EP0619136B1 - Method of defoaming a liquid - Google Patents

Method of defoaming a liquid Download PDF

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Publication number
EP0619136B1
EP0619136B1 EP94104601A EP94104601A EP0619136B1 EP 0619136 B1 EP0619136 B1 EP 0619136B1 EP 94104601 A EP94104601 A EP 94104601A EP 94104601 A EP94104601 A EP 94104601A EP 0619136 B1 EP0619136 B1 EP 0619136B1
Authority
EP
European Patent Office
Prior art keywords
liquid
transporting means
opening
mounting frame
agitator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94104601A
Other languages
German (de)
French (fr)
Other versions
EP0619136A1 (en
Inventor
Hideo Noda
Kazuo Kinjo
Takaya Inoue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kansai Chemical Engineering Co Ltd
Original Assignee
Kansai Chemical Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kansai Chemical Engineering Co Ltd filed Critical Kansai Chemical Engineering Co Ltd
Priority to EP98107451A priority Critical patent/EP0861685B1/en
Priority to DK98107451T priority patent/DK0861685T3/en
Publication of EP0619136A1 publication Critical patent/EP0619136A1/en
Application granted granted Critical
Publication of EP0619136B1 publication Critical patent/EP0619136B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/234—Surface aerating
    • B01F23/2342—Surface aerating with stirrers near to the liquid surface, e.g. partially immersed, for spraying the liquid in the gas or for sucking gas into the liquid, e.g. using stirrers rotating around a horizontal axis or using centrifugal force
    • B01F23/23421—Surface aerating with stirrers near to the liquid surface, e.g. partially immersed, for spraying the liquid in the gas or for sucking gas into the liquid, e.g. using stirrers rotating around a horizontal axis or using centrifugal force the stirrers rotating about a vertical axis
    • B01F23/234211—Stirrers thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/234—Surface aerating
    • B01F23/2342—Surface aerating with stirrers near to the liquid surface, e.g. partially immersed, for spraying the liquid in the gas or for sucking gas into the liquid, e.g. using stirrers rotating around a horizontal axis or using centrifugal force
    • B01F23/23421—Surface aerating with stirrers near to the liquid surface, e.g. partially immersed, for spraying the liquid in the gas or for sucking gas into the liquid, e.g. using stirrers rotating around a horizontal axis or using centrifugal force the stirrers rotating about a vertical axis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05—Stirrers
    • B01F27/11—Stirrers characterised by the configuration of the stirrers
    • B01F27/15—Stirrers with tubes for guiding the material

