EP0601792A1 - Lavatory cleansing compositions - Google Patents

Lavatory cleansing compositions Download PDF

Info

Publication number
EP0601792A1
EP0601792A1 EP93309649A EP93309649A EP0601792A1 EP 0601792 A1 EP0601792 A1 EP 0601792A1 EP 93309649 A EP93309649 A EP 93309649A EP 93309649 A EP93309649 A EP 93309649A EP 0601792 A1 EP0601792 A1 EP 0601792A1
Authority
EP
European Patent Office
Prior art keywords
hydrogen peroxide
weight
composition
agent
limescale removing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP93309649A
Other languages
German (de)
French (fr)
Inventor
Nigel Frederick Cooper
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jeyes Group Ltd
Original Assignee
Jeyes Group Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jeyes Group Ltd filed Critical Jeyes Group Ltd
Publication of EP0601792A1 publication Critical patent/EP0601792A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/08—Acids

Definitions

  • This invention is concerned with improvements in and relating to lavatory cleansing compositions; more particularly, the invention is concerned with thickened liquid lavatory cleansing compositions for application to toilet bowls.
  • the present invention provides a thickened aqueous toilet cleaning composition
  • a thickened aqueous toilet cleaning composition comprising
  • compositions in accordance with the invention are intended for application to the inside surface especially of a toilet bowl to provide a limescale removing action and, also, to provide a bleaching action due to the presence of hydrogen peroxide).
  • the compositions of the invention will tend to cling to the inner surface of the toilet bowl, thereby providing a longer contact time for improved limescale removing and bleaching activity.
  • compositions in accordance with the invention will be packaged in so-called “squeeze bottles” so that a jet of the composition may be directed to the desired portion of the toilet bowl, optionally through an angled orifice jet provided on the squeeze container.
  • the limescale removal agent is acidic in nature and should be water-soluble.
  • the preferred limescale removing agent is phosphoric acid but other acids may be used such as sulphamic or sulphuric acids and, surprisingly, hydrochloric acid.
  • organic acids may be employed, such as acetic acid, and, in accordance with a modification of the invention, some or all of the limescale removal agent and peroxide may be replaced by an organic peracid such as peracetic acid.
  • the limescale removing agent should be present in the composition in an amount sufficient to afford adequate limescale removing activity, e.g. in an amount of from 1 to 20% by weight, preferably 2 to 7% by weight.
  • the hydrogen peroxide will be introduced into the composition in the form of an aqueous solution thereof, typically containing to 5% by weight of H2O2.
  • the hydrogen peroxide should be present in the final make up composition in an amount sufficient to afford effective bleaching activity, typically it will be present in an amount of from 1 to 15 % by weight, more especially 2 to 6 % by weight.
  • a suitable buffering agent for use in the composition is sodium borate and this is suitably present in an amount of 1 to 10 % by weight, preferably 1 to 2 % by weight.
  • a range of thickening agents may be used to thicken the compositions in accordance with the invention.
  • Preferred systems are those described in EP-A-0265979 and basically comprising a quaternary ammonium salt or amine oxide sulphate together with cumene sulphate, xylene sulphonate and/or toluene sulphonate, suitably in the proportions therein mentioned.
  • compositions in accordance with the invention can, and often will, contain other ingredients.
  • other adjuvants such as perfumes and/or colorants may be present, e.g. in amounts of up to about 1.5% by weight.
  • Suitable colorants are water-insoluble pigments such as Unisperse green or Flexobrite yellow.
  • composition was made up:- aqueous H2O2 solution (35%) 14.30 % by wt hexadecyl trimethylammonium chloride 7.11 % by wt aqueous sodium xylene sulphonate solution (30%) 4.00 % by wt sodium borate 1.50 % by wt demineralized water to 100 % by wt Perfume 0.10 % by wt Unisperse green (1%) 0.45 % by wt Flexobrite yellow (1%) 0.18 % by wt Phosphoric acid 5.0 % by wt
  • compositions were prepared, replacing the phosphoric acid with other acids as noted above.
  • a modified composition was prepared by replacing the hydrogen peroxide solution and phosphoric acid by an aqueous solution comprising about 1% peracetic acid, about 8% acetic acid and about 7% hydrogen peroxide.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

A thickened aqueous toilet cleaning composition comprises
  • (i) an acidic limescale removing agent;
  • (ii) hydrogen peroxide;
  • (iii) a buffering agent;
  • (iv) one or more thickening agents; and
  • (v) water.

