EP0635566A1 - Die Farbstoffübertragung hemmende Waschmittelzusammensetzungen - Google Patents

Die Farbstoffübertragung hemmende Waschmittelzusammensetzungen Download PDF

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Publication number
EP0635566A1
EP0635566A1 EP93870155A EP93870155A EP0635566A1 EP 0635566 A1 EP0635566 A1 EP 0635566A1 EP 93870155 A EP93870155 A EP 93870155A EP 93870155 A EP93870155 A EP 93870155A EP 0635566 A1 EP0635566 A1 EP 0635566A1
Authority
EP
European Patent Office
Prior art keywords
alkyl
surfactants
acid
vinylimidazole
detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP93870155A
Other languages
English (en)
French (fr)
Other versions
EP0635566B1 (de
Inventor
Alfred Busch (Nmn)
Andre Christian Convents
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8215381&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0635566(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to DK93870155T priority Critical patent/DK0635566T3/da
Priority to EP19930870155 priority patent/EP0635566B1/de
Priority to DE1993619237 priority patent/DE69319237T2/de
Priority to EP93203611A priority patent/EP0628624A1/de
Priority to CA002167373A priority patent/CA2167373C/en
Priority to US08/583,109 priority patent/US5710119A/en
Priority to CN94193284A priority patent/CN1073151C/zh
Priority to CZ96204A priority patent/CZ20496A3/cs
Priority to PCT/US1994/006951 priority patent/WO1995003382A1/en
Priority to BR9407201A priority patent/BR9407201A/pt
Priority to HU9503869A priority patent/HUT74035A/hu
Priority to JP7505142A priority patent/JPH09502745A/ja
Priority to AU73150/94A priority patent/AU7315094A/en
Priority to PH48667A priority patent/PH11994048667B1/en
Priority to TR00694/94A priority patent/TR27763A/xx
Priority to MX9405642A priority patent/MX193592B/es
Publication of EP0635566A1 publication Critical patent/EP0635566A1/de
Publication of EP0635566B1 publication Critical patent/EP0635566B1/de
Application granted granted Critical
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38654—Preparations containing enzymes, e.g. protease or amylase containing oxidase or reductase

Definitions

  • the present invention comprises as an essential detergent ingredient a polymer selected from the N-vinylimidazole N-vinylpyrrolidone copolymers.
  • Said N-vinylimidazole N-vinylpyrrolidone have found to enhance the detergency performance of certain detergent ingredients formulated therewith.
  • the N-vinylimidazole N-vinylpyrrolidone polymers have an average molecular weight range from 5000-1,000,000 , preferably from 20 000 -200,000.
  • the level of the N-vinylimidazole N-vinylpyrrolidone present in the detergent compositions is from 0.01 to 10% , more preferably from 0.05 to 5% , most preferably from 0.1 to 1% by weight of the detergent composition.
  • a first class of ingredients are surfactant systems wherein the surfactant is a non-alkylbenzene sulfonate salt containing surfactant system wherein the surfactant can be selected from nonionic and/or anionic and/or cationic and/or ampholytic and/or zwitterionic and/or semi-polar surfactants.
  • Preferred non-alkylbenzene sulfonate salt containing surfactant systems to be used according to the present invention comprise as a surfactant one or more of the nonionic and/or anionic surfactants described herein. These surfactants have found to be very useful in that the dye transfer inhibiting performance of the N-vinylimidazole N-vinylpyrrolidone copolymers has been increased in the presence of said surfactants.
  • Polyethylene, polypropylene, and polybutylene oxide condensates of alkyl phenols are suitable for use as the nonionic surfactant of the surfactant systems of the present invention, with the polyethylene oxide condensates being preferred.
  • These compounds include the condensation products of alkyl phenols having an alkyl group containing from about 6 to about 14 carbon atoms, preferably from about 8 to about 14 carbon atoms, in either a straight-chain or branched-chain configuration with the alkylene oxide.
  • the ethylene oxide is present in an amount equal to from about 2 to about 25 moles, more preferably from about 3 to about 15 moles, of ethylene oxide per mole of alkyl phenol.
  • R1 is methyl
  • R2 is a straight C11 ⁇ 15 alkyl or alkenyl chain such as coconut alkyl or mixtures thereof
  • Z is derived from a reducing sugar such as glucose, fructose, maltose, lactose, in a reductive amination reaction.
  • Suitable anionic surfactants to be used are alkyl ester sulfonate surfactants including linear esters of C8-C20 carboxylic acids (i.e., fatty acids) which are sulfonated with gaseous SO3 according to "The Journal of the American Oil Chemists Society", 52 (1975), pp. 323-329.
  • Suitable starting materials would include natural fatty substances as derived from tallow, palm oil, etc.
  • amine oxide surfactants in particular include C10-C18 alkyl dimethyl amine oxides and C8-C12 alkoxy ethyl dihydroxy ethyl amine oxides.
  • proteases are the subtilisins which are obtained from particular strains of B.subtilis and B.licheniforms.
  • proteases suitable for removing protein-based stains that are commercially available include those sold under the tradenames Alcalase, Savinase and Esperase by Novo Industries A/S (Denmark) and Maxatase by International Bio-Synthetics, Inc. (The Netherlands) and FN-base by Genencor, Optimase and opticlean by MKC.
  • compositions can comprise a silicone/silica mixture in combination with fumed nonporous silica such as Aerosil R .
EP19930870155 1993-06-09 1993-07-23 Die Farbstoffübertragung hemmende Waschmittelzusammensetzungen Revoked EP0635566B1 (de)