Definitions

  • the present invention relates to a method for extinguishing foam from foamable liquids
  • the fermenting liquids and culturing liquids are very prone to foam. Agitation foam causes foam during the process, and the foam often impairs operability of the process.
  • anti-foaming agents such as silicone is generally adopted.
  • the use of such anti-foaming agents not only requires significant cost, but also poses a risk adversely affecting the fermentation and culturing processes, because these anti-foaming agents are, in themselves, foreign substances to the liquids.
  • the anti-foaming agents are often included as impurities in the product until the product is degraded. It requires additional labor to remove them from the product. Furthermore, they contaminate waste liquid and impede a treatment of waste liquid. Accordingly, addition of anti-foaming agents is not desirable and should be controlled as little as possible.
  • the inventors achieved the present invention as expressed in claim 1 after conducting elaborate research regarding conventional defoaming by agitation.
  • the method of the invention can efficiently and thoroughly extinguish foam and can clean the inner wall surface of agitation tank and the surface of heating and cooling apparatuses and can inhibit the reduction of heat transfer area of the inner wall surface of agitation tank and heating and cooling apparatuses.
  • the mounting frame is designed to mount the agitator blade on an agitator shaft and to hold one or more liquid transporting means.
  • the mounting frame may be formed of either rods, square bars, shaped steels, plates provided with many perforations (sometimes referred to as perforated plates hereinafter) or non-perforated plates. These non-perforated plates and perforated plates are preferably provided at the agitator shaft so as to reduce fluid resistance as much as possible when rotated in liquid.
  • the non-perforated plates are preferably those which have a narrow width when they are used in longitudinal state (in the state perpendicular to rotating plane of the agitator blade).
  • These rods, square bars, shaped steels, perforated plates and non-perforated plates are positioned approximately on the diameter line of the rotating plane.
  • the number of these rods, square bars, shaped steels, perforated plates and non-perforated plates may be one or more.
  • each member may be positioned either on the same rotating plane or on a plane differing from each other.
  • These mounting frames are arranged approximately perpendicular to the agitator shaft.
  • the liquid-transporting means may be ones through which liquid can move and are usually tube bodies, but may be gutter bodies, plate bodies and bottomless and hollow truncated cone bodies.
  • the tube body can be a straight tube as a whole, but may have an upper portion formed straight and a lower portion formed bent or may be nearly S shaped. It is preferred in practice that the bent portion be fixed approximately perpendicular to the rotating axis or slightly inclined downward with respect thereto. Furthermore, the upper straight portion may be preferably directed to obliquely upper or lower direction or to side wall of the agitation tank, or may be bent to optional directions such as toward the rotating axis.
  • the lower bent portion of tube body may be formed either by bending the lower portion or by connecting a separate tube to the end of the straight portion, for example, by welding or screwing.
  • the bent portion of the tube body is preferably formed, on the rotating plane containing the junction point between the bent and straight portions, at an angle of substantially 0-90° to radial direction of the rotating plane, namely, on the radius of the rotating plane or along a circle drawn with a radius equal to the distance from the rotating axis to said junction point, or along the tangent line to the above circle.
  • the whole tube body can be curved along an arc of a circle having a radius nearly equal to the distance from the agitation shaft to the position at which the tube body is fixed.
  • liquid transport means in the form of gutter body or plate body.
  • the upper and lower ends of the tube body are opened in the agitation tank to form an upper opening and a lower opening, respectively.
  • the hollow upper openings and the hollow lower openings may respectively be located either on substantially the same rotating plane or on different planes.
  • Shape of the upper opening of the tube body is unlimited and usually circular form such as circle, ellipse or oval or polygon such as triangle, square, rectangle, rhombus, hexagon or octagon.
  • the upper opening can be covered with a perforated plate and, if necessary, this upper opening can be in the form of funnel and thus, the tube body can be shower spray type tube body.
  • the spray type tube body can also be formed by using a blind tube with no opening as the upper opening portion and perforating many holes therethrough.
  • Shape of the lower opening of the tube body and that of section of the tube body are also unlimited and usually circular form such as circle, ellipse or oval or polygon such as triangle, square, rectangle, rhombus, hexagon or octagon.
  • the gutter body as liquid-transporting means corresponds to the above-mentioned tube body from which the upper part is cut away, and shapes of section and upper and lower openings are, for example, half circle, half ellipse, half oval, U-shape and V-shape, and polygon such as square or rectangle from which one side is omitted.
  • the plate body as liquid-transporting means has a whole side shape such as linear shape or long S shape and has a whole planar shape such as long trapezoid or rectangle or either of these shapes curved at a small curveture.
  • a whole side shape such as linear shape or long S shape and has a whole planar shape such as long trapezoid or rectangle or either of these shapes curved at a small curveture.
  • One of the both ends of this plate body which is allowed to go ahead may be upwardly or downwardly twisted so that the outer periphery side (in use of the agitator) is directed to the mounting frame.
  • the upper end and the lower end of the plate body as the liquid-transporting means correspond to the upper opening and the lower opening, respectively.
  • the shape of upper opening and that of lower opening of the liquid-transporting means such as tube body, gutter body and plate body (sometimes referred to as long and narrow liquid-transporting means hereinafter) may be the same or different.
  • One of the both openings of the long and narrow liquid transporting-means which is allowed to go advance at the time of agitation may be thin and sharp in its end to reduce fluid resistance.
  • the area of the upper opening and the lower opening of the long and narrow liquid-transporting means may be either substantially equal or different, the latter being preferred for practical use. In the latter case, the ratio of the both openings is optionally selected depending on the kind of the liquid, purpose of agitation and operational conditions.
  • either of the openings can be an opening which scoops up the liquid (sometimes referred to as intake opening hereinafter) or an opening which discharges the liquid (sometimes referred to as discharge opening hereinafter), but for practical use the larger opening is normally employed as the intake opening.
  • the area of opening is total area of the holes.
  • the length of the line and that of the curve correspond to the area of the openings.
  • the upper opening is preferably in the form substantially parallel to the mounting frame, namely, flat shape substantially parallel to the rotating plane, for instance, long rectangular, rhombus, oval or ellipse.
  • the upper opening is not covered with a perforated plate and completely opened.
  • the long and narrow liquid-transporting means are arranged either perpendicular or inclined to the mounting frame.
  • the liquid-transporting means become almost parallel to the rotating axis in the former case, while inclined in the latter case.
  • the inclined arrangement is preferred.
  • the long and narrow liquid-transporting means are usually arranged so that the intake opening is allowed to go ahead in rotation of the agitator.
  • the angles of inclination may be the same or different.
  • the angle of inclination of the long and narrow liquid-transporting means may vary depending on the viscosity of the liquid, the size of the long and narrow liquid-transporting means, etc. and is not able to be generally fixed to a given angle. The range from about 15-75° is preferable in practice.
  • a plurality of long and narrow liquid-transporting means arranged on the mounting frame are generally same in size, shape and type, but may be different.
  • the long and narrow liquid-transporting means can be rotatably attached to the mounting frame so as to be able to freely adjust the angle to the rotating axis and the angle to the radial direction of rotating plane.
  • liquid-transporting means is a bottomless and hollow truncated cone body (sometimes referred to as hollow truncated cone body hereinafter)
