EP0683883A1 - Blue-flame burner with optimized combustion characteristics - Google Patents
Blue-flame burner with optimized combustion characteristicsInfo
- Publication number
- EP0683883A1 EP0683883A1 EP95905077A EP95905077A EP0683883A1 EP 0683883 A1 EP0683883 A1 EP 0683883A1 EP 95905077 A EP95905077 A EP 95905077A EP 95905077 A EP95905077 A EP 95905077A EP 0683883 A1 EP0683883 A1 EP 0683883A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- recirculation
- burner according
- combustion chamber
- flow
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 200
- 235000009781 Myrtillocactus geometrizans Nutrition 0.000 title abstract 2
- 240000009125 Myrtillocactus geometrizans Species 0.000 title abstract 2
- 239000000446 fuel Substances 0.000 claims abstract description 178
- 239000000567 combustion gas Substances 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims description 4
- 230000001427 coherent effect Effects 0.000 claims 1
- 239000003344 environmental pollutant Substances 0.000 abstract description 6
- 231100000719 pollutant Toxicity 0.000 abstract description 4
- 238000005192 partition Methods 0.000 abstract 1
- 230000006641 stabilisation Effects 0.000 description 14
- 238000011105 stabilization Methods 0.000 description 14
- 239000007789 gas Substances 0.000 description 9
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000000087 stabilizing effect Effects 0.000 description 6
- 230000003134 recirculating effect Effects 0.000 description 5
- 239000007921 spray Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/006—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber the recirculation taking place in the combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D11/00—Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space
- F23D11/24—Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space by pressurisation of the fuel before a nozzle through which it is sprayed by a substantial pressure reduction into a space
- F23D11/26—Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space by pressurisation of the fuel before a nozzle through which it is sprayed by a substantial pressure reduction into a space with provision for varying the rate at which the fuel is sprayed
- F23D11/28—Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space by pressurisation of the fuel before a nozzle through which it is sprayed by a substantial pressure reduction into a space with provision for varying the rate at which the fuel is sprayed with flow-back of fuel at the burner, e.g. using by-pass
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D11/00—Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space
- F23D11/36—Details, e.g. burner cooling means, noise reduction means
- F23D11/40—Mixing tubes or chambers; Burner heads
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2202/00—Fluegas recirculation
- F23C2202/40—Inducing local whirls around flame
Definitions
- the invention relates to a burner for liquid media comprising a burner housing which has a support tube and an adjoining flame tube, a nozzle assembly arranged in the support tube in a prechamber with a nozzle generating a fuel jet, and an essentially mixing tube-free burner chamber arranged in the flame tube in which the fuel jet spreads, a separating element between the prechamber and the combustion chamber with a central opening through which the fuel jet passes, a blower for generating a combustion air flow entering the combustion chamber, which comprises a partial flow close to the fuel jet, the fuel having a blue-burning one in the combustion chamber Flame burns essentially stoichiometric or near stoichiometric.
- DE-OS 40 09 222 discloses a burner for the stoichiometric combustion of liquid or gaseous fuels from an atomizer nozzle. With this burner, air is passed through a screen into the atomizer nozzle
- Combustion chamber in which the fuel emerging from the nozzle also enters.
- slit-shaped openings running parallel to the flow direction are provided in the wall of the combustion chamber, via which recirculation of cold combustion gases from outside the burner tube takes place, which are mixed with the fuel and the air entering around the atomizing nozzle in order to achieve stoichiometric combustion in the combustion chamber to obtain.
- EP-A-0 430 011 also discloses a blue-burning burner in which a mixture of fresh air and recirculating combustion gases are supplied and mixed around an atomizer nozzle before they again lead to stoichiometric combustion with the fuel coming from the atomizer nozzle.
- the combustion air and recirculating combustion gas are mixed in front of the plane in which an orifice of the nozzle is located, and after this in a mixing chamber the combustion air and the recirculating combustion gases are mixed with the fuel, which then enter the actual combustion chamber.
- the feed is
- a controllable burner is known from DE-OS 27 12 564, in which a baffle plate is present and a vacuum region is created downstream of the baffle plate by generating a rotating hollow air column, so that combustion gases are sucked back into this vacuum region.
- the rotating hollow air column is generated by radial slots running in the radial direction and covered with scoops.
- the atomizer nozzle with the ignition electrodes is arranged in a closed space, to which only as much fresh air is supplied as is necessary to move the ignition spark.
- DE-PS 29 08 427 discloses a burner in which, with the addition of flue gases, substoichiometric combustion takes place in a primary combustion zone with direct supply of a jacket air stream enveloping the fuel flow and then in a superstoichiometric secondary combustion zone, in the residual air over the peripheral area of the primary Combustion zone is fed, another combustion takes place.
- the residual air is fed coaxially around the respective burner in at least two partial flows, which reach the flame from the burner mouth after a certain free flow path.
- a so-called blue burner is known, in which internal recirculation is forced through a mixing tube, the fuel jet emerging from an atomizer nozzle being supplied on the one hand with this directly surrounding combustion air and on the other hand, further air passage bores are provided radially on the outside, but these are lie radially inside the mixing tube.
- a burner with a recirculation is known from EP-A-0 538 761, in which the external recirculation is generated by a longitudinal direction of the slots, these slots extending with their longitudinal direction in the circumferential direction.
- a so-called mixing tube is required to form a stable recirculation flow, which defines a single recirculation flow of hot gas and thus enables the flame to burn blue.
- a blue burning of the flame is understood to mean that this flame burns a completely gasified fuel, which makes it necessary, in particular when oil is used as fuel, that flows from the nozzle into the Small oil droplets initially emerging from the fuel jet are essentially completely evaporated until they are burned by the flame.
- the invention has for its object to improve a burner of the generic type in such a way that a low-pollutant and stable stoichiometric or near-stoichiometric combustion allows.
