten ebenfalls Kerngebiete darstellten bzw. darstellen würden. Die vorbestimmte Anzahl hängt dabei von der erwünschten Hüllendicke un dem räumlichen Abstand der Einzelbereiche ab; bei Schichtdicken von 0.1mm und einer Hüllendicke von 0.5mm werden beispielsweise beträgt diese Anzahl beispielsweise 5. Dieselbe Betrachtung gilt auch für nachfolgende Schichten: es werden nur diejenigen Einzelbereiche zum Kern gerechnet, die in einer vorgegebenen Anzahl von nachfolgenden Schichten ebenfalls zum Kern gehören bzw. gehören würden.In this case, contour line 1 corresponds to a contour surface and when calculating the core area all individual areas marked that fully inside this contour area lie. Each individual area i, j contains in addition to the Information about the current shift including the corresponding one Information about previous shifts. Here, only those individual areas marked as belonging to the core, the in a predetermined number of previous shifts also represented or would represent core areas. The predetermined number depends on the desired number Shell thickness and the spatial distance between the individual areas; with layer thicknesses of 0.1mm and a shell thickness of 0.5mm For example, this number is 5. The same consideration also applies to subsequent layers: it only those individual areas are included in the core that in a given number of subsequent layers also belong to the core or would belong to it.
Nach der Zuordnung aller Einzelbereiche einer Schicht erfolgt
die Verfestigung durch Bestrahlen der Schicht innerhalb der
Einzelbereiche an den dem Objekt entsprechenden Stellen.
Diese Bestrahlung erfolgt nun in unterschiedlicher Art und
Weise, je nachdem ob es sich um einen Einzelbereich im Kernbereich
oder einen solchen im Hüllbereich handelt. Da es im
Kernbereich 2 (im Vergleich zum schmalen Hüllbereich 3) auf
einen geringen Verzug, einen geringen Materialverbrauch und
geringe Bauzeiten ankommt, werden dort die Einzelbereiche
nicht vollflächig, sondern in Form einzelner Zellen bestrahlt
bzw. verfestigt, die untereinander entweder durch schmale
Stege oder vorzugsweise überhaupt nicht verbunden, sondern
durch Trennfugen getrennt sind. Alternativ ist es möglich,
die Einzelbereiche im Kernbereich 2 nur entlang geschlossener
Linienzüge zu verfestigen, sodaß sich Hohlstrukturen wie z.B.
Wabenstrukturen ergeben, in denen noch flüssiges oder
pulverförmiges Material eingeschlossen ist, das nach der
Verfestigung des Objekts entweder abgelassen oder durch Nachhärten
verfestigt wird. Dieses Verfahren eignet sich besonders
zur Vermeidung von thermischen Ausdehnungen, beispielsweise
bei Ausschmelzformen, und auch zur direkten Herstellung
von Gußformen. Hierbei wird das invertierte Objekt in einen
einhüllenden Quader gesetzt. Hieraus ergibt sich eine Negativform,
an der in der oben beschriebenen Weise eine
Zerlegung in Hülle und Kern vorgenommen wird.After assigning all individual areas to a shift
the solidification by irradiating the layer within the
Individual areas at the locations corresponding to the object.
