EP0613836B1 - Spender zur Ausgabe von unter Druck stehendem Schaum - Google Patents

Spender zur Ausgabe von unter Druck stehendem Schaum Download PDF

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Publication number
EP0613836B1
EP0613836B1 EP94400394A EP94400394A EP0613836B1 EP 0613836 B1 EP0613836 B1 EP 0613836B1 EP 94400394 A EP94400394 A EP 94400394A EP 94400394 A EP94400394 A EP 94400394A EP 0613836 B1 EP0613836 B1 EP 0613836B1
Authority
EP
European Patent Office
Prior art keywords
dispenser
dispenser according
frit
lying
foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94400394A
Other languages
English (en)
French (fr)
Other versions
EP0613836A1 (de
Inventor
Patrice Brunerie
Vincent De Laforcade
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP0613836A1 publication Critical patent/EP0613836A1/de
Application granted granted Critical
Publication of EP0613836B1 publication Critical patent/EP0613836B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/28Nozzles, nozzle fittings or accessories specially adapted therefor
    • B65D83/30Nozzles, nozzle fittings or accessories specially adapted therefor for guiding the flow of spray, e.g. funnels, hoods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/75Aerosol containers not provided for in groups B65D83/16 - B65D83/74
    • B65D83/754Aerosol containers not provided for in groups B65D83/16 - B65D83/74 comprising filters in the fluid flow path

