EP0633264A1 - Dérivés d'aluminoxanes et des halogénures d'amines tertiaires - Google Patents

Dérivés d'aluminoxanes et des halogénures d'amines tertiaires Download PDF

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Publication number
EP0633264A1
EP0633264A1 EP94110613A EP94110613A EP0633264A1 EP 0633264 A1 EP0633264 A1 EP 0633264A1 EP 94110613 A EP94110613 A EP 94110613A EP 94110613 A EP94110613 A EP 94110613A EP 0633264 A1 EP0633264 A1 EP 0633264A1
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EP
European Patent Office
Prior art keywords
aluminoxane
tertiary
aluminum
mole
catalyst
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EP94110613A
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German (de)
English (en)
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EP0633264B1 (fr
Inventor
Samuel Ayodele Sangokoya
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Albemarle Corp
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Albemarle Corp
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Definitions

  • This invention relates generally to soluble aluminoxane derivatives and more particularly to tertiary amino-aluminoxane halide derivatives, obtained by the reaction of aluminoxanes with less than stoichiometric amounts of tertiary amine hydrohalides, which in the presence of metallocenes form catalytically active compositions for olefin polymerization.
  • Pasynkiewicz (Polyhedron (1990), 9 , 429-453) describes the synthesis and characterization of aluminoxane complexes with electron donor reagents. These reactions generally result in complex equilibrium products. Isolation of characterizable products from these reactions is often very difficult. Thus, a crystalline complex of tetramethylaluminoxane and N,N,N',N'-tetramethylethylenediamine (TMEDA) was obtained in 5-10% yield, by partial hydrolysis of trimethylaluminum (TMA) in TMEDA.
  • TMEDA trimethylaluminum
  • Amines and ether complexes of aluminoxanes have been described, but they are usually unstable and decompose into the corresponding trialkylaluminum adduct, for example Et3Al ⁇ THF and Me3Al ⁇ PhOMe.
  • Et3Al ⁇ THF and Me3Al ⁇ PhOMe the corresponding trialkylaluminum adduct
  • tetraalkylaluminoxane adducts having one or two Al-O-Al bonds are formed.
  • These materials are usually inactive or have inferior activity, compared to the regular oligomeric aluminoxanes, in olefin oligomerization or polymerization.
  • a British patent 1,319,746 describes the hydrolysis of R3Al (C2 to C4) in tertiary amine solvent whereby the resulting aluminoxane contained no amine (or N atoms) after removal of the amine by distillation.
  • the aluminoxane also has a major part to play in what happens during polymerization and it has now been discovered that the addition of an appropriate amount of a tertiary amine hydrohalide to the aluminoxane improves the solubility of the aluminoxane with a concomitant improvement in the activity of the catalyst system. For example, within the limits of the appropriate amount of added amine, a 20 to 80 percent increase in polymer yield compared to regular MAO is observed. However, when certain limits ( ⁇ 20%, amine:Al molar value) of addition is exceeded, a marked reduction in activity is observed.
  • a tertiary amino-aluminoxane halide derivative which comprises the reaction product of an aluminoxane and from about 0.005 to less than about 0.2 mole per mole of aluminum in said aluminoxane of a tertiary amine hydrohalide.
  • an olefin polymerization catalyst comprising a metallocene and a tertiary amino-aluminoxane halide derivative which is the reaction product of an aluminoxane and from about 0.005 to less than about 0.2 mole per mole of aluminum in said aluminoxane of a tertiary amine halohalide.
  • Also provided is a process for polymerizing an olefin comprising contacting, under polymerization conditions, an olefin with a catalyst comprising a metallocene and a tertiary amino-aluminoxane halide derivative which is the reaction product of aluminoxane and from about 0.005 to less than about 0.2 mole per mole of aluminum in said aluminoxane of a tertiary amine hydrohalide.
  • Preferred aluminoxanes for use in making the tertiary amino-aluminoxane halide derivatives are hydrocarbylaluminoxanes.
  • Hydrocarbylaluminoxanes may exist in the form of linear or cyclic polymers with the simplest compounds being a tetralylaluminoxane such as tetramethylaluminoxane, (CH3)2AlOAl(CH3)2, or tetraethylaluminoxane, (C2H5)2AlOAl(C2H5)2.