  • this hollow truncated cone body is attached to the agitation shaft through the mounting frame with allowing the longer axis to substantially coincide with the longer axis of the agitating axis.
  • One hollow truncated cone body may be used as the liquid-transporting means.
  • a plurality of hollow truncated cone bodies differing in diameter may be cocentrically arranged.
  • a baffle may be provided at the inner wall surface of the hollow truncated cone body along the slant of the wall or in the inclined direction.
  • the opening corresponding to the bottom of the truncated cone is the opening of the liquid transporting means.
  • the space formed by side walls of a plurality of the hollow truncated cone bodies is a channel of liquid when the hollow truncated cone bodies are rotated.
  • the hollow truncated cone body is in the form of a reverse truncated cone wherein the opening of smaller diameter forms the lower opening.
  • the opening of smaller diameter and the opening of larger diameter are respectively the intake opening and the discharge opening irrespective of rotating direction of the agitator blade.
  • the liquid in the agitation tank is transferred through the liquid-transporting means according to Bernoulli's theorem and/or centrifugal force by rotating the liquid-transporting means.
  • the agitator blade used in the present invention is rigidly fixed to the agitator shaft by means of the mounting frame or slidably fitted to the shaft.
  • Any fixing may be employed, for example, sealing, screwing, welding or bonding.
  • grooves, projections or projected lines are provided on the surface of the agitator shaft along the longer axis and projections, projected lines or grooves which can be fitted with said grooves, projections or projected lines to slide the agitator blade are provided on the mounting frame.
  • the mounting frame slidably fitted to the agitator shaft can be automatically or manually moved.
  • floats are provided at the mounting frame and floated on the surface of liquid so that the mounting frame can be moved in correspondence to the rising and falling of the surface of liquid in the tank.
  • the mounting frame can be moved up and down by remote handling outside the tank and stopped at a desired position.
  • the mounting frame can be manually moved up and down by suspending the mounting frame by a wire connected to outside and stretching or relaxing the wire outside the tank.
  • the above floats can also serve as the mounting frame.
  • the floats preferably have such a shape and structure as reducing fluid resistance as much as possible in agitation.
  • This agitator blade is usually rotated so as to allow the intake opening to go ahead in operation when a long and narrow liquid-transporting means is used.
  • the rotating speed of the agitator blade is adequately selected according to kinds of liquid, the degree of foamability and the degree of foaming, preferably not smaller than about 2.5 m/sec as a speed of the tip of the blade in practice.
  • the upper opening and the lower opening are located in the space above the surface of liquid and in the liquid in the agitation tank, respectively, and the agitator blade is rotated with allowing the lower opening to go ahead to scoop up the liquid in the tank from the lower opening of the liquid transporting means, thereby to discharge the liquid from the upper opening of the liquid-transporting means.
  • the opening on circumferential side of the rotating plane is exposed above the surface of liquid and is used as an upper opening.
  • the liquid in the tank can be scooped up into the liquid-transporting means from the lower opening on the central side of the rotating plane and can be discharged from the upper opening into the space above the surface of the liquid.
  • the liquid transporting means is a hollow truncated cone body
  • this can be used in the form of reverse truncated cone and the opening of larger diameter may be exposed from the surface of liquid as an upper opening.
  • the liquid discharged from this upper opening is discharged over the surface of foam layer in order to carry out defoaming.
  • the liquid discharged from the upper opening is sprayed to the inner wall surface of the agitation tank and to the surface of heating-cooling apparatuses and is allowed to fall along these surfaces This method is applied to a foamable liquid.
  • the agitator blade used in the present invention may be used in combination with conventional agitation blades such as turbine blades, propellers, angled flat vanes, pitched flat vanes, flat vane disk turbines, flat vanes, curved vanes, or Faudola vanes and Bulmargin vanes, as well as other agitating means such as agitation by jetting and/or ventilating agitation.
  • conventional agitation blades such as turbine blades, propellers, angled flat vanes, pitched flat vanes, flat vane disk turbines, flat vanes, curved vanes, or Faudola vanes and Bulmargin vanes
  • other agitating means such as agitation by jetting and/or ventilating agitation.
  • the combination is preferable.
  • the mounting frame per se can be served as agitator blade.
  • the agitator blade 1 includes a mounting frame 11 and a tube body 12 which is a liquid-transporting means.
  • a non-perforated plate of narrow width is used as the mounting frame 11.
  • a total of six tube bodies 12 which are the liquid transporting means are provided, three on each side of the mounting frame 11. These tube bodies 12 are arranged tilting on the mounting frame 11, and inclined to the agitator shaft 2 (rotating axis) at the time of running. Angle of inclination is about 30°.
  • the tube body 12 consists of an upper straight portion 121 and a lower bent portion 122.
  • the tube body 12 is formed here by screwing the bent portion 122 to the bottom end of the straight portion 121 at the junction point 123.
  • the bent portion 122 is formed at an angle of 90° to the radial direction at rotating plane of the junction point 123, namely, formed to go along the tangent line to a circle drawn on the rotation plane of the junction point 123 with a radius equal to the distance between the junction point 123 and the agitating axis (the center of the rotating plane).
  • the bent portion 122 is attached almost perpendicular (almost parallel to the rotating plane) to the rotating axis (agitator shaft 2).
  • the ends of the straight portion 121 and the bent portion 122 are opened in the agitation tank to form an upper opening 124 and a lower opening 125, respectively.
  • the hollow upper openings 124 and the hollow lower openings 125 are arranged to open on substantially the same rotating plane, respectively.
  • the shape of the upper openings 124 is a flat rectangular form substantially parallel to the mounting frame 11 or the rotating plane, while the shape of the lower openings 125 is substantially circular.
  • the opening direction of the upper openings 124 and the lower openings 125 are upwardly inclined and horizontal, respectively.
  • the area of the upper opening 124 is smaller than that of the lower opening 125.
  • the agitator blade 1 is installed in the agitation tank 3 by fixing the mounting frame 11 with its center to the agitator shaft 2, the frame 11 becoming almost perpendicular to the agitator shaft 2.
  • the agitation tank 3 includes a cylindrical tank body 31, the center of the top plate of which is penetrated by the agitator shaft 2, the point of the penetration being sealed by a shaft seal 32.
  • the lower end of the agitator shaft 2 is borne by a bearing 33 at the bottom of the tank body 31.
  • the top plate and the bottom plate of the tank body 31 are provided with a gas inlet 34 and a liquid outlet 35 and a gas outlet 36, respectively.
  • a pipe is extended from the gas inlet 34 to the inner bottom of the tank body 31, its end portion being provided with a ring gas distributor 37 drilled of many holes, while at the middle of the pipe said bearing 33 being mounted.
  • the agitator shaft 2 is connected to a motor 4 at its top end.
  • the agitator shaft 2 has three turbine blades 5, 5, 5 mounted thereon below the agitator blade 1.
  • the upper opening 124 and the lower opening 125 of the tube body 12 are located in the space above the foam layer 6 on the surface of the liquid and in the unfoamed liquid 7 under the foam layer and the agitator blade 1 is rotated with allowing the lower opening 125 to go ahead (clockwise in Fig. 1) to scoop up the liquid from the lower opening 125 and this liquid is allowed to rise through the liquid transporting means 12 and discharged from the upper opening 124, and sprayed on the surface of the foam layer 6 to smash the foam to carry out defoaming.
  • the liquid thus discharged from the upper opening 124 is sprayed onto the inner wall surface of the tank body 31 and is dropped along the inner wall surface whereby the inner wall surface of the tank body 31 is cleaned and the heat transfer area is effectively used.
  • two frames such as perforated plate bodies of narrow width can be crossed at right angles on the same rotation plane on a plan view as shown in (a) of Fig. 4.
  • the frame may be perforated disk as shown in (b) of Fig. 4.