Definitions

  • DE-A-26 15 668 which has served as the basis for the preamble of claim 1, relates to a method of manufacturing foam using a distributor comprising a valve and an additional gas outlet opening into a chamber placed before the valve and not in the valve.
  • the additional gas intake is used to make the foam in the dispenser.
  • the product to be dispensed leaves as a foam from the dispensing valve.
  • GB-A-2 184 789 describes a device for dispensing foam using a liquefied propellant comprising a valve and a nozzle.
  • the foam is produced at the outlet of the valve and the nozzle is used to modify the consistency of the foam.
  • the Applicant has found that by providing the distributor with a nozzle for transforming a spray into foam with dimensional characteristics as described below, said distributor is adapted to supply foam under good conditions.
  • the present invention relates to a pressurized foam distributor containing a foaming liquid pressurized by a non-liquefiable compressed gas equipped with a distribution valve and an additional gas intake, said distributor being provided with a push button comprising a spraying member, characterized by the fact that a distribution valve with additional gas intake is used such that the gas / liquid ratio of the mixture distributed is between 95/5 and 99/1 (vol / vol), and that said dispenser is provided with a push button and a nozzle, said nozzle comprising a housing defining an accumulation chamber in which the spraying member sprays the product to be dispensed through a spray nozzle opening into said chamber accumulation, said nozzle having a diameter of between 0.7 and 2 mm, said chamber being closed by a porous sinter constituting at least partially a wall of said chamber re accumulation opposite to that in which is formed the spray nozzle and located at a distance therefrom between 0.5 and 5 mm.
  • the sinter has a thickness of between 0.5 and 4 mm, preferably 0.75 mm; the size of the sintered pores is between 10 and 50 microns, preferably between 15 and 25 microns and more particularly of the order of 20 microns.
  • the non-liquefiable compressed gas is in particular air or nitrogen.
  • a dispenser consists of a container 18 having a bottom 28, and closed at its upper part by a metal cup 3, a seal 2 ensuring the tightness of the closure.
  • the container 18 is filled with a liquid to be sprayed, and with a gas under pressure, for example compressed air.
  • a dispensing valve 7 comprises a valve body 6 and an operating rod 1; the valve body 6, of generally cylindrical shape, has at its upper part a bead 6 has a larger diameter than the rest of the body and allowing the body 6 to be held in place by crimping by the metal cup 3.
  • the transverse upper wall of the cup 3 is pierced with a circular orifice 3 has an annular seal 4, placed inside the bead 6 a , is compressed, during crimping, between the upper wall of the cup 3 and an annular bearing 6 b , concentric with the bead 6 a and carried by the valve body 6, extending to the joint 4 the cylindrical inner wall 25 of the body 6;
  • the operating rod 1 comprises two coaxial cylindrical portions 23 and 24, defining a transverse annular surface 17; the portion 23 of the rod 1 has a diameter slightly less than that of the orifice 3 a of the cup 3, while the portion 24 of the rod 1 has a diameter greater than that of the orifice 3 a , while being slightly smaller than the diameter of the inner wall 25 of the body 6.
  • the portion 23 passes through the seal 4 and the orifice 3 a of the upper wall of the cup 3, the portion 24 is in the chamber 10 defined inside the body 6;
  • the body 6 has, at its lower part, an extension 16, of smaller diameter than that of the rest of the body, along the axis of the body 6, and shaped as a nozzle to which a plunger tube 22, made of plastic, is connected, allowing communication between the chamber 10 and the product to be sprayed contained in the container 18, the dip tube 22 plunging to the vicinity of the bottom 28 of said container.
  • the second cylindrical portion 24 of the rod 1 has an axial blind passage 14 followed by a radial passage 5 passing through the wall of said second portion 24, said axial 14 and radial 5 passages opening respectively into the chamber 10.
  • a blind axial channel 13 is also provided in the first portion 23 of the rod 1; the channel 13 is, moreover, in communication with the outside of the rod 1 by a radial channel 12 passing through the wall of the first portion 23 of the rod 1; the section of said channel 12 through which it opens to the outside is less than the thickness of the joint 4; in the rest position, as shown in the drawing, the channel 12 opens to the right of the thickness of the seal 4.
  • the dispenser comprises a push button 30; the push button 30 comprises a cylindrical body 31 of circular section having at its lower part a housing 32 allowing the fitting of the portion 23 of the rod 1 to place the push button 30 on the container 18.
  • the body 31 carries a col 33; according to an exemplary embodiment, the neck 33 is inclined relative to the axis longitudinal of the body 31.
  • the body 31 and the neck 33 are crossed by channels 37 and 38, in the extension of one another, the channel 37 opening into the housing 32, and the channel 38 ending in a nozzle 39 spray.
  • the dispenser according to the invention operates as follows. From the rest position, as shown in the figure, a downward action on the push button 30, therefore on the operating rod 1, lowers the latter in the body 6; the radial channel 12 is no longer obstructed by the seal 4. Thus, the liquid to be sprayed is pushed by the gas under pressure from the dip tube 22 towards the chamber 10 and the channels 14, 5, 12, 13, and towards the spray nozzle 39; in parallel, the small orifice 8 communicating the upper part of the container containing the pressurized gas with the chamber 10, pressurized gas is also brought to join the nozzle via the upper part of the chamber 10 and the channels 12 and 13; in fact, it is a mixture of propellant gas and liquid product which is sprayed through the spray nozzle 39; the pressure drop through the additional gas intake constituted by the small orifice 8 results in a pressure in the chamber 10 lower than the pressure in the container 18, which allows the distribution of the product, from the container, as described below -above.
  • the neck 33 supports a housing 34 defining a chamber 40 for accumulation; according to the example shown, the housing 34 is cylindrical, of circular section, along an axis perpendicular to the longitudinal axis of the container 18.
  • the nozzle 39 opens into the chamber 40 of the housing 34 which, on the side opposite to the nozzle 39, is closed by a pellet 36 of sintered material held by a support cover 35 clipped onto the housing 34.
  • the nozzle having a diameter between 0.7 and 2 mm, and the pellet 36 being at a distance from the nozzle 39 between 0.5 and 5 mm, the spray produced by the valve 7 is distributed in the form of foam at the outlet of the housing 34.
  • Excellent results have been obtained with a sinter having a thickness of between 0.5 and 4 mm, preferably 0.75 mm , the size of the sintered pores being of the order of 20 microns.
  • the dispenser is advantageously pressurized with compressed air, at a pressure of 1.5 to 6 bars, preferably 3.5 to 6 bars; the section of the orifice 8 is such that the spray produced in the housing 34 contains by volume 95 to 99% of air.
  • the air is replaced by another non-liquefiable compressed gas such as nitrogen.
  • the housing 34 and the push button 30 are in one piece; alternatively, the housing 34 is attached to the conventional button 30 provided.
  • the bottom 28 of the container 18 has a connector 26 provided with a valve 27, for example of the ball valve type, allowing the entry of pressurized gas into the container 18, but opposing its exit.
  • This connector 26 allows connection to a source of pressurized gas, in particular the outlet of a compressor (not shown), which allows the container 18 to be recharged with pressurized gas.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Nozzles (AREA)

