EP0599897B1 - Control of cigarette smoke chemistry - Google Patents

Control of cigarette smoke chemistry Download PDF

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Publication number
EP0599897B1
EP0599897B1 EP92916991A EP92916991A EP0599897B1 EP 0599897 B1 EP0599897 B1 EP 0599897B1 EP 92916991 A EP92916991 A EP 92916991A EP 92916991 A EP92916991 A EP 92916991A EP 0599897 B1 EP0599897 B1 EP 0599897B1
Authority
EP
European Patent Office
Prior art keywords
filter element
tobacco
smoke
cigarette
flavour
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP92916991A
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German (de)
French (fr)
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EP0599897A1 (en
Inventor
Warren A. Brackmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rothmans Benson and Hedges Inc
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Rothmans Benson and Hedges Inc
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Publication date
Application filed by Rothmans Benson and Hedges Inc filed Critical Rothmans Benson and Hedges Inc
Publication of EP0599897A1 publication Critical patent/EP0599897A1/en
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Publication of EP0599897B1 publication Critical patent/EP0599897B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure

Definitions

  • the present invention relates to controlling the chemistry of cigarette smoke entering a smoker's mouth, to provide a desirable combination of high sensory appeal and low tar.
  • Tar is a component of cigarette smoke considered undesirable and attempts are continually being made to deliver lower quantities of tar to the smoker.
  • Conventional procedures have included increased filtration and ventilation. However, only a certain level of filtration can be achieved with conventional filters before the pressure drop across the filter becomes unacceptably high.
  • EP-A-226,368 describes the provision of a cigarette in which the filler rod is formed from two different blends of tobacco and which has an approximately uniform delivery of flavour along its length.
  • One of the blends is of high flavour-to-tar ratio tobacco, which may be leaves from the higher part of the plant. Such higher flavour-to-tar ratio tobacco is employed in the novel cigarette provided herein.
  • the present invention seeks to achieve a unique result, in providing the high flavour level associated with popular brands of cigarettes but at a significantly lower tar level.
  • the present invention is able to provide a more uniform delivery of flavour and tar as the cigarette is smoked, as compared with a conventional cigarette.
  • a cigarette smoke filter element comprising:
  • Figure 1 is a graphical presentation of smoking test results.
  • flavour produced by tobacco from such leaves, or the tips generally is too high to be acceptable to a smoker in a conventional cigarette and hence the tobacco usually is blended with tobacco from the whole plant to provide an overall lower flavoured tobacco blend.
  • the applicants have found that it is possible to employ such strongly flavoured tobacco and not only achieve a flavour level comparable to that of popular brands, but thereby deliver a much lower level of tar, consistent with the higher flavour/tar ratio of smoke produced by such tobacco.
  • a higher flavour level may be provided but at a lower or the same tar level, as required.
  • microfine fibers in tubular form may be used herein to decrease the flavour level produced by the tobacco.
  • the microfine fibers in the cylinder thereof generally each has a diameter of about 0.5 to 10 microns.
  • the cylinder of such fibers generally has a thickness of about 0.05 to about 4 mm and a density of about 0.05 to about 0.3 g/cc.
  • the elongate cylinder of microfine fibers preferably is arranged so that all the tobacco smoke passing through the filter containing the microfine fibers cylinder is directed through the cylinder wall.
  • This result may be achieved by providing an outer annulus of high density conventional acetate filter tow material surrounding the microfine fiber cylinder, which in turn surrounds an inner core.
  • a baffle, or other tobacco flow path directing means, is provided at the upstream end to direct tobacco smoke from the cigarette only into the high density material.
  • Such a known filter structure is disclosed in PCT publication No. WO 90/09741.
  • the microfine fiber cylinder is a highly efficient filtration medium but rapidly becomes clogged, so that the tobacco smoke must traverse an increasingly longer path through the outer annulus of conventional tow material and is filtered thereby before passing through the wall of the cylinder of microfine fibers into an inner axial cigarette smoke flow path leading to the downstream end of the filter element.
  • the filter achieves a greater degree of filtration of the tobacco smoke as smoking proceeds and hence tends to counteract the increasing level of flavour and tar delivery which results as smoking progresses, so that a more uniform flavour delivery to the smoker is achieved.
  • EP 364,253 describes a similar filter structure to that provided herein, in which an opening is provided through an elongate cylinder of microfine fibres. However, this opening is provided at the approximate midpoint of the length of the filler, rather than at the upstream end, and does not provide the initial high flavour puffs achieved herein.