  • the mounting frame shown here is fitted to the agitator shaft so that its plane is substantially parallel to the rotating plane of the agitator blade.
  • the tube portion 126 of the tube body 12 shown in Fig. 5 is curved upwardly viewing from the side and is also slightly curved viewing from above.
  • the top end of the tube portion 126 is in the form of a funnel, namely, forms a funnel portion 127.
  • the upper opening 124 is in the rectangular form and is covered with a perforated plate.
  • the shape of the lower opening 125 is circular.
  • the opening directions of the upper opening 124 and the lower opening 125 are inclined upwardly and horizontal, respectively.
  • the tube portion 126 of the tube body 12 shown in Fig. 6 is in the form of long S viewing from the side and the top end thereof is bent in downwardly inclined direction and is curved at a small curvature seeing from below.
  • the top end of the tube portion 126 is in the form of a funnel, namely, forms a funnel portion 127.
  • the upper opening 124 is in the form of ellipse and is covered with a perforated plate.
  • the shape of the lower opening 125 is circular.
  • the opening directions of the upper opening 124 and the lower opening 125 are downwardly inclined and horizontal, respectively.
  • the tube portion 126 of the tube body 12 shown in Fig. 7 is in the form of long S viewing from the side and is slightly curved seeing from below.
  • the top end of the tube portion 126 is in the form of a funnel, namely, forms a funnel portion 127.
  • the upper opening 124 is in the form of circle and is covered with a perforated plate.
  • the shape of the lower opening 125 is circular.
  • the opening directions of the upper opening 124 and the lower opening 125 are side direction far off from the agitator shaft and horizontal direction, respectively.
  • the tube portion 126 of the tube body 12 shown in Fig. 8 is in the form of flat S viewing from the side and the lower end is curved at a small curvature seeing from below.
  • the direction of the curving is such as the lower opening 125 coming near the rotating axis when fitted to the mounting frame.
  • the top end of the tube portion 126 is closed to form a blind tube. Many holes are drilled at the underside of the top end portion of the tube portion 126 to form the upper opening 124.
  • the shape of the lower opening 125 is circular.
  • the opening direction of the lower opening 125 is horizontal.
  • the lower part of the tube body is thicker than the upper part and the opening area of the lower opening is larger than that of the upper opening.
  • the gutter body 8 shown in Fig. 9 is in the form of a long and nearly half hollow truncated cone with no bottom.
  • the shape of the upper opening 81 and that of the lower opening 82 are both semicircular. Planar shape is long trapezoid and the lower portion is slightly curved. The curving direction is such that the lower opening 82 comes close to the rotating axis when fitted to the mounting frame.
  • area of the lower opening is larger than that of the upper opening.
  • the area of opening of these liquid transporting means is a length of the arc of the semicircle of the upper and lower end openings.
  • the whole side shape of the plate body 9 shown in (a)-(c) of Fig. 10 is a long S and the whole planar shape is a long trapezoid.
  • a plate body 91 in Figure 10(d) is upwardly bent at the lower end corner 911 (the right end in (d) which is allowed to go behind at the time of rotating).
  • a plate body 92 in Figure 10(e) has a whole front shape of long trapezoid curved at a small curvature.
  • area of the lower opening is larger than that of the upper opening.
  • the area of opening of these liquid transporting means is a length of the straight line of the upper end opening and is defined to be a length of the straight line or the curve of the lower end opening.
  • Fig. 11 shows an agitator blade provided with float 10 which also serves as a mounting frame and slidably fitted to an agitator shaft.
  • the floats 10 in Figure 11 are ring-shaped and have a section of nearly a square. One of them has a larger diameter and the one has a a float of smaller diameter and they are concentrically positioned on the same rotating plane.
  • a plurality of tube bodies 12 are fixed to the inner circumferential side face of the floats 10, 10 by fixers 101 (in Fig. 11, each two of four tube bodies 12 are fixed to the floats 10 on the same diameter symmetrically with respect to the rotating axis as an axis of symmetry and the agitator blade is omitted).
  • the floats 10 are connected by a central ring 102 provided at the center and supporting rods 103. These supporting rods 103 cross each other at right angles.
  • a protrusion 104 is provided at the inner peripheral face of the central ring 102.
  • a groove 21 is cut on the outer peripheral face of the agitator shaft 2 along its longer axis.
  • the agitator blade 1 can be slidably attached to the agitator shaft 2 by inserting the agitator shaft 2 through the central ring 102 and fitting the groove 21 of the agitator shaft with the protrusion 104.
  • Fig. 12 shows the agitator blade used in the present invention comprising an agitator shaft to which tube bodies are fitted at an angle of 0° to the radial direction of rotating plane by the mounting frame.
  • Fig. 12 shows a plan view of the agitator blade and
  • b) shows a sectional view of the agitator blade shown in (a) taken along the line B-B.
  • the tube body 12 is attached to the top end of the mounting frame 11 at an inclination angle of about 45° to the rotating axis 2.
  • the tube 12 is provided at substantially 0° to the radial direction of its rotating plane, namely, on the radius of the rotating plane.
  • the four mounting frames 11 provided with the tube bodies 12 are arranged on the outer periphery of the central ring 102 at a center angle of 90°.
  • the tube body 12 is an almost straight cylinder.
  • the upper end is nearly horizontally bent and the top end is flattened in horizontal direction.
  • the shape of the lower opening is circle.
  • the agitator shaft 2 is inserted through the central ring 102.
  • the upper opening 124 and the lower opening 125 of the tube body 12 are respectively a dicharge opening and intake opening irrespective of the direction of rotating direction of the agitator blade.
  • the hollow truncated cone body 201 is the liquid-transporting means which is attached to the agitator shaft 2 with the longer axis thereof being allowed to nearly coincide with the longer axis of the agitator shaft 2.
  • Four baffles 203 are provided at equal intervals on the inner peripheral face of this hollow truncated cone body along the inclination of the inner peripheral face.
  • This hollow truncated cone body 201 is in the form of a reverse truncated cone with the larger opening being an upper opening and arranged on the central ring 102 through mounting frame 11. Through this central ring 102 is inserted the agitator shaft 2.
  • the lower opening 204 of smaller diameter and the upper opening 205 of larger diameter are respectively an intake opening and a discharge opening irrespective of its rotating direction.
  • the liquid in the agitation tank is scooped up from the lower opening 204 as an intake opening and is allowed to rise along the inner peripheral face of this hollow truncated cone body 201 and discharged from the upper opening 205 as a discharge opening by rotating the agitator blade.
  • the agitator blade shown in Fig. 14 is substantially not different from the agitator blade shown in Fig. 13 except that a hollow truncated cone body 202 having a smaller diameter than that of the hollow truncated cone body 201 and equal in gradient of peripheral wall to the hollow truncated cone body 201 is concentrically provided in the hollow truncated cone body 201, no baffles are provided on the inner peripheral faces of the hollow truncated cone bodies 201 and 202, and the liquid in the agitation tank is allowed to rise through the space 206 between the hollow truncated cone bodies 201 and 202 and along the inner peripheral face of the hollow truncated cone body 202.
  • the agitation tank shown in Fig. 3 was used as a fermentation equipment.
  • the inventive use of the agitator blade facilitated thorough defoamation without any defoaming agent. There was no substantial difference in power required over a case where no agitator blade was used.
  • the method of the present invention makes it possible to completely defoam without any defoaming agent in agitation of foamable liquids. There is no difficulty encountered in fermentation and culturing. No defoaming agents are left unremoved as impurity in the product. High quality of the product is secured. No additional labor is required in order to remove the defoaming agent from the product. A treatment of waste liquid is effected without any difficulty.
  • the inner peripheral face of the agitation tank and the surface of heating cooling apparatuses can be cleaned and the heating surface area can be effectively used without stopping the operation in the agitation tank.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)
  • Accessories For Mixers (AREA)