Claims (8)

  1. Spender von unter Druck stehendem Schaum, wobei der Spender eine schäumende Flüssigkeit enthält, die durch ein nicht verflüssigbares verdichtetes Gas unter Druck gesetzt ist, sowie mit einem Abgabeventil (7) und einem zusätzlichen Gasanschluß versehen ist und einen ein Zerstäubungsorgan aufweisenden Druckknopf besitzt, dadurch gekennzeichnet, daß ein Abgabeventil (7) mit zusätzlichem Gasanschluß verwendet wird, wobei das Verhältnis Gas/Flüssigkeit der abgegebenen Mischung 95/5 bis 99/1 (Vol./Vol.) beträgt, und daß der Spender mit einem Druckknopf und einem Aufsatz versehen ist, der ein Gehäuse (34) aufweist, das eine Sammelkammer (40) definiert, in der das Zerstäubungsorgan das zu spendende Produkt über eine in die Sammelkammer (40) mündende Zerstäubungsdüse (39) zerstäubt, die einen Durchmesser von 0,7 bis 2 mm hat, wobei die Kammer (40) durch ein poröses Sinterelement (36) geschlossen ist, das mindestens zum Teil eine Wand der Sammelkammer (40) bildet, die zu derjenigen gegenüberliegt, in der die Zerstäubungsdüse (39) vorgesehen ist und die in einem Abstand von 0,5 bis 5 mm von dieser angeordnet ist.
  2. Spender nach Anspruch 1, dadurch gekennzeichnet, daß das Sinterelement (36) eine Dicke von 0,5 bis 4 mm, vorzugsweise 0,75 mm, hat.
  3. Spender nach Anspruch 2, dadurch gekennzeichnet, daß die Größe der Poren des Sinterelements (36) 10 bis 50 Mikron beträgt.
  4. Spender nach Anspruch 3, dadurch gekennzeichnet, daß die Größe der Poren des Sinterelements (36) 15 bis 25 Mikron beträgt.
  5. Spender nach Anspruch 4, dadurch gekennzeichnet, daß die Größe der Poren des Sinterelements (36) etwa 20 Mikron beträgt.
  6. Spender nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß die Zerstäubung unter einem absoluten Druck von 1,5 bis 6 bar stattfindet.
  7. Spender nach Anspruch 6, dadurch gekennzeichnet, daß die Zerstäubung unter einem absoluten Druck von 3,5 bis 6 bar stattfindet.
  8. Spender nach Anspruch 6, dadurch gekennzeichnet, daß der Druck durch verdichtete Druckluft hergestellt wird, die das Treibgas des in Form von Schaum abzugebenden Produkts bildet.
EP94400394A 1993-03-05 1994-02-24 Spender zur Ausgabe von unter Druck stehendem Schaum Expired - Lifetime EP0613836B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9302575A FR2702196B1 (fr) 1993-03-05 1993-03-05 Distributeur de mousse sous pression.
FR9302575 1993-03-05

Publications (2)

Publication Number Publication Date
EP0613836A1 EP0613836A1 (de) 1994-09-07
EP0613836B1 true EP0613836B1 (de) 1996-10-23

Family

ID=9444695

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94400394A Expired - Lifetime EP0613836B1 (de) 1993-03-05 1994-02-24 Spender zur Ausgabe von unter Druck stehendem Schaum

Country Status (5)