- This object is achieved according to the invention in a burner of the type described at the outset in that, in addition to the partial flow near the fuel jet, a recirculation-stabilizing partial flow of combustion air occurs at a defined distance from the latter in a defined distance, that in the combustion chamber one of the blue-burning flame to the non-burning part of the Forms back internal recirculation flow of fuel jet and that the recirculation-stabilizing partial flow of the combustion air stabilizes the internal recirculation flow.
- the advantage of the solution according to the invention can be seen in the fact that the additional recirculation-stabilizing partial flow of the combustion air enables the internal recirculation flow in the combustion chamber to be stabilized.
- Openings are provided through which an external recirculation flow leading to cold combustion gases into the
- Combustion chamber occurs that the external recirculation flow enters the combustion chamber near the separating element and is so large that a flame root of the blue-burning flame is at least 1 cm away from the nozzle and that there is a non-burning part between the nozzle and the flame root of the fuel jet spreads conically with the addition of combustion air.
- the sufficient length of the non-burning part of the fuel jet creates the possibility of mixing the hot gases from the internal recirculation flow into the non-burning part of the fuel jet and thus in turn the possibility of reliably evaporating the oil droplets in the fuel jet down to the flame root that ultimately a stable blue-burning flame is created, which is highly insensitive to small changes in the setting parameters.
- Burner of the type mentioned in the invention solved in that openings are provided in the burner housing, through which an external, cold combustion gas carrying recirculation flow enters the combustion chamber, the external recirculation flow near the separating element enters the combustion chamber and this shields an internal recirculation flow against the separating element, which as in the combustion chamber from the blue-burning flame to the non-burning part of the Forms backward flow of fuel jet.
- the outer recirculation flow which is usually used to reduce the pollutants, in particular the nitrogen oxides, is used according to the invention to shield the hot combustion gases of the inner recirculation flow from the cold separating element and thus to prevent excessive cooling of these hot combustion gases by the cold separating element. Rather, these hot combustion gases are supplied to the fuel jet essentially with little or no cooling in order to ensure that the oil droplets evaporate as optimally as possible through the heat input.
- An advantageous exemplary embodiment provides that the inner recirculation flow flows from the flame on an inside of the flame tube in the direction of the separating element. In this position, the internal recirculation flow can be stabilized particularly simply and sustainably by the recirculation-stabilizing partial flow of the combustion air.
- the inner recirculation flow is yellow-burning.
- a particularly advantageous effect of the inner recirculation flow in particular with regard to the heat transfer to the fuel jet for the evaporation of the oil droplets, can be achieved if the inner recirculation flow through the partial flow which stabilizes the recirculation
- the recirculation-stabilizing partial flow passes through.
- the recirculation-stabilizing partial flow could be directed parallel to the cone jacket of the fuel jet.
- the recirculation-stabilizing partial flow enters the combustion chamber essentially parallel to the direction of flow of the fuel jet.
- the stabilization of the recirculation flow can be achieved particularly advantageously with the simplest means with each setting of the fuel quantity and air quantity.
- the amount of fuel is adjustable.
- the recirculation-stabilizing partial flow can be adjusted with regard to the air quantity.
- the adjustability of the recirculation-stabilizing partial flow can be used in particular to achieve an advantageous stabilization of the recirculation flow at any burner output, since this partial flow acts directly on the formation of the recirculation flows and thus an adjustment of the same can be carried out in such a way that the recirculation flow due to the local entry of this partial flow into the Combustion chamber can be stabilized.
- the recirculation-stabilizing partial flow preferably enters the combustion chamber in the form of a ring flow interrupted in the circumferential direction around its fuel jet, as a result of which the stabilization of the recirculation flow is further improved, since "flow" through the ring flow in the radial direction is possible in a simple manner at the points of the interruption while stabilizing vortices are created between breaks.
- the air quantity in the recirculation-stabilizing partial flow is maximal at maximum fuel quantity and minimal with minimum fuel quantity, so that the air quantity of the recirculation-stabilizing partial flow is at maximum fuel quantity and thus largest Gas velocity of the flame also maintains sufficient recirculation flow for the flame to burn blue in the combustion chamber.
- the amount of air in the sub-stream close to the fuel jet is constant at all settings of the amount of fuel, so that the sub-stream close to the fuel jet always ensures a basic supply of the fuel jet with air.
- the amount of air in the partial stream near the fuel jet is dimensioned such that the maximum amount of fuel in the partial flow of the recirculation-stabilizing stream is maximum and with a minimum amount of fuel, the combustion air flow is formed only by the partial stream near the fuel jet.
- the amount of air in the sub-stream near the fuel jet is between about 0.6 times and about 0.2 times the amount of air of the maximum recirculation-stabilizing sub-stream, this being provided in particular for a burner whose
- Burner output can be varied by a factor of five.
- the fuel jet forms a pointed cone starting from a simply connected nozzle opening, in particular essentially a full cone, in which the most homogeneous possible droplets of the oil are distributed.
- An advantageous exemplary embodiment provides that the fuel-near partial flow is essentially parallel to the flow direction of the
- Fuel jet enters the combustion chamber.
- the partial stream near the fuel jet enters the fuel chamber flowing around the fuel jet in order to enable this part of the combustion air to be mixed well with the fuel jet in the combustion chamber.
- the cross section required for the partial flow near the fuel jet can be made available by the partial flow near the fuel jet flowing into the combustion chamber through a passage between the nozzle head and an edge of an inflow opening provided for the partial flow near the fuel jet, so that the size of the passage has the flow cross section for the partial stream close to the fuel jet.
- the inflow opening is provided with a swirl edge or a swirl cutting edge.
- the burner housing comprises a prechamber in which the nozzle is arranged and which is separated from the combustion chamber by the separating element.
- Such a construction of the burner housing has the advantage of great simplicity and high structural flexibility.
- combustion air flow enters the combustion chamber through the separating element.