  • the compounds preferred for use in olefin polymerization catalysts usually contain about 4 to 20 of the repeating units: where R is C1-C10 alkyl and especially preferred are methylaluminoxanes (MAO).
  • the methylaluminoxanes can contain some higher alkyl groups to improve their solubility.
  • Such modified methylaluminoxanes are described, for example, in U.S. Patent No. 5,157,008.
  • hydrocarbylaluminoxanes for use in the invention include ethylaluminoxanes (EAO), isobutylaluminoxanes (IBAO), n-propylaluminoxanes, n-octylaluminoxanes, and the like.
  • the aluminoxanes can be prepared as known in the art by the partial hydrolysis of trialkylaluminum compounds.
  • the trialkylaluminoxane compounds can be hydrolyzed by adding either free water or water containing solids, which can be either hydrates or porous materials which have absorbed water. Because it is difficult to control the reaction by adding water per se, even with vigorous agitation of the mixture, the free water is preferably added in the form of a solution or a dispersion in an organic solvent.
  • Suitable hydrates include salt hydrates such as, for example, CuSO4 ⁇ 5H2O, Al2(SO4)3 ⁇ 18H2O, FeSO4 ⁇ 7H2O, AlCl3 ⁇ 6H2O, Al(NO3)3 ⁇ 9H2O, MgSO4 ⁇ 7H2O, ZnSO4 ⁇ 7H2O, Na2SO4 ⁇ 10H2O, Na3PO4 ⁇ 12H2O, LiBr ⁇ 2H2O, LiCl ⁇ 1H2O, LiI ⁇ 2H2O, LiI ⁇ 3H2O, KF ⁇ 2H2O, NaBr ⁇ 2H2O and the like and alkali or alkaline earth metal hydroxides such as, for example, NaOH ⁇ H2O, NaOH ⁇ 2H2O, Ba(OH)2 ⁇ 8H2O, KOH ⁇ 2H2O, CsOH ⁇ 1H2O, LiOH ⁇ 1H2O and the like.
  • salt hydrates such as, for example, CuSO4 ⁇ 5H2O,
  • the mole ratios of free water or water in the hydrate or in porous materials such as alumina or silica to total alkyl aluminum compounds in the mixture can vary widely, such as for example from about 2:1 to 1:4 with ratios of from about 4:3 to 1:3.5 being preferred.
  • methylaluminoxanes contain varying amounts, of from about 5 to 35 mole percent, of the aluminum value as unreacted trimethyl-aluminum.
  • tertiary amine hydrohalides for use in the invention can be represented by the formula R3N ⁇ HX where each R is selected from C1 to C20 cyclic or linear hydrocarbyl groups and X is any halogen and, preferably, Cl.
  • Non-limiting examples of tertiary amine hydrohalides include aliphatic or aromatic tertiary amine hydrohalides such as, trimethylamine hydro-chloride, trimethylamine hydrobromide, trimethylamine hydrofluoride, triethylamine hydrochloride, triethylamine hydrobromide, triethylamine hydrofluoride, tribenzylamine hydrochloride, tribenzylamine hydrobromide, tribenzylamine hydrofluoride, and the like.
  • the tertiary amino-aluminoxane hydrohalide can be prepared by reacting the aluminoxane and tertiary amine hydrohalide in an organic solvent in molar proportions of amine hydrohalide (N or X) of from about 0.005 to less than about 0.2 mole per mole of aluminum in the aluminoxane and preferably from about 0.01 to 0.15 mole of amine hydrochloride per mole of aluminum. Amounts of 0.2 mole per mole have reduced polymerization activity compared with untreated aluminoxane. Mixtures of aluminoxanes and tertiary amine hydrohalides can be used in forming the derivatives. Any inert organic solvent can be used as the reaction medium.
  • Non-limiting examples of solvents include aliphatic hydrocarbons such as pentane, isopentane, hexane, cyclohexane, heptane, octane, decane, dodecane, hexadecane, octadecane and the like with those having carbon numbers of 5 to 10 being preferred and aromatic hydrocarbons such as benzene, toluene, xylene, cumene and the like with those having carbon numbers of 6 to 20 being preferred.
  • aromatic hydrocarbons such as benzene, toluene, xylene, cumene and the like with those having carbon numbers of 6 to 20 being preferred.
  • amounts of solvent to provide a total concentration of reactants of from about 10 to 30 wt. percent are used.
  • Preferred reaction temperatures range from about 25 to 90°C.
  • the tertiary amino-aluminoxane derivatives can be used in combination with metallocenes to provide olefin polymerization catalysts.
  • metallocenes are well known in the art and non-limiting examples include the metallocenes of Groups 3, 4, 5, 6, lathanide and actinide metals such as the metallocenes of transition metals which are described in published European patent application No. 0 129,368 and U.S. Patent Nos. 5,017,714, 5,026,798 and 5,036,034, whose teachings with respect to such metallocenes are incorporated herein by reference.