Description

The present invention relates to a method for extinguishing foam from foamable liquids,
In fermentation or culturing processes, the fermenting liquids and culturing liquids are very prone to foam. Agitation foam causes foam during the process, and the foam often impairs operability of the process. In order to inhibit such foaming and to extinguish such foam, addition of anti-foaming agents such as silicone is generally adopted. The use of such anti-foaming agents, however, not only requires significant cost, but also poses a risk adversely affecting the fermentation and culturing processes, because these anti-foaming agents are, in themselves, foreign substances to the liquids. In addition, the anti-foaming agents are often included as impurities in the product until the product is degraded. It requires additional labor to remove them from the product. Furthermore, they contaminate waste liquid and impede a treatment of waste liquid. Accordingly, addition of anti-foaming agents is not desirable and should be controlled as little as possible.
Moreover, attempts have been made to carry out defoaming by a mechanical means which is to suppress the foam by shearing force by rotating a disk in a foam layer on the surface of the liquid or rotating a frusto-conical tube with allowing the lower opening of the larger diameter to be in the foam layer. However, such means requires a great power and besides, the foam is often merely subdivided and is not extinguished.
The inventors achieved the present invention as expressed in claim 1 after conducting elaborate research regarding conventional defoaming by agitation. The method of the invention can efficiently and thoroughly extinguish foam and can clean the inner wall surface of agitation tank and the surface of heating and cooling apparatuses and can inhibit the reduction of heat transfer area of the inner wall surface of agitation tank and heating and cooling apparatuses.
  • Fig. 1 is a plan view of the agitator blade used in the present invention.
  • Fig. 2 is a side view of the agitator blade used in the present invention.
  • Fig. 3 is a longitudinal sectional view of an agitation tank in which the agitator blade shown in Figs. 1 and 2 is used.
  • Fig. 4 is a plan view of the mounting frame of the agitator blade used in the present invention.
  • Fig. 5 shows a spray shower type tube body which is the liquid-transporting means used in the present invention and (a) and (b) are a side view and a plan view, respectively.
  • Fig. 6 shows a spray shower type tube body which is the liquid-transporting means used in the present invention, and (a) and (b) are a side view and an underside view, respectively.
  • Fig. 7 shows a spray shower type tube body which is the liquid-transporting means used in the present invention, and (a) and (b) are a side view and an underside view, respectively.
  • Fig. 8 shows a spray type tube body which is the liquid-transporting means used in the present invention, and (a) and (b) are a side view and a bottom view, respectively.
  • Fig. 9 shows a gutter body which is the liquid transporting means used in the present invention, and (a), (b) and (c) are an oblique view, a side view and a plan view, respectively.
  • Fig. 10 shows a plate body which is the liquid transporting means used in the present invention and (a), (b) and (c) are an oblique view, a side view and a plan view, respectively and (d) and (e) are an oblique view and a plan view of a modified plate body, respectively.
  • Fig. 11 shows the agitator blade used in the present invention attached slidably to the agitator shaft, and (a) is a plan view and (b) is a sectional view taken along the line A-A.
  • Fig. 12 shows the agitator blade used in the present invention where the tube body which is the liquid-transporting means is attached to the agitation shaft through a mounting frame at an angle of 0° to the radial direction of the rotating plane, and (a) is a plan view of the agitator blade and (b) is a sectional view of the agitator blade shown in (a), taken along the line B-B.
  • Fig. 13 shows the agitator blade used in the present invention where the liquid-transporting means is a hollow truncated cone body, and (a) is a plan view of the agitator blade and (b) is a sectional view of the agitator blade shown in a, taken along the line C-C.
  • Fig. 14 shows the agitator blade used in the present invention where the liquid-transporting means comprises two hollow truncated cone bodies, and (a) is a plan view of the agitator blade and (b) is a sectional view of the agitator blade shown in (a), taken along the line D-D.
    • In the present specification and claims, "lower" and "upper" mean "a position near the bottom of liquid" and "a position far from the bottom", respectively.
    The mounting frame is designed to mount the agitator blade on an agitator shaft and to hold one or more liquid transporting means. The mounting frame may be formed of either rods, square bars, shaped steels, plates provided with many perforations (sometimes referred to as perforated plates hereinafter) or non-perforated plates. These non-perforated plates and perforated plates are preferably provided at the agitator shaft so as to reduce fluid resistance as much as possible when rotated in liquid. The non-perforated plates are preferably those which have a narrow width when they are used in longitudinal state (in the state perpendicular to rotating plane of the agitator blade).
    These rods, square bars, shaped steels, perforated plates and non-perforated plates are positioned approximately on the diameter line of the rotating plane. The number of these rods, square bars, shaped steels, perforated plates and non-perforated plates may be one or more. When plural members are used, each member may be positioned either on the same rotating plane or on a plane differing from each other.
    These mounting frames are arranged approximately perpendicular to the agitator shaft.
    When a plurality of the liquid-transporting means are used, their intervals are appropriately selected depending on viscosity of liquid, size of the liquid-transporting means, diameter of an agitation tank body, and angle between the rotating axis and the liquid tranporting means.
    The liquid-transporting means may be ones through which liquid can move and are usually tube bodies, but may be gutter bodies, plate bodies and bottomless and hollow truncated cone bodies.
    The tube body can be a straight tube as a whole, but may have an upper portion formed straight and a lower portion formed bent or may be nearly S shaped. It is preferred in practice that the bent portion be fixed approximately perpendicular to the rotating axis or slightly inclined downward with respect thereto. Furthermore, the upper straight portion may be preferably directed to obliquely upper or lower direction or to side wall of the agitation tank, or may be bent to optional directions such as toward the rotating axis.
    The lower bent portion of tube body may be formed either by bending the lower portion or by connecting a separate tube to the end of the straight portion, for example, by welding or screwing.
    The bent portion of the tube body is preferably formed, on the rotating plane containing the junction point between the bent and straight portions, at an angle of substantially 0-90° to radial direction of the rotating plane, namely, on the radius of the rotating plane or along a circle drawn with a radius equal to the distance from the rotating axis to said junction point, or along the tangent line to the above circle. Alternatively, the whole tube body can be curved along an arc of a circle having a radius nearly equal to the distance from the agitation shaft to the position at which the tube body is fixed. Moreover, it is also possible to form the whole tube body straight viewing from upper or lower side of the rotating plane and to arrange the tube body on the mounting frame at an angle of substantially 0-90° to the radial direction of rotating plane as mentioned above.
    The same can be applied to the liquid transport means in the form of gutter body or plate body.
    The upper and lower ends of the tube body are opened in the agitation tank to form an upper opening and a lower opening, respectively. When a plurality of the tube bodies are provided, the hollow upper openings and the hollow lower openings may respectively be located either on substantially the same rotating plane or on different planes.
    Shape of the upper opening of the tube body is unlimited and usually circular form such as circle, ellipse or oval or polygon such as triangle, square, rectangle, rhombus, hexagon or octagon.
    The upper opening can be covered with a perforated plate and, if necessary, this upper opening can be in the form of funnel and thus, the tube body can be shower spray type tube body.
    The spray type tube body can also be formed by using a blind tube with no opening as the upper opening portion and perforating many holes therethrough.
    Shape of the lower opening of the tube body and that of section of the tube body are also unlimited and usually circular form such as circle, ellipse or oval or polygon such as triangle, square, rectangle, rhombus, hexagon or octagon.
    The gutter body as liquid-transporting means corresponds to the above-mentioned tube body from which the upper part is cut away, and shapes of section and upper and lower openings are, for example, half circle, half ellipse, half oval, U-shape and V-shape, and polygon such as square or rectangle from which one side is omitted.
    The plate body as liquid-transporting means has a whole side shape such as linear shape or long S shape and has a whole planar shape such as long trapezoid or rectangle or either of these shapes curved at a small curveture. One of the both ends of this plate body which is allowed to go ahead may be upwardly or downwardly twisted so that the outer periphery side (in use of the agitator) is directed to the mounting frame.
    The upper end and the lower end of the plate body as the liquid-transporting means correspond to the upper opening and the lower opening, respectively.
    The shape of upper opening and that of lower opening of the liquid-transporting means such as tube body, gutter body and plate body (sometimes referred to as long and narrow liquid-transporting means hereinafter) may be the same or different.
    One of the both openings of the long and narrow liquid transporting-means which is allowed to go advance at the time of agitation may be thin and sharp in its end to reduce fluid resistance.
    The area of the upper opening and the lower opening of the long and narrow liquid-transporting means may be either substantially equal or different, the latter being preferred for practical use. In the latter case, the ratio of the both openings is optionally selected depending on the kind of the liquid, purpose of agitation and operational conditions.
    Furthermore, in the latter case, either of the openings can be an opening which scoops up the liquid (sometimes referred to as intake opening hereinafter) or an opening which discharges the liquid (sometimes referred to as discharge opening hereinafter), but for practical use the larger opening is normally employed as the intake opening.