  • conventional cellulose acetate tow material is provided at the core of the filter element, with low flow resistance cellulose acetate tow being provided as the outer annulus.
  • a baffle or other smoke path directing means can be provided to direct smoke into the central core.
  • ventilation holes may be provided in the filter wrapper closer to downstream end of the filter than is normal to improve CO dispersion of carbon monoxide (CO). In general, ventilation decreases the CO content of the smoke entering the smoker's mouth.
  • CO carbon monoxide
  • the higher-than-normal flavour/tar ratio tobacco which is used in a cigarette for which the filter element is envisaged produces a higher-than-normal flavour level in the tobacco smoke from a burning cigarette containing the same.
  • the flavour level of tobacco reaching the smoker's mouth from the burning cigarette is decreased to conventional levels.
  • this same ratio may be retained when the smoke reaches the smoker's mouth, so that a significantly lower tar delivery results while the same flavour level is achieved as in a conventional highly-flavoured brand of cigarette.
  • the uniformity of delivery of the tobacco flavour to the smoker from a cigarette can be improved further by providing a greater proportion of more highly-flavoured tobacco towards the lighting end and a greater proportion of less highly-flavoured tobacco towards the filter end of the cigarette.
  • the flavour strength produced by a cigarette increases as smoking progresses.
  • this effect tends to be counteracted.
  • a filler rod containing a combination of differently-flavoured tobacco may be provided in the manner described in US-A-4,896,681. Alternatively, discrete segments of differently-flavoured tobacco may be employed in the filler rod.
  • the present invention therefore, provides a filter element for use with a cigarette, which, in combination, exhibit a high sensory appeal while delivering a low level of tar to the smoker with a more uniform flavour delivery, by a combination of factors, as follows:
  • the latter puff manipulation with respect to the flavour and tar produced in the latter puffs of smoking the cigarette may be effected, as described above, by utilizing a smoke re-route filtration technique optionally in combination with using lesser strength tobacco at the filter end.
  • Flavour strength reset is achieved, as described above, by utilizing a cylinder of microfine fibers as a filter element, optionally in combination with by using lesser strength tobacco at the filter end or preferably by using expanded tobacco at the filter end, or preferably a combination thereof.
  • the cylinder of microfine fibers being incorporated into a smoke re-route filter and a higher proportion of lesser-flavoured expanded tobacco being used at the filter end and a higher proportion of the higher-than-normal flavour tobacco, possessing the high flavour-to-tar ratio, being used at the lighting end.
  • the standard Benson & Hedges 100s (B & H) cigarettes (plot 3) increased from an initial tar level of 0.5 mg to a last puff tar level of 1.8 mg for a total of 13.1 mg.
  • the highly flavoured tobacco was provided as a segment at the lighting end of the cigarette and a segment of expanded tobacco was provided at the filter end. Again a standard B & H filter was used. Plot (4) was obtained for this cigarette. In this instance, the tar rose from an initial level of 0.9 mg to 1.9 mg for the latter puff, for a total tar delivery of 12.5 mg, well below that for the highly flavoured tobacco above.
  • a comparison of plots (4) and (5) illustrates the significant improvement in tar delivery which is attainable using a segment of expanded tobacco at the filter end of the cigarette filler rod. Both plots (4) and (5) exhibit a significant dip in the tar delivery during the middle puffs. The reason for this is unknown but is generally a characteristic of all cigarettes to some degree.
  • plot (2) shown an increase from 0.3 to 1.7 mg during smoking for a total tar deliveries of 10.1 mg, i.e. significantly below the B & H value.
  • a comparison of plots (2) and (5) illustrates the significant effect that the replacement of the conventional filter by one containing a cylinder of microfine fibers has on the tar delivery.
  • plot (1) there is shown the tar delivery from a cigarette having a filter containing a cylinder of microfine fibers and containing a segment of expanded tobacco at the filter end.
  • the tar increased from 0.2 mg for the first puff to 0.9 mg at the last puff, for a total tar delivery of only 4.7 mg.
  • a comparison of plots (1) and (4) illustrates the effect on tar delivery of the utilization of a filter comprising a cylinder of microfine fibers in place of a conventional filter.
  • a comparison of plots (1) and (3) illustrates the effect on the tar delivery of the utilization of a cigarette constructed according to the present invention in comparison to a standard cigarette delivering the same flavour level. It will also be seen that, not only is a lower puff-to-puff level of tar delivery and an overall significantly lower tar delivery achieved, but the curve is flatter in the case of the present invention, so that a more uniform delivery of tar and flavour is achieved.