Description

  • This invention is concerned with improvements in and relating to lavatory cleansing compositions; more particularly, the invention is concerned with thickened liquid lavatory cleansing compositions for application to toilet bowls.
  • Basically, the present invention provides a thickened aqueous toilet cleaning composition comprising
    • (i) an acidic limescale removing agent;
    • (ii) hydrogen peroxide;
    • (iii) a buffering agent;
    • (iv) one or more thickening agents; and
    • (v) water.
  • The compositions in accordance with the invention are intended for application to the inside surface especially of a toilet bowl to provide a limescale removing action and, also, to provide a bleaching action due to the presence of hydrogen peroxide). By virtue of being thickened, that is more viscous, the compositions of the invention will tend to cling to the inner surface of the toilet bowl, thereby providing a longer contact time for improved limescale removing and bleaching activity.
  • Typically, compositions in accordance with the invention will be packaged in so-called "squeeze bottles" so that a jet of the composition may be directed to the desired portion of the toilet bowl, optionally through an angled orifice jet provided on the squeeze container.
  • The limescale removal agent is acidic in nature and should be water-soluble. The preferred limescale removing agent is phosphoric acid but other acids may be used such as sulphamic or sulphuric acids and, surprisingly, hydrochloric acid. Alternatively, organic acids may be employed, such as acetic acid, and, in accordance with a modification of the invention, some or all of the limescale removal agent and peroxide may be replaced by an organic peracid such as peracetic acid. The limescale removing agent should be present in the composition in an amount sufficient to afford adequate limescale removing activity, e.g. in an amount of from 1 to 20% by weight, preferably 2 to 7% by weight.
  • The hydrogen peroxide will be introduced into the composition in the form of an aqueous solution thereof, typically containing to 5% by weight of H₂O₂. The hydrogen peroxide should be present in the final make up composition in an amount sufficient to afford effective bleaching activity, typically it will be present in an amount of from 1 to 15 % by weight, more especially 2 to 6 % by weight.
  • A suitable buffering agent for use in the composition is sodium borate and this is suitably present in an amount of 1 to 10 % by weight, preferably 1 to 2 % by weight.
  • A range of thickening agents may be used to thicken the compositions in accordance with the invention. Preferred systems are those described in EP-A-0265979 and basically comprising a quaternary ammonium salt or amine oxide sulphate together with cumene sulphate, xylene sulphonate and/or toluene sulphonate, suitably in the proportions therein mentioned.
  • In addition to the above ingredients, compositions in accordance with the invention can, and often will, contain other ingredients. Thus, other adjuvants such as perfumes and/or colorants may be present, e.g. in amounts of up to about 1.5% by weight. Suitable colorants are water-insoluble pigments such as Unisperse green or Flexobrite yellow.
  • In order that the invention may be well understood the following Example is given by way of illustration only.
    • Example
  • The following composition was made up:-
    aqueous H₂O₂ solution (35%) 14.30 % by wt
    hexadecyl trimethylammonium chloride 7.11 % by wt
    aqueous sodium xylene sulphonate solution (30%) 4.00 % by wt
    sodium borate 1.50 % by wt
    demineralized water to 100 % by wt
    Perfume 0.10 % by wt
    Unisperse green (1%) 0.45 % by wt
    Flexobrite yellow (1%) 0.18 % by wt
    Phosphoric acid 5.0 % by wt
  • Similar compositions were prepared, replacing the phosphoric acid with other acids as noted above. A modified composition was prepared by replacing the hydrogen peroxide solution and phosphoric acid by an aqueous solution comprising about 1% peracetic acid, about 8% acetic acid and about 7% hydrogen peroxide.