- the separating element has an inflow opening facing the nozzle for the partial flow close to the fuel jet.
- the separating element has at least one radially external opening for the recirculation-stabilizing component relative to the inflow opening for the partial flow near the fuel jet
- An advantageous exemplary embodiment provides that the combustion chamber is enclosed by a flame tube of the burner, so that this flame tube of the burner permits a defined geometrical environment of the combustion chamber and thus in particular a defined configuration of the recirculation flows.
- this flame tube is preferably provided with openings for forming the external recirculation flow.
- combustion chamber extends from a plane which is close to the nozzle opening.
- Such training the Combustion chamber allows the individual recirculation flows, in particular the inner and the outer recirculation flow, to be optimally guided to the non-burning part of the fuel jet.
- a particularly simple and efficient design of the combustion chamber provides that it has an essentially constant cross section between the separating element and the area of the flame root. This has the advantage that there is sufficient space for guiding and forming the recirculation flows, in particular the inner recirculation flow.
- the separating element could be designed according to EP 0 430 011. However, it is structurally particularly simple if the separating element is an aperture.
- the aperture in turn could also be curved, as follows.
- the orifice extends in one plane, since such a shape of the orifice also allows optimal guidance of the recirculation flows to the non-burning part of the fuel jet in the area of the orifice.
- the combustion chamber has a non-burning part of the fuel jet and a recirculation space extending around it, which offers optimal possibilities for supplying the individual recirculation flows to the non-burning part of the fuel jet.
- the recirculation space is expediently designed such that it extends at least to the flame root in order to create sufficient space for the internal recirculation flow.
- the recirculation-stabilizing partial flow enters the recirculation space.
- the recirculation-stabilizing partial flow is preferably designed such that it enters the combustion chamber symmetrically to an axis of the combustion chamber and thus to an axis of the recirculation space.
- the recirculation-stabilizing partial flow is preferably designed such that it enters the combustion chamber in the form of a current pattern lying on a cylinder.
- This form of the recirculation-stabilizing partial flow enables a particularly optimal stabilization of the internal recirculation flow.
- the cylinder is designed as a circular cylinder which is defined by a partial circle lying in the center thereof.
- the component streams are arranged at a constant angular distance from one another in order to create defined spaces between the individual component streams through which the recirculation flows can pass.
- the ratio of the angular spacing between two component streams to the angular width of the inlet cross section of each component stream is between approximately 10 and approximately 0.1. It is more advantageous if this ratio is between approximately 3 and approximately 0.1, better between approximately 2 and approximately, 0.1, still better between approximately 1 and approximately 0.1, and it has proven particularly optimal if this ratio is in the range of about 1.5 to about 0.3.
- the circular ring region has a pitch circle diameter which lies in a range from approximately 0.2 to approximately 0.7 an outer diameter of the combustion chamber or the recirculation space
- a particularly optimal effect of the recirculation-stabilizing partial flow can be achieved if the recirculation space has an outer diameter, for example corresponding to the inner diameter of the flame tube, which is approximately 1.5 to 3 times larger than the diameter of the partial circle of the circular cylinder.
- the recirculation space has an outer diameter which is approximately 1.8 to approximately 2.6 times, more preferably approximately 2 to approximately 2.5 times, larger than the diameter of the pitch circle of the circular cylinder.
- the outer diameter of the recirculation space is approximately 2.4 ⁇ 10% as large, more optimally approximately 2.5 times as large as the pitch circle diameter.
- This flame chamber can have the same inner diameter as the recirculation chamber for large outputs, but it has proven advantageous in terms of spatial stabilization, in particular for small outputs, if the flame chamber has a diameter which is at most the same size or smaller than the recirculation chamber.
- the diameter of the flame space is in the range of approximately 0.6 to 0.9 times the diameter of the recirculation space. It is particularly advantageous if the inner diameter of the flame space is in the range of approximately 0.8 times the inner diameter of the recirculation space.
- This exemplary embodiment has the great advantage that the outer recirculation flow can be guided in a defined manner on the one hand and also defined in terms of the mass flow on the other hand, which is important for the aspects according to the invention, in particular the guidance of the outer recirculation flow to shield the inner recirculation flow from the separating element and the dimensioning of the
- Mass flow is important for reaching a sufficiently long non-burning part of the fuel jet. This also defines the volume for the internal recirculation flow.
- An advantageous exemplary embodiment provides that a maximum area of the openings provided for the entry of the combustion air flow into the combustion chamber corresponds approximately to the area of the recirculation openings provided in the flame tube for the external recirculation flow. With this dimensioning, a sufficiently large mass flow is guaranteed in the recirculation flow in order to obtain a sufficiently elongated part of the non-burning fuel jet in the combustion chamber.
- a flow stabilization element in the flame tube, which element extends from the diaphragm in the direction of a foot region of the flame to a maximum of approximately a quarter of the distance between the diaphragm and the flame.
- This flow stabilization element has nothing to do with the mixing tube known from the prior art, since the known mixing tube only permits the formation of a single recirculation flow, while the flow stabilization element according to the invention is also designed such that it permits the formation of several recirculation flows that can be defined by the recirculation-stabilizing partial flow, in particular the formation of the recirculation flows required for the respective fuel quantities and air quantities.
- the flow stabilizing element extends at most over approximately one sixth of the distance between the diaphragm and the foot region of the flame.
- the flow stabilization elements explained above are not absolutely necessary for the sufficient stabilization of recirculation flows and always create the risk of soot deposits in the burner.
- the combustion chamber is designed free of flow stabilization elements for recirculation arranged within it.
- combustion chamber - as already mentioned at the beginning - is designed without a mixing tube.
- An advantageous exemplary embodiment provides that an adjusting device is provided for adjusting the air quantity of the combustion air flow.
