EP0638116B1 - Non-staining solid lubricants - Google Patents
Non-staining solid lubricants Download PDFInfo
- Publication number
- EP0638116B1 EP0638116B1 EP90916328A EP90916328A EP0638116B1 EP 0638116 B1 EP0638116 B1 EP 0638116B1 EP 90916328 A EP90916328 A EP 90916328A EP 90916328 A EP90916328 A EP 90916328A EP 0638116 B1 EP0638116 B1 EP 0638116B1
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- EP
- European Patent Office
- Prior art keywords
- lubricant
- film
- metal
- saturated aliphatic
- aliphatic monohydric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/10—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M105/12—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms monohydroxy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/68—Esters
- C10M129/70—Esters of monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/06—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing butene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/02—Natural products
- C10M159/06—Waxes, e.g. ozocerite, ceresine, petrolatum, slack-wax
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/14—Synthetic waxes, e.g. polythene waxes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/17—Fisher Tropsch reaction products
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/0215—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/284—Esters of aromatic monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
Definitions
- the present invention relates to non-staining solid lubricants suitable for use in metal working operations, for instance in cold-rolling, drawing or extrusion of metals, especially aluminium.
- Lubricants usually liquid lubricants, are used in metal working operations to reduce friction between the surface of metal being worked and a surface of the apparatus carrying out the operation.
- a liquid lubricant reduces friction by separating the two surfaces with a thin fluid film having little resistance to shear.
- the pressure between a surface of the metal being worked and a surface of the apparatus is so great that the fluid film of a liquid lubricant may be squeezed out so allowing actual metal-to-metal contact with the result that excessive damage to the surfaces may occur.
- Solid film lubricants having much greater load bearing properties have been developed to overcome this and other disadvantages associated with liquid lubricants.
- a lubricant may be expected to fulfil certain other requirements if it is to be useful industrially. For instance, it should be easy to apply and easy to remove, it should afford some protection to the metal surface during handling and storage, it should present no health hazard to persons coming into contact with it and, obviously, should be inert to the surfaces with which it comes into contact. Many lubricants produce severe stains on the surface of the metal during annealing thereof. It is, therefore, highly desirable to avoid such staining by using a lubricant having the properties demanded by the particular conditions under which the lubricated metal is to be worked and which is also non-staining.
- the present invention is based on the discovery that a solid film of one or more saturated aliphatic monohydric alcohols having from 14 to 18 carbon atoms provided on the surface of the metal being worked has good lubrication characteristics under cold-working conditions and can be removed by heating to leave substantially no stain on the metal surface.
- the present invention provides a method of cold forming a metal workpiece comprising providing on the surface of the workpiece to be subjected to forming a film of a lubricant, subjecting the workpiece to a forming operation and removing the film of lubricant from the metal surface characterised in that the lubricant film comprises a solid film of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms and in that the lubricant film is removed from the metal surface without causing staining by the application of heat thereto.
- the present invention further provides the use of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms as a solid lubricant in the cold working of a metal workpiece removed from the surface of the metal by heating without staining.
- the present invention also provides the use of a composition comprising a solution of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms in an inert volatile organic solid as a lubricant film-forming agent in the cold working of a metal workpiece to form a film of solid 14-18 C saturated aliphatic monohydric alcohol lubricant on the workpiece surface removed from the metal surface by heating without staining.
- a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms.
- Such alcohols have good lubricating and load-supporting properties, are solid at room temperatures (20-25°C) and may be, at worst, only slightly staining or, at best, totally non-staining.
- these alcohols include myristyl alcohol, cetyl alcohol and stearyl alcohol. Commercial purity compounds may be used and these generally contain proportions of higher and/or lower homologues as impurities.
- Cetyl alcohol (hexadecanol) is highly preferred for use in the present invention in view of its melting point ( ⁇ 49°C) and because of its excellent non-staining property.
