EP0589811B1 - Side wall for a continuous cashing plkant for cashing metal between movable walls and apparatus - Google Patents

Side wall for a continuous cashing plkant for cashing metal between movable walls and apparatus Download PDF

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Publication number
EP0589811B1
EP0589811B1 EP93470020A EP93470020A EP0589811B1 EP 0589811 B1 EP0589811 B1 EP 0589811B1 EP 93470020 A EP93470020 A EP 93470020A EP 93470020 A EP93470020 A EP 93470020A EP 0589811 B1 EP0589811 B1 EP 0589811B1
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EP
European Patent Office
Prior art keywords
plate
wall according
walls
elements
spiral
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP93470020A
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German (de)
French (fr)
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EP0589811A1 (en
Inventor
Jean-Marie Galpin
Gérard Raisson
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Thyssen Stahl AG
USINOR SA
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Thyssen Stahl AG
USINOR SA
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Publication of EP0589811A1 publication Critical patent/EP0589811A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0637Accessories therefor
    • B22D11/0665Accessories therefor for treating the casting surfaces, e.g. calibrating, cleaning, dressing, preheating
    • B22D11/0671Accessories therefor for treating the casting surfaces, e.g. calibrating, cleaning, dressing, preheating for heating or drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0637Accessories therefor
    • B22D11/0648Casting surfaces
    • B22D11/066Side dams

