EP0635566A1 - Compositions détergentes empêchant le transfert de colorant - Google Patents
Compositions détergentes empêchant le transfert de colorant Download PDFInfo
- Publication number
- EP0635566A1 EP0635566A1 EP93870155A EP93870155A EP0635566A1 EP 0635566 A1 EP0635566 A1 EP 0635566A1 EP 93870155 A EP93870155 A EP 93870155A EP 93870155 A EP93870155 A EP 93870155A EP 0635566 A1 EP0635566 A1 EP 0635566A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- surfactants
- acid
- vinylimidazole
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 120
- 239000003599 detergent Substances 0.000 title claims abstract description 93
- 230000002401 inhibitory effect Effects 0.000 title description 13
- 229920001577 copolymer Polymers 0.000 claims abstract description 48
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 72
- 125000000217 alkyl group Chemical group 0.000 claims description 44
- 239000004094 surface-active agent Substances 0.000 claims description 39
- 102000004190 Enzymes Human genes 0.000 claims description 16
- 108090000790 Enzymes Proteins 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 108010084185 Cellulases Proteins 0.000 claims description 13
- 102000005575 Cellulases Human genes 0.000 claims description 13
- 102000003992 Peroxidases Human genes 0.000 claims description 10
- 239000004927 clay Substances 0.000 claims description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 5
- 108700020962 Peroxidase Proteins 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 238000010410 dusting Methods 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 24
- 239000004615 ingredient Substances 0.000 abstract description 16
- 125000004432 carbon atom Chemical group C* 0.000 description 24
- 239000002736 nonionic surfactant Substances 0.000 description 24
- 239000007844 bleaching agent Substances 0.000 description 23
- 239000000975 dye Substances 0.000 description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 18
- 239000002253 acid Substances 0.000 description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 16
- 239000004744 fabric Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
- 239000007859 condensation product Substances 0.000 description 15
- 229940088598 enzyme Drugs 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 14
- 108010059892 Cellulase Proteins 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 12
- 229920005646 polycarboxylate Polymers 0.000 description 12
- 229940106157 cellulase Drugs 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 11
- 239000000194 fatty acid Substances 0.000 description 11
- 229930195729 fatty acid Natural products 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 11
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 11
- 150000007513 acids Chemical class 0.000 description 10
- 229920001296 polysiloxane Polymers 0.000 description 10
- 239000003945 anionic surfactant Substances 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 102000004882 Lipase Human genes 0.000 description 8
- 108090001060 Lipase Proteins 0.000 description 8
- 108091005804 Peptidases Proteins 0.000 description 8
- 150000001768 cations Chemical class 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 239000004367 Lipase Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 238000004061 bleaching Methods 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 7
- 235000019421 lipase Nutrition 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000010457 zeolite Substances 0.000 description 7
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 6
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 6
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000004365 Protease Substances 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical group OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 6
- 239000008103 glucose Substances 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 239000011591 potassium Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 229910021653 sulphate ion Inorganic materials 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 150000001720 carbohydrates Chemical group 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 239000003093 cationic surfactant Substances 0.000 description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 description 5
- 238000004900 laundering Methods 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 102000004169 proteins and genes Human genes 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000006641 stabilisation Effects 0.000 description 5
- 238000011105 stabilization Methods 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 4
- 102000035195 Peptidases Human genes 0.000 description 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 4
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 4
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 description 4
- 150000001860 citric acid derivatives Chemical class 0.000 description 4
- 239000002563 ionic surfactant Substances 0.000 description 4
- 159000000003 magnesium salts Chemical class 0.000 description 4
- 108040007629 peroxidase activity proteins Proteins 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- GECBFCPDQHIKOX-UHFFFAOYSA-N 1-ethenylimidazole;1-ethenylpyrrolidin-2-one Chemical compound C=CN1C=CN=C1.C=CN1CCCC1=O GECBFCPDQHIKOX-UHFFFAOYSA-N 0.000 description 3
- ZMPRRFPMMJQXPP-UHFFFAOYSA-N 2-sulfobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1S(O)(=O)=O ZMPRRFPMMJQXPP-UHFFFAOYSA-N 0.000 description 3
- XHULUQRDNLRXPF-UHFFFAOYSA-N 3-ethenyl-1,3-oxazolidin-2-id-4-one Chemical compound C(=C)N1[CH-]OCC1=O XHULUQRDNLRXPF-UHFFFAOYSA-N 0.000 description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- 108010056079 Subtilisins Proteins 0.000 description 3