- the 14-18C saturated aliphatic monohydric alcohol lubricant is applied to the surface of the metal workpiece by dip coating the workpiece in a solution of the alcohol lubricant in an inert volatile organic solvent. After removal of the volatile solvent by evaporation a film of the solid alcohol remains on the surface of the workpiece. It is possible that the film obtained in this way may not be of uniform thickness; the deposited alcohol lubricant being thicker in some regions than in other regions of the surface of the workpiece. We have observed, however, that in such cases where the thickness of the deposited film of solid alcohol is non-uniform the film flows at the point where pressure is applied to the workpiece during working thereof, e.g. at the die in a metal drawing operation or at the press platen in a metal pressing operation, with the result that the workpiece becomes evenly covered at the point of working.
- the 14-18C saturated aliphatic monohydric alcohol is dissolved in an inert volatile organic solvent.
- any organic solvent for the alcohol which is liquid at normal room temperature but which evaporates at a temperature just above that and which is inert to both the alcohol and the metal surface may be used.
- suitable solvents include diethyl ether, methanol and benzene and chlorinated hydrocarbons, such as trichloroethylene and 1,1,1-trichloroethane.
- the concentration of the 14-18C alcohol in the volatile organic solvent is not critical and, in principle, any concentration up to the solubility limit of the particular solvent may be used. Typically, the concentration of alcohol in the organic solvent will be about 10% by weight.
- a liquid polybutene may be incorporated in an amount of up to 10% by weight of the total weight of the lubricant composition (excluding solvent) to modify the film properties of the lubricant on the surface of the workpiece and the flow characteristics of the lubricant film during the deformation without causing staining of the metal surface on annealing.
- liquid polybutene tends to soften any film containing it and the 14-18 saturated aliphatic monohydric alcohol and, therefore, if more than 10% by weight of the liquid polybutene is used the lubricant film obtained on the surface of the workpiece may become tacky and rather unstable.
- Any liquid polybutene may be used according to this embodiment of the invention.
- Liquid polybutenes are available commercially under the name Hyvis ("Hyvis is a registered trademark), for example Hyvis 200, having a molecular mass (number average) of 2400 and a Kinematic viscosity of 4300 cSt at 98.9°C.
- the non-staining solid lubricant according to the present invention may contain a small amount of a solid or semiliquid (e.g. gelatinous) alkane species or mixture of alkane species which does not leave a staining residue on annealing, for example petroleum jelly (petrolatum), to modify the film properties of the lubricant.
- a solid or semiliquid (e.g. gelatinous) alkane species or mixture of alkane species which does not leave a staining residue on annealing for example petroleum jelly (petrolatum)
- Such an alkane-based film modifier may be used together with or as an alternative to the liquid polybutene mentioned above.
- any alkane-based film modifier if used will be used in an amount such that the combined weight of alkane-based film modifier and any liquid polybutene does not represent more than 10% of the weight of the total lubricant composition (excluding solvent).
- an (liquid) ester e.g. butyl stearate, methyl laurate or methyl myristate
- the ester may be used in an amount not exceeding 10% by weight based on the total weight of the lubricant (excluding solvent) and would be incorporated as an alternative to an equivalent amount of liquid polybutene. We refer, however, not to use more than about 1% by weight of the ester.
- the solid lubricant after evaporation of the volatile carrier solvent, forms a tenaceous film on the surface of a metal workpiece.
- a typical lubricant coverage would be less than about 10gm -2 .
- the lubricant solution will be applied to a metal surface to provide about 5g of solid lubricant per square metre of surface.
- the solid film lubricant does not require removal prior to annealing the metal since the component(s) of the solid lubricant, i.e. the alcohol and any optionally present polybutene, petroleum jelly and/or butyl stearate, will evaporate from or decompose on the metal surface cleanly without staining.
- the component(s) of the solid lubricant i.e. the alcohol and any optionally present polybutene, petroleum jelly and/or butyl stearate
- a series of disc compression tests was carried out using various lubricants.
- an aluminium disc having a diameter of 32mm and a thickness of 5mm was dipped into a solution of the lubricant under test in a volatile organic solvent so that both the upper and the lower surfaces of the disc were coated with the lubricant solution.
- the coated disc was then left until the organic solvent had evaporated to leave a coating of lubricant on the aluminium surface.