Definitions

  • the present invention relates to the continuous casting of metals, especially steel, between movable walls cooled, especially between cylinders. It concerns more precisely the lateral shutter walls of the space of casting defined between said walls.
  • the invention aims to solve the problems mentioned above, to allow inductive heating effective metal near the side walls, limit friction, and therefore wear, on said walls, and improve the seal between the movable walls and said side walls.
  • the invention relates to a lateral sealing wall of a casting installation continuous between movable walls comprising two movable walls cooled defining between them a limited casting space laterally by two of said lateral closure walls which adjoin the edges of said movable walls, characterized in that said lateral closure wall comprises a cooled plate of electrically conductive material, oriented along a vertical plane perpendicular to the walls mobile, and an inductor powered by a variable current, including alternative, and consisting of a conductor wound in spiral parallel to the plate and in close proximity to this, and such that at least a first angular sector of the spiral is located opposite a first coplanar zone with the plate and electrically isolated from a second area included in the plate and which faces a second spiral sector.
  • the invention also relates to a casting installation continuous between cylinders, characterized in that it comprises two walls as above, said cylinders constituting said movable walls.
  • a "cold crucible” device is composed of a cylinder, usually made of copper, cooled by water circulation and radially segmented, surrounded by a solenoid which is coaxial with it and powered by a current at high frequency.
  • This cold crucible technique has already been the subject of many developments which respect the basic technique of the segmented cylinder surrounded by a solenoid generating a magnetic field oriented along the axis of the cylinder.
  • the metal is heated as in the technique of the cold crucible by the eddy currents which are developed by the inductor via the material plate electrically conductive, and electromagnetic forces resulting from the interaction of these eddy currents with the induced magnetic field tend to move the cast metal away of said plate, which therefore reduces friction.
  • the principle of the invention will be more clearly explained in the description given below of an exemplary embodiment.
  • the steel casting installation shown in Figure 1 has two movable walls here formed by the two cylinders 1 and 2 with parallel and horizontal axes.
  • the cylinders 1, 2 are internally cooled and rotated in direction opposite.
  • Two lateral closing walls 3 and 4 are arranged against the front faces of the cylinders, and therefore oriented along vertical planes, such as the P plane, perpendicular to the cylindrical walls of the cylinders.
  • These lateral obturation walls define with the walls of the cylinders, in the area above the level of their axes, a casting space 5.
  • molten steel 6 is poured (according to arrow F 2 ) into the casting space 5, where it gradually solidifies on contact with the cooled walls of the cylinders, forming skins of solidified steel.
  • the solidified skins are driven downwards and meet at the neck between the cylinders to form the thin product 7 continuously extracted.
  • FIG. 2 shows the closure wall side 3 which has a plate 31 made of material electrically conductive, such as copper or an alloy of copper, trapezoidal, with lateral edges adjoin the front ends of the cylinders.
  • An inductor 10 formed of a conductor 11 wound in a spiral 12 plane is placed parallel to plate 31, and in close proximity to this one.
  • the inductor 10 is supplied by a source 13 of alternating current, for example from 50 Hz to 500 KHz, and high intensity. Inductors shaped in this way are commonly called "Pancake".
  • the spiral 12 has a trapezoidal shape, and is arranged relative to the plate 31 so that the horizontal parts 14 of the conductor are facing plate 31, while the lateral parts obliques 15, 16 project laterally from said plate.
  • the angular sectors 15, 16, diametrically opposite are located in front of zones 17, 18 (framed on Figure 2 by dashed lines, which do not have here physical reality) coplanar with plate 31, and located out of said plate, and therefore implicitly electrically isolated from it.
  • the angular sectors corresponding to the horizontal parts 14 of the conductor is face zone 19 defined here by the surface of the plate 31.
  • the plate 31 is formed of two elements 32 ', 33' juxtaposed, and the center of the spiral 12 'is located at the interface between the two elements 32 ', 33'.
  • a first angular sector of the spiral, formed by its half upper is located opposite a first zone constituted here from the surface of element 32 ', which is insulated electrically of a second zone, constituted here of the surface of the element 33 ′, which faces the second angular sector of the spiral formed by its half superior.
  • the interest of the arrangement of the inductor according to the invention is avoid looping the eddy currents generated in the plate 31 when the inductor is supplied, in a plane parallel to those of the plate and the inductor.
  • the currents, fields and forces flowing or acting in the plane of the sheet by arrows, and by circles when they are perpendicular to the plane of the sheet.
  • the fields or currents directed from front to back of the sheet are represented by a circle containing a cross, and those directed inversely by a circle containing a point.
  • the diagram in Figure 3 shows these currents, fields and forces in a vertical section along line III-III of Figure 2; the diagram in Figure 4 shows them in a horizontal section at line IV-IV in figure 3, in the case of a one-piece plate 31 such as that of the Figure 2; the diagram in Figure 5 is similar to that of Figure 4, but in the case where the plate 31 is formed of several vertically elongated and joined elements, and electrically isolated from each other.
  • the current I 1 flowing in the conductor 11 generates a magnetic field B 1 whose penetration depth in the plate 31 is small.
  • This field B 1 creates in the skin thickness of the plate induced currents I 2 which loop horizontally.
  • the currents I 2 generate a field B 2 which penetrates into the skin thickness of the steel 6 contained in the casting space and in turn generates there induced currents I 3 .
  • These currents on the one hand cause the steel to heat up and thus prevent premature solidification of the steel near the plate 31, and on the other hand, by interaction with the field B 2 , create directed forces F R towards the middle of the casting space, which tend to move the solidified metal film 6 'away from said plate, thereby reducing the friction of the metal poured onto this plate.
  • the two objectives of the invention which are to limit the solidification of the steel near the lateral obturation wall and to limit the friction against this wall, are achieved.
  • the currents I 2 generate, in a similar manner to what has been explained above, induced currents I 4 , generating their turn in the steel located in the corners of the casting space of the currents I 3 ′, which circulate according to the arrows indicated in FIG. 4, which also tend to repel the steel cast from the wall of the cylinders.
  • the composition of the forces exerted leads to a resultant F R 'which tends to push back the steel from the joint between the cylinders 1, 2 and the side wall, and therefore improves the sealing by preventing infiltration of liquid metal into this joint.
  • the induced currents and forces in cast steel can only exist thanks to the fact that the currents induced in the plate 31 or in each element 31 ', 31' ', 31' '' of plates circulate according to a plan perpendicular to the general plane of the plate. That is why no coil of the inductor is entirely facing the same plate element. If this were the case, the induced currents would loop in the surface area of this element located opposite the inductor, parallel to the plane of the plate and on the one hand would not reach the area surface of the element located on the side of the cast steel, and on the other hand would only create a heating of said element.
  • the induced currents I 2 , I 3 , I 3 ', I 4 circulate near the surfaces of the different materials because the frequency of the inductor current I 1 is such that the penetration depth of the induced fields is weak.
  • the frequency must therefore be high enough, depending on the material of which the plate 31 is made, so as not to have too deep a penetration depth of the field B 1 in the plate 31.
  • the repulsion forces F R are strong, but the stirring effect of the liquid steel can be weak or even almost zero.
  • the inductor current could be 50 Hz at 500 kHz, which corresponds to penetration depths in copper from 9.2 mm to 0.09 mm respectively.
  • the frequency will therefore be chosen mainly in depending on the desired effect in the steel, taking into account that the total thickness of the copper plate is largely greater than the depth of penetration indicated above.
  • these elements can be made of different materials having different electroconductive characteristics.
  • This particular arrangement makes it possible to adapt the intensity of the currents and the forces as a function of the location of the elements in the plate with respect to the casting space. For example, a judicious choice, in the plate represented in FIG.
  • FIG. 6 shows a side wall according to the invention, in the variant where the plate 31 is formed of three elements 32, 33, 34 elongated in a direction vertical and juxtaposed horizontally, a thin film 35 in electrically insulating material being placed between two adjacent elements.
  • Each element has a conduit longitudinal center 36 (only that of element 32 has been shown in the figure so as not to overload it).
  • the three conduits 36 open down into a channel of distribution 37 ( Figure 7) connected by piping 38 to a supply circuit, not shown, with a cooling, for example water.
  • the pipes 36 open up into a collector 39 connected to a outlet piping 40.
  • the distribution channel 37 is arranged in a housing lower 41 and the collector is arranged in a housing upper 42, these two housings used to maintain the assembly of elements 32, 33, 34, as well as positioning of the entire plate with respect to cylinders 1, 2, and to the fixing on the installation.
  • These housings 41, 42 are electrically insulated from elements 32, 33, 34 of the plate.
  • the inductor 10 is a flat inductor of the "Pancake” type, kept at a short distance from the plate, so as to have the highest possible proportion of induced magnetic field in said plate, while being electrically isolated from the latter.
  • the lateral parts of the inductor protrude from the plate 31. These lateral parts could also, especially if we increase the number of elements juxtaposed, be located facing the elements located on the edges of the plate, in which case the induced currents would circulate in the area of these side walls either horizontally as in the other elements, but vertically.
  • Figure 8 shows another alternative embodiment in which the plate 31 consists of four elements horizontal 45 juxtaposed vertically, two boxes side 46, 47 ensuring the same function as the housings 41, 42 of the previous variant.
  • the inductor here overflows with the plate up and down.
  • the plate 31 may constitute only part of the obturation side wall, for example by being placed at the level of the neck between the movable walls and surmounted by a another plate of refractory material.
  • the plate as well that the inductor may be slightly concave in their part in contact with the liquid metal 6, which allows concentrating the power injected into said metal.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Induction Heating (AREA)
  • Continuous Casting (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
  • Specific Sealing Or Ventilating Devices For Doors And Windows (AREA)
  • Fencing (AREA)
  • Door And Window Frames Mounted To Openings (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Power-Operated Mechanisms For Wings (AREA)

Abstract

The wall comprises a cooled plate (31) made from electrically conducting material, oriented in a vertical plane perpendicular to the movable walls, and an inductor (10) supplied with an alternating current and consisting of a spiral-wound conductor parallel to the plate and in direct proximity therewith, and such that at least one first angular sector (15, 16) of the spiral is located opposite a first zone (17, 18) coplanar with the plate and electrically insulated from a second zone (19) included in the plate and which is located opposite a second sector (14). The invention applies to the continuous casting of metals between movable walls, particularly between rolls. <IMAGE>

Description

La présente invention concerne la coulée continue des métaux, notamment de l'acier, entre parois mobiles refroidies, notamment entre cylindres. Elle concerne plus précisément les parois d'obturation latérale de l'espace de coulée défini entre lesdites parois.The present invention relates to the continuous casting of metals, especially steel, between movable walls cooled, especially between cylinders. It concerns more precisely the lateral shutter walls of the space of casting defined between said walls.