  • metallocenes are bis-(cyclopentadienyl)zirconium dimethyl, bis-(cyclopentadienyl)zirconium dichloride, bis-(cyclopentadienyl)zirconium monomethylmonochloride, bis-(cyclopentadienyl)titanium dichloride, bis-(cyclopentadienyl)-titanium difluoride, cyclopentadienylzirconium tri-(2-ethylhexanoate), bis-cyclopentadienyl)zirconium hydrogen chloride, bis-(cyclopentadienyl)hafnium dichloride and the like.
  • the catalyst components are used in proportions to provide mole ratios of metal atom in the metallocene to aluminum atom in the amino-aluminoxane of from about 0.0002:1 to 0.2:1 and preferably 0.0005:1 to 0.02:1.
  • the catalyst components can be used in solution or deposited on a solid support.
  • the solid support can be any particulate solid, and particularly porous supports such as talc or inorganic oxides, or resinous support material such as polyolefins.
  • the support material is an inorganic oxide in finely divided form.
  • Suitable inorganic oxide support materials which are desirably employed include Group IIA, IIIA, IVA or IVB metal oxides such as silica, alumina, silica-alumina and mixtures thereof.
  • Other inorganic oxides that may be employed either alone or in combination with the silica, alumina or silica-alumina are magnesia, titania, zirconia, and the like.
  • Other suitable support materials are finely divided polyolefins such as finely divided polyethylene.
  • the catalysts are effective to produce olefin polymers and especially ethylene polymers and ethylene/ ⁇ -olefin copolymers.
  • olefins that can be polymerized in the presence of the catalysts of the invention include ⁇ -olefins having 2 to 20 carbon atoms such as ethylene, propylene, 1-butene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, and 1-octadecene.
  • Polymerization of ethylene or copolymerization with ethylene and an ⁇ -olefin having 3 to 10 carbon atoms is preferable.
  • Such polymerizations may be performed in either the gas or liquid phase (e.g. in a solvent, such as toluene, or in a diluent, such as heptane).
  • the polymerization can be conducted at conventional temperatures (e.g., 0° to 120°C.) and pressures (e.g., ambient to 50 kg/cm2) using conventional procedures as to molecular weight regulations and the like.
  • a 10 wt. % toluene solution of methylaluminoxane (MAO, 260 mmol Al) was placed in a reaction flask in a N2-dry box.
  • Trimethylamine hydrochloride (0.25 g, 2.6 mmol) was added in batches. Gas evolution (methane) was observed. After the addition was completed, the mixture was stirred at room temperature for about 30 minutes. Dissolved gas was allowed to escape. The reaction flask was then heated (oil bath) at about 70°C for about one hour. The initially cloudy MAO solution became clearer.
  • the product solution was filtered with some difficulties through a medium frit. After filtration, the solution remained clear even after four months.
  • the final product contained 218 mmol of Al, which is 84% of the initial aluminum value.
  • Some of the liquid product was concentrated under vacuum to give a free flowing, colorless solid product. Analyses of the liquid and solid products are shown in Table 1. The product is found to be more active than regular MAO for ethylene polymerization (Table 2).
  • Et3NHCl (9.4 g, 68 mmol) was added in batches during a period of about 90 minutes to a MAO solution (340 mmol Al). After addition, the mixture was allowed to stir at room temperature overnight. A lot of gas evolution was observed. The mixture was heated at 90°C (oil bath) for about two hours. Filtration through a medium frit was fast and easy. An attempt to obtain solid product by concentration to dryness resulted in an oily, low melting solid. Furthermore, an attempt to use this product as a co-catalyst in ethylene polymerization resulted in a negligible production of polyethylene. Polyethylene productivity was somewhat improved by addition of TMA (Table 2).
  • Liquid and solid products from the above mentioned Examples were used in conjunction with zirconocene dichloride to polymerize ethylene.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
EP94110613A 1993-07-09 1994-07-07 Dérivés d'aluminoxanes et des halogénures d'amines tertiaires Expired - Lifetime EP0633264B1 (fr)