- Each disc was subjected to pressing at 5.6 x 10 7 kg m -2 over a period of 30 seconds and the thickness of the disc was then measured.
- the test was carried out 5 times for each lubricant and the mean reduction (%) was calculated.
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- Lubricants (AREA)
Abstract
Description
- The present invention relates to non-staining solid lubricants suitable for use in metal working operations, for instance in cold-rolling, drawing or extrusion of metals, especially aluminium.
- Lubricants, usually liquid lubricants, are used in metal working operations to reduce friction between the surface of metal being worked and a surface of the apparatus carrying out the operation. A liquid lubricant reduces friction by separating the two surfaces with a thin fluid film having little resistance to shear. In many metal working operations the pressure between a surface of the metal being worked and a surface of the apparatus is so great that the fluid film of a liquid lubricant may be squeezed out so allowing actual metal-to-metal contact with the result that excessive damage to the surfaces may occur. Solid film lubricants having much greater load bearing properties have been developed to overcome this and other disadvantages associated with liquid lubricants.
- In addition to its lubrication characteristics, a lubricant may be expected to fulfil certain other requirements if it is to be useful industrially. For instance, it should be easy to apply and easy to remove, it should afford some protection to the metal surface during handling and storage, it should present no health hazard to persons coming into contact with it and, obviously, should be inert to the surfaces with which it comes into contact. Many lubricants produce severe stains on the surface of the metal during annealing thereof. It is, therefore, highly desirable to avoid such staining by using a lubricant having the properties demanded by the particular conditions under which the lubricated metal is to be worked and which is also non-staining.
- The present invention is based on the discovery that a solid film of one or more saturated aliphatic monohydric alcohols having from 14 to 18 carbon atoms provided on the surface of the metal being worked has good lubrication characteristics under cold-working conditions and can be removed by heating to leave substantially no stain on the metal surface.
- The present invention provides a method of cold forming a metal workpiece comprising providing on the surface of the workpiece to be subjected to forming a film of a lubricant, subjecting the workpiece to a forming operation and removing the film of lubricant from the metal surface characterised in that the lubricant film comprises a solid film of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms and in that the lubricant film is removed from the metal surface without causing staining by the application of heat thereto.
- The present invention further provides the use of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms as a solid lubricant in the cold working of a metal workpiece removed from the surface of the metal by heating without staining. The present invention also provides the use of a composition comprising a solution of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms in an inert volatile organic solid as a lubricant film-forming agent in the cold working of a metal workpiece to form a film of solid 14-18 C saturated aliphatic monohydric alcohol lubricant on the workpiece surface removed from the metal surface by heating without staining.
- According to the invention, use is made of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms. Such alcohols have good lubricating and load-supporting properties, are solid at room temperatures (20-25°C) and may be, at worst, only slightly staining or, at best, totally non-staining. Examples of these alcohols include myristyl alcohol, cetyl alcohol and stearyl alcohol. Commercial purity compounds may be used and these generally contain proportions of higher and/or lower homologues as impurities. Cetyl alcohol (hexadecanol) is highly preferred for use in the present invention in view of its melting point (∼49°C) and because of its excellent non-staining property.
- Typically, the 14-18C saturated aliphatic monohydric alcohol lubricant is applied to the surface of the metal workpiece by dip coating the workpiece in a solution of the alcohol lubricant in an inert volatile organic solvent. After removal of the volatile solvent by evaporation a film of the solid alcohol remains on the surface of the workpiece. It is possible that the film obtained in this way may not be of uniform thickness; the deposited alcohol lubricant being thicker in some regions than in other regions of the surface of the workpiece. We have observed, however, that in such cases where the thickness of the deposited film of solid alcohol is non-uniform the film flows at the point where pressure is applied to the workpiece during working thereof, e.g. at the die in a metal drawing operation or at the press platen in a metal pressing operation, with the result that the workpiece becomes evenly covered at the point of working.