- 102000005158 Subtilisins Human genes 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 3
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000002538 fungal effect Effects 0.000 description 3
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 3
- 125000003147 glycosyl group Chemical group 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 3
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000003751 zinc Chemical class 0.000 description 3
- 239000002888 zwitterionic surfactant Substances 0.000 description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 2
- XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical compound CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 description 2
- YJHSJERLYWNLQL-UHFFFAOYSA-N 2-hydroxyethyl(dimethyl)azanium;chloride Chemical compound Cl.CN(C)CCO YJHSJERLYWNLQL-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 108010065511 Amylases Proteins 0.000 description 2
- 102000013142 Amylases Human genes 0.000 description 2
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical group CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 241000223198 Humicola Species 0.000 description 2
- 241001480714 Humicola insolens Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 101710180012 Protease 7 Proteins 0.000 description 2
- 241000589516 Pseudomonas Species 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical group OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 2
- 235000019418 amylase Nutrition 0.000 description 2
- 229940025131 amylases Drugs 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000001851 biosynthetic effect Effects 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002255 enzymatic effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229930182830 galactose Chemical group 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- 150000008131 glucosides Chemical class 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 150000002402 hexoses Chemical class 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- ROBFUDYVXSDBQM-UHFFFAOYSA-N hydroxymalonic acid Chemical compound OC(=O)C(O)C(O)=O ROBFUDYVXSDBQM-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000012669 liquid formulation Substances 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 108010020132 microbial serine proteinases Proteins 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
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- 239000006072 paste Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 150000004976 peroxydisulfates Chemical class 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- NJKRDXUWFBJCDI-UHFFFAOYSA-N propane-1,1,2,3-tetracarboxylic acid Chemical class OC(=O)CC(C(O)=O)C(C(O)=O)C(O)=O NJKRDXUWFBJCDI-UHFFFAOYSA-N 0.000 description 1
- NJEVMKZODGWUQT-UHFFFAOYSA-N propane-1,1,3,3-tetracarboxylic acid Chemical class OC(=O)C(C(O)=O)CC(C(O)=O)C(O)=O NJEVMKZODGWUQT-UHFFFAOYSA-N 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000006268 reductive amination reaction Methods 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229950009390 symclosene Drugs 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38654—Preparations containing enzymes, e.g. protease or amylase containing oxidase or reductase
Definitions
- the present invention comprises as an essential detergent ingredient a polymer selected from the N-vinylimidazole N-vinylpyrrolidone copolymers.
- Said N-vinylimidazole N-vinylpyrrolidone have found to enhance the detergency performance of certain detergent ingredients formulated therewith.
- the N-vinylimidazole N-vinylpyrrolidone polymers have an average molecular weight range from 5000-1,000,000 , preferably from 20 000 -200,000.
- the level of the N-vinylimidazole N-vinylpyrrolidone present in the detergent compositions is from 0.01 to 10% , more preferably from 0.05 to 5% , most preferably from 0.1 to 1% by weight of the detergent composition.
- a first class of ingredients are surfactant systems wherein the surfactant is a non-alkylbenzene sulfonate salt containing surfactant system wherein the surfactant can be selected from nonionic and/or anionic and/or cationic and/or ampholytic and/or zwitterionic and/or semi-polar surfactants.
- Preferred non-alkylbenzene sulfonate salt containing surfactant systems to be used according to the present invention comprise as a surfactant one or more of the nonionic and/or anionic surfactants described herein. These surfactants have found to be very useful in that the dye transfer inhibiting performance of the N-vinylimidazole N-vinylpyrrolidone copolymers has been increased in the presence of said surfactants.
- Polyethylene, polypropylene, and polybutylene oxide condensates of alkyl phenols are suitable for use as the nonionic surfactant of the surfactant systems of the present invention, with the polyethylene oxide condensates being preferred.
- These compounds include the condensation products of alkyl phenols having an alkyl group containing from about 6 to about 14 carbon atoms, preferably from about 8 to about 14 carbon atoms, in either a straight-chain or branched-chain configuration with the alkylene oxide.
- the ethylene oxide is present in an amount equal to from about 2 to about 25 moles, more preferably from about 3 to about 15 moles, of ethylene oxide per mole of alkyl phenol.
- R1 is methyl
- R2 is a straight C11 ⁇ 15 alkyl or alkenyl chain such as coconut alkyl or mixtures thereof
- Z is derived from a reducing sugar such as glucose, fructose, maltose, lactose, in a reductive amination reaction.
- Suitable anionic surfactants to be used are alkyl ester sulfonate surfactants including linear esters of C8-C20 carboxylic acids (i.e., fatty acids) which are sulfonated with gaseous SO3 according to "The Journal of the American Oil Chemists Society", 52 (1975), pp. 323-329.