Dans ces installations, un problème connu de longue date est d'éviter une solidification prématurée du métal coulé au contact des parois d'obturation latérale, et de limiter le frottement dudit métal sur lesdites parois qui sont fixes.In these installations, a long known problem date is to avoid premature solidification of the metal poured in contact with the lateral obturation walls, and limit the friction of said metal on said walls which are fixed.

Pour tenter de résoudre ce problème, il a déjà été proposé de chauffer soit les parois latérales, soit le métal se trouvant à proximité de celles-ci, de manière à empêcher, ou au moins retarder sa solidification.In an attempt to resolve this problem, it has already been offered to heat either the side walls or the metal being close to them, so as to prevent, or at least delay its solidification.

Ainsi il a déjà été proposé, dans le document JP 62 77156, de chauffer le métal par induction, au moyen d'inducteurs en U disposés derrière des parois latérales en matériau réfractaire et générant dans le métal coulé des courants de Foucault. Les contraintes d'encombrement et les limitations technologiques actuelles empêchent la mise en oeuvre pratique de telles solutions.Thus it has already been proposed, in document JP 62 77156, to heat the metal by induction, using U-shaped inductors arranged behind side walls in refractory material and generating in the cast metal eddy currents. Congestion constraints and current technological limitations prevent the implementation practical work of such solutions.

Il a aussi été proposé dans le document FR 2670413, de chauffer de manière similaire le métal, mais en utilisant des parois latérales métalliques refroidies suffisamment minces pour que le champ magnétique induit agisse directement sur le métal coulé. Dès lors que l'épaisseur des parois atteint ou dépasse la profondeur de pénétration du champ magnétique, ce mode de chauffage n'est plus efficace.It has also been proposed in document FR 2670413, to similarly heat the metal, but using sufficiently thin cooled metal side walls so that the induced magnetic field acts directly on the cast metal. As soon as the wall thickness reaches or exceeds the penetration depth of the magnetic field, this heating mode is no longer effective.

L'invention a pour buts de résoudre les problèmes évoqués ci-dessus, de permettre un réchauffage inductif efficace du métal à proximité des parois latérales, de limiter le frottement, et donc l'usure, sur lesdites parois, et d'améliorer l'étanchéité entre les parois mobiles et lesdites parois latérales. The invention aims to solve the problems mentioned above, to allow inductive heating effective metal near the side walls, limit friction, and therefore wear, on said walls, and improve the seal between the movable walls and said side walls.

Avec ces objectifs en vue, l'invention a pour objet une paroi d'obturation latérale d'une installation de coulée continue entre parois mobiles comprenant deux parois mobiles refroidies définissant entre elles un espace de coulée limité latéralement par deux desdites parois d'obturation latérale qui jouxtent les bords desdites parois mobiles, caractérisé en ce que ladite paroi d'obturation latérale comprend une plaque refroidie en matériau électriquement conducteur, orientée selon un plan vertical perpendiculaire aux parois mobiles, et un inducteur alimenté par un courant variable, notamment alternatif, et constitué d'un conducteur enroulé en spirale parallèle à la plaque et à proximité directe de celle-ci, et telle que au moins un premier secteur angulaire de la spirale soit situé face à une première zone coplanaire avec la plaque et isolée électriquement d'une deuxième zone incluse dans la plaque et qui se trouve face à un deuxième secteur de la spirale.With these objectives in view, the invention relates to a lateral sealing wall of a casting installation continuous between movable walls comprising two movable walls cooled defining between them a limited casting space laterally by two of said lateral closure walls which adjoin the edges of said movable walls, characterized in that said lateral closure wall comprises a cooled plate of electrically conductive material, oriented along a vertical plane perpendicular to the walls mobile, and an inductor powered by a variable current, including alternative, and consisting of a conductor wound in spiral parallel to the plate and in close proximity to this, and such that at least a first angular sector of the spiral is located opposite a first coplanar zone with the plate and electrically isolated from a second area included in the plate and which faces a second spiral sector.

L'invention concerne aussi une installation de coulée continue entre cylindres, caractérisée en ce qu'elle comporte deux parois telles que ci-dessus, lesdits cylindres constituant lesdites parois mobiles.The invention also relates to a casting installation continuous between cylinders, characterized in that it comprises two walls as above, said cylinders constituting said movable walls.

L'idée inventive à la base de la présente invention a été d'utiliser les principes de base de la technique dite de "creuset froid" connue depuis de nombreuses années pour le chauffage et la fusion par induction de certains métaux soit à point de fusion très élevé, soit dont on veut éviter le contact avec un creuset réfractaire pour des raisons de pureté du métal fondu. Un dispositif à "creuset froid" est composé d'un cylindre, couramment en cuivre, refroidi par circulation d'eau et segmenté radialement, entouré d'un solénoïde qui lui est coaxial et alimenté par un courant à haute fréquence. Par l'effet du champ magnétique induit et des courants de Foucault qui se développent dans le cylindre et le métal à fondre, d'une part le métal est chauffé et fondu, et d'autre part les forces électromagnétiques créées tendent à éloigner le métal fondu de la paroi du cylindre.The inventive idea underlying the present invention has been to use the basic principles of the so-called technique of "cold crucible" known for many years for the heating and induction melting of certain metals either with a very high melting point, which is to be avoided contact with a refractory crucible for reasons of purity of the molten metal. A "cold crucible" device is composed of a cylinder, usually made of copper, cooled by water circulation and radially segmented, surrounded by a solenoid which is coaxial with it and powered by a current at high frequency. By the effect of the induced magnetic field and eddy currents that develop in the cylinder and the metal to be melted, on the one hand the metal is heated and melted, and on the other hand the electromagnetic forces created tend to move molten metal away from the cylinder wall.