This radiation is now carried out in different ways and
Way, depending on whether it is a single area in the core area
or one in the envelope area. Since it is in
Core area 2 (compared to the narrow envelope area 3)
low warpage, low material consumption and
If the construction times are short, the individual areas are there
not irradiated over the entire area but in the form of individual cells
or solidified, either by narrow
Bridges or preferably not connected at all, but
are separated by parting lines. Alternatively, it is possible
the individual areas in the
Im Kernbereich 2 wird die Bestrahlung derart durchgeführt,
daß sich ein hoher Polymerisationsgrad und damit eine hohe
Festigkeit bei geringer Verzugstendenz ergibt.In
Im Hüllbereich 3 kommt es dagegen auf eine hohe Genauigkeit
und Qualität der Oberfläche an der Kontur 1 an. Hierzu erfolgt
die Bestrahlung bzw. Verfestigung im Hüllbereich 3
vollflächig entweder in Form nebeneinanderliegender
Schraffurlinien oder einer bzw. mehrerer nebeneinanderliegenden
Konturlinien, d.h. der Kontur 1 beispielsweise als
Polygonzug folgenden Liniengruppen. Auch eine Kombination
dieser Linientypen in einer Schicht oder in übereinanderliegenden
Schichten ist möglich. In the
Die Bestrahlung im Kernbereich 2 und im Hüllbereich 3 einer
einzigen Schicht kann gleichzeitig oder auch nacheinander
durch entsprechende Steuerung mittels eines einzigen oder
auch mehrerer Lichtstrahlen bzw. Laserstrahlen erfolgen, wobei
die Schichtdicke im Kernbereich 2 und Hüllbereich 3
gleich ist. Es ist jedoch besonders vorteilhaft, zunächst
eine Anzahl N von Schichten des Hüllbereichs 3 zu
verfestigen, wobei N eine ganze Zahl darstellt. Das Material
im Kernbereich 2 bleibt zunächst flüssig bzw. pulverförmig
mit einer Schichtdicke, die dem N-fachen der Schichtdicke des
Hüllbereichs 3 entspricht. Bei der N-ten Schicht wird auch
diese dicke Schicht des Kernbereichs durch entsprechend intensives
Bestrahlen verfestigt. Dadurch kann der Zeitaufwand
für die Herstellung des Kerns und damit für die Herstellung
des Objekts erheblich reduziert werden.The radiation in the
Wird der Kern nicht vollständig verfestigt, so ist es vorteilhaft,
in der Hülle Öffnungen vorzusehen, durch die das im
Kern verbliebene flüssige oder pulverförmige Material nach
der Verfestigung des Objekts abfließen kann. Dies kann beispielsweise
so erfolgen, daß in jeder n-ten Schicht
Durchbrechungen des Hüllbereichs 3 vorgesehen werden, die so
groß bemessen sind, daß sie ein Ausströmen des Materials zulassen,
aber die Oberflächenqualität nicht beeinträchtigen.If the core is not fully solidified, it is advantageous
to provide openings in the shell through which the
Core remaining liquid or powdery material after
the solidification of the object can flow off. For example
so that in every nth layer
Breakthroughs of the
Der besondere Vorteil des beschriebenen Verfahrens liegt darin, daß durch die übereinanderliegenden Hüllbereiche 3 eine verhältnismäßig stabile Hülle hergestellt wird, die es erlaubt, den Kernbereich mittels einer einen Verzug minimierenden Technik herzustellen, ohne daß die Stabilität des Objekts leidet. Beispielsweise ist es nur wegen dieser Hülle möglich, auf die Verbindungsstege zwischen den einzelnen Zellen oder Hohlstrukturen des Kernbereichs zu verzichten. Ferner wird die Herstellungszeit dadurch erheblich reduziert, daß im Kern, der den ganz überwiegenden Teil des Objektvolumens bildet, nur partiell verfestigt wird.The particular advantage of the described method lies in that through the superimposed envelope areas 3 a relatively stable shell is made that it allowed the core area by means of a default minimizing technique without losing stability of the object suffers. For example, it's only because of this Cover possible on the connecting webs between the individual Dispense with cells or hollow structures in the core area. Furthermore, the manufacturing time is significantly reduced that at the core, which covers the vast majority of the Object volume forms, is only partially solidified.
Claims (17)
- Process for producing a three-dimensional object, in which the object is created by successive solidifying of individual layers of liquid or powdered, solidifiable material by the action of an electromagnetic radiation, each layer being broken down into an inner core region (2) and an outer shell region (3) and that the action of radiation in the core region (2) and in the shell region (3) is controlled differently to create different properties of the two regions, characterized in that the shell region (3) is determined by subtraction in a three-dimensional way of individual regions of the core region (2) from the overall body.