- To form the lubricant coating composition, the 14-18C saturated aliphatic monohydric alcohol is dissolved in an inert volatile organic solvent. Generally, any organic solvent for the alcohol which is liquid at normal room temperature but which evaporates at a temperature just above that and which is inert to both the alcohol and the metal surface may be used. Examples of suitable solvents include diethyl ether, methanol and benzene and chlorinated hydrocarbons, such as trichloroethylene and 1,1,1-trichloroethane. The concentration of the 14-18C alcohol in the volatile organic solvent is not critical and, in principle, any concentration up to the solubility limit of the particular solvent may be used. Typically, the concentration of alcohol in the organic solvent will be about 10% by weight.
- According to the present invention, it is possible to incorporate certain amounts of other substances in the lubricating film of 14-18C saturated aliphatic monohydric alcohol in order to modify the properties of the film. For instance, a liquid polybutene may be incorporated in an amount of up to 10% by weight of the total weight of the lubricant composition (excluding solvent) to modify the film properties of the lubricant on the surface of the workpiece and the flow characteristics of the lubricant film during the deformation without causing staining of the metal surface on annealing. The use of the liquid polybutene tends to soften any film containing it and the 14-18 saturated aliphatic monohydric alcohol and, therefore, if more than 10% by weight of the liquid polybutene is used the lubricant film obtained on the surface of the workpiece may become tacky and rather unstable. Any liquid polybutene may be used according to this embodiment of the invention. Liquid polybutenes are available commercially under the name Hyvis ("Hyvis is a registered trademark), for example Hyvis 200, having a molecular mass (number average) of 2400 and a Kinematic viscosity of 4300 cSt at 98.9°C.
- The non-staining solid lubricant according to the present invention may contain a small amount of a solid or semiliquid (e.g. gelatinous) alkane species or mixture of alkane species which does not leave a staining residue on annealing, for example petroleum jelly (petrolatum), to modify the film properties of the lubricant. Such an alkane-based film modifier may be used together with or as an alternative to the liquid polybutene mentioned above. Generally, any alkane-based film modifier if used will be used in an amount such that the combined weight of alkane-based film modifier and any liquid polybutene does not represent more than 10% of the weight of the total lubricant composition (excluding solvent). We have further found that the incorporation of an (liquid) ester, e.g. butyl stearate, methyl laurate or methyl myristate, in the 14-18C saturated aliphatic monohydric alcohol lubricant film tends to aid the production of a uniform film and also tends to soften the film. This tendency to soften the film is an additional advantage in the case where the lubricant also contains a polybutene additive since it makes it easier for the polybutene-containing lubricant to be removed from surfaces (including hands). If used, the ester may be used in an amount not exceeding 10% by weight based on the total weight of the lubricant (excluding solvent) and would be incorporated as an alternative to an equivalent amount of liquid polybutene. We refer, however, not to use more than about 1% by weight of the ester.
- The solid lubricant, after evaporation of the volatile carrier solvent, forms a tenaceous film on the surface of a metal workpiece. A typical lubricant coverage would be less than about 10gm-2. Preferably, however, the lubricant solution will be applied to a metal surface to provide about 5g of solid lubricant per square metre of surface.
- After deformation etc. of the workpiece the solid film lubricant does not require removal prior to annealing the metal since the component(s) of the solid lubricant, i.e. the alcohol and any optionally present polybutene, petroleum jelly and/or butyl stearate, will evaporate from or decompose on the metal surface cleanly without staining.
- An aluminium tube was dipped in a 10% w/w solution of cetyl alcohol in trichloroethylene and then allowed to dry. The coated tube was passed four times through a drawing machine. After each pass, the tube was annealed by heating to 400°C, with no prior degreasing and no staining and then re-dipped in the cetyl alcohol solution. The following Table 1 shows the outside and inside diameters of the tube, the percentage reduction in the cross sectional area, and the length of the tube after each pass. The reductions are set by the size of the die used, which is why they are variable. However, the final reduction of 23% is excellent and the tube after the final pass showed no surface staining.