- Suitable starting materials would include natural fatty substances as derived from tallow, palm oil, etc.
- amine oxide surfactants in particular include C10-C18 alkyl dimethyl amine oxides and C8-C12 alkoxy ethyl dihydroxy ethyl amine oxides.
- proteases are the subtilisins which are obtained from particular strains of B.subtilis and B.licheniforms.
- proteases suitable for removing protein-based stains that are commercially available include those sold under the tradenames Alcalase, Savinase and Esperase by Novo Industries A/S (Denmark) and Maxatase by International Bio-Synthetics, Inc. (The Netherlands) and FN-base by Genencor, Optimase and opticlean by MKC.
- compositions can comprise a silicone/silica mixture in combination with fumed nonporous silica such as Aerosil R .
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (16)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1993619237 DE69319237T2 (de) | 1993-07-23 | 1993-07-23 | Die Farbstoffübertragung hemmende Waschmittelzusammensetzungen |
| DK93870155T DK0635566T3 (da) | 1993-07-23 | 1993-07-23 | Detergentsammensætninger, der inhiberer farvestofoverførsel |
| EP19930870155 EP0635566B1 (fr) | 1993-07-23 | 1993-07-23 | Compositions détergentes empêchant le transfert de colorant |
| EP93203611A EP0628624A1 (fr) | 1993-06-09 | 1993-12-21 | Compositions détergentes contenant une protéase et des additifs pour empêcher le transfert de colorant |
| US08/583,109 US5710119A (en) | 1993-07-23 | 1994-06-20 | Detergent compositions inhibiting dye transfer comprising copolymers of N-vinylimidazole and N-vinylpyrrolidone |
| HU9503869A HUT74035A (en) | 1993-07-23 | 1994-06-20 | Detergent compositions inhibiting dye transfer |
| AU73150/94A AU7315094A (en) | 1993-07-23 | 1994-06-20 | Detergent compositions inhibiting dye transfer |
| JP7505142A JPH09502745A (ja) | 1993-07-23 | 1994-06-20 | 染料移動を抑制する洗剤組成物 |
| BR9407201A BR9407201A (pt) | 1993-07-23 | 1994-06-20 | Composições detergentes que inibem transferência de corante |
| CA002167373A CA2167373C (fr) | 1993-07-23 | 1994-06-20 | Compositions detergentes empechant le transfert de colorants |
| CN94193284A CN1073151C (zh) | 1993-07-23 | 1994-06-20 | 抑制染料转移的洗涤剂组合物 |
| CZ96204A CZ20496A3 (en) | 1993-07-23 | 1994-06-20 | Detergents inhibiting transfer of dyestuff |
| PCT/US1994/006951 WO1995003382A1 (fr) | 1993-07-23 | 1994-06-20 | Compositions detergentes inhibant le transfert de colorants |
| PH48667A PH11994048667B1 (en) | 1993-07-23 | 1994-07-20 | Detergent compositions inhibiting dye transfer |
| TR00694/94A TR27763A (tr) | 1993-07-23 | 1994-07-21 | Boya aktarilmasini engelleyen deterjan terkipleri. |
| MX9405642A MX193592B (en) | 1993-07-23 | 1994-07-22 | Detergent compositions inhibiting dye transfer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP19930870155 EP0635566B1 (fr) | 1993-07-23 | 1993-07-23 | Compositions détergentes empêchant le transfert de colorant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0635566A1 true EP0635566A1 (fr) | 1995-01-25 |
| EP0635566B1 EP0635566B1 (fr) | 1998-06-17 |
Family
ID=8215381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19930870155 Revoked EP0635566B1 (fr) | 1993-06-09 | 1993-07-23 | Compositions détergentes empêchant le transfert de colorant |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0635566B1 (fr) |
| JP (1) | JPH09502745A (fr) |
| CN (1) | CN1073151C (fr) |
| AU (1) | AU7315094A (fr) |
| BR (1) | BR9407201A (fr) |
| CA (1) | CA2167373C (fr) |
| CZ (1) | CZ20496A3 (fr) |
| DE (1) | DE69319237T2 (fr) |
| DK (1) | DK0635566T3 (fr) |
| HU (1) | HUT74035A (fr) |
| MX (1) | MX193592B (fr) |
| PH (1) | PH11994048667B1 (fr) |
| TR (1) | TR27763A (fr) |
| WO (1) | WO1995003382A1 (fr) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0628624A1 (fr) * | 1993-06-09 | 1994-12-14 | The Procter & Gamble Company | Compositions détergentes contenant une protéase et des additifs pour empêcher le transfert de colorant |