Cette technique du creuset froid a déjà fait l'objet de nombreux développements qui respectent la technique de base du cylindre segmenté entouré par un solénoïde générateur d'un champ magnétique orienté selon l'axe du cylindre.This cold crucible technique has already been the subject of many developments which respect the basic technique of the segmented cylinder surrounded by a solenoid generating a magnetic field oriented along the axis of the cylinder.

Comme on le comprendra aisément une telle technique n'est pas applicable telle quelle dans une installation de coulée entre parois mobiles, du fait de la configuration de ce type d'installation. Aussi les inventeurs ont-ils dû imaginer une structure entièrement originale pour trouver une solution au problème du chauffage du métal coulé à proximité des parois latérales et de la diminution du frottement du métal sur ces parois.As will be easily understood, such a technique is not applicable as is in a pouring between movable walls, due to the configuration of this type of installation. The inventors therefore had to imagine an entirely original structure to find a solution to the problem of heating nearby cast metal side walls and decrease the friction of the metal on these walls.

Grâce à l'invention, le métal est chauffé comme dans la technique du creuset froid par les courants de Foucault qui y sont développés par l'inducteur via la plaque en matériau électriquement conducteur, et les forces électromagnétiques résultant de l'interaction de ces courants de Foucault avec le champ magnétique induit tendent à éloigner le métal coulé de ladite plaque, ce qui réduit donc le frottement. Le principe de l'invention sera plus clairement explicité dans la description faite plus loin d'un exemple de réalisation.Thanks to the invention, the metal is heated as in the technique of the cold crucible by the eddy currents which are developed by the inductor via the material plate electrically conductive, and electromagnetic forces resulting from the interaction of these eddy currents with the induced magnetic field tend to move the cast metal away of said plate, which therefore reduces friction. The principle of the invention will be more clearly explained in the description given below of an exemplary embodiment.

Selon des dispositions particulières de l'invention :

  • la plaque est formée d'un seul élément et deux desdits premiers secteurs angulaires de la spirale, diamétralement opposés, sont situés face à des zones coplanaires avec la plaque et situées hors dudit élément ;
  • la plaque est formée de plusieurs éléments juxtaposés isolés électriquement entre eux ;
  • les éléments sont allongés selon une direction horizontale et juxtaposés verticalement ;
  • les éléments sont allongés selon une direction verticale et juxtaposés horizontalement ;
  • tous les éléments sont réalisés en un même matériau électriquement conducteur ;
  • au moins un élément est réalisé en un matériau ayant des caractéristiques électromagnétiques différentes de celles des matériaux des autres éléments ;
  • chaque élément est refroidi par circulation interne d'un fluide refroidissant.
According to specific provisions of the invention:
  • the plate is formed from a single element and two of said first angular sectors of the spiral, which are diametrically opposite, are situated opposite coplanar zones with the plate and situated outside said element;
  • the plate is formed of several juxtaposed elements electrically insulated from each other;
  • the elements are elongated in a horizontal direction and juxtaposed vertically;
  • the elements are elongated in a vertical direction and juxtaposed horizontally;
  • all the elements are made of the same electrically conductive material;
  • at least one element is made of a material having electromagnetic characteristics different from those of the materials of the other elements;
  • each element is cooled by internal circulation of a cooling fluid.

D'autres caractéristiques et avantages apparaítront dans la description qui va être faite de plusieurs variantes de l'invention, dans le cas d'une installation de coulée continue entre cylindres de produits minces en acier.Other characteristics and advantages will appear in the description which will be made of several variants of the invention, in the case of a casting installation continuous between cylinders of thin steel products.

On se reportera aux dessins annexés dans lesquels :

  • la figure 1 est une vue schématique en perspective de l'installation de coulée entre cylindres ;
  • la figure 2 est une vue frontale selon la flèche F1 de la figure 1 montrant la disposition générale d'une paroi d'obturation latérale conforme l'invention ;
  • la figure 3 est une représentation didactique en coupe selon la ligne III-III de la figure 2 montrant les courants, champ magnétique et forces agissant dans l'installation selon l'invention ;
  • la figure 4 est une représentation en vue de dessus de la figure 3 .
  • la figure 5 est une représentation similaire dans le cas d'une plaque d'obturation en plusieurs éléments verticaux ;
  • la figure 6 est une vue en perspective d'une première variante de la paroi d'obturation latérale selon l'invention ;
  • la figure 7 est une vue en coupe verticale de la paroi, où l'inducteur n'a pas été représenté ;
  • la figure 8 est une vue frontale d'une deuxième variante de la paroi d'obturation latérale ;
  • la figure 9 est une vue simplifiée d'une troisième variante, et
  • la figure 10 est une vue schématique de dessus d'une quatrième variante.
Reference is made to the appended drawings in which:
  • Figure 1 is a schematic perspective view of the casting installation between cylinders;
  • Figure 2 is a front view along arrow F1 of Figure 1 showing the general arrangement of a side closure wall according to the invention;
  • Figure 3 is a didactic sectional representation along line III-III of Figure 2 showing the currents, magnetic field and forces acting in the installation according to the invention;
  • FIG. 4 is a view from above of FIG. 3.
  • Figure 5 is a similar representation in the case of a cover plate in several vertical elements;
  • Figure 6 is a perspective view of a first variant of the lateral closure wall according to the invention;
  • Figure 7 is a vertical sectional view of the wall, where the inductor has not been shown;
  • Figure 8 is a front view of a second variant of the lateral closure wall;
  • FIG. 9 is a simplified view of a third variant, and
  • Figure 10 is a schematic top view of a fourth variant.