Landscapes

  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Indole Compounds (AREA)
  • Manufacture Of Tobacco Products (AREA)

Abstract

A high level of flavour can be provided in cigarette smoke at a low tar level while providing a more uniform delivery of flavour and tar as the cigarette is smoked, in comparison to a conventional cigarette. A tobacco blend is employed using higher-than-normal quantities of tobacco from the upper levels of a tobacco plant, to provide an initial high flavour-to-tar ratio. A flavour reset technique is employed to attenuate the flavour strength of the smoke to the smoker, so that such attenuated but acceptable flavour level is provided at a much lower tar level. In addition, latter puff manipulation of the tobacco smoke is effected to decrease the flavour level and tar produced in the latter puffs of smoking to provide a more uniform flavour delivery. Filter element structures and other specific elements to achieve these results are described.

Description

  • The present invention relates to controlling the chemistry of cigarette smoke entering a smoker's mouth, to provide a desirable combination of high sensory appeal and low tar.
  • Tar is a component of cigarette smoke considered undesirable and attempts are continually being made to deliver lower quantities of tar to the smoker. Conventional procedures have included increased filtration and ventilation. However, only a certain level of filtration can be achieved with conventional filters before the pressure drop across the filter becomes unacceptably high.
  • Similarly, only a certain level of ventilation can be achieved before the cigarette smoke takes on an unacceptable "airy" taste. Generally, "low tar" cigarettes tend to be unpopular with smokers, since they fail to deliver sufficient flavour in the smoke to satisfy the smoker.
  • Another problem encountered by smokers is the increasing levels of tar and flavour delivered by a cigarette as it is smoked, sometimes reaching unacceptable levels in the later puffs.
  • EP-A-226,368 describes the provision of a cigarette in which the filler rod is formed from two different blends of tobacco and which has an approximately uniform delivery of flavour along its length. One of the blends is of high flavour-to-tar ratio tobacco, which may be leaves from the higher part of the plant. Such higher flavour-to-tar ratio tobacco is employed in the novel cigarette provided herein.
  • The present invention seeks to achieve a unique result, in providing the high flavour level associated with popular brands of cigarettes but at a significantly lower tar level. In addition, the present invention is able to provide a more uniform delivery of flavour and tar as the cigarette is smoked, as compared with a conventional cigarette.
  • According to the invention there is provided a cigarette smoke filter element, comprising:
  • an elongate plug of tobacco smoke filter material;
  • an elongate cylinder of non-absorbent microfine fibres provided on said elongate plus and having a lesser resistance to the flow of cigarette smoke radially therethrough than longitudinally through said elongate plus; and,
  • an axially-directed annular tobacco smoke flow path located radially outwardly of said elongate cylinder;
    characterised by:
  • said axially directed annular tobacco smoke path having a lesser resistance to the flow of cigarette smoke longitudinally therein than longitudinally through said elongate plus; and,
  • tobacco smoke flow path directing means located at the upstream end of said filter element in the intended direction of flow of cigarette smoke thereto for directing cigarette smoke from a cigarette to which the filter element is attached only into said elongate plug of tobacco filter material.
  • Figure 1 is a graphical presentation of smoking test results.
  • The applicants have found that the ability of a tobacco leaf to produce tobacco type flavour increases as the tobacco plant is ascended and that the ability to produce tar from such leaves also increases but to a much lesser degree. In particular, it has been found that the greatest flavour/tar ratio of the leaves of a tobacco plant is provided by the tips of the highest leaves.
  • The flavour produced by tobacco from such leaves, or the tips, generally is too high to be acceptable to a smoker in a conventional cigarette and hence the tobacco usually is blended with tobacco from the whole plant to provide an overall lower flavoured tobacco blend. The applicants have found that it is possible to employ such strongly flavoured tobacco and not only achieve a flavour level comparable to that of popular brands, but thereby deliver a much lower level of tar, consistent with the higher flavour/tar ratio of smoke produced by such tobacco. Alternatively, a higher flavour level may be provided but at a lower or the same tar level, as required.