Country Link
US (1) US5368231A (de)
EP (1) EP0613836B1 (de)
DE (1) DE69400767T2 (de)
ES (1) ES2093493T3 (de)
FR (1) FR2702196B1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5881493A (en) * 1995-09-14 1999-03-16 D. B. Smith & Co. Inc. Methods for applying foam
FR2755109B1 (fr) * 1996-10-25 1999-01-08 Oreal Dispositif de distribution de mousse
FR2772007B1 (fr) * 1997-12-08 2000-02-04 Sivel Dispositif de conditionnement et distribution d'un produit, avec pompe manuelle et recipient a filtre d'entree d'air dans le recipient
GB9912356D0 (en) 1999-05-26 1999-07-28 Btg Int Ltd Generation of microfoam
GB0028692D0 (en) 2000-11-24 2001-01-10 Btg Int Ltd Generation of therapeutic microform
US8512680B2 (en) 2001-08-08 2013-08-20 Btg International Ltd. Injectables in foam, new pharmaceutical applications
GB0321210D0 (en) * 2003-09-10 2003-10-08 Btg Int Ltd Apparatus and method for dispensing foam
SI1701701T1 (sl) * 2003-11-17 2010-05-31 Btg Int Ltd Postopki za pripravo pene ki obsega sklerozirajoče sredstvo
US8048439B2 (en) 2003-11-17 2011-11-01 Btg International Ltd. Therapeutic foam
US7571841B2 (en) * 2004-04-19 2009-08-11 Illinois Tool Works, Inc. Interchangeable adapter for in-can and on-can fuel cells
US7392922B2 (en) * 2004-04-19 2008-07-01 Illinois Tool Works Inc. In-can fuel cell metering valve
US20050274743A1 (en) * 2004-05-26 2005-12-15 Solo, Inc. Portable foaming apparatus
GB0509824D0 (en) 2005-05-13 2005-06-22 Btg Int Ltd Therapeutic foam
FR2903329B3 (fr) * 2006-07-10 2008-10-03 Rexam Dispensing Systems Sas Buse de pulverisation, dispositif de pulverisation et utilisation de ce dispositif.
WO2011138186A1 (en) * 2010-05-05 2011-11-10 Unilever Plc Actuator for an aerosol container
US8978937B2 (en) 2010-05-05 2015-03-17 Conopco Inc. Actuator for an aerosol container
US11285277B2 (en) * 2014-03-31 2022-03-29 Boehringer Ingelheim Vetmedica Gmbh Inhaler
WO2015149921A1 (en) 2014-03-31 2015-10-08 Boehringer Ingelheim Vetmedica Gmbh Inhaler
US9758295B2 (en) * 2015-06-25 2017-09-12 The Gillette Company Compressible valve for a pressurized container
US10166666B2 (en) 2015-11-25 2019-01-01 Illinois Tool Works Inc. Adapter for combustion tool fuel cells
EP3513880B1 (de) 2018-01-23 2021-08-25 The Procter & Gamble Company Abgabevorrichtung, die für schäumende produkte geeignet ist
US11267644B2 (en) * 2018-11-08 2022-03-08 The Procter And Gamble Company Aerosol foam dispenser and methods for delivering a textured foam product

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3653553A (en) * 1969-10-27 1972-04-04 Dart Ind Inc Self-cleaning valve for aerosol containers
AU1264976A (en) * 1975-04-09 1977-10-13 Spitzer J G Aerosol containders
GB1572818A (en) * 1976-08-20 1980-08-06 Afa Corp Foam device
US4174811A (en) * 1977-02-15 1979-11-20 Firma Airotechnik Siegfried Binder Gmbh Fluid substance sprayer having propellant gas and substance refill
US4156505A (en) * 1977-09-28 1979-05-29 Bennett Robert S Device for producing foam
JPS6020262B2 (ja) * 1981-11-24 1985-05-21 東洋製罐株式会社 泡状液体発生絞り出し容器
FR2592004B1 (fr) * 1985-12-24 1988-09-02 Oreal Recipient pressurise destine a distribuer, de facon controlee, une mousse de qualite amelioree
LU86368A1 (fr) * 1986-03-24 1987-11-11 Oreal Procede pour preparer et distribuer un produit comprenant au moins deux composants,et dispositif pour sa mise en oeuvre
JPH0615891Y2 (ja) * 1986-10-31 1994-04-27 高圧化工株式会社 発泡性液体の小出し容器
FR2672038B1 (fr) * 1991-01-25 1993-05-14 Oreal Dispositif distributeur de mousse a partir d'un recipient pressurise.

Also Published As

Publication number Publication date
FR2702196B1 (fr) 1995-05-12
FR2702196A1 (fr) 1994-09-09
DE69400767D1 (de) 1996-11-28
ES2093493T3 (es) 1996-12-16
US5368231A (en) 1994-11-29
EP0613836A1 (de) 1994-09-07
DE69400767T2 (de) 1997-02-27

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