L'installation de coulée d'acier représentée à la figure 1 comporte deux parois mobiles ici constituées par les deux cylindres 1 et 2 d'axes parallèles et horizontaux. De manière classique et connue en soi, les cylindres 1, 2 sont refroidis intérieurement et entraínés en rotation en sens contraire. Deux parois d'obturation latérales 3 et 4 sont disposés contre les faces frontales des cylindres, et donc orientées selon des plans verticaux, tels que le plan P, perpendiculaire aux parois cylindriques des cylindres. Ces parois d'obturation latérale définissent avec les parois des cylindres, dans la zone située au-dessus du niveau de leurs axes, un espace de coulée 5.The steel casting installation shown in Figure 1 has two movable walls here formed by the two cylinders 1 and 2 with parallel and horizontal axes. Of in a conventional manner and known per se, the cylinders 1, 2 are internally cooled and rotated in direction opposite. Two lateral closing walls 3 and 4 are arranged against the front faces of the cylinders, and therefore oriented along vertical planes, such as the P plane, perpendicular to the cylindrical walls of the cylinders. These lateral obturation walls define with the walls of the cylinders, in the area above the level of their axes, a casting space 5.

Lors de la coulée, de l'acier en fusion 6 est versé (selon la flèche F2) dans l'espace de coulée 5, où il se solidifie progressivement au contact des parois refroidies des cylindres en formant des peaux d'acier solidifié. Par la rotation des cylindres, les peaux solidifiées sont entraínées vers le bas et se rejoignent au niveau du col entre les cylindres pour former le produit mince 7 extrait en continu.During casting, molten steel 6 is poured (according to arrow F 2 ) into the casting space 5, where it gradually solidifies on contact with the cooled walls of the cylinders, forming skins of solidified steel. By the rotation of the cylinders, the solidified skins are driven downwards and meet at the neck between the cylinders to form the thin product 7 continuously extracted.

On a représenté à la figure 2 la paroi d'obturation latérale 3 qui comporte une plaque 31 en matériau électriquement conducteur, tel que du cuivre ou un alliage de cuivre, de forme trapézoïdale, dont les bords latéraux jouxtent les extrémités frontales des cylindres. Un inducteur 10 formé d'un conducteur 11 enroulé en spirale 12 plane est placé parallèlement à la plaque 31, et à proximité directe de celle-ci. L'inducteur 10 est alimenté par une source 13 de courant alternatif, par exemple de 50 Hz à 500 KHz, et de forte intensité. Les inducteurs conformés de cette manière sont couramment appelés de type "Pancake".FIG. 2 shows the closure wall side 3 which has a plate 31 made of material electrically conductive, such as copper or an alloy of copper, trapezoidal, with lateral edges adjoin the front ends of the cylinders. An inductor 10 formed of a conductor 11 wound in a spiral 12 plane is placed parallel to plate 31, and in close proximity to this one. The inductor 10 is supplied by a source 13 of alternating current, for example from 50 Hz to 500 KHz, and high intensity. Inductors shaped in this way are commonly called "Pancake".

Dans la disposition de la figure 2, la spirale 12 a une forme trapézoïdale, et est disposé par rapport à la plaque 31 de manière que les parties horizontales 14 du conducteur soient face à la plaque 31, alors que les parties latérales obliques 15, 16 débordent latéralement de ladite plaque. En d'autres termes, on peut assimiler la spirale de forme trapézoïdale de l'inducteur à une spirale de forme circulaire, et lesdites parties horizontales 14, et latérales obliques 15, 16 à des secteurs angulaires de cette spirale. Alors, les secteurs angulaires 15, 16, diamétralement opposés, sont situés face à des zones 17, 18 (encadrées sur la figure 2 par des traits mixtes, et qui n'ont pas ici de réalité physique) coplanaires avec la plaque 31, et situées hors de ladite plaque, et donc implicitement électriquement isolées de celle-ci. Par ailleurs les secteurs angulaires correspondant aux parties horizontales 14 du conducteur, se trouvent face à la zone 19 définie ici par la surface de la plaque 31.In the arrangement of Figure 2, the spiral 12 has a trapezoidal shape, and is arranged relative to the plate 31 so that the horizontal parts 14 of the conductor are facing plate 31, while the lateral parts obliques 15, 16 project laterally from said plate. In other words, we can assimilate the spiral of form trapezoidal inductor to a spiral shape circular, and said horizontal portions 14, and lateral obliques 15, 16 to angular sectors of this spiral. So, the angular sectors 15, 16, diametrically opposite, are located in front of zones 17, 18 (framed on Figure 2 by dashed lines, which do not have here physical reality) coplanar with plate 31, and located out of said plate, and therefore implicitly electrically isolated from it. In addition the angular sectors corresponding to the horizontal parts 14 of the conductor, is face zone 19 defined here by the surface of the plate 31.

Dans une autre disposition schématisée à la figure 9, la plaque 31 est formée de deux éléments 32', 33' juxtaposés, et le centre de la spirale 12' est situé au niveau de l'interface entre les deux éléments 32', 33'. Un premier secteur angulaire de la spirale, constitué par sa moitié supérieure est situé face à une première zone constituée ici de la surface de l'élément 32', lequel est isolé électriquement d'une deuxième zone, constituée ici de la surface de l'élément 33', laquelle se trouve face au deuxième secteur angulaire de la spirale constitué par sa moitié supérieure.In another arrangement shown diagrammatically in FIG. 9, the plate 31 is formed of two elements 32 ', 33' juxtaposed, and the center of the spiral 12 'is located at the interface between the two elements 32 ', 33'. A first angular sector of the spiral, formed by its half upper is located opposite a first zone constituted here from the surface of element 32 ', which is insulated electrically of a second zone, constituted here of the surface of the element 33 ′, which faces the second angular sector of the spiral formed by its half superior.