Outside diameter Inside diameter % Reduction Length (mm) (mm) (m) Initial dimensions of tube 293.0 275.4 - 3 After 1st pass 287.3 272.6 21 3.6 After 2nd pass 283 269.9 12.4 4.2 After 3rd pass 278 267.2 19 5.2 After 4th pass 273.8 265.4 23 6.8 - A series of disc compression tests was carried out using various lubricants. In each case, an aluminium disc having a diameter of 32mm and a thickness of 5mm was dipped into a solution of the lubricant under test in a volatile organic solvent so that both the upper and the lower surfaces of the disc were coated with the lubricant solution. The coated disc was then left until the organic solvent had evaporated to leave a coating of lubricant on the aluminium surface. Each disc was subjected to pressing at 5.6 x 107 kg m-2 over a period of 30 seconds and the thickness of the disc was then measured. The test was carried out 5 times for each lubricant and the mean reduction (%) was calculated. Each lubricated disc was annealed at 400°C and checked for any staining. The results are shown below in Table 2.
Lubricant Reduction (%) Staining of Metal Surface on annealing (400°C) Mean Std.deviation 'Batoyl' 49.9 0.77 heavy dark stain 'Silkolene' 48.4 0.33 heavy dark stain 100% cetyl alcohol 56.7 0.55 none 90% cetyl alcohol 60.9 0.61 none 10% petroleum jelly 75% cetyl alcohol 59.5 0.62 none 25% petroleum jelly
Claims (14)
- A method of cold working a metal workpiece comprising providing on the surface of the workpiece to be subjected to forming a film of a lubricant, subjecting the workpiece to a forming operation and removing the film of lubricant from the metal surface characterised in that the lubricant film comprises a solid film of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms and in that the lubricant film is removed from the metal surface without causing staining by the application of heat thereto.
- A method according to claim 1, wherein the solid lubricant film is caused to flow on the metal surface at a point where pressure, due to the forming operation, is applied.
- A method according to either claim 1 or claim 2, wherein the saturated aliphatic monohydric alcohol is cetyl alcohol.
- A method according to any one of claims 1 to 3, wherein the lubricant further contains from 1 to 10% by weight of the total weight of the lubricant of a polybutene, petroleum jelly or butyl stearate.
- The use of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms as a solid lubricant in the cold working of a metal workpiece removed from the surface of the metal by heating without staining.
- The use according to claim 5, wherein the saturated aliphatic monohydric alcohol is cetyl alcohol.
- The use according to either claim 5 or claim 6, wherein the lubricant also contains from 1 to 10% by weight of the total weight of the lubricant of a polybutene, petroleum jelly or butyl stearate.
- The use of a composition comprising a solution of a saturated aliphatic monohydric alcohol having from 14 to 18 carbon atoms in an inert volatile organic solid as a lubricant film-forming agent in the cold working of a metal workpiece to form a film of solid 14-18 C saturated aliphatic monohydric alcohol lubricant on the workpiece surface removed from the metal surface by heating without staining.
- The use according to claim 8, wherein the saturated aliphatic monohydric alcohol is cetyl alcohol.
- The use according to either claim 8 or claim 9, wherein the inert volatile organic solvent is selected from trichloroethylene and 1,1,1 -trichloroethane.
- The use according to any one of claims 8 to 10, wherein the solution contains about 10% by weight of the saturated aliphatic monohydric alcohol.
- The use according to any one of claims 8 to 11, wherein the solution additionally contains a material selected from a polybutene, petroleum jelly and butyl stearate in an amount of from 1 to 10% by weight based on the combined weight of the saturated aliphatic monohydric alcohol and the said material.
- The use according to any one of claims 5 to 12, wherein the metal workpiece is formed of aluminium or an aluminium alloy.