- Process according to Claim 1, characterized in that the action of radiation in the core region (2) takes place in such a way that the deformation of the object during and after the solidification is minimal, and in that the action of radiation in the shell region (3) takes place to create as smooth and accurate a surface as possible.
- Process according to Claim 2, characterized in that, in the core region (2), individual spaced-apart subregions are solidified, and in that, if appropriate, the intermediate regions between the subregions are likewise solidified after solidifying the subregions of one layer or after solidifying all the subregions of the object.
- Process according to Claim 2 or 3, characterized in that, in the core region (2), individual strips are solidified which are joined to neighbouring strips and strips lying underneath by means of a supporting structure are solidified.
- Process according to Claim 2, characterized in that, in the core region (2), first of all subregions of one layer are solidified and are thereby joined to subregions lying underneath of the previously solidified layer to form multi-layered cells, in that thereafter the subregions are joined to the neighbouring subregions of the same layer by solidifying of narrow joining regions between the subregions in the form of joining webs, and in that finally the intermediate regions between the subregions are solidified.
- Process according to Claim 5, characterized in that the joining regions are solidified only after a waiting time, which corresponds to a shrinkage of the subregions by at least a given amount.
- Process according to Claim 3, characterized in that the subregions are formed to create hollow structures, preferably honeycomb structures.
- Process according to one of the preceding claims, characterized in that, in the shell region (3), sub-regions lying closely next to one another are solidified.
- Process according to one of the preceding claims, characterized in that the action of radiation in the shell region (3) takes place along one or more lines, which describe the outer edge of the shell region or are parallel to the latter.
- Process according to one of the preceding claims, characterized in that the layer thickness in the shell region (3) is chosen to be less than in the core region.
- Process according to Claim 10, characterized in that first of all a whole number N of layers of the shell region (3) are solidified and thereafter a layer of the core region (2) is solidified with a layer thickness corresponding to N times the thickness of the shell region layers.
- Process according to one of the preceding claims, characterized in that, for the shell region (3), there are defined in a layer volume elements of the object which lie within a given distance from the edge of the object in this layer.
- Process according to Claim 12, characterized in that those volume elements which are touched or intersected by the edge or the contour of the object in a layer and/or in a predetermined number of preceding and/or subsequent layers of this layer are defined.
- Process according to one of the preceding claims, characterized in that, for the shell region (3), a thickness of 0.1 to 5 mm, preferably 0.5 to 2 mm, is chosen.
- Process according to one of the preceding claims, characterized in that, in the shell region (3), openings through which the unsolidified material can flow out of the core region (2) are formed.
- Process according to one of Claims 1 to 15, characterized in that the shell region (3) has a defined thickness, its width in a layer corresponding on average to approximately the side length of the individual regions.