Comme on va mieux le comprendre par la suite, l'intérêt de la disposition de l'inducteur selon l'invention est d'éviter un bouclage des courants de Foucault, générés dans la plaque 31 lorsque l'inducteur est alimenté, dans un plan parallèle à ceux de la plaque et de l'inducteur.As we will understand better later, the interest of the arrangement of the inductor according to the invention is avoid looping the eddy currents generated in the plate 31 when the inductor is supplied, in a plane parallel to those of the plate and the inductor.

En regard avec les figures 3 à 5 on va maintenant décrire le principe de fonctionnement de la paroi d'obturation conforme à l'invention.Next to Figures 3 to 5 we will now describe the operating principle of the wall shutter according to the invention.

On a symbolisé sur ces schémas les courants, champs et forces qui circulent ou s'exercent dans le plan de la feuille par des flèches, et par des cercles lorsqu'ils sont perpendiculaires au plan de la feuille. Les champs ou courants dirigés de l'avant vers l'arrière de la feuille sont représentés par un cercle contenant une croix, et ceux dirigés inversement par un cercle contenant un point.The currents, fields and forces flowing or acting in the plane of the sheet by arrows, and by circles when they are perpendicular to the plane of the sheet. The fields or currents directed from front to back of the sheet are represented by a circle containing a cross, and those directed inversely by a circle containing a point.

Le schéma de la figure 3 montre ces courants, champs et forces dans une section verticale selon la ligne III-III de la figure 2 ; le schéma de la figure 4 les montre dans une section horizontale au niveau de la ligne IV-IV de la figure 3, dans le cas d'une plaque 31 monobloc telle que celle de la figure 2 ; le schéma de la figure 5 est similaire à celui de la figure 4, mais dans le cas où la plaque 31 est formée de plusieurs éléments allongés verticalement et accolés, et isolés électriquement entre eux. The diagram in Figure 3 shows these currents, fields and forces in a vertical section along line III-III of Figure 2; the diagram in Figure 4 shows them in a horizontal section at line IV-IV in figure 3, in the case of a one-piece plate 31 such as that of the Figure 2; the diagram in Figure 5 is similar to that of Figure 4, but in the case where the plate 31 is formed of several vertically elongated and joined elements, and electrically isolated from each other.

De manière simplifiée, on peut dire que le courant I1 circulant dans le conducteur 11 génère un champ magnétique B1 dont la profondeur de pénétration dans la plaque 31 est faible. Ce champ B1 crée dans l'épaisseur de peau de la plaque des courants induits I2 qui bouclent horizontalement. Les courants I2 génèrent un champ B2 qui pénètre dans l'épaisseur de peau de l'acier 6 contenu dans l'espace de coulée et y génère à son tour des courants induits I3. Ces courants d'une part provoquent un échauffement de l'acier et empêchent ainsi une solidification prématurée de l'acier à proximité de la plaque 31, et d'autre part, par interaction avec le champ B2, créent des forces FR dirigées vers le milieu de l'espace de coulée, qui tendent à éloigner de ladite plaque la pellicule de métal solidifiée 6', réduisant ainsi le frottement du métal coulé sur cette plaque. Ainsi les deux objectifs de l'invention, qui sont de limiter la solidification de l'acier à proximité de la paroi latérale d'obturation et de limiter le frottement contre cette paroi, sont atteints.In a simplified manner, it can be said that the current I 1 flowing in the conductor 11 generates a magnetic field B 1 whose penetration depth in the plate 31 is small. This field B 1 creates in the skin thickness of the plate induced currents I 2 which loop horizontally. The currents I 2 generate a field B 2 which penetrates into the skin thickness of the steel 6 contained in the casting space and in turn generates there induced currents I 3 . These currents on the one hand cause the steel to heat up and thus prevent premature solidification of the steel near the plate 31, and on the other hand, by interaction with the field B 2 , create directed forces F R towards the middle of the casting space, which tend to move the solidified metal film 6 'away from said plate, thereby reducing the friction of the metal poured onto this plate. Thus, the two objectives of the invention, which are to limit the solidification of the steel near the lateral obturation wall and to limit the friction against this wall, are achieved.

De plus, dans la zone de contact entre la plaque 31 et les bords 1', 2' des cylindres, les courants I2 génèrent, de manière similaire à ce qui a été exposé ci-dessus, des courants induits I4, générant à leur tour dans l'acier situé dans les angles de l'espace de coulée des courants I3', qui circulent selon les flèches indiquées sur la figure 4, lesquels tendent également à repousser l'acier coulé de la paroi des cylindres. La composition des forces exercées conduit à une résultante FR' qui tend à repousser l'acier du joint entre les cylindres 1, 2 et la paroi latérale, et donc améliore l'étanchéité en évitant les infiltrations de métal liquide dans ce joint.In addition, in the contact zone between the plate 31 and the edges 1 ′, 2 ′ of the cylinders, the currents I 2 generate, in a similar manner to what has been explained above, induced currents I 4 , generating their turn in the steel located in the corners of the casting space of the currents I 3 ′, which circulate according to the arrows indicated in FIG. 4, which also tend to repel the steel cast from the wall of the cylinders. The composition of the forces exerted leads to a resultant F R 'which tends to push back the steel from the joint between the cylinders 1, 2 and the side wall, and therefore improves the sealing by preventing infiltration of liquid metal into this joint.

Les explications données ci-dessus dans le cas d'une plaque 31 formée d'un seul élément s'appliquent également au cas représenté à la figure 5 où la plaque est formée de trois éléments 31', 31'', 31''', la seule différence étant que les courants I2 bouclent dans chaque élément au lieu de boucler dans la section entière de la plaque. The explanations given above in the case of a plate 31 formed of a single element also apply to the case represented in FIG. 5 where the plate is formed of three elements 31 ', 31'',31''' , the only difference being that the currents I 2 loop in each element instead of looping in the entire section of the plate.