| EP0736085A1 (fr) † | 1993-12-21 | 1996-10-09 | The Procter & Gamble Company | Composition detergente contenant du percarbonate et de l'amylase |
| WO1997023592A1 (fr) * | 1995-12-21 | 1997-07-03 | Unilever Plc | Composition detergente |
| WO1997023591A1 (fr) * | 1995-12-21 | 1997-07-03 | Unilever Plc | Composition detergente |
| WO1997045517A1 (fr) * | 1996-05-29 | 1997-12-04 | Basf Aktiengesellschaft | Utilisation de copolymerisats solubles dans l'eau contenant des unites n-vinylimidazol comme inhibiteurs de transfert de couleurs dans des detergents |
| US5880081A (en) * | 1997-04-07 | 1999-03-09 | Gopalkrishnan; Sridhar | Concentrated built liquid detergents containing a dye-transfer inhibiting additive |
| US6121223A (en) * | 1997-04-30 | 2000-09-19 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent composition comprising dye transfer inhibiting polymer and water soluble sunscreen |
| US6127329A (en) * | 1997-10-02 | 2000-10-03 | The Procter & Gamble Company | Detergent compositions |
| EP3085761A1 (fr) * | 2015-04-20 | 2016-10-26 | Hayata Kimya Sanayi Anonim Sirketi | Détergent à lessive pour une utilisation dans le lavage de blanc et de tissus colorés ensemble |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10257389A1 (de) | 2002-12-06 | 2004-06-24 | Henkel Kgaa | Flüssiges saures Waschmittel |
| DE102005039580A1 (de) | 2005-08-19 | 2007-02-22 | Henkel Kgaa | Farbschützendes Waschmittel |
| DE102006012018B3 (de) | 2006-03-14 | 2007-11-15 | Henkel Kgaa | Farbschützendes Waschmittel |
| DE102012219403A1 (de) | 2012-10-24 | 2014-04-24 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| DE102013203484A1 (de) | 2013-03-01 | 2014-09-04 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| DE102014220663A1 (de) | 2014-10-13 | 2016-04-14 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| DE102014220662A1 (de) | 2014-10-13 | 2016-04-14 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| DE102017004698A1 (de) | 2017-05-17 | 2018-11-22 | Henkel Ag & Co. Kgaa | Farbschützende Waschmittel |
| CN111848868B (zh) * | 2020-07-16 | 2022-05-13 | 重庆市化工研究院有限公司 | 一种共聚物及其制备方法和用途 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2814287A1 (de) * | 1978-04-03 | 1979-10-11 | Henkel Kgaa | Waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen |
| WO1992004437A1 (fr) * | 1990-09-01 | 1992-03-19 | Henkel Kommanditgesellschaft Auf Aktien | Produit de lavage liquide empechant la decoloration |
| EP0522206A1 (fr) * | 1991-07-08 | 1993-01-13 | The Procter & Gamble Company | Compositions détergentes contenant des tensio-actifs d'acide gras polyhydroxylé et un système adoucissant à base d'argile |
| EP0538228A1 (fr) * | 1991-10-14 | 1993-04-21 | The Procter & Gamble Company | Détergents avec additifs pour éviter le transfert de colorant |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3803630A1 (de) * | 1988-02-06 | 1989-08-17 | Henkel Kgaa | Waschmittelzusatz |
| DE3840056A1 (de) * | 1988-11-28 | 1990-05-31 | Henkel Kgaa | Verfahren zum waschen von verfaerbungsempfindlichen textilien |
-
1993
- 1993-07-23 EP EP19930870155 patent/EP0635566B1/fr not_active Revoked
- 1993-07-23 DK DK93870155T patent/DK0635566T3/da active
- 1993-07-23 DE DE1993619237 patent/DE69319237T2/de not_active Expired - Fee Related
-
1994
- 1994-06-20 JP JP7505142A patent/JPH09502745A/ja active Pending
- 1994-06-20 CA CA002167373A patent/CA2167373C/fr not_active Expired - Fee Related
- 1994-06-20 CZ CZ96204A patent/CZ20496A3/cs unknown
- 1994-06-20 HU HU9503869A patent/HUT74035A/hu unknown
- 1994-06-20 AU AU73150/94A patent/AU7315094A/en not_active Abandoned
- 1994-06-20 WO PCT/US1994/006951 patent/WO1995003382A1/fr not_active Application Discontinuation
- 1994-06-20 BR BR9407201A patent/BR9407201A/pt not_active IP Right Cessation