Priority Applications (16)

Application Number Priority Date Filing Date Title
DK93870155T DK0635566T3 (da) 1993-07-23 1993-07-23 Detergentsammensætninger, der inhiberer farvestofoverførsel
EP19930870155 EP0635566B1 (de) 1993-07-23 1993-07-23 Die Farbstoffübertragung hemmende Waschmittelzusammensetzungen
DE1993619237 DE69319237T2 (de) 1993-07-23 1993-07-23 Die Farbstoffübertragung hemmende Waschmittelzusammensetzungen
EP93203611A EP0628624A1 (de) 1993-06-09 1993-12-21 Protease enthaltende Waschmittelzusammensetzungen mit Zusätzen zur Verhinderung der Farbstoffübertragung
PCT/US1994/006951 WO1995003382A1 (en) 1993-07-23 1994-06-20 Detergent compositions inhibiting dye transfer
US08/583,109 US5710119A (en) 1993-07-23 1994-06-20 Detergent compositions inhibiting dye transfer comprising copolymers of N-vinylimidazole and N-vinylpyrrolidone
CN94193284A CN1073151C (zh) 1993-07-23 1994-06-20 抑制染料转移的洗涤剂组合物
CZ96204A CZ20496A3 (en) 1993-07-23 1994-06-20 Detergents inhibiting transfer of dyestuff
CA002167373A CA2167373C (en) 1993-07-23 1994-06-20 Detergent compositions inhibiting dye transfer
BR9407201A BR9407201A (pt) 1993-07-23 1994-06-20 Composições detergentes que inibem transferência de corante
HU9503869A HUT74035A (en) 1993-07-23 1994-06-20 Detergent compositions inhibiting dye transfer
JP7505142A JPH09502745A (ja) 1993-07-23 1994-06-20 染料移動を抑制する洗剤組成物
AU73150/94A AU7315094A (en) 1993-07-23 1994-06-20 Detergent compositions inhibiting dye transfer
PH48667A PH11994048667B1 (en) 1993-07-23 1994-07-20 Detergent compositions inhibiting dye transfer
TR00694/94A TR27763A (tr) 1993-07-23 1994-07-21 Boya aktarilmasini engelleyen deterjan terkipleri.
MX9405642A MX193592B (en) 1993-07-23 1994-07-22 Detergent compositions inhibiting dye transfer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP19930870155 EP0635566B1 (de) 1993-07-23 1993-07-23 Die Farbstoffübertragung hemmende Waschmittelzusammensetzungen

Publications (2)

Publication Number Publication Date
EP0635566A1 true EP0635566A1 (de) 1995-01-25
EP0635566B1 EP0635566B1 (de) 1998-06-17