- the adjusting device is preferably designed such that when the amount of air is set, the location of the entry of the combustion air flow into the combustion chamber in the radial direction is essentially invariant to the fuel jet. This has the great advantage that by determining the location of the
- the adjusting device has locally fixed openings for the combustion air flow, which can be adjusted to different cross sections.
- the adjusting device comprises an adjusting element which is rotatably mounted on the diaphragm and with which the cross section of an opening provided in the diaphragm can be adjusted.
- the adjusting element is designed as an adjusting disk rotatably mounted on the diaphragm, which can be brought into different rotational positions relative to the diaphragm and to the openings provided in the diaphragm.
- this setting element can be designed in such a way that it can be set in different discrete setting positions.
- the setting element is continuously adjustable, so that the cross sections between a maximum value and a continuously
- the minimum value can be varied.
- the adjusting device can be designed such that it can be adjusted manually, for example with an appropriate tool.
- the setting device can be set via a controllable actuator.
- An advantageous exemplary embodiment provides that the nozzle is a return nozzle.
- Such a return nozzle can be adjusted particularly simply by assigning an adjustable return valve to it, which enables the return of the return nozzle to be variably adjusted and thus also the amount of fuel emitted by the nozzle.
- the return valve is designed in such a way that different amounts of fuel in the fuel jet can be set with it.
- the return valve is continuously adjustable, so that the fuel quantity can be continuously adjusted and adjusted.
- the return valve is adjustable by means of an actuator.
- the burner has a control with which the fuel quantity and the air quantity of the combustion air flow can be adjusted. With such a control, an optimal setting of both the amount of fuel and the amount of combustion air can be achieved, in particular in a simple manner
- controller controls the actuator of the return valve.
- controller controls the actuator of the adjusting device.
- Adjust the actuator for the other size it is particularly advantageous if the controller controls both the actuator of the return valve and the actuator of the adjusting device.
- control adjusts the air volume and the fuel volume according to a stoichiometric or near-stoichiometric combustion.
- control burner outputs can be predetermined.
- control burner outputs can be predetermined.
- Control burner outputs can be variably specified.
- a particularly advantageous exemplary embodiment provides that the control regulates the amount of fuel and the amount of air in accordance with a predetermined output on the one hand in accordance with this output and on the other hand with regard to stoichiometric or near-stoichiometric combustion.
- an advantageous exemplary embodiment provides that the amount of fuel can be adjusted in that the burner is designed as a kit with different nozzles that can be inserted into the same burner housing.
- the amount of fuel is adjusted by inserting the appropriate nozzle into the burner. It is preferably provided that the nozzles all have essentially the same spray pattern and in particular a substantially identical outer contour on the air flow side and only deliver different amounts of fuel.
- an advantageous embodiment regarding the adjustment of the air quantity provides that the air quantity is adjustable in such a way that the burner is designed as a kit with setting parts for the air quantity of the combustion air flow that can be interchangeably inserted into the same burner housing. By providing the different adjustment parts, an adjustment of the combustion air flow is possible.
- At least one partial flow of the combustion air flow can be set for all setting parts.
- a particularly advantageous exemplary embodiment provides that the partial flow near the fuel jet is constant in the setting parts, while the recirculation stabilizing one
- the kit comprises an identical burner housing for all burner outputs.
- Burner performance includes an identical fan.
- the kit comprises an identical combustion chamber.
- the kit comprises an identical nozzle assembly for all burner outputs.
- FIG. 1 shows a longitudinal section through a first embodiment of a burner according to the invention.
- FIG. 2 shows a partial longitudinal section through a nozzle of the burner according to the invention
- Fig. 3 is an enlarged view of a front area of the
- FIG. 4 shows a section along line IV-IV in FIG. 3;
- FIG. 5 shows a section along line V-V in FIG. 1 with the recirculation-stabilizing partial stream maximally or reduced to zero, with the adjusting disk partially broken away;
- FIG. 6 shows a section as in FIG. 5 with a reduced recirculation-stabilizing partial flow with the adjusting disk partially broken away;
- Fig. 7 shows a section as in Fig. 5 with minimal recirculation stabilizing. Partial flow
- FIG. 8 shows a perspective illustration of the conditions in the combustion chamber with the flame tube partially broken away
- Fig. 9 is an enlarged fragmentary representation of the in
- Fig. 1 shown section in the area of the aperture, with maximum recirculation stabilizing. Partial flow in the upper and reduced to zero minimal recirculation-stabilizing partial flow in the lower half;
- FIG. 10 shows a section similar to FIG. 1 of a second exemplary embodiment of the burner according to the invention
- 11 shows a section similar to FIG. 1 of a third exemplary embodiment of the burner according to the invention
- FIG. 12 shows a section similar to FIG. 1 of a fourth exemplary embodiment
- FIG. 13 shows a section similar to FIG. 1 of a fifth exemplary embodiment
- FIG. 14 shows a section similar to FIG. 1 of a sixth exemplary embodiment of the burner according to the invention.
- FIG. 16 shows a section as in FIG. 15 with the orifice used for a reduced recirculation-stabilizing partial flow
- FIG. 17 shows a section as in FIG. 15 with the orifice used for the minimal, recirculation-stabilizing partial flow reduced to zero.
- the burner shown in FIG. 1, comprises a burner housing, designated as a whole by 10, with a support tube 12 and a flame tube 14 adjoining this.
- a blower Arranged in the support tube 12 in an end region opposite the flame tube is a blower, designated as a whole, which comprises a blower drive 18 and a blower wheel 20.
- This fan 16 produces a
- a nozzle assembly designated as a whole by 24, which has a nozzle carrier 26 with a nozzle 28 screwed into it.
- the nozzle 28 is designed as a return nozzle described in detail below and is supplied with liquid fuel, in particular oil, via a nozzle feed line 30, while part of the fuel fed into the nozzle feed line 30 flows back again via a nozzle return line 32, throttling the return line via an adjustable return valve 34 arranged in the nozzle return line 32.