- 1994-06-20 CN CN94193284A patent/CN1073151C/zh not_active Expired - Fee Related
- 1994-07-20 PH PH48667A patent/PH11994048667B1/en unknown
- 1994-07-21 TR TR00694/94A patent/TR27763A/xx unknown
- 1994-07-22 MX MX9405642A patent/MX193592B/es unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2814287A1 (de) * | 1978-04-03 | 1979-10-11 | Henkel Kgaa | Waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen |
| WO1992004437A1 (fr) * | 1990-09-01 | 1992-03-19 | Henkel Kommanditgesellschaft Auf Aktien | Produit de lavage liquide empechant la decoloration |
| EP0522206A1 (fr) * | 1991-07-08 | 1993-01-13 | The Procter & Gamble Company | Compositions détergentes contenant des tensio-actifs d'acide gras polyhydroxylé et un système adoucissant à base d'argile |
| EP0538228A1 (fr) * | 1991-10-14 | 1993-04-21 | The Procter & Gamble Company | Détergents avec additifs pour éviter le transfert de colorant |
Non-Patent Citations (1)
| Title |
|---|
| U.JÄGER, W.DENZINGER: "Wirkungsweise von Polymeren mit farbübertragungsinhibierenden Eigenschaften", TENSIDE, vol. 28, no. 6, 1991, MUNCHEN, DE, pages 428 - 433, XP000237159 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0628624A1 (fr) * | 1993-06-09 | 1994-12-14 | The Procter & Gamble Company | Compositions détergentes contenant une protéase et des additifs pour empêcher le transfert de colorant |
| EP0736085A1 (fr) † | 1993-12-21 | 1996-10-09 | The Procter & Gamble Company | Composition detergente contenant du percarbonate et de l'amylase |
| EP0736085B2 (fr) † | 1993-12-21 | 2009-12-16 | The Procter & Gamble Company | Composition detergente contenant du percarbonate, de de l'amylase et une protease |
| US5977046A (en) * | 1995-12-21 | 1999-11-02 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent composition |
| WO1997023591A1 (fr) * | 1995-12-21 | 1997-07-03 | Unilever Plc | Composition detergente |
| WO1997023592A1 (fr) * | 1995-12-21 | 1997-07-03 | Unilever Plc | Composition detergente |
| WO1997045517A1 (fr) * | 1996-05-29 | 1997-12-04 | Basf Aktiengesellschaft | Utilisation de copolymerisats solubles dans l'eau contenant des unites n-vinylimidazol comme inhibiteurs de transfert de couleurs dans des detergents |
| US6172027B1 (en) | 1996-05-29 | 2001-01-09 | Basf Aktiengesellschaft | Use of water-soluble copolymers comprising N-vinylimidazole units as color transfer inhibitors in detergents |
| US5880081A (en) * | 1997-04-07 | 1999-03-09 | Gopalkrishnan; Sridhar | Concentrated built liquid detergents containing a dye-transfer inhibiting additive |
| US6121223A (en) * | 1997-04-30 | 2000-09-19 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent composition comprising dye transfer inhibiting polymer and water soluble sunscreen |
| US6127329A (en) * | 1997-10-02 | 2000-10-03 | The Procter & Gamble Company | Detergent compositions |
| EP3085761A1 (fr) * | 2015-04-20 | 2016-10-26 | Hayata Kimya Sanayi Anonim Sirketi | Détergent à lessive pour une utilisation dans le lavage de blanc et de tissus colorés ensemble |
| WO2016171636A1 (fr) * | 2015-04-20 | 2016-10-27 | Hayat Kimya Sanayi Anonim Şirketi | Détergent à lessive destiné à être utilisé dans le lavage de tissus colorés et blancs ensemble |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69319237D1 (de) | 1998-07-23 |
| CN1073151C (zh) | 2001-10-17 |
| AU7315094A (en) | 1995-02-20 |
| PH11994048667B1 (en) | 2001-06-19 |
| CN1130399A (zh) | 1996-09-04 |
| DE69319237T2 (de) | 1999-02-25 |
| HUT74035A (en) | 1996-10-28 |
| DK0635566T3 (da) | 1998-10-19 |
| BR9407201A (pt) | 1996-09-17 |
| TR27763A (tr) | 1995-08-04 |
| CZ20496A3 (en) | 1996-07-17 |
| CA2167373A1 (fr) | 1995-02-02 |
| EP0635566B1 (fr) | 1998-06-17 |
| HU9503869D0 (en) | 1996-02-28 |
| JPH09502745A (ja) | 1997-03-18 |
| CA2167373C (fr) | 1999-10-19 |
| WO1995003382A1 (fr) | 1995-02-02 |
| MX193592B (en) | 1999-10-05 |
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