Family

ID=8215381

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19930870155 Revoked EP0635566B1 (de) 1993-06-09 1993-07-23 Die Farbstoffübertragung hemmende Waschmittelzusammensetzungen

Country Status (14)

Country Link
EP (1) EP0635566B1 (de)
JP (1) JPH09502745A (de)
CN (1) CN1073151C (de)
AU (1) AU7315094A (de)
BR (1) BR9407201A (de)
CA (1) CA2167373C (de)
CZ (1) CZ20496A3 (de)
DE (1) DE69319237T2 (de)
DK (1) DK0635566T3 (de)
HU (1) HUT74035A (de)
MX (1) MX193592B (de)
PH (1) PH11994048667B1 (de)
TR (1) TR27763A (de)
WO (1) WO1995003382A1 (de)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0736085A1 (de) † 1993-12-21 1996-10-09 The Procter & Gamble Company Percarbonat und amylase enthaltende waschmittelzusammensetzungen
WO1997023592A1 (en) * 1995-12-21 1997-07-03 Unilever Plc A detergent composition
WO1997023591A1 (en) * 1995-12-21 1997-07-03 Unilever Plc A detergent composition
WO1997045517A1 (de) * 1996-05-29 1997-12-04 Basf Aktiengesellschaft Verwendung von wasserlöslichen, n-vinylimidazol-einheiten enthaltenden copolymerisaten als farbübertragungsinhibitoren in waschmitteln
US5880081A (en) * 1997-04-07 1999-03-09 Gopalkrishnan; Sridhar Concentrated built liquid detergents containing a dye-transfer inhibiting additive
US6121223A (en) * 1997-04-30 2000-09-19 Lever Brothers Company, Division Of Conopco, Inc. Detergent composition comprising dye transfer inhibiting polymer and water soluble sunscreen
US6127329A (en) * 1997-10-02 2000-10-03 The Procter & Gamble Company Detergent compositions
EP3085761A1 (de) * 2015-04-20 2016-10-26 Hayata Kimya Sanayi Anonim Sirketi Waschmittel für den einsatz in zusammenwaschen von weissen und farbigen stoffen

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10257389A1 (de) 2002-12-06 2004-06-24 Henkel Kgaa Flüssiges saures Waschmittel
DE102005039580A1 (de) 2005-08-19 2007-02-22 Henkel Kgaa Farbschützendes Waschmittel
DE102006012018B3 (de) 2006-03-14 2007-11-15 Henkel Kgaa Farbschützendes Waschmittel
DE102012219403A1 (de) 2012-10-24 2014-04-24 Henkel Ag & Co. Kgaa Farbschützende Waschmittel
DE102013203484A1 (de) 2013-03-01 2014-09-04 Henkel Ag & Co. Kgaa Farbschützende Waschmittel
DE102014220663A1 (de) 2014-10-13 2016-04-14 Henkel Ag & Co. Kgaa Farbschützende Waschmittel
DE102014220662A1 (de) 2014-10-13 2016-04-14 Henkel Ag & Co. Kgaa Farbschützende Waschmittel
DE102017004698A1 (de) 2017-05-17 2018-11-22 Henkel Ag & Co. Kgaa Farbschützende Waschmittel
CN111848868B (zh) * 2020-07-16 2022-05-13 重庆市化工研究院有限公司 一种共聚物及其制备方法和用途

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2814287A1 (de) * 1978-04-03 1979-10-11 Henkel Kgaa Waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen
WO1992004437A1 (de) * 1990-09-01 1992-03-19 Henkel Kommanditgesellschaft Auf Aktien Flüssiges verfärbungsinhibierendes waschmittel
EP0522206A1 (de) * 1991-07-08 1993-01-13 The Procter & Gamble Company Polyhydroxyfettsäureamidtenside und ein weichmachendes System auf Basis von Ton enthaltenden Waschmittelzusammensetzungen
EP0538228A1 (de) * 1991-10-14 1993-04-21 The Procter & Gamble Company Waschmittelzusammensetzungen zur Vermeidung der Farbstoffübertragung