- the fuel is fed into the nozzle feed line 30 via a fuel feed pump 36, which is preferably also driven by the drive 18 of the blower 16, in particular on the same shaft as the blower wheel 20.
- This fuel feed pump 36 is fed with fuel via a pump feed line 38 and is also connected to a return line 40, in which excess fuel flows back from the fuel feed pump 36.
- the nozzle return line 32 after the return valve 34 also opens into this return line 40. 2, 3 and 4, the nozzle 28 comprises a nozzle head 50, which in turn is screwed onto a nozzle body 52 and receives a swirl body 54.
- the nozzle head 50 is in turn also screwed into the nozzle carrier 26 so that the nozzle body 52 lies in a recess 56 of the nozzle carrier 26, the recess 56 forming a fuel supply area 58 which is connected to the nozzle feed line 30 and a return area 60 which is connected to the nozzle return line 32 is connected.
- the fuel entering the fuel supply area 58 preferably flows through a filter 62 and then flows through two opposite inlet channels 64 of the nozzle body 52 into further inlet channels 66 in the swirl body 54 and from these, as shown in FIG. 3, into an annular inlet space 68 of the swirl body 54 , which is closed by a support plate 70 which closes the swirl body 54 on the end face.
- the fuel enters into a swirl space 74 located radially inside the annular inlet space 68, in which a swirl flow is formed which corresponds to the orientation of the swirl channels 72, and from this swirl space 72 the fuel passes through an annular circumferential gap 76 into a spray bore 78, from which a conical fuel jet 80 emerges.
- a return channel 82 in the swirl body 54 Opposed to the spray-out bore 78 is a return channel 82 in the swirl body 54, which passes through the swirl body 54 and merges into a return channel 84 arranged in the nozzle body 52, which then finally opens into the return area 60 of the recess 56, which in turn then in turn communicates with the nozzle return line 32 communicates.
- the nozzle assembly 24 together with the nozzle 28 is within the
- Support tube 12 arranged in a prechamber 48, which is also traversed by the air flow 22.
- the prechamber 48 is closed off by a diaphragm designated as a whole by 90 and inserted into the support tube 12, to which a combustion chamber 92 adjoins, which is located downstream of the nozzle 28 and is enclosed by the flame tube 14.
- the flame tube 14 is also preferably held on the support tube 12.
- the orifice 90 is arranged in such a way that the spray bore 78 with a nozzle opening is close to or in the plane 89 of the orifice 90 and the fuel jet 80 emerging at the nozzle 28 essentially spreads completely in the combustion chamber 92.
- the screen 90 is provided with an inflow opening 94 arranged coaxially to the longitudinal axis 86 of the nozzle 28.
- the inflow opening 94 is also selected to be large enough that between an edge 96 of the inflow opening 94 and an outer side 98 of the nozzle head 50 facing this edge 96 there remains an annular passage 100 through which a partial stream 102 close to the fuel jet, one overall from the antechamber 48, into the combustion chamber 92 incoming combustion air flow passes.
- the edge 96 of the inflow opening 94 is also provided with a vortex edge 104, which leads to the formation of eddies in the partial flow 102 and is formed, for example, by a step-like cross-sectional constriction of the inflow opening 94.
- Another partial flow 106 of the combustion air flow entering the combustion chamber 92 from the pre-chamber 48 passes through openings 110 arranged radially outside the inflow opening 94 in a circular ring area 108, which are preferably on the partial circle 109 at equal angular intervals and with spaces 111 around the center of the circular ring area 108 are arranged.
- the openings 110 preferably have an extension in the azimuthal direction with respect to the pitch circle 109 which corresponds to an angle which is approximately one to two times the angle corresponding to the extension of the spaces 111.
- the openings 110 can extend in the azimuthal direction over an angle which corresponds to approximately 0.1 to approximately 8 times the angle of the extension of the spaces 111.
- the openings 110 are arranged in such a way that the partial flow 106 of the combustion air flow enters the combustion chamber 92 through the spaces 111 between the openings 110 in the form of a flow pattern corresponding to a circumferentially interrupted ring flow and thus the formation of an inner recirculation flow 112 and also an outer flow Recirculation flow 119 in the combustion chamber 92 is stabilized so that a flame root 114 of a flame 116 formed in the combustion chamber 92 is at substantially the same distance from the orifice 90, irrespective of a quantity of fuel carried by the fuel jet 80 and a corresponding amount by the partial flows 102 and 106 corresponding amount of combustion air entering the combustion chamber 92.
- the flows according to the invention in the combustion chamber 92 thus include the partial flow 102 close to the fuel cone, which is cylindrically surrounding the fully conical fuel jet 80, which enters the combustion chamber 92 with a flow direction 103, which runs parallel to a flow direction 79 of the fuel jet 80. Furthermore, the recirculation-stabilizing partial flow 106 which has a flow direction 79 parallel flow direction 107 in the form of individual flows 105 enters the combustion chamber 92, the individual flows 105 lying on a circular cylinder which has the shape of the circular ring region 108 in cross section on the orifice 90 and is defined by the partial circle 109 lying in the middle of the jacket.
- the flame root 114 in turn adjoins a non-burning part 81 of the fuel jet 80, which has a length of approximately 1 to approximately 4 cm, preferably approximately 1 to approximately 3 cm, and from this the flame 116 spreads out, which spreads out creates an inner wall region 15 of the flame tube 14 before it leaves it.
- the area of the combustion chamber 92 from the orifice 90 to the inner wall area 15 on which the flame 116 contacts forms a so-called recirculation space 91.
- hot gas flows in the form of an internal recirculation 112 between the flame tube 14 and the partial flow 106 back in the direction to the aperture 90 and in front of the aperture 90 inwards between the individual streams 105 in the direction of the non-burning part 81 of the fuel jet 80 in order to heat the non-burning fuel on the way to the flame root 115 and also the combustion air.