- Use of a process according to one of Claims 1 to 15 for producing casting moulds, the inverted object being placed into an enveloping block and a negative mould obtained from it, on which the breakdown into shell and core is performed.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4309524A DE4309524C2 (en) | 1993-03-24 | 1993-03-24 | Method of making a three-dimensional object |
DE4309524 | 1993-03-24 | ||
PCT/EP1994/000900 WO1994021446A1 (en) | 1993-03-24 | 1994-03-22 | Three-dimensional object production process |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0690780A1 EP0690780A1 (en) | 1996-01-10 |
EP0690780B1 true EP0690780B1 (en) | 1998-07-01 |
Family
ID=6483701
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94912502A Expired - Lifetime EP0690780B1 (en) | 1993-03-24 | 1994-03-22 | Three-dimensional object production process |
Country Status (5)
Country | Link |
---|---|
US (1) | US5932059A (en) |
EP (1) | EP0690780B1 (en) |
JP (1) | JPH08504139A (en) |
DE (2) | DE4309524C2 (en) |
WO (1) | WO1994021446A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016007817A1 (en) | 2016-06-23 | 2017-12-28 | Daimler Ag | Method for smoothing a surface of a component |
US10625374B2 (en) | 2013-02-27 | 2020-04-21 | SLM Solutions Group AG | Method for producing work pieces having a tailored microstructure |
Families Citing this family (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4440397C2 (en) * | 1994-11-11 | 2001-04-26 | Eos Electro Optical Syst | Methods of making molds |
PT711213E (en) * | 1994-05-27 | 2000-10-31 | Eos Electro Optical Syst | PROCESS FOR USE IN FOUNDATION |
DE4436695C1 (en) * | 1994-10-13 | 1995-12-21 | Eos Electro Optical Syst | Stereolithography, the making of a three dimensional object by irradiation of powder or liquid layers |
WO1997014549A1 (en) * | 1995-10-13 | 1997-04-24 | Eos Gmbh Electro Optical Systems | Process for producing a three-dimensional object |
DE19606128A1 (en) * | 1996-02-20 | 1997-08-21 | Eos Electro Optical Syst | Device and method for producing a three-dimensional object |
DE19929199A1 (en) * | 1999-06-25 | 2001-01-18 | Hap Handhabungs Automatisierun | Method and device for producing a three-dimensional object |
JP3687475B2 (en) * | 2000-03-28 | 2005-08-24 | 松下電工株式会社 | Method for modeling solid objects |
DE10042134C2 (en) * | 2000-08-28 | 2003-06-12 | Concept Laser Gmbh | Process for the production of three-dimensional sintered workpieces |
US6699424B2 (en) | 2001-06-29 | 2004-03-02 | 3D Systems, Inc. | Method for forming three-dimensional objects |
WO2003039844A1 (en) * | 2001-10-30 | 2003-05-15 | Concept Laser Gmbh | Method for the production of three-dimensional sintered workpieces |
DE10219984C1 (en) * | 2002-05-03 | 2003-08-14 | Bego Medical Ag | Device for producing freely formed products through a build-up of layers of powder-form material, has powder spread over a lowerable table, and then solidified in layers by a laser energy source |
DE10219983B4 (en) * | 2002-05-03 | 2004-03-18 | Bego Medical Ag | Process for manufacturing products using free-form laser sintering |
EP1536395A4 (en) * | 2002-05-10 | 2012-08-01 | Nagoya Ind Science Res Inst | Three-dimensional model |
SE524420C2 (en) * | 2002-12-19 | 2004-08-10 | Arcam Ab | Apparatus and method for making a three-dimensional product |
SE524439C2 (en) * | 2002-12-19 | 2004-08-10 | Arcam Ab | Apparatus and method for making a three-dimensional product |
SE524421C2 (en) * | 2002-12-19 | 2004-08-10 | Arcam Ab | Apparatus and method for making a three-dimensional product |
GB0317387D0 (en) * | 2003-07-25 | 2003-08-27 | Univ Loughborough | Method and apparatus for combining particulate material |
DE10336561B4 (en) | 2003-08-07 | 2019-05-02 | Lim Laserinstitut Mittelsachsen Gmbh | Method for producing a miniature body or microstructured body |
US20050087897A1 (en) * | 2003-10-23 | 2005-04-28 | Nielsen Jeffrey A. | Systems and methods for reducing waste in solid freeform fabrication |
US7569174B2 (en) * | 2004-12-07 | 2009-08-04 | 3D Systems, Inc. | Controlled densification of fusible powders in laser sintering |