Claims (3)

  1. A thickened aqueous toilet cleaning composition comprising
    (i) an acidic limescale removing agent;
    (ii) hydrogen peroxide;
    (iii) a buffering agent;
    (iv) one or more thickening agents; and
    (v) water.
  2. A composition as claimed in claim 1 containing from 1 to 20% by weight of limescale removing agent, from 1 to 15% by weight of hydrogen peroxide, and from 1 to 10% by weight of buffering agent.
  3. A modification of the composition claimed in claim 1 or claim 2 in which all or a part of the limescale removing agent and the hydrogen peroxide are replaced by an organic peracid.
EP93309649A 1992-12-03 1993-12-02 Lavatory cleansing compositions Withdrawn EP0601792A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB929225333A GB9225333D0 (en) 1992-12-03 1992-12-03 Lavatory cleansing compositions
GB9225333 1992-12-03

Publications (1)

Publication Number Publication Date
EP0601792A1 true EP0601792A1 (en) 1994-06-15

Family

ID=10726087

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93309649A Withdrawn EP0601792A1 (en) 1992-12-03 1993-12-02 Lavatory cleansing compositions

Country Status (2)

Country Link
EP (1) EP0601792A1 (en)
GB (2) GB9225333D0 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996017044A1 (en) * 1994-11-25 1996-06-06 The Procter & Gamble Company Thickened bleaching compositions, method of use and process for making them
EP0726309A1 (en) * 1995-02-08 1996-08-14 The Procter & Gamble Company Limescale removal compositions
EP0745663A1 (en) 1995-05-31 1996-12-04 The Procter & Gamble Company Colored acidic aqueous liquid compositions comprising a peroxy-bleach
US5910473A (en) * 1995-05-31 1999-06-08 The Procter & Gamble Company Colored acidic aqueous liquid compositions comprising a peroxy-bleach
EP1132458A2 (en) * 1995-02-08 2001-09-12 The Procter & Gamble Company Limescale removing compositions
GB2393464A (en) * 2002-09-24 2004-03-31 Bj Services Co Compositions for improving the permeability of wells
DE102004056554A1 (en) * 2004-11-23 2006-05-24 Buck-Chemie Gmbh Adhesive sanitary cleaning and scenting agent

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2283048T3 (en) * 1998-11-10 2007-10-16 THE PROCTER & GAMBLE COMPANY CLEANING PROCEDURE OF ENAMEL SURFACES.

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0188025A2 (en) * 1985-01-03 1986-07-23 Unilever N.V. Liquid bleaching compositions
JPH01240600A (en) * 1988-03-18 1989-09-26 Seiwa Kogyo Kk Cleaning agent for toilet
US5078896A (en) * 1986-09-29 1992-01-07 Akzo N.V. Thickened aqueous cleaning compositions
JPH04332800A (en) * 1991-05-07 1992-11-19 Kao Corp Detergent composition for acidic rigid surface
JPH04332799A (en) * 1991-05-07 1992-11-19 Kao Corp Detergent composition for acidic rigid surface

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2602563B2 (en) * 1989-12-15 1997-04-23 花王株式会社 Liquid oxygen bleach composition
ES2062748T3 (en) * 1991-06-14 1994-12-16 Procter & Gamble STABLE BLEACHING COMPOSITIONS CONTAINING HYDROGEN PEROXIDE.