  • There is disclosed in EP-A-453,299, the use of non-absorbent microfine fibers in tubular form to achieve high levels of filtration. Such microfine fibers may be used herein to decrease the flavour level produced by the tobacco. As described therein, the microfine fibers in the cylinder thereof generally each has a diameter of about 0.5 to 10 microns. The cylinder of such fibers generally has a thickness of about 0.05 to about 4 mm and a density of about 0.05 to about 0.3 g/cc.
  • The smoke aerosol passing in contact with such filter material impinges on the non-absorbent fibers to cause tar particles to wet and adhere to the surface of the fibers as well as aqueous droplets of flavour components.
  • The elongate cylinder of microfine fibers preferably is arranged so that all the tobacco smoke passing through the filter containing the microfine fibers cylinder is directed through the cylinder wall. This result may be achieved by providing an outer annulus of high density conventional acetate filter tow material surrounding the microfine fiber cylinder, which in turn surrounds an inner core. A baffle, or other tobacco flow path directing means, is provided at the upstream end to direct tobacco smoke from the cigarette only into the high density material. Such a known filter structure is disclosed in PCT publication No. WO 90/09741.
  • As described therein, the microfine fiber cylinder is a highly efficient filtration medium but rapidly becomes clogged, so that the tobacco smoke must traverse an increasingly longer path through the outer annulus of conventional tow material and is filtered thereby before passing through the wall of the cylinder of microfine fibers into an inner axial cigarette smoke flow path leading to the downstream end of the filter element. In this way, the filter achieves a greater degree of filtration of the tobacco smoke as smoking proceeds and hence tends to counteract the increasing level of flavour and tar delivery which results as smoking progresses, so that a more uniform flavour delivery to the smoker is achieved.
  • EP 364,253 describes a similar filter structure to that provided herein, in which an opening is provided through an elongate cylinder of microfine fibres. However, this opening is provided at the approximate midpoint of the length of the filler, rather than at the upstream end, and does not provide the initial high flavour puffs achieved herein.
  • In a further embodiment of the filter element according to the invention conventional cellulose acetate tow material is provided at the core of the filter element, with low flow resistance cellulose acetate tow being provided as the outer annulus. A baffle or other smoke path directing means can be provided to direct smoke into the central core.
  • In this novel filter arrangement, ventilation holes may be provided in the filter wrapper closer to downstream end of the filter than is normal to improve CO dispersion of carbon monoxide (CO). In general, ventilation decreases the CO content of the smoke entering the smoker's mouth.
  • The higher-than-normal flavour/tar ratio tobacco which is used in a cigarette for which the filter element is envisaged produces a higher-than-normal flavour level in the tobacco smoke from a burning cigarette containing the same. However, by using in the filter element a cylinder of microfine fibers, the flavour level of tobacco reaching the smoker's mouth from the burning cigarette is decreased to conventional levels. However, since the tobacco produces a higher-than-normal flavour-to-tar ratio smoke, this same ratio may be retained when the smoke reaches the smoker's mouth, so that a significantly lower tar delivery results while the same flavour level is achieved as in a conventional highly-flavoured brand of cigarette.
  • This result is achieved without the necessity for resorting to high pressure drop filtration or excessive ventilation, both of which are objectionable to a smoker, for the reasons outlined above and lead to a lower level of flavour delivery. The ability to provide a lower tar level for a particular flavour level to a smoker provides considerable versatility in achieving any desired combination of results.
  • The uniformity of delivery of the tobacco flavour to the smoker from a cigarette can be improved further by providing a greater proportion of more highly-flavoured tobacco towards the lighting end and a greater proportion of less highly-flavoured tobacco towards the filter end of the cigarette. As mentioned previously, the flavour strength produced by a cigarette increases as smoking progresses. By providing the greater proportion of less highly-flavoured tobacco towards the filter end of the cigarette, this effect tends to be counteracted.
  • A filler rod containing a combination of differently-flavoured tobacco may be provided in the manner described in US-A-4,896,681. Alternatively, discrete segments of differently-flavoured tobacco may be employed in the filler rod.