    Here, in the case of the opening covered with a perforated plate or the opening comprising many holes, the area of opening is total area of the holes.
    As for the liquid-transporting means of gutter body and plate body, when the top opening is linear or curved, the length of the line and that of the curve correspond to the area of the openings.
    When this agitator blade is used for defoaming, the upper opening is preferably in the form substantially parallel to the mounting frame, namely, flat shape substantially parallel to the rotating plane, for instance, long rectangular, rhombus, oval or ellipse. Preferably, the upper opening is not covered with a perforated plate and completely opened.
    The long and narrow liquid-transporting means are arranged either perpendicular or inclined to the mounting frame. In operation, the liquid-transporting means become almost parallel to the rotating axis in the former case, while inclined in the latter case. In practice, the inclined arrangement is preferred.
    The long and narrow liquid-transporting means are usually arranged so that the intake opening is allowed to go ahead in rotation of the agitator. When a plurality of the long and narrow liquid-transporting means are arranged inclined, the angles of inclination may be the same or different.
    When the inclined arrangement is adopted, the angle of inclination of the long and narrow liquid-transporting means (the angle between the rotating axis and the long and narrow liquid-transporting means) may vary depending on the viscosity of the liquid, the size of the long and narrow liquid-transporting means, etc. and is not able to be generally fixed to a given angle. The range from about 15-75° is preferable in practice.
    A plurality of long and narrow liquid-transporting means arranged on the mounting frame are generally same in size, shape and type, but may be different.
    The long and narrow liquid-transporting means can be rotatably attached to the mounting frame so as to be able to freely adjust the angle to the rotating axis and the angle to the radial direction of rotating plane.
    In case the liquid-transporting means is a bottomless and hollow truncated cone body (sometimes referred to as hollow truncated cone body hereinafter), this hollow truncated cone body is attached to the agitation shaft through the mounting frame with allowing the longer axis to substantially coincide with the longer axis of the agitating axis.
    One hollow truncated cone body may be used as the liquid-transporting means. Alternatively, a plurality of hollow truncated cone bodies differing in diameter may be cocentrically arranged. Moreover, a baffle may be provided at the inner wall surface of the hollow truncated cone body along the slant of the wall or in the inclined direction.
    In the case of liquid-transporting means of hollow truncated cone body, the opening corresponding to the bottom of the truncated cone is the opening of the liquid transporting means.
    The space formed by side walls of a plurality of the hollow truncated cone bodies is a channel of liquid when the hollow truncated cone bodies are rotated.
    The hollow truncated cone body is in the form of a reverse truncated cone wherein the opening of smaller diameter forms the lower opening.
    In this hollow truncated cone body, the opening of smaller diameter and the opening of larger diameter are respectively the intake opening and the discharge opening irrespective of rotating direction of the agitator blade.
    In the present invention, the liquid in the agitation tank is transferred through the liquid-transporting means according to Bernoulli's theorem and/or centrifugal force by rotating the liquid-transporting means.
    The agitator blade used in the present invention is rigidly fixed to the agitator shaft by means of the mounting frame or slidably fitted to the shaft.
    Any fixing may be employed, for example, sealing, screwing, welding or bonding.
    For slidably fitting the agitator blade, for example, grooves, projections or projected lines are provided on the surface of the agitator shaft along the longer axis and projections, projected lines or grooves which can be fitted with said grooves, projections or projected lines to slide the agitator blade are provided on the mounting frame.
    The mounting frame slidably fitted to the agitator shaft can be automatically or manually moved. For example, floats are provided at the mounting frame and floated on the surface of liquid so that the mounting frame can be moved in correspondence to the rising and falling of the surface of liquid in the tank. Alternatively, the mounting frame can be moved up and down by remote handling outside the tank and stopped at a desired position. The mounting frame can be manually moved up and down by suspending the mounting frame by a wire connected to outside and stretching or relaxing the wire outside the tank.
    The above floats can also serve as the mounting frame. The floats preferably have such a shape and structure as reducing fluid resistance as much as possible in agitation.
    This agitator blade is usually rotated so as to allow the intake opening to go ahead in operation when a long and narrow liquid-transporting means is used.
    In the defoaming method of the present invention, the rotating speed of the agitator blade is adequately selected according to kinds of liquid, the degree of foamability and the degree of foaming, preferably not smaller than about 2.5 m/sec as a speed of the tip of the blade in practice.
    In the defoaming method of the present invention, in order to discharge the liquid in the tank from the upper opening of the long and narrow liquid-transporting means into the space above the surface of liquid, when said long and narrow liquid transporting means is provided, for example, at substantially 90° to the radius of rotating plane, the upper opening and the lower opening are located in the space above the surface of liquid and in the liquid in the agitation tank, respectively, and the agitator blade is rotated with allowing the lower opening to go ahead to scoop up the liquid in the tank from the lower opening of the liquid transporting means, thereby to discharge the liquid from the upper opening of the liquid-transporting means.
    When the long and narrow liquid-transporting means is provided, for example, at 0° to the radius of rotating plane, the opening on circumferential side of the rotating plane is exposed above the surface of liquid and is used as an upper opening. Thus, irrespective of whether the long and narrow liquid-transporting means is rotated clockwise or counterclockwise in respect to the rotating axis, the liquid in the tank can be scooped up into the liquid-transporting means from the lower opening on the central side of the rotating plane and can be discharged from the upper opening into the space above the surface of the liquid.
    When the liquid transporting means is a hollow truncated cone body, this can be used in the form of reverse truncated cone and the opening of larger diameter may be exposed from the surface of liquid as an upper opening. The liquid discharged from this upper opening is discharged over the surface of foam layer in order to carry out defoaming.
    Furthermore, the liquid discharged from the upper opening is sprayed to the inner wall surface of the agitation tank and to the surface of heating-cooling apparatuses and is allowed to fall along these surfaces This method is applied to a foamable liquid.
    It is also possible to use for defoaming the liquid discharged from the upper openings of a part of a plurality of the long and narrow liquid-transporting means and to use the liquid discharged from the upper openings of the other liquid transporting means for cleaning of the inner wall surface of the tank and the surface of heating cooling apparatuses and increasing the heat transfer area.
    The agitator blade used in the present invention may be used in combination with conventional agitation blades such as turbine blades, propellers, angled flat vanes, pitched flat vanes, flat vane disk turbines, flat vanes, curved vanes, or Faudola vanes and Bulmargin vanes, as well as other agitating means such as agitation by jetting and/or ventilating agitation. The combination is preferable.
    The mounting frame per se can be served as agitator blade.
    The present invention will be explained in concrete by the examples referring to the drawings, but it is not limited thereto.
    According to Figures 1 to 11, the agitator blade 1 includes a mounting frame 11 and a tube body 12 which is a liquid-transporting means. A non-perforated plate of narrow width is used as the mounting frame 11. A total of six tube bodies 12 which are the liquid transporting means are provided, three on each side of the mounting frame 11. These tube bodies 12 are arranged tilting on the mounting frame 11, and inclined to the agitator shaft 2 (rotating axis) at the time of running. Angle of inclination is about 30°.
    The tube body 12 consists of an upper straight portion 121 and a lower bent portion 122. The tube body 12 is formed here by screwing the bent portion 122 to the bottom end of the straight portion 121 at the junction point 123. The bent portion 122 is formed at an angle of 90° to the radial direction at rotating plane of the junction point 123, namely, formed to go along the tangent line to a circle drawn on the rotation plane of the junction point 123 with a radius equal to the distance between the junction point 123 and the agitating axis (the center of the rotating plane). The bent portion 122 is attached almost perpendicular (almost parallel to the rotating plane) to the rotating axis (agitator shaft 2).
    The ends of the straight portion 121 and the bent portion 122 are opened in the agitation tank to form an upper opening 124 and a lower opening 125, respectively.
    The hollow upper openings 124 and the hollow lower openings 125 are arranged to open on substantially the same rotating plane, respectively.
    The shape of the upper openings 124 is a flat rectangular form substantially parallel to the mounting frame 11 or the rotating plane, while the shape of the lower openings 125 is substantially circular.
    The opening direction of the upper openings 124 and the lower openings 125 are upwardly inclined and horizontal, respectively.
    The area of the upper opening 124 is smaller than that of the lower opening 125.
    The agitator blade 1 is installed in the agitation tank 3 by fixing the mounting frame 11 with its center to the agitator shaft 2, the frame 11 becoming almost perpendicular to the agitator shaft 2.
    The agitation tank 3 includes a cylindrical tank body 31, the center of the top plate of which is penetrated by the agitator shaft 2, the point of the penetration being sealed by a shaft seal 32. The lower end of the agitator shaft 2 is borne by a bearing 33 at the bottom of the tank body 31. The top plate and the bottom plate of the tank body 31 are provided with a gas inlet 34 and a liquid outlet 35 and a gas outlet 36, respectively. A pipe is extended from the gas inlet 34 to the inner bottom of the tank body 31, its end portion being provided with a ring gas distributor 37 drilled of many holes, while at the middle of the pipe said bearing 33 being mounted. The agitator shaft 2 is connected to a motor 4 at its top end. The agitator shaft 2 has three turbine blades 5, 5, 5 mounted thereon below the agitator blade 1.