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0188025A2 (en) * 1985-01-03 1986-07-23 Unilever N.V. Liquid bleaching compositions
US5078896A (en) * 1986-09-29 1992-01-07 Akzo N.V. Thickened aqueous cleaning compositions
JPH01240600A (en) * 1988-03-18 1989-09-26 Seiwa Kogyo Kk Cleaning agent for toilet
JPH04332800A (en) * 1991-05-07 1992-11-19 Kao Corp Detergent composition for acidic rigid surface
JPH04332799A (en) * 1991-05-07 1992-11-19 Kao Corp Detergent composition for acidic rigid surface

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
ANONYMOUS: "Thickenend cleaning composition", RESEARCH DISCLOSURE, no. 301, May 1989 (1989-05-01), NEW YORK, pages 303 *
DATABASE WPI Derwent World Patents Index; AN 89-321432 *
DATABASE WPI Derwent World Patents Index; AN 93-004726 *
DATABASE WPI Derwent World Patents Index; AN 93-004727 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996017044A1 (en) * 1994-11-25 1996-06-06 The Procter & Gamble Company Thickened bleaching compositions, method of use and process for making them
EP0726309A1 (en) * 1995-02-08 1996-08-14 The Procter & Gamble Company Limescale removal compositions
EP1132458A2 (en) * 1995-02-08 2001-09-12 The Procter & Gamble Company Limescale removing compositions
EP1132458A3 (en) * 1995-02-08 2001-09-19 The Procter & Gamble Company Limescale removing compositions
EP0745663A1 (en) 1995-05-31 1996-12-04 The Procter & Gamble Company Colored acidic aqueous liquid compositions comprising a peroxy-bleach
US5910473A (en) * 1995-05-31 1999-06-08 The Procter & Gamble Company Colored acidic aqueous liquid compositions comprising a peroxy-bleach
GB2393464A (en) * 2002-09-24 2004-03-31 Bj Services Co Compositions for improving the permeability of wells
GB2393464B (en) * 2002-09-24 2006-10-18 Bj Services Co Compositions containing a buffer and a peroxide or peracid useful for treating wells
US7156178B2 (en) 2002-09-24 2007-01-02 Bj Services Company Compositions containing a buffer and a peroxide or peracid useful for treating wells
DE102004056554A1 (en) * 2004-11-23 2006-05-24 Buck-Chemie Gmbh Adhesive sanitary cleaning and scenting agent

Also Published As

Publication number Publication date
GB9324751D0 (en) 1994-01-19
GB9225333D0 (en) 1993-01-27
GB2273105A (en) 1994-06-08

Similar Documents

Publication Publication Date Title
EP1473998B1 (en) Enhanced activity hydrogen peroxide disinfectant
US6080712A (en) Thickened peracid compositions
EP0799298B1 (en) Thickened peracid compositions
US6153572A (en) Acidic liquid toilet bowl cleaner
CA2304669A1 (en) Acidic, thickened cleaning and disinfecting compositions
CA2104817A1 (en) Composition and method for developing extensional viscosity in cleaning compositions
AU692667B2 (en) Peracid compositions
EP0601792A1 (en) Lavatory cleansing compositions
US6248705B1 (en) Stable perfumed bleaching compositions
US6042744A (en) Bleaching compositions comprising hypochlorite and delivery systems therefor
EP0784091A1 (en) Stable perfumed bleaching composition
CA2204507C (en) Thickened bleaching compositions, method of use and process for making them
MXPA97003841A (en) Thickening compositions thickenes, method of use and procedure to make mys
JP4323093B2 (en) Alkoxylated amines and their use in cleaning compositions
EP1527156B1 (en) Improvements in or relating to cleaning
WO1997005220A1 (en) Compositions
EP0745663A1 (en) Colored acidic aqueous liquid compositions comprising a peroxy-bleach
EP1123375B1 (en) Thickened liquid hydrogen peroxide bleach compositions
MXPA97009359A (en) Aqueous colored acid liquid compositions that comprise a perox whitener
MXPA00003494A (en) Alkoxylated amines and their usein cleaning compositions
MXPA97004644A (en) Peracid compositions espe

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19941216