- cold combustion gas exits the respective boiler in the form of the outer one via outer recirculation openings 118 arranged in the flame tube 14 after the orifice 90 Recirculation flow 119 into the recirculation space 91 close to the orifice and substantially prevents contact between the hot gases of the inner recirculation flow 112 and the cold orifice 90.
- the outer recirculation flow 118 also passes close to the blinding between the individual flows 105 and then mixes with the combustion air flow 102, 106 by the through the
- the sum of the areas of the openings provided for the entry of the combustion air flow into the combustion chamber is such that it is at most approximately the sum of the areas of the recirculation openings for the external recirculation, in particular the Sum of the areas of the outer recirculation openings 118 formed as elongated slots in the circumferential direction.
- the ratio of the area of the recirculation openings 118 to the area of the central inflow opening 94 is between approximately 0.3 to approximately 19.2, preferably between approximately 0.9 and 5.1.
- the flame chamber 117 then adjoins the recirculation chamber 91.
- the partial flow 102 near the fuel jet is preferably designed such that it stabilizes the corresponding recirculation flow without the recirculation-stabilizing partial flow 106 at the lowest burner output (FIG. 9 lower half) and then the recirculation-stabilizing partial flow in the case of large burner outputs 106 takes over the stabilization (FIG. 9 upper half) which the partial stream 102 near the fuel jet can no longer perform.
- the burner is dimensioned differently, it is also possible to provide both the partial flow 102 close to the fuel jet and a minimum partial flow 106 which stabilizes recirculation at the lowest power.
- Such stabilization of the recirculation flows 112 and 119 can be achieved in particular if an outer diameter of the recirculation space 91 of the combustion chamber 92, for example corresponding to the inner diameter of the flame tube, is approximately 1.5 to approximately 3.9 times, better still approximately two to three times of the diameter of a partial circle 109 of the annular region 108, it is even more advantageous if the inner diameter of the recirculation space 91 of the combustion chamber 92 is approximately 2.2 to approximately 2.6 times, more preferably approximately 2.2 to approximately 2, 5 times the diameter of the pitch circle 109.
- the diameter of the central inflow opening 94 is between approximately 1.0 and approximately 4.2, preferably approximately 2.6 to approximately 4.0, more preferably approximately 2.8 to approximately 3.5 and preferably between approximately 1.82 and approximately 2.0 .
- the central inflow opening 94 is dimensioned such that an outer diameter of the recirculation space 91 of the combustion chamber 92 is approximately 3.4 to approximately 8.5 times, more preferably approximately 4 to approximately 6 times, even better is about 4.4 to about 5.9 times the diameter of the central inflow opening 94.
- an adjusting device designated as a whole by 120, which, as shown in FIGS. 5 to 7, comprises an annular adjusting disc 122 which has openings 124 identical to the openings 110, which also in FIG the same angular distances as the openings 110 and at the same radial distance from a center of the annular region 108.
- the annular adjusting disk 122 lies, as shown enlarged in FIG. 9, in a cylindrical disk-shaped depression 126 provided in the diaphragm 90, which is open to the antechamber 48.
- the rotatable guidance of the shim takes place via the
- the shim 122 is adjustable so that, as shown in FIGS. 5 to 7, either the openings 124
- the partial flow 106 can be completely interrupted, namely when the openings 124 are at a gap between the openings 110.
- a toothing 132 in which a toothing 134 of an adjusting pinion of the adjusting device 120, designated as a whole by 136, engages.
- This adjusting pinion is in turn rotatably mounted on the diaphragm 90, and in the simplest case in a further cylindrical bearing recess 138 in the diaphragm 90, the rotatable bearing being in contact with the toothing 134 on cylindrical wall surfaces 140
- Storage deepening 138 takes place.
- the bearing recess 138 opens towards the antechamber 48.
- Both the adjusting disk 122 and the adjusting pinion 136 are held in their respective recesses 126 and 138 by fixing elements (not shown in FIG. 9), so that they each abut the recesses on the bottom side.
- the setting pinion 136 is, for example, self-lockingly mounted in the bearing recess 138 and is provided, for example, with a slot 142, which makes it possible to turn the setting pinion 136 using a conventional screwdriver, so that setting the setting disks 122 is also possible, the respective settings of the shims 122 are maintained by the self-locking adjustment pinion 136.
- the first embodiment now works such that when the partial flow 106 is interrupted, only the combustion air flowing from the partial flow 102 through the passage 100 into the combustion chamber 92 is available as combustion air quantity.
- the amount of fuel emitted from the nozzle 28 into the fuel jet 80 is adjusted in accordance with this amount of air, the amount of fuel being adjusted so that the flame 116 burns blue and stoichiometric or near-stoichiometric combustion occurs.
- This adjustment of the fuel quantity takes place via the adjustment of the return valve 34 and thus via the fuel flow returning from the nozzle 28 via the nozzle return line 32 into the return line 40.
- the sub-stream 106 can also contribute to the sub-stream 102 of the combustion air stream close to the fuel jet, this sub-stream 106 having the higher burner outputs
- Recirculation flow 112 additionally stabilized. With the maximum amount of combustion air in the partial flow 106, approximately 5 times the cross-sectional area is available for the entry of the combustion air flow from the pre-chamber 48 into the combustion chamber 92 than with a completely prevented partial flow 106.
- the amount of fuel discharged from the nozzle 28 into the fuel jet 80 is adjusted by the aforementioned setting of the return valve 34 with a corresponding throttling of the fuel returning from the nozzle 28.
- the distance between the flame root 114 of the flame 116 and the diaphragm 90 is essentially constant and it is a blue burning of the flame 116 with essentially stoichiometric or at all power settings of the burner
- a flow guide ring 150 is provided in the second exemplary embodiment, which is arranged at a distance from the orifice 90, and with its front edge 152 up to a maximum of up to a quarter a distance between the aperture 90 and the foot portion 114 of the flame 116 extends. Furthermore, the flow guide ring 150 is arranged with a rear edge 154 facing the orifice 90 at a distance from the orifice 90, so that the recirculation flow 112 between the in the edge 154 and a front side 156 of the orifice 90 from rarely the orifice 90 in the flow guide ring 150 can occur.