US7829000B2 (en) * | 2005-02-25 | 2010-11-09 | Hewlett-Packard Development Company, L.P. | Core-shell solid freeform fabrication |
US8044437B1 (en) | 2005-05-16 | 2011-10-25 | Lsi Logic Corporation | Integrated circuit cell architecture configurable for memory or logic elements |
DE102005027311B3 (en) * | 2005-06-13 | 2006-11-02 | Trumpf Werkzeugmaschinen Gmbh + Co. Kg | Toolmaking process to fabricate a form by successive application of powder layers solidified by laser beam |
DE102005030067A1 (en) * | 2005-06-27 | 2006-12-28 | FHS Hochschule für Technik, Wirtschaft und soziale Arbeit St. Gallen | Apparatus for producing objects using generative method, e.g. selective laser sintering, has system for generating mist of fluid between electromagnetic component and process chamber |
DE102006008332B4 (en) * | 2005-07-11 | 2009-06-04 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Process for the production of a functional structural unit and functional structural unit |
DE102005049886A1 (en) * | 2005-10-17 | 2007-04-19 | Sirona Dental Systems Gmbh | Tooth replacement part manufacturing method involves energy beam sintering powder material at the edge area to a greater density than in inner region by varying process parameters during sintering |
DE102005050665A1 (en) * | 2005-10-20 | 2007-04-26 | Bego Medical Gmbh | Layer-wise production process with grain size influencing |
ES2328430B1 (en) * | 2006-04-06 | 2010-09-16 | Moises Mora Garcia | MANUFACTURING MACHINE FOR DENTAL AND MAXILOFACIAL PROTESIS FROM A THREE-DIGITAL DIGITAL MODEL THROUGH DIRECT APPLICATION OF LASER AND SINTERIZATION, AND PROCEDURE OF OPERATION OF THE MACHINE SAID. |
EP1880830B1 (en) * | 2006-07-19 | 2011-12-21 | Envisiontec GmbH | Method and device for producing a three-dimensional object, and computer and data carrier useful thereof |
DK2052693T4 (en) † | 2007-10-26 | 2021-03-15 | Envisiontec Gmbh | Process and free-form manufacturing system to produce a three-dimensional object |
DE102007057129B4 (en) | 2007-11-24 | 2010-07-22 | Hochschule Mittweida (Fh) | Method and apparatus for high performance micromachining a body or powder layer with a high brilliance laser |
EP2402097A4 (en) | 2009-02-24 | 2014-04-09 | Panasonic Corp | Process for producing three-dimensional shape and three-dimensional shape obtained thereby |
ES2663554T5 (en) | 2009-04-28 | 2022-05-06 | Bae Systems Plc | Layered additive manufacturing method |
WO2010125381A1 (en) | 2009-04-28 | 2010-11-04 | Bae Systems Plc | Additive layer fabrication method |
WO2010150805A1 (en) | 2009-06-23 | 2010-12-29 | パナソニック電工株式会社 | Method for producing three-dimensional formed shapes, and three-dimensional formed shapes obtained thereby |
DE102009043597A1 (en) * | 2009-09-25 | 2011-04-07 | Siemens Aktiengesellschaft | Method for producing a marked object |
GB201016169D0 (en) * | 2010-09-27 | 2010-11-10 | Materialise Nv | Method for reducing differential shrinkage in stereolithography |
DE102011089194A1 (en) * | 2011-12-20 | 2013-06-20 | BAM Bundesanstalt für Materialforschung und -prüfung | Method of manufacturing a compact component and component that can be produced by the method |
DE102012212587A1 (en) | 2012-07-18 | 2014-01-23 | Eos Gmbh Electro Optical Systems | Apparatus and method for layering a three-dimensional object |
DE102013212803A1 (en) | 2013-07-01 | 2015-01-08 | Eos Gmbh Electro Optical Systems | Method for producing a three-dimensional object |
JP6229155B2 (en) * | 2013-10-03 | 2017-11-15 | パナソニックIpマネジメント株式会社 | Manufacturing method of three-dimensional shaped object |
EP2875897B1 (en) * | 2013-11-21 | 2016-01-20 | SLM Solutions Group AG | Method of and device for controlling an irradiation system for producing a three-dimensional workpiece |
JP6146294B2 (en) * | 2013-12-25 | 2017-06-14 | トヨタ自動車株式会社 | Manufacturing method of three-dimensional shaped object |