On comprendra aisément aussi que les explications données ci-dessus, en considération des champs, courants et forces dans la moitié supérieure du dispositif s'appliquent à la moitié inférieure avec une simple inversion du sens des courants et des champs.It will also be easily understood that the explanations above, taking into account fields, currents and forces in the upper half of the device apply to the bottom half with a simple reversal of the direction of currents and fields.

On comprendra aussi que les courants et forces induits dans l'acier coulé ne peuvent exister que grâce au fait que les courants induits dans la plaque 31 ou dans chaque élément 31', 31'', 31''' de plaque circulent selon un plan perpendiculaire au plan général-de la plaque. C'est pourquoi aucune spire de l'inducteur ne se trouve entièrement face à un même élément de plaque. En effet, si tel était le cas, les courants induits boucleraient dans la zone superficielle de cet élément située face à l'inducteur, parallèlement au plan de la plaque et d'une part n'atteindraient pas la zone superficielle de l'élément située du côté de l'acier coulé, et d'autre part créeraient uniquement un échauffement dudit élément.We will also understand that the induced currents and forces in cast steel can only exist thanks to the fact that the currents induced in the plate 31 or in each element 31 ', 31' ', 31' '' of plates circulate according to a plan perpendicular to the general plane of the plate. That is why no coil of the inductor is entirely facing the same plate element. If this were the case, the induced currents would loop in the surface area of this element located opposite the inductor, parallel to the plane of the plate and on the one hand would not reach the area surface of the element located on the side of the cast steel, and on the other hand would only create a heating of said element.

Il convient aussi de noter que les courants induits I2, I3, I3',I4 circulent à proximité des surfaces des différents matériaux parce que la fréquence du courant I1 d'inducteur est telle que la profondeur de pénétration des champs induits est faible. La fréquence devra donc être suffisamment élevée, en fonction du matériau constitutif de la plaque 31 pour ne pas avoir une profondeur de pénétration du champ B1 dans la plaque 31 trop forte. Par ailleurs si la profondeur de pénétration du champ B2 dans l'acier coulé est faible, les forces de répulsion FR sont fortes, mais l'effet de brassage de l'acier liquide peut être faible voire quasi nul.It should also be noted that the induced currents I 2 , I 3 , I 3 ', I 4 circulate near the surfaces of the different materials because the frequency of the inductor current I 1 is such that the penetration depth of the induced fields is weak. The frequency must therefore be high enough, depending on the material of which the plate 31 is made, so as not to have too deep a penetration depth of the field B 1 in the plate 31. Furthermore, if the penetration depth of the field B 2 in the cast steel is small, the repulsion forces F R are strong, but the stirring effect of the liquid steel can be weak or even almost zero.

Par exemple pour une plaque 31, ou des éléments de plaque, en cuivre, le courant inducteur pourra être de 50 Hz à 500 kHz, ce qui correspond à des profondeurs de pénétration dans le cuivre respectivement de 9,2 mm à 0,09 mm.For example for a plate 31, or elements of plate, copper, the inductor current could be 50 Hz at 500 kHz, which corresponds to penetration depths in copper from 9.2 mm to 0.09 mm respectively.

La fréquence sera donc choisie principalement en fonction de l'effet recherché dans l'acier, compte tenu que l'épaisseur totale de la plaque en cuivre est largement supérieure à la profondeur de pénétration indiquée ci-dessus. The frequency will therefore be chosen mainly in depending on the desired effect in the steel, taking into account that the total thickness of the copper plate is largely greater than the depth of penetration indicated above.

Il est encore précisé que, dans le cas d'une plaque constituée de plusieurs éléments, ces éléments peuvent être réalisés en des matériaux différents présentant des caractéristiques électroconductrices différentes. Cette disposition particulière permet d'adapter l'intensité des courants et des forces en fonction de la localisation des éléments dans la plaque par rapport à l'espace de coulée. Par exemple un choix judicieux, dans la plaque représentée à la figure 5, du matériau des éléments 31', 31''' qui se trouvent proches des parois des cylindres, permet, en utilisant un seul inducteur parcouru par le courant I1, de créer des forces de répulsion plus importantes, ou un réchauffage préférentiel, dans les coins de l'espace de coulée que vers le milieu de la paroi latérale où agit l'élément 31'', réalisé en un autre matériau, le choix des matériaux étant basé sur la valeur de leurs profondeurs de pénétration respectives, et leurs conductibilités électriques.It is further specified that, in the case of a plate made up of several elements, these elements can be made of different materials having different electroconductive characteristics. This particular arrangement makes it possible to adapt the intensity of the currents and the forces as a function of the location of the elements in the plate with respect to the casting space. For example, a judicious choice, in the plate represented in FIG. 5, of the material of the elements 31 ', 31''' which are located near the walls of the cylinders, allows, by using a single inductor traversed by the current I 1 , to create greater repulsion forces, or preferential reheating, in the corners of the casting space than towards the middle of the side wall where the element 31 '' acts, made of another material, the choice of materials being based on the value of their respective penetration depths, and their electrical conductivities.

On a représenté à la figure 6 une paroi latérale selon l'invention, dans la variante où la plaque 31 est formée de trois éléments 32, 33, 34 allongés selon une direction verticale et juxtaposés horizontalement, un film mince 35 en matériau électriquement isolant étant placé entre deux éléments adjacents. Chaque élément comporte un conduit central longitudinal 36 (seul celui de l'élément 32 a été représenté sur la figure pour ne pas la surcharger). Les trois conduits 36 débouchent vers le bas dans un canal de répartition 37 (figure 7) relié par une tuyauterie 38 à un circuit d'alimentation, non représenté, en un fluide de refroidissement, par exemple de l'eau. De même les conduites 36 débouchent vers le haut dans un collecteur 39 relié à une tuyauterie de sortie 40.FIG. 6 shows a side wall according to the invention, in the variant where the plate 31 is formed of three elements 32, 33, 34 elongated in a direction vertical and juxtaposed horizontally, a thin film 35 in electrically insulating material being placed between two adjacent elements. Each element has a conduit longitudinal center 36 (only that of element 32 has been shown in the figure so as not to overload it). The three conduits 36 open down into a channel of distribution 37 (Figure 7) connected by piping 38 to a supply circuit, not shown, with a cooling, for example water. Likewise the pipes 36 open up into a collector 39 connected to a outlet piping 40.