- the Flow ring 150 also serves to additionally stabilize the recirculation flow 112, a significant distance between the front edge 152 and the foot region 114 of the flame 116 being necessary in order to ensure the formation of a strong recirculation flow 112 when the burner according to the invention has different power ratings and to support the effect of the recirculation-stabilizing partial flow 106.
- the flow guide ring 150 is preferably held on the orifice 90 with webs 158.
- a third exemplary embodiment of a burner according to the invention shown in FIG. 11, those parts which are identical to the first exemplary embodiment are provided with the same reference numerals, so that with regard to the description of these parts, full reference can also be made to the embodiment of the first exemplary embodiment .
- an actuator 160 is provided for the setting of the return valve 34 and an actuator 162 for the setting of the setting pinion 136, both of which can be controlled via a common controller 164.
- This control 164 is preconfigured via an input 166 power settings of the burner according to the invention, the control 164 for each power setting at the input 166 the corresponding setting of Return valve 34 and the actuator 162 of the adjusting device 120 performs. For example, this can be carried out by positions of the actuators 160 and 162 which can be predetermined in a memory of the controller 164.
- Lambda probe 168 arranged in the exhaust gas flow of the flame 116 which is also connected to the controller 164, so that the controller 164, after rough adjustment of the power via the actuators 160 and 162, is additionally able to carry out a fine adjustment of either the amount of combustion air or the amount of fuel, to maintain stoichiometric or near stoichiometric combustion conditions.
- control 164 is constructed in such a way that the desired outputs of the burner according to the invention can be set by means of a setting transmitter, for example manually.
- control 164 is designed in such a way that, via an overall control of a system, for example a heating system, in which the burner according to the invention is integrated, a specification is made for the required output of the burner according to the invention, so that the control 164 then, depending on the requested output of the burner according to the invention, the actuators 160 and 162 are adjusted accordingly and a fine adjustment on the basis of the measured values of the
- Lambda probe 168 carries out.
- the flame tube 14 is narrowed radially over its length in the region of the flame chamber 117 following the recirculation chamber 91 up to the front end 170, so that the inner wall region 15 against which the flame 116 rests is already radially offset inwards.
- This flame tube makes it possible, particularly with small burner outputs, preferably less than 20 kW, to obtain a flame 116 which is stable in the flame tube 14. Furthermore, this geometry prevents undesired drawing in of smoke gases from the front end of the flame tube 14.
- the openings 110 are closed by means of conical plugs 172 which are held on rods 174 and are movably guided in the axial direction of the support tube 12 via a guide 176 on the nozzle assembly 24 in the support tube 12.
- a reduction in the cross-sectional area of each opening 110 is possible.
- a power setting is also possible in the sixth exemplary embodiment, shown in FIGS. 14 to 17, but in this exemplary embodiment the burner according to the invention is constructed in the form of a kit.
- a nozzle 28 designed as a return nozzle with a nozzle return line 32 and a return valve 34 provided therein for adjusting the fuel flow
- a set of several nozzles 228 are provided, each of which has the same spray pattern and the same air flow side Deliver outer contour and thus the same shape of the fuel jet 80, but with different amounts of fuel.
- the fuel is supplied via the fuel feed pump 36 and the nozzle feed line 30, but a nozzle return line 32 is unnecessary.
- the different nozzles 228 correspond to different outputs of the burner according to the invention.
- the orifices 290a to c differ in the cross section of the openings 210 provided for the partial flow 106, but not with regard to their position, the openings 210a being identical to the openings 110 with regard to the total cross section of the openings, while the openings 210b show a total cross section which corresponds to an intermediate setting, for example shown in FIG. 6, and thus also an intermediate output of the corresponding nozzle 228.
- the openings 210 are completely absent from the orifice 290c, so that this corresponds to the position of the adjusting device 120 shown in FIG. 7, in which the partial flow 106 is completely prevented and the combustion air flow is formed only by the partial flow 102.
- one of the orifices 290a to 290c is to be installed in the support tube 12, the orifices 190 being removably held in the support tube in the fourth exemplary embodiment.
- a holding ring 292 is used, for example, on the nozzle assembly 24
- Tripod 294 held, which acts on the respective panel 290 on its side facing the pre-chamber 48 296 and presses it against a sealing ring 298 in the direction of the flame tube 14.
- the nozzle assembly 26 as a whole is displaceable in the direction of a longitudinal axis 300 of the support tube 12 and is acted upon by a spring (not shown in FIG. 14) in the direction of the flame tube 12. It is thus possible to remove the diaphragm 290 in the direction of the prechamber 48, while the diaphragm 290 is fixed in the direction of the flame tube 14 by the abutment, for example designed as a sealing ring 298.