CN106061718B (en) | 2014-03-05 | 2018-01-02 | 松下知识产权经营株式会社 | The manufacture method of three dimensional structure |
TWI609769B (en) * | 2014-06-03 | 2018-01-01 | 三緯國際立體列印科技股份有限公司 | Three dimensional structure and three dimensional printing method |
WO2015196149A1 (en) | 2014-06-20 | 2015-12-23 | Velo3D, Inc. | Apparatuses, systems and methods for three-dimensional printing |
GB201500607D0 (en) * | 2015-01-14 | 2015-02-25 | Digital Metal Ab | Additive manufacturing method, method of processing object data, data carrier, object data processor and manufactured object |
DE102015201775A1 (en) | 2015-02-02 | 2016-08-04 | Gkn Sinter Metals Engineering Gmbh | Method and device for the additive production of components |
DE102015217469A1 (en) * | 2015-09-11 | 2017-03-16 | Eos Gmbh Electro Optical Systems | Method and device for producing a three-dimensional object |
CN108367498A (en) | 2015-11-06 | 2018-08-03 | 维洛3D公司 | ADEPT 3 D-printings |
EP3386662A4 (en) | 2015-12-10 | 2019-11-13 | Velo3d Inc. | Skillful three-dimensional printing |
US20170239719A1 (en) | 2016-02-18 | 2017-08-24 | Velo3D, Inc. | Accurate three-dimensional printing |
US11691343B2 (en) | 2016-06-29 | 2023-07-04 | Velo3D, Inc. | Three-dimensional printing and three-dimensional printers |
EP3263316B1 (en) | 2016-06-29 | 2019-02-13 | VELO3D, Inc. | Three-dimensional printing and three-dimensional printers |
US20180126460A1 (en) | 2016-11-07 | 2018-05-10 | Velo3D, Inc. | Gas flow in three-dimensional printing |
US20180186082A1 (en) | 2017-01-05 | 2018-07-05 | Velo3D, Inc. | Optics in three-dimensional printing |
US10442003B2 (en) | 2017-03-02 | 2019-10-15 | Velo3D, Inc. | Three-dimensional printing of three-dimensional objects |
US10695865B2 (en) | 2017-03-03 | 2020-06-30 | General Electric Company | Systems and methods for fabricating a component with at least one laser device |
US10449696B2 (en) | 2017-03-28 | 2019-10-22 | Velo3D, Inc. | Material manipulation in three-dimensional printing |
EP3482853A1 (en) | 2017-11-13 | 2019-05-15 | Renishaw PLC | Additive manufacturing apparatus and methods |
WO2019063999A1 (en) | 2017-09-29 | 2019-04-04 | Renishaw Plc | Additive manufacturing apparatus and methods |
US11292071B2 (en) * | 2017-11-15 | 2022-04-05 | Kobe Steel, Ltd. | Method for producing molded article, production device, and molded article |
US10272525B1 (en) | 2017-12-27 | 2019-04-30 | Velo3D, Inc. | Three-dimensional printing systems and methods of their use |
US10144176B1 (en) | 2018-01-15 | 2018-12-04 | Velo3D, Inc. | Three-dimensional printing systems and methods of their use |
US10518356B2 (en) | 2018-02-05 | 2019-12-31 | General Electric Company | Methods and apparatus for generating additive manufacturing scan paths using thermal and strain modeling |
JP6956044B2 (en) * | 2018-06-04 | 2021-10-27 | 株式会社日立製作所 | Powdered additive manufacturing and its manufacturing method |
JP7322145B2 (en) * | 2018-11-09 | 2023-08-07 | レイヤーワイズ エヌヴェ | Alternating double layer contouring and hatching for 3D manufacturing |
CN110654028B (en) * | 2019-10-12 | 2021-03-05 | 上海联泰科技股份有限公司 | Three-dimensional object data layering processing method and 3D printing equipment |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4575330A (en) * | 1984-08-08 | 1986-03-11 | Uvp, Inc. | Apparatus for production of three-dimensional objects by stereolithography |
ES2063737T3 (en) * | 1986-06-03 | 1995-01-16 | Cubital Ltd | APPARATUS AND METHOD FOR THREE-DIMENSIONAL MODELING. |
IL79007A (en) * | 1986-06-03 | 1989-09-10 | Scitex Corp Ltd | Apparatus and method for three-dimensional mapping and modeling |
KR0178873B1 (en) * | 1988-04-18 | 1999-05-15 | 찰스 윌리엄 헐 | Stereolithographic curl reduction |
US5130064A (en) * | 1988-04-18 | 1992-07-14 | 3D Systems, Inc. | Method of making a three dimensional object by stereolithography |