  • It is preferred to employ the lesser flavoured blend in the form of expanded tobacco, since expanded tobacco exhibits a tendency to effect a greater degree of filtration of smoke components than non-expanded tobacco.
  • The present invention, therefore, provides a filter element for use with a cigarette, which, in combination, exhibit a high sensory appeal while delivering a low level of tar to the smoker with a more uniform flavour delivery, by a combination of factors, as follows:
  • 1. Use in the tobacco blend from which the cigarette is formed of higher-than-normal quantities of tobacco from the upper levels of the tobacco plant, preferably their tips, which provides an initial high flavour-to-tar ratio, which then is maintained in the smoke delivered to the smoker, but at an acceptable attenuated flavour level;
  • 2. Use of latter puff manipulation in the filter element to decrease the flavour level and tar produced by the latter puffs of smoking of the cigarette; and
  • 3. Use of a flavour strength reset to attenuate the flavour strength of the smoke to the level desired by the smoker.
  • The latter puff manipulation with respect to the flavour and tar produced in the latter puffs of smoking the cigarette may be effected, as described above, by utilizing a smoke re-route filtration technique optionally in combination with using lesser strength tobacco at the filter end. Flavour strength reset is achieved, as described above, by utilizing a cylinder of microfine fibers as a filter element, optionally in combination with by using lesser strength tobacco at the filter end or preferably by using expanded tobacco at the filter end, or preferably a combination thereof. Preferably, all these factors are employed, with the cylinder of microfine fibers being incorporated into a smoke re-route filter and a higher proportion of lesser-flavoured expanded tobacco being used at the filter end and a higher proportion of the higher-than-normal flavour tobacco, possessing the high flavour-to-tar ratio, being used at the lighting end.
  • EXAMPLE Example
  • Smoking tests were carried out to explore the effect of various manipulations of a cigarette. The tar/puff values were plotted against puff number. The results obtained are plotted graphically in Figure 2.
  • The standard Benson & Hedges 100s (B & H) cigarettes (plot 3) increased from an initial tar level of 0.5 mg to a last puff tar level of 1.8 mg for a total of 13.1 mg. Using highly flavoured tobacco only with a standard filter from a Benson & Hedges cigarette produced plot 5, where the tar increased from a 1.0 mg level for the first puff to 3.0 mg for the last puff, for a total tar delivery of 22.5 mg, over twice that delivered by the standard B & H blend.
  • The highly flavoured tobacco was provided as a segment at the lighting end of the cigarette and a segment of expanded tobacco was provided at the filter end. Again a standard B & H filter was used. Plot (4) was obtained for this cigarette. In this instance, the tar rose from an initial level of 0.9 mg to 1.9 mg for the latter puff, for a total tar delivery of 12.5 mg, well below that for the highly flavoured tobacco above. A comparison of plots (4) and (5) illustrates the significant improvement in tar delivery which is attainable using a segment of expanded tobacco at the filter end of the cigarette filler rod. Both plots (4) and (5) exhibit a significant dip in the tar delivery during the middle puffs. The reason for this is unknown but is generally a characteristic of all cigarettes to some degree.
  • The highly flavoured tobacco used to prepare plot (5) again was smoked, but with the standard B & H filter being replaced by a filter comprising a cylinder of microfine fibers. In this case, plot (2) shown an increase from 0.3 to 1.7 mg during smoking for a total tar deliveries of 10.1 mg, i.e. significantly below the B & H value. A comparison of plots (2) and (5) illustrates the significant effect that the replacement of the conventional filter by one containing a cylinder of microfine fibers has on the tar delivery.
  • Finally, in plot (1), there is shown the tar delivery from a cigarette having a filter containing a cylinder of microfine fibers and containing a segment of expanded tobacco at the filter end. The tar increased from 0.2 mg for the first puff to 0.9 mg at the last puff, for a total tar delivery of only 4.7 mg.
  • A comparison of plots (1) and (4) illustrates the effect on tar delivery of the utilization of a filter comprising a cylinder of microfine fibers in place of a conventional filter. A comparison of plots (1) and (3) illustrates the effect on the tar delivery of the utilization of a cigarette constructed according to the present invention in comparison to a standard cigarette delivering the same flavour level. It will also be seen that, not only is a lower puff-to-puff level of tar delivery and an overall significantly lower tar delivery achieved, but the curve is flatter in the case of the present invention, so that a more uniform delivery of tar and flavour is achieved.