    In order to carry out defoaming of the liquid in the agitation tank 3 by discharging the liquid from the upper opening 124 of the tube body 12 of the agitator blade 1 into the space above the surface of the liquid, the upper opening 124 and the lower opening 125 of the tube body 12 are located in the space above the foam layer 6 on the surface of the liquid and in the unfoamed liquid 7 under the foam layer and the agitator blade 1 is rotated with allowing the lower opening 125 to go ahead (clockwise in Fig. 1) to scoop up the liquid from the lower opening 125 and this liquid is allowed to rise through the liquid transporting means 12 and discharged from the upper opening 124, and sprayed on the surface of the foam layer 6 to smash the foam to carry out defoaming.
    The liquid thus discharged from the upper opening 124 is sprayed onto the inner wall surface of the tank body 31 and is dropped along the inner wall surface whereby the inner wall surface of the tank body 31 is cleaned and the heat transfer area is effectively used.
    As other possible forms of the mounting frame 11, two frames such as perforated plate bodies of narrow width can be crossed at right angles on the same rotation plane on a plan view as shown in (a) of Fig. 4. Alternatively, the frame may be perforated disk as shown in (b) of Fig. 4.
    The mounting frame shown here is fitted to the agitator shaft so that its plane is substantially parallel to the rotating plane of the agitator blade.
    The tube portion 126 of the tube body 12 shown in Fig. 5 is curved upwardly viewing from the side and is also slightly curved viewing from above. The top end of the tube portion 126 is in the form of a funnel, namely, forms a funnel portion 127. The upper opening 124 is in the rectangular form and is covered with a perforated plate. The shape of the lower opening 125 is circular. The opening directions of the upper opening 124 and the lower opening 125 are inclined upwardly and horizontal, respectively.
    The tube portion 126 of the tube body 12 shown in Fig. 6 is in the form of long S viewing from the side and the top end thereof is bent in downwardly inclined direction and is curved at a small curvature seeing from below. The top end of the tube portion 126 is in the form of a funnel, namely, forms a funnel portion 127. The upper opening 124 is in the form of ellipse and is covered with a perforated plate. The shape of the lower opening 125 is circular. The opening directions of the upper opening 124 and the lower opening 125 are downwardly inclined and horizontal, respectively.
    The tube portion 126 of the tube body 12 shown in Fig. 7 is in the form of long S viewing from the side and is slightly curved seeing from below. The top end of the tube portion 126 is in the form of a funnel, namely, forms a funnel portion 127. The upper opening 124 is in the form of circle and is covered with a perforated plate. The shape of the lower opening 125 is circular. The opening directions of the upper opening 124 and the lower opening 125 are side direction far off from the agitator shaft and horizontal direction, respectively.
    The tube portion 126 of the tube body 12 shown in Fig. 8 is in the form of flat S viewing from the side and the lower end is curved at a small curvature seeing from below. The direction of the curving is such as the lower opening 125 coming near the rotating axis when fitted to the mounting frame.
    The top end of the tube portion 126 is closed to form a blind tube. Many holes are drilled at the underside of the top end portion of the tube portion 126 to form the upper opening 124. The shape of the lower opening 125 is circular. The opening direction of the lower opening 125 is horizontal.
    In the liquid-transporting means shown in Figs. 5-8, the lower part of the tube body is thicker than the upper part and the opening area of the lower opening is larger than that of the upper opening.
    The gutter body 8 shown in Fig. 9 is in the form of a long and nearly half hollow truncated cone with no bottom. The shape of the upper opening 81 and that of the lower opening 82 are both semicircular. Planar shape is long trapezoid and the lower portion is slightly curved. The curving direction is such that the lower opening 82 comes close to the rotating axis when fitted to the mounting frame.
    In the liquid-transporting means shown in Fig. 9, area of the lower opening is larger than that of the upper opening. The area of opening of these liquid transporting means is a length of the arc of the semicircle of the upper and lower end openings.
    The whole side shape of the plate body 9 shown in (a)-(c) of Fig. 10 is a long S and the whole planar shape is a long trapezoid.
    A plate body 91 in Figure 10(d) is upwardly bent at the lower end corner 911 (the right end in (d) which is allowed to go behind at the time of rotating).
    A plate body 92 in Figure 10(e) has a whole front shape of long trapezoid curved at a small curvature.
    In the liquid-transporting means shown in Fig. 10, area of the lower opening is larger than that of the upper opening. The area of opening of these liquid transporting means is a length of the straight line of the upper end opening and is defined to be a length of the straight line or the curve of the lower end opening.
    Fig. 11 shows an agitator blade provided with float 10 which also serves as a mounting frame and slidably fitted to an agitator shaft.
    The floats 10 in Figure 11 are ring-shaped and have a section of nearly a square. One of them has a larger diameter and the one has a a float of smaller diameter and they are concentrically positioned on the same rotating plane. A plurality of tube bodies 12 are fixed to the inner circumferential side face of the floats 10, 10 by fixers 101 (in Fig. 11, each two of four tube bodies 12 are fixed to the floats 10 on the same diameter symmetrically with respect to the rotating axis as an axis of symmetry and the agitator blade is omitted). The floats 10 are connected by a central ring 102 provided at the center and supporting rods 103. These supporting rods 103 cross each other at right angles. A protrusion 104 is provided at the inner peripheral face of the central ring 102. A groove 21 is cut on the outer peripheral face of the agitator shaft 2 along its longer axis. The agitator blade 1 can be slidably attached to the agitator shaft 2 by inserting the agitator shaft 2 through the central ring 102 and fitting the groove 21 of the agitator shaft with the protrusion 104.
    Fig. 12 shows the agitator blade used in the present invention comprising an agitator shaft to which tube bodies are fitted at an angle of 0° to the radial direction of rotating plane by the mounting frame. (a) in Fig. 12 shows a plan view of the agitator blade and (b) shows a sectional view of the agitator blade shown in (a) taken along the line B-B. The tube body 12 is attached to the top end of the mounting frame 11 at an inclination angle of about 45° to the rotating axis 2. The tube 12 is provided at substantially 0° to the radial direction of its rotating plane, namely, on the radius of the rotating plane. The four mounting frames 11 provided with the tube bodies 12 are arranged on the outer periphery of the central ring 102 at a center angle of 90°. The tube body 12 is an almost straight cylinder. The upper end is nearly horizontally bent and the top end is flattened in horizontal direction. The shape of the lower opening is circle. The agitator shaft 2 is inserted through the central ring 102.
    In this agitator blade, the upper opening 124 and the lower opening 125 of the tube body 12 are respectively a dicharge opening and intake opening irrespective of the direction of rotating direction of the agitator blade.
    In the agitator blade shown in Fig. 13, the hollow truncated cone body 201 is the liquid-transporting means which is attached to the agitator shaft 2 with the longer axis thereof being allowed to nearly coincide with the longer axis of the agitator shaft 2. Four baffles 203 are provided at equal intervals on the inner peripheral face of this hollow truncated cone body along the inclination of the inner peripheral face.
    This hollow truncated cone body 201 is in the form of a reverse truncated cone with the larger opening being an upper opening and arranged on the central ring 102 through mounting frame 11. Through this central ring 102 is inserted the agitator shaft 2.
    In this hollow truncated cone body 201, the lower opening 204 of smaller diameter and the upper opening 205 of larger diameter are respectively an intake opening and a discharge opening irrespective of its rotating direction.
    The liquid in the agitation tank is scooped up from the lower opening 204 as an intake opening and is allowed to rise along the inner peripheral face of this hollow truncated cone body 201 and discharged from the upper opening 205 as a discharge opening by rotating the agitator blade.
    The agitator blade shown in Fig. 14 is substantially not different from the agitator blade shown in Fig. 13 except that a hollow truncated cone body 202 having a smaller diameter than that of the hollow truncated cone body 201 and equal in gradient of peripheral wall to the hollow truncated cone body 201 is concentrically provided in the hollow truncated cone body 201, no baffles are provided on the inner peripheral faces of the hollow truncated cone bodies 201 and 202, and the liquid in the agitation tank is allowed to rise through the space 206 between the hollow truncated cone bodies 201 and 202 and along the inner peripheral face of the hollow truncated cone body 202.
    Example of use
    The agitation tank shown in Fig. 3 was used as a fermentation equipment.
    In this equipment, when a customarily employed turbine blade was used in place of the agitator blade as according to the invention defoaming was not able to be performed only by the agitation machine using the turbine blade and when a defoamer was additionally used, the cost for silicone used as the defoamer for completely extinguishing foam was about 70,000 yen per day.
    The inventive use of the agitator blade facilitated thorough defoamation without any defoaming agent. There was no substantial difference in power required over a case where no agitator blade was used.
    The method of the present invention makes it possible to completely defoam without any defoaming agent in agitation of foamable liquids. There is no difficulty encountered in fermentation and culturing. No defoaming agents are left unremoved as impurity in the product. High quality of the product is secured. No additional labor is required in order to remove the defoaming agent from the product. A treatment of waste liquid is effected without any difficulty.
    Furthermore, the inner peripheral face of the agitation tank and the surface of heating cooling apparatuses can be cleaned and the heating surface area can be effectively used without stopping the operation in the agitation tank.