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3803630A1 (de) * 1988-02-06 1989-08-17 Henkel Kgaa Waschmittelzusatz
DE3840056A1 (de) * 1988-11-28 1990-05-31 Henkel Kgaa Verfahren zum waschen von verfaerbungsempfindlichen textilien

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2814287A1 (de) * 1978-04-03 1979-10-11 Henkel Kgaa Waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen
WO1992004437A1 (de) * 1990-09-01 1992-03-19 Henkel Kommanditgesellschaft Auf Aktien Flüssiges verfärbungsinhibierendes waschmittel
EP0522206A1 (de) * 1991-07-08 1993-01-13 The Procter & Gamble Company Polyhydroxyfettsäureamidtenside und ein weichmachendes System auf Basis von Ton enthaltenden Waschmittelzusammensetzungen
EP0538228A1 (de) * 1991-10-14 1993-04-21 The Procter & Gamble Company Waschmittelzusammensetzungen zur Vermeidung der Farbstoffübertragung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
U.JÄGER, W.DENZINGER: "Wirkungsweise von Polymeren mit farbübertragungsinhibierenden Eigenschaften", TENSIDE, vol. 28, no. 6, 1991, MUNCHEN, DE, pages 428 - 433, XP000237159 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0736085A1 (de) † 1993-12-21 1996-10-09 The Procter & Gamble Company Percarbonat und amylase enthaltende waschmittelzusammensetzungen
EP0736085B2 (de) † 1993-12-21 2009-12-16 The Procter & Gamble Company Percarbonat , amylase und protease enthaltende waschmittelzusammensetzungen
WO1997023592A1 (en) * 1995-12-21 1997-07-03 Unilever Plc A detergent composition
WO1997023591A1 (en) * 1995-12-21 1997-07-03 Unilever Plc A detergent composition
US5977046A (en) * 1995-12-21 1999-11-02 Lever Brothers Company, Division Of Conopco, Inc. Detergent composition
WO1997045517A1 (de) * 1996-05-29 1997-12-04 Basf Aktiengesellschaft Verwendung von wasserlöslichen, n-vinylimidazol-einheiten enthaltenden copolymerisaten als farbübertragungsinhibitoren in waschmitteln
US6172027B1 (en) 1996-05-29 2001-01-09 Basf Aktiengesellschaft Use of water-soluble copolymers comprising N-vinylimidazole units as color transfer inhibitors in detergents
US5880081A (en) * 1997-04-07 1999-03-09 Gopalkrishnan; Sridhar Concentrated built liquid detergents containing a dye-transfer inhibiting additive
US6121223A (en) * 1997-04-30 2000-09-19 Lever Brothers Company, Division Of Conopco, Inc. Detergent composition comprising dye transfer inhibiting polymer and water soluble sunscreen
US6127329A (en) * 1997-10-02 2000-10-03 The Procter & Gamble Company Detergent compositions
EP3085761A1 (de) * 2015-04-20 2016-10-26 Hayata Kimya Sanayi Anonim Sirketi Waschmittel für den einsatz in zusammenwaschen von weissen und farbigen stoffen
WO2016171636A1 (en) * 2015-04-20 2016-10-27 Hayat Kimya Sanayi Anonim Şirketi Laundry detergent for use in washing of white and colored fabrics together

Also Published As

Publication number Publication date
CA2167373C (en) 1999-10-19
HUT74035A (en) 1996-10-28
EP0635566B1 (de) 1998-06-17
MX193592B (en) 1999-10-05
JPH09502745A (ja) 1997-03-18
HU9503869D0 (en) 1996-02-28
WO1995003382A1 (en) 1995-02-02
TR27763A (tr) 1995-08-04
DE69319237D1 (de) 1998-07-23
AU7315094A (en) 1995-02-20
DK0635566T3 (da) 1998-10-19
CN1130399A (zh) 1996-09-04
DE69319237T2 (de) 1999-02-25
CZ20496A3 (en) 1996-07-17
CN1073151C (zh) 2001-10-17
PH11994048667B1 (en) 2001-06-19
BR9407201A (pt) 1996-09-17
CA2167373A1 (en) 1995-02-02

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