Applications Claiming Priority (2)

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US08/087,444 US5412131A (en) 1993-07-09 1993-07-09 Teritary amino-aluminoxane halides
US87444 1993-07-09

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EP0633264A1 true EP0633264A1 (fr) 1995-01-11
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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997014700A1 (fr) * 1995-10-19 1997-04-24 Albemarle Corporation Compositions liquides de clathrate d'aluminoxane
US5840949A (en) * 1996-05-04 1998-11-24 Basf Aktiengesellschaft Recovery of metallocene complexes
WO1998055546A1 (fr) 1997-06-02 1998-12-10 Basf Aktiengesellschaft Melange polymere
US5919961A (en) * 1996-06-03 1999-07-06 Basf Aktiengesellschaft Chiral compounds
US5922631A (en) * 1995-10-19 1999-07-13 Albemarle Corporation Liquid clathrate aluminoxane compositions as co-catalysts with transition metal catalyst compounds
US6022935A (en) * 1996-04-22 2000-02-08 Basf Aktiengesellschaft Preparation of polymers of alk-1-enes in the presence of a supported metallocene catalyst system and of antistatic agent
US6114478A (en) * 1996-12-19 2000-09-05 Basf Aktiengesellschaft Gas-phase polymerization of C2 -C8 -alk-l-enes by means of Ziegler-Natta or metallocene catalyst systems
US6127495A (en) * 1996-05-31 2000-10-03 Basf Aktiengesellschaft Preparation of polymers of C2 -C12 -alkenes with the addition of a reaction retarder
US6180737B1 (en) 1996-01-25 2001-01-30 Basf Aktiengesellschaft Process for preparing polymers of C2-C10 alkenes in the presence of metallocene complexes with cationically functionalized cyclopentadienyl ligands
US6265339B1 (en) 1996-07-04 2001-07-24 Basf Aktiengesellschaft Process for preparing carrier-borne transition metal catalysts
US6350814B1 (en) 1997-10-11 2002-02-26 Basell Polyolefine Gmbh Polymer mixture with good workability
US6444764B1 (en) 1997-03-11 2002-09-03 Basell Polyolefine Gmbh Supported catalyst system for polymerizing alk-1-enes
US6759500B1 (en) 1999-11-29 2004-07-06 Basell Polyolefine Gmbh High-molecular polypropylene with a broad distribution of the molecular weight and a short isotactic sequence length
US6815490B2 (en) 1996-09-02 2004-11-09 Basell Polyolefine Gmbh Toughened propylene polymers having little tendency to white fracture
US6864208B2 (en) 1999-12-21 2005-03-08 Basell Polyolefine Gmbh Method for production of a solid catalyst for olefin polymerization
US7049264B1 (en) 1999-06-17 2006-05-23 Basell Polyolefine Gmbh Supported catalyst for olefin polymerization
US7816456B2 (en) 1999-12-21 2010-10-19 Basell Polyolefine Gmbh Semicrystalline propylene polymer composition for producing biaxially stretched polypropylene films

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2160283C2 (ru) * 1995-03-10 2000-12-10 Дзе Дау Кемикал Компани Компонент катализатора на носителе, катализатор на носителе, аддукт, применяемый в качестве компонента катализатора полимеризации олефинов, способ полимеризации олефинов
ES2178712T3 (es) 1995-08-10 2003-01-01 Exxonmobil Chem Patents Inc Alumoxano estabilizado por metalocenos.
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
JP2000514493A (ja) 1996-07-15 2000-10-31 モービル・オイル・コーポレーション 吹込成形およびフィルム用途用コモノマー前処理２金属系触媒
US6051525A (en) 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6127302A (en) * 1997-12-09 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
EP1461364A4 (fr) * 2001-11-30 2010-11-17 Exxonmobil Chem Patents Inc Copolymere d'ethylene/d'alpha-olefine constitue d'une combinaison de catalyseurs a site unique et a site non unique, sa preparation et son utilisation
EP3318544B1 (fr) * 2016-11-07 2020-03-18 Scg Chemicals Co. Ltd. Procédé de préparation de cire de polyéthylène polymérisé

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU462389A1 (ru) * 1973-09-10 1977-06-25 Ордена Ленина Институт Химической Физики Ан Ссср Катализатор дл полимеризации олефинов
EP0561476A1 (fr) * 1992-03-18 1993-09-22 Akzo Nobel N.V. Solution de polyméthylaluminoxane avec stabilisation améliorée de la solution

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1319746A (en) * 1971-03-11 1973-06-06 Sakharovskaya G B Method of producing linear polyalkylalumoxanes
SU366207A1 (ru) * 1971-04-08 1973-01-16 ашо НйШйШ ПНО Способ получения полиорганоалюмоксанов
US4900856A (en) * 1988-05-26 1990-02-13 Ethyl Corporation Preparation of metal halide-amine complexes
US5093295A (en) * 1989-03-23 1992-03-03 Idemitsu Kosan Company Limited Process for producing homogeneous aluminoxane solution
US4968827A (en) * 1989-06-06 1990-11-06 Ethyl Corporation Alkylaluminoxane process
US5003095A (en) * 1990-03-08 1991-03-26 Ethyl Corporation Process for preparing methylaluminoxanes
US5066631A (en) * 1990-10-16 1991-11-19 Ethyl Corporation Hydrocarbon solutions of alkylaluminoxane compounds