Claims (9)

  1. A cigarette smoke filter element, comprising:
    an elongate plug of tobacco smoke filter material;
    an elongate cylinder of non-absorbent microfine fibres provided on said elongate plug and having a lesser resistance to the flow of cigarette smoke radially therethrough than longitudinally through said elongate plug; and,
    an axially-directed annular tobacco smoke flow path located radially outwardly of said elongate cylinder;
    characterised by:
    said axially directed annular tobacco smoke path having a lesser resistance to the flow of cigarette smoke longitudinally therein than longitudinally through said elongate plug; and,
    tobacco smoke flow path directing means located at the upstream end of said filter element in the intended direction of flow of cigarette smoke thereto for directing cigarette smoke from a cigarette to which the filter element is attached only into said elongate plug of tobacco filter material.
  2. The filter element claimed in claim 1, characterised in that the elongate plug of tobacco smoke filter material is conventional cellulose acetate tow filter material.
  3. The filter element claimed in claim 1 or 2, characterised in that said tobacco flow path directing means is provided by baffle means at said upstream end of said filter.
  4. The filter element claimed in any one of claims 1 to 3, characterised in that said annular cigarette smoke path is provided by a low flow resistance cellulose acetate material.
  5. The filter element claimed in any one of claims 1 to 4, characterised in that a plurality of ventilation openings is provided through an outer wrapper to said filter element in communication with said annular flow path to facilitate dispersion of carbon monoxide in cigarette smoke flowing in said annular flow path.
  6. The filter element claimed in any one of claims 1 to 5, characterised in that at least one opening is provided through said elongate cylinder adjacent the upstream end of the filter element to permit preferential passage of cigarette smoke from said elongate plug through said at least one opening to said annular flow path during initial smoking of a cigarette to which the filter element is attached.
  7. The filter element claimed in any one of claims 1 to 6, characterised in that tobacco smoke flow path blocking means is located at the downstream end of the filter element to permit filtered tobacco smoke to pass only from the annular flow path.
  8. The filter element claimed in any one of claims 1 to 7, characterised in that of the microfine fibres in said cylinder each has a diameter of 0.5 to 10 microns.
  9. The filter element as claimed in any one of claims 1 to 8, characterised in that said cylinder of microfine fibres has a thickness of 0.5 to 4 mm and a density of 0.05 to 0.3 g/cc.
EP92916991A 1991-08-08 1992-08-07 Control of cigarette smoke chemistry Expired - Lifetime EP0599897B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9117118 1991-08-08
GB919117118A GB9117118D0 (en) 1991-08-08 1991-08-08 Control of cigarette smoke chemistry
PCT/CA1992/000344 WO1993002575A1 (en) 1991-08-08 1992-08-07 Control of cigarette smoke chemistry

Publications (2)

Publication Number Publication Date
EP0599897A1 EP0599897A1 (en) 1994-06-08
EP0599897B1 true EP0599897B1 (en) 1999-07-21

Family

ID=10699690

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92916991A Expired - Lifetime EP0599897B1 (en) 1991-08-08 1992-08-07 Control of cigarette smoke chemistry

Country Status (9)

Country Link
EP (1) EP0599897B1 (en)
JP (1) JPH07503603A (en)
AT (1) ATE182249T1 (en)
AU (1) AU668876B2 (en)
CA (1) CA2114128C (en)
DE (1) DE69229635T2 (en)
GB (1) GB9117118D0 (en)
WO (1) WO1993002575A1 (en)
ZA (1) ZA925956B (en)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8529852D0 (en) * 1985-12-04 1986-01-15 Rothmans Of Pall Mall Sculptured cigarette
GB8823902D0 (en) * 1988-10-12 1988-11-16 Rothmans Int Tobacco Cigarette filter rod elements & cigarettes incorporating such filter rod elements
DE69031032T2 (en) * 1989-03-02 1998-01-29 Rothmans Benson & Hedges FILTER WITH EVEN DELIVERY OF TAR
GB8916137D0 (en) * 1989-07-14 1989-08-31 Rothmans Int Tobacco Cigarettes
GB9008887D0 (en) * 1990-04-20 1990-06-20 Rothmans Benson & Hedges Cigarette smoke filter

Also Published As

Publication number Publication date
GB9117118D0 (en) 1991-09-25
ZA925956B (en) 1993-04-28
WO1993002575A1 (en) 1993-02-18
EP0599897A1 (en) 1994-06-08
ATE182249T1 (en) 1999-08-15
CA2114128A1 (en) 1993-02-18
CA2114128C (en) 1999-10-12
DE69229635T2 (en) 2000-03-16
AU2417692A (en) 1993-03-02
JPH07503603A (en) 1995-04-20
AU668876B2 (en) 1996-05-23
DE69229635D1 (en) 1999-08-26

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