    Claims (8)

    1. A method for defoaming a liquid in a tank, said method comprising
      providing an agitator blade (1) including a mounting frame (11) mounted on an agitator shaft (2), said agitator blade (1) having one or more liquid-transporting means (12; 8; 9; 91, 92; 201; 202) each of which has an upper liquid-discharging end (124, 81; 205) and a lower liquid-intake end (125; 82; 204), said upper liquid-discharging end (124; 81; 205) being positioned above a level of possible foam on a foamable liquid contained in the tank and said lower liquid-intake end (125, 82; 204) being positioned in said liquid;
      rotating the agitator shaft (2) in a manner that the liquid not yet being foamed is suctioned from said lower liquid-intake end (125, 82; 204) and discharged from said upper liquid-discharging end (124, 81; 205); and
      distributing said discharged liquid onto the foam in a manner that defoaming is effected.
    2. The method according to claim 1, wherein said liquid-transporting means are tube bodies (12).
    3. The method according to claim 1, wherein said liquid-transporting means are gutter bodies (8).
    4. The method according to claim 1, wherein said liquid-transporting means are plate bodies (9; 91, 92).
    5. The method according to claim 1, wherein said liquid-transporting means are bottomless and hollow truncated cone bodies (201; 202) which are allowed to substantially coincide with the longer axis of the agitator shaft (2).
    6. The method according to any of claims 2 to 5, wherein said liquid-transporting means (12; 8; 91, 92) are arranged inclined on the mounting frame (11).
    7. The method according to any of the claims 1 to 6, wherein said mounting frame (11) is fixed to the agitator shaft (2).
    8. The method according to any of the claims 1 to 6, wherein said mounting frame (11) is slidably fitted to the agitator shaft (2).
    EP94104601A 1993-03-31 1994-03-23 Method of defoaming a liquid Expired - Lifetime EP0619136B1 (en)

    Priority Applications (2)

    Application Number Priority Date Filing Date Title
    EP98107451A EP0861685B1 (en) 1993-03-31 1994-03-23 An agitation tank
    DK98107451T DK0861685T3 (en) 1993-03-31 1994-03-23 stirring tank

    Applications Claiming Priority (3)

    Application Number Priority Date Filing Date Title
    JP95128/93 1993-03-31
    JP9512893 1993-03-31
    JP9512893 1993-03-31

    Related Child Applications (1)

    Application Number Title Priority Date Filing Date
    EP98107451.1 Division-Into 1998-04-23

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    EP0619136A1 EP0619136A1 (en) 1994-10-12
    EP0619136B1 true EP0619136B1 (en) 1999-07-14

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    EP98107451A Expired - Lifetime EP0861685B1 (en) 1993-03-31 1994-03-23 An agitation tank

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    JP (2) JP3253212B2 (en)
    DE (2) DE69432802T2 (en)
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    CA2298879C (en) 1999-02-22 2004-09-14 Hideo Noda Liquid ejection apparatus and liquid ejection method
    ES2295020T3 (en) * 1999-08-25 2008-04-16 Kansai Chemical Engineering Co. Ltd CRYSTALLIZER APPLIANCE AND METHOD.
    ATE321606T1 (en) * 2000-09-28 2006-04-15 Kansai Chem Eng HEAT TRANSFER DEVICE
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    DE69432802D1 (en) 2003-07-10
    EP0861685A3 (en) 2000-02-09
    JP3253212B2 (en) 2002-02-04
    EP0861685A2 (en) 1998-09-02
    DK0619136T3 (en) 1999-11-29
    EP0861685B1 (en) 2003-06-04
    DE69419444D1 (en) 1999-08-19
    JP2002119838A (en) 2002-04-23
    JPH06335627A (en) 1994-12-06
    DE69432802T2 (en) 2004-05-06
    JP3677227B2 (en) 2005-07-27
    EP0619136A1 (en) 1994-10-12
    DK0861685T3 (en) 2003-06-23
    DE69419444T2 (en) 2000-03-30

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