DE362982T1 (en) * | 1988-04-18 | 1996-06-27 | 3D Systems Inc | Reduce stereolithographic bending. |
US5182056A (en) * | 1988-04-18 | 1993-01-26 | 3D Systems, Inc. | Stereolithography method and apparatus employing various penetration depths |
US5256340A (en) * | 1988-04-18 | 1993-10-26 | 3D Systems, Inc. | Method of making a three-dimensional object by stereolithography |
EP0338751B1 (en) * | 1988-04-18 | 1996-03-20 | 3D Systems, Inc. | Stereolithographic supports |
US5182055A (en) | 1988-04-18 | 1993-01-26 | 3D Systems, Inc. | Method of making a three-dimensional object by stereolithography |
US5015424A (en) * | 1988-04-18 | 1991-05-14 | 3D Systems, Inc. | Methods and apparatus for production of three-dimensional objects by stereolithography |
JPH0757531B2 (en) * | 1988-10-01 | 1995-06-21 | 松下電工株式会社 | Three-dimensional shape forming method |
JPH0757532B2 (en) * | 1988-10-19 | 1995-06-21 | 松下電工株式会社 | Three-dimensional shape forming method |
DE69034126T2 (en) * | 1989-10-30 | 2004-10-28 | 3D Systems, Inc., Valencia | Stereolithographic shaping techniques |
JP2671534B2 (en) * | 1989-12-25 | 1997-10-29 | 松下電工株式会社 | 3D shape forming method |
DE555369T1 (en) * | 1990-10-30 | 1996-10-10 | 3D Systems Inc | LAYER COMPARISON TECHNIQUES IN STEREOLITHOGRAPHY. |
US5238639A (en) * | 1990-10-31 | 1993-08-24 | 3D Systems, Inc. | Method and apparatus for stereolithographic curl balancing |
JPH0745196B2 (en) * | 1990-11-02 | 1995-05-17 | 三菱商事株式会社 | Light solidification modeling device |
JP3170832B2 (en) * | 1991-12-26 | 2001-05-28 | ソニー株式会社 | Optical molding method |
JPH06114948A (en) * | 1992-10-01 | 1994-04-26 | Shiimetsuto Kk | Optically curable molded form with uncured liquid outlet and molding method therefor |
DE4233812C1 (en) * | 1992-10-07 | 1993-11-04 | Eos Electro Optical Syst | METHOD AND DEVICE FOR PRODUCING THREE-DIMENSIONAL OBJECTS |
JP2853497B2 (en) * | 1993-01-12 | 1999-02-03 | ソニー株式会社 | Optical molding equipment |
JP3422039B2 (en) * | 1993-03-19 | 2003-06-30 | ソニー株式会社 | Optical shaping method and optical shaping apparatus |
JPH0757532A (en) * | 1993-08-09 | 1995-03-03 | Tosoh Corp | Ion conductor and manufacture thereof |
JP3331017B2 (en) * | 1993-08-18 | 2002-10-07 | 松下電工株式会社 | Lighting equipment |
-
1993
- 1993-03-24 DE DE4309524A patent/DE4309524C2/en not_active Expired - Fee Related
-
1994
- 1994-03-22 JP JP6520669A patent/JPH08504139A/en active Pending
- 1994-03-22 WO PCT/EP1994/000900 patent/WO1994021446A1/en active IP Right Grant
- 1994-03-22 DE DE59406372T patent/DE59406372D1/en not_active Expired - Lifetime
- 1994-03-22 EP EP94912502A patent/EP0690780B1/en not_active Expired - Lifetime
-
1997
- 1997-10-22 US US08/956,078 patent/US5932059A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10625374B2 (en) | 2013-02-27 | 2020-04-21 | SLM Solutions Group AG | Method for producing work pieces having a tailored microstructure |
DE102016007817A1 (en) | 2016-06-23 | 2017-12-28 | Daimler Ag | Method for smoothing a surface of a component |
Also Published As
Publication number | Publication date |
---|---|
EP0690780A1 (en) | 1996-01-10 |
DE59406372D1 (en) | 1998-08-06 |
US5932059A (en) | 1999-08-03 |
WO1994021446A1 (en) | 1994-09-29 |
DE4309524C2 (en) | 1998-05-20 |
DE4309524C1 (en) | 1993-11-25 |
JPH08504139A (en) | 1996-05-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0690780B1 (en) | Three-dimensional object production process | |
DE4436695C1 (en) | Stereolithography, the making of a three dimensional object by irradiation of powder or liquid layers | |
DE19507881B4 (en) | Method of supporting an object made by stereolithography or another rapid prototype manufacturing method | |
DE4233812C1 (en) | METHOD AND DEVICE FOR PRODUCING THREE-DIMENSIONAL OBJECTS | |
EP1993812B1 (en) | Method and device for the production of a three-dimensional object | |