- The use according to any one of claims 5 to 13, wherein a metal workpiece in the form of a tube is selected to a cold drawing operation.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8924457 | 1989-10-31 | ||
GB898924457A GB8924457D0 (en) | 1989-10-31 | 1989-10-31 | Non-staining solid lubricants |
PCT/GB1990/001659 WO1991006619A1 (en) | 1989-10-31 | 1990-10-30 | Non-staining solid lubricants |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0638116A1 EP0638116A1 (en) | 1995-02-15 |
EP0638116B1 true EP0638116B1 (en) | 1999-06-02 |
Family
ID=10665440
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90916328A Expired - Lifetime EP0638116B1 (en) | 1989-10-31 | 1990-10-30 | Non-staining solid lubricants |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0638116B1 (en) |
JP (1) | JPH05501427A (en) |
AU (1) | AU6638490A (en) |
CA (1) | CA2071830A1 (en) |
DE (1) | DE69033147T2 (en) |
GB (1) | GB8924457D0 (en) |
WO (1) | WO1991006619A1 (en) |
ZA (1) | ZA908752B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3165589A1 (en) | 2015-11-04 | 2017-05-10 | Henkel AG & Co. KGaA | Powder lubricant based on zinc salts of fatty acids and use thereof |
US10975324B2 (en) | 2015-11-04 | 2021-04-13 | Henkel Ag & Co. Kgaa | Powder lubricant based on fatty acids and fatty acid glycerides and use thereof |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04233998A (en) * | 1990-12-28 | 1992-08-21 | Nippon Parkerizing Co Ltd | Aluminum plate subjected to lubricating treatment and lubrication treating agent for aluminum plate |
US5401575A (en) * | 1992-12-04 | 1995-03-28 | Aluminum Company Of America | Aluminum sheet coated with a lubricant comprising dioctyl sebacate and petrolatum |
US5672401A (en) * | 1995-10-27 | 1997-09-30 | Aluminum Company Of America | Lubricated sheet product and lubricant composition |
US6749772B2 (en) * | 2002-04-24 | 2004-06-15 | Illinois Tool Works, Inc. | Fluorescent lubricant |
JP5566037B2 (en) * | 2009-02-10 | 2014-08-06 | Jx日鉱日石エネルギー株式会社 | Oil processing composition for aluminum processing with ultra-trace oil supply |
EP3130653B1 (en) | 2015-08-13 | 2018-11-21 | Fuchs Petrolub SE | Composition for minimal lubrication and its use |
DE202015005833U1 (en) | 2015-08-13 | 2015-11-18 | Fuchs Petrolub Se | Composition for minimal quantity lubrication and its use |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4948068B1 (en) * | 1970-07-30 | 1974-12-19 | ||
US3899433A (en) * | 1972-06-29 | 1975-08-12 | Ethyl Corp | Method of metalworking utilizing a particular lubricant composition |
GB8502148D0 (en) * | 1985-01-29 | 1985-02-27 | Alcan Int Ltd | Metal-forming lubricant |
-
1989
- 1989-10-31 GB GB898924457A patent/GB8924457D0/en active Pending
-
1990
- 1990-10-30 EP EP90916328A patent/EP0638116B1/en not_active Expired - Lifetime
- 1990-10-30 AU AU66384/90A patent/AU6638490A/en not_active Abandoned
- 1990-10-30 WO PCT/GB1990/001659 patent/WO1991006619A1/en active IP Right Grant
- 1990-10-30 CA CA002071830A patent/CA2071830A1/en not_active Abandoned
- 1990-10-30 JP JP2515193A patent/JPH05501427A/en active Pending
- 1990-10-30 DE DE69033147T patent/DE69033147T2/en not_active Expired - Fee Related
- 1990-10-31 ZA ZA908752A patent/ZA908752B/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3165589A1 (en) | 2015-11-04 | 2017-05-10 | Henkel AG & Co. KGaA | Powder lubricant based on zinc salts of fatty acids and use thereof |
US10975324B2 (en) | 2015-11-04 | 2021-04-13 | Henkel Ag & Co. Kgaa | Powder lubricant based on fatty acids and fatty acid glycerides and use thereof |
Also Published As
Publication number | Publication date |
---|---|
DE69033147T2 (en) | 2000-01-05 |
AU6638490A (en) | 1991-05-31 |
DE69033147D1 (en) | 1999-07-08 |
ZA908752B (en) | 1991-09-25 |
JPH05501427A (en) | 1993-03-18 |
CA2071830A1 (en) | 1991-05-01 |
WO1991006619A1 (en) | 1991-05-16 |
GB8924457D0 (en) | 1989-12-20 |
EP0638116A1 (en) | 1995-02-15 |
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