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU462389A1 (ru) * 1973-09-10 1977-06-25 Ордена Ленина Институт Химической Физики Ан Ссср Катализатор дл полимеризации олефинов
EP0561476A1 (fr) * 1992-03-18 1993-09-22 Akzo Nobel N.V. Solution de polyméthylaluminoxane avec stabilisation améliorée de la solution

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 87, no. 14, 3 October 1977, Columbus, Ohio, US; abstract no. 102851s, CHIRKOV, N.M. ET AL.: "CATALYST FOR POLYMERIZATION OF OLEFINS" page 14; *
CHEMICAL ABSTRACTS, vol. 88, no. 6, 6 February 1978, Columbus, Ohio, US; abstract no. 38222d, MESHKOVA, I.N. ET AL.: "ALKYLALUMINOXANES AS COCATALYSTS OF ETHYLENE POLYMERIZATION" page 5; *
VYSOKOMOL. SOEDIN., SER. B, vol. 19, no. 11, 1977, pages 849 - 852 *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5922631A (en) * 1995-10-19 1999-07-13 Albemarle Corporation Liquid clathrate aluminoxane compositions as co-catalysts with transition metal catalyst compounds
WO1997014700A1 (fr) * 1995-10-19 1997-04-24 Albemarle Corporation Compositions liquides de clathrate d'aluminoxane
US6180737B1 (en) 1996-01-25 2001-01-30 Basf Aktiengesellschaft Process for preparing polymers of C2-C10 alkenes in the presence of metallocene complexes with cationically functionalized cyclopentadienyl ligands
US6022935A (en) * 1996-04-22 2000-02-08 Basf Aktiengesellschaft Preparation of polymers of alk-1-enes in the presence of a supported metallocene catalyst system and of antistatic agent
US5840949A (en) * 1996-05-04 1998-11-24 Basf Aktiengesellschaft Recovery of metallocene complexes
US6127495A (en) * 1996-05-31 2000-10-03 Basf Aktiengesellschaft Preparation of polymers of C2 -C12 -alkenes with the addition of a reaction retarder
US5919961A (en) * 1996-06-03 1999-07-06 Basf Aktiengesellschaft Chiral compounds
US6265339B1 (en) 1996-07-04 2001-07-24 Basf Aktiengesellschaft Process for preparing carrier-borne transition metal catalysts
US6815490B2 (en) 1996-09-02 2004-11-09 Basell Polyolefine Gmbh Toughened propylene polymers having little tendency to white fracture
US6114478A (en) * 1996-12-19 2000-09-05 Basf Aktiengesellschaft Gas-phase polymerization of C2 -C8 -alk-l-enes by means of Ziegler-Natta or metallocene catalyst systems
US6444764B1 (en) 1997-03-11 2002-09-03 Basell Polyolefine Gmbh Supported catalyst system for polymerizing alk-1-enes
US6297323B1 (en) 1997-06-02 2001-10-02 Basf Aktiengesellschaft Polymer mixture
WO1998055546A1 (fr) 1997-06-02 1998-12-10 Basf Aktiengesellschaft Melange polymere
US6350814B1 (en) 1997-10-11 2002-02-26 Basell Polyolefine Gmbh Polymer mixture with good workability
US7049264B1 (en) 1999-06-17 2006-05-23 Basell Polyolefine Gmbh Supported catalyst for olefin polymerization
US6759500B1 (en) 1999-11-29 2004-07-06 Basell Polyolefine Gmbh High-molecular polypropylene with a broad distribution of the molecular weight and a short isotactic sequence length
US6864208B2 (en) 1999-12-21 2005-03-08 Basell Polyolefine Gmbh Method for production of a solid catalyst for olefin polymerization
US7816456B2 (en) 1999-12-21 2010-10-19 Basell Polyolefine Gmbh Semicrystalline propylene polymer composition for producing biaxially stretched polypropylene films

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Publication number Publication date
DE69416735D1 (de) 1999-04-08
DE69416735T2 (de) 1999-07-08
EP0633264B1 (fr) 1999-03-03
JPH07173172A (ja) 1995-07-11
US5466647A (en) 1995-11-14
US5412131A (en) 1995-05-02

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