DE60115136T2 (en) | Production of three-dimensional objects by controlled photocuring | |
EP0821647B1 (en) | Device and method for producing three-dimensional objects | |
DE60021440T2 (en) | Method and apparatus for stereolithographically forming three-dimensional objects with reduced curvature | |
EP2275247B1 (en) | Apparatus and method for producing three dimensional objects by means of a generative production method | |
DE102017126624A1 (en) | LAYERED LIGHT EXPOSURE IN GENERATIVE MANUFACTURING | |
DE102007039035B3 (en) | Method for producing a component and use of the component produced by the method | |
DE10235434A1 (en) | Device for producing a three-dimensional object by e.g. selective laser sintering comprises a support and a material-distributing unit which move relative to each other | |
EP2386405A1 (en) | Device and method for generative manufacturing of a three dimensional object with construction area limit | |
EP2576191A2 (en) | Building-space changing device and an apparatus for producing a three-dimensional object with a building-space changing device | |
DE102016209933A1 (en) | Apparatus and method for generatively producing a three-dimensional object | |
DE60031317T2 (en) | Stereolithographic method and apparatus for producing three-dimensional objects, wherein smoothing parameters apply to layer groups | |
DE102017213720A1 (en) | Optimized segmentation process | |
DE102015207306A1 (en) | Method and device for producing a three-dimensional object | |
DE102015219866A1 (en) | Device and method for producing a three-dimensional object | |
EP3297813B1 (en) | Method and device for producing a three-dimensional object | |
DE102018202506A1 (en) | Controlled solidification additive manufacturing process and associated apparatus | |
EP3579998B1 (en) | Increase in surface quality | |
WO2018172079A1 (en) | Overlap optimization | |
DE10042132A1 (en) | Production of sintered workpieces involves binding layers of material by irradiation, where each layer comprises core and coating, and irradiation is controlled to produce complete fusion of material in coating in at least its surface area | |
DE4326986C1 (en) | Method and device for producing three-dimensional objects |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19950811 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): CH DE FR GB IT LI SE |
|
17Q | First examination report despatched |
Effective date: 19961204 |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): CH DE FR GB IT LI SE |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: R. A. EGLI & CO. PATENTANWAELTE Ref country code: CH Ref legal event code: EP |
|
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 19980703 |
|
REF | Corresponds to: |
Ref document number: 59406372 Country of ref document: DE Date of ref document: 19980806 |
|
ET | Fr: translation filed | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 19990322 Year of fee payment: 6 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 19990324 Year of fee payment: 6 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000323 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000331 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000331 |
|
EUG | Se: european patent has lapsed |
Ref document number: 94912502.5 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20120329 Year of fee payment: 19 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20130321 Year of fee payment: 20 Ref country code: FR Payment date: 20130408 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20130522 Year of fee payment: 20 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R071 Ref document number: 59406372 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: PE20 Expiry date: 20140321 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20140321 Ref country code: DE Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20140325 |