- the combustion chamber 92 is designed free of mechanical flow guiding elements, so that when the nozzle 228 corresponding to the respective power and the respective orifice 290 are installed, a stable design is likewise formed the appropriate recirculation flow 112 is ensured and it is also ensured that the flame 116 as a blue-burning flame delivers a stoichiometric or near-stoichiometric combustion. Furthermore, a function corresponding to the first exemplary embodiment is ensured by the cross sections of the openings 210 correspondingly provided for the partial flow 106.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Pressure-Spray And Ultrasonic-Wave- Spray Burners (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00111167A EP1030106B1 (en) | 1993-12-18 | 1994-12-17 | Blue-flame burner with optimized combustion characteristics |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4343430 | 1993-12-18 | ||
DE4343430 | 1993-12-18 | ||
DE4430889 | 1994-08-31 | ||
DE4430889A DE4430889A1 (en) | 1993-12-18 | 1994-08-31 | Combustion-optimized blue burner |
PCT/EP1994/004204 WO1995016882A1 (en) | 1993-12-18 | 1994-12-17 | Blue-flame burner with optimized combustion characteristics |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00111167.3 Division-Into | 2000-05-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0683883A1 true EP0683883A1 (en) | 1995-11-29 |
EP0683883B1 EP0683883B1 (en) | 2001-02-28 |
Family
ID=25932245
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95905077A Expired - Lifetime EP0683883B1 (en) | 1993-12-18 | 1994-12-17 | Blue-flame burner with optimized combustion characteristics |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0683883B1 (en) |
AT (2) | ATE199451T1 (en) |
DK (1) | DK0683883T3 (en) |
ES (1) | ES2154722T3 (en) |
GR (1) | GR3035908T3 (en) |
PT (1) | PT683883E (en) |
WO (1) | WO1995016882A1 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10254664B3 (en) * | 2002-11-23 | 2004-03-04 | Buderus Heiztechnik Gmbh | Liquid fuel burner has housing with support pipe, combustion chamber, fuel jet, separating element with central opening, current recirculating and stabilizing parts |
DE10327391B3 (en) | 2003-06-18 | 2004-12-16 | Bbt Thermotechnik Gmbh | Mixer unit for a gas- or oil-fired central heating burner has chamber with a fuel supply harmonisation unit with numerous fine apertures |
DE10348272B3 (en) * | 2003-10-17 | 2005-02-03 | Bbt Thermotechnik Gmbh | Mixing device for oil or gas burner has guide element downstream of diaphragm, by which exhaust gas is directed to diaphragm |
DE10349836B3 (en) * | 2003-10-25 | 2005-04-14 | Bbt Thermotechnik Gmbh | Mixer for air and oil or gas in a burner has throttle formed by annular gap |
DE102004009787B3 (en) * | 2004-02-28 | 2005-08-11 | Bbt Thermotechnik Gmbh | Mixing device for oil or gas fan burner has burner tube with endface against surface on endface of support tube |
DE102004021093B3 (en) * | 2004-04-29 | 2005-08-04 | Bbt Thermotechnik Gmbh | Oil or gas burner for boiler has flame tube serving as ionization electrode and electrically insulated from other components |
DE102005020664B4 (en) * | 2005-05-07 | 2008-11-06 | Robert Bosch Gmbh | Burner for liquid fuels |
DE102005026649A1 (en) * | 2005-06-09 | 2006-12-28 | Robert Bosch Gmbh | Burner for liquid fuels |
DE102006049294A1 (en) * | 2006-10-19 | 2008-04-24 | Robert Bosch Gmbh | Mixing device for e.g. oil burner, has face plate including central flow opening arranged coaxial to fuel nozzle for combustion air, where inner combustion air stream surrounds fuel nozzle via flow opening |
DE102007059063B3 (en) * | 2007-12-07 | 2009-04-30 | Robert Bosch Gmbh | Modulating oil burner, has induced draft fan arranged in exhaust pipe, and chamber for formation of aerosol provided upstream of burner surface, where primary air flows into chamber, and oil is injected into chamber by nozzle |
DE202009014953U1 (en) | 2009-08-29 | 2010-10-21 | Robert Bosch Gmbh | Mixing device for an oil burner |
DE102013100990A1 (en) * | 2013-01-31 | 2014-07-31 | Mhg Heiztechnik Gmbh | burner housing |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3109988A1 (en) * | 1981-03-14 | 1982-12-02 | Klaus 2000 Hamburg Eckloff | Gasifier-type oil burner |
JPH0232531B2 (en) * | 1984-05-01 | 1990-07-20 | Korona Kk | EKITAINENRYONENSHOSOCHI |
FR2582781A1 (en) * | 1985-06-04 | 1986-12-05 | Mueller Rudolf | BURNER FOR LIQUID COMBUSTION BOILER WITH COMBUSTION GAS RECYCLING CIRCUIT |
WO1992020964A1 (en) * | 1991-05-24 | 1992-11-26 | Sci Mercimmo | Method of burning fuel to produce low pollutant emissions |
DE4201060C2 (en) * | 1992-01-17 | 1994-07-14 | Man B & W Diesel Ag | Burner for gasified liquid fuel |
DE59303606D1 (en) * | 1992-02-28 | 1996-10-10 | Fuellemann Patent Ag | Burners, in particular oil burners or combined oil / gas burners |
DE4209221A1 (en) * | 1992-03-21 | 1993-09-23 | Deutsche Forsch Luft Raumfahrt | LOW-NITROXIDE BURNER |
-
1994
- 1994-12-17 WO PCT/EP1994/004204 patent/WO1995016882A1/en active IP Right Grant
- 1994-12-17 ES ES95905077T patent/ES2154722T3/en not_active Expired - Lifetime
- 1994-12-17 PT PT95905077T patent/PT683883E/en unknown
- 1994-12-17 AT AT95905077T patent/ATE199451T1/en active
- 1994-12-17 AT AT00111167T patent/ATE283449T1/en active
- 1994-12-17 EP EP95905077A patent/EP0683883B1/en not_active Expired - Lifetime
- 1994-12-17 DK DK95905077T patent/DK0683883T3/en active
-
2001
- 2001-05-22 GR GR20010400762T patent/GR3035908T3/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9516882A1 * |
Also Published As
Publication number | Publication date |
---|---|
ATE199451T1 (en) | 2001-03-15 |
EP0683883B1 (en) | 2001-02-28 |
ES2154722T3 (en) | 2001-04-16 |
GR3035908T3 (en) | 2001-08-31 |
PT683883E (en) | 2001-08-30 |
ATE283449T1 (en) | 2004-12-15 |
DK0683883T3 (en) | 2001-06-25 |
WO1995016882A1 (en) | 1995-06-22 |
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