Le canal de répartition 37 est aménagé dans un boítier inférieur 41 et le collecteur est aménagé dans un boítier supérieur 42, ces deux boítiers servant à maintenir l'assemblage des éléments 32, 33, 34, ainsi qu'au positionnement de l'ensemble de la plaque par rapport aux cylindres 1, 2, et à la fixation sur l'installation. Ces boítiers 41, 42 sont isolés électriquement des éléments 32, 33, 34 de la plaque.The distribution channel 37 is arranged in a housing lower 41 and the collector is arranged in a housing upper 42, these two housings used to maintain the assembly of elements 32, 33, 34, as well as positioning of the entire plate with respect to cylinders 1, 2, and to the fixing on the installation. These housings 41, 42 are electrically insulated from elements 32, 33, 34 of the plate.

L'inducteur 10 est un inducteur plat de type "Pancake", maintenu à faible distance de la plaque, de manière à avoir la plus forte proportion possible de champ magnétique induit dans ladite plaque, tout en étant isolé électriquement de cette dernière. Les parties latérales de l'inducteur débordent de la plaque 31. Ces parties latérales pourraient également, notamment si l'on augmentait le nombre d'éléments juxtaposés, être situées face aux éléments situés sur les bords de la plaque, auquel cas les courants induits circuleraient, dans la zone de ces parois latérales, non plus horizontalement comme dans les autres éléments, mais verticalement.The inductor 10 is a flat inductor of the "Pancake" type, kept at a short distance from the plate, so as to have the highest possible proportion of induced magnetic field in said plate, while being electrically isolated from the latter. The lateral parts of the inductor protrude from the plate 31. These lateral parts could also, especially if we increase the number of elements juxtaposed, be located facing the elements located on the edges of the plate, in which case the induced currents would circulate in the area of these side walls either horizontally as in the other elements, but vertically.

La figure 8 montre une autre variante de réalisation dans laquelle la plaque 31 est constituée de quatre éléments horizontaux 45 juxtaposés verticalement, deux boítiers latéraux 46, 47 assurant la même fonction que les boítiers 41, 42 de la variante précédente. L'inducteur déborde ici de la plaque vers le haut et vers le bas. On comprendra aisément que dans cette variante les courants induits circulent dans des plans sensiblement verticaux, les courants et forces induites dans le métal coulé se déduisent des explications précédentes par simple transposition.Figure 8 shows another alternative embodiment in which the plate 31 consists of four elements horizontal 45 juxtaposed vertically, two boxes side 46, 47 ensuring the same function as the housings 41, 42 of the previous variant. The inductor here overflows with the plate up and down. We will easily understand that in this variant the induced currents flow in substantially vertical planes, currents and forces induced in the cast metal are deduced from the explanations previous by simple transposition.

D'autres variantes d'exécution sont réalisables tout en restant dans le champ de la présente invention. Par exemple le nombre d'éléments constitutifs de la plaque 31 peut être modifié. La plaque 31 peut ne constituer qu'une partie de la paroi latérale d'obturation, par exemple en étant placée au niveau du col entre les parois mobiles et surmontée d'une autre plaque en matériau réfractaire. Ou encore, comme représenté schématiquement à la figure 10, la plaque ainsi que l'inducteur peuvent être légèrement concaves dans leur partie en contact avec le métal liquide 6, ce qui permet de concentrer la puissance injectée dans ledit métal.Other execution variants are possible while remaining within the scope of the present invention. for example the number of components of the plate 31 can be amended. The plate 31 may constitute only part of the obturation side wall, for example by being placed at the level of the neck between the movable walls and surmounted by a another plate of refractory material. Or again, like shown schematically in Figure 10, the plate as well that the inductor may be slightly concave in their part in contact with the liquid metal 6, which allows concentrating the power injected into said metal.

Claims (12)

  1. Side closure wall of a plant for continuous casting between moving walls, comprising two cooled moving walls (1, 2) which between them define a casting space (5) bounded laterally by two of the said side closure walls (3) which adjoin the edges of the said moving walls, characterized in that the said side closure wall comprises a cooled plate (31) made of an electrically conductive material, oriented in a vertical plane perpendicular to the moving walls, and an inductor (10) which is supplied with a variable current and consists of a conductor wound in a spiral parallel to the plate and in direct proximity to the latter, and such that at least one first angular sector (15, 16) of the spiral lies opposite a first region (17, 18) which is coplanar with the plate and electrically insulated from a second region (19), the latter being included in the plate and lying opposite a second sector (14) of the spiral.
  2. Wall according to Claim 1, characterized in that the plate (31) is formed from a single element and two (15, 16) of the said first angular sectors of the spiral, which are diametrically opposed, lie opposite regions coplanar with the plate and lying outside the said element.
  3. Wall according to Claim 1, characterized in that the plate is formed from several juxtaposed elements (32, 33, 34) which are electrically insulated from one another.
  4. Wall according to Claim 3, characterized in that the elements are elongate in a horizontal direction and are juxtaposed vertically.
  5. Wall according to Claim 3, characterized in that the elements are elongate in a vertical direction and are juxtaposed horizontally.
  6. Wall according to Claim 3, characterized in that all the elements are made of the same electrically conductive material.
  7. Wall according to Claim 3, characterized in that at least one element is made of a material having electrical conductivity characteristics different from those of the materials of the other elements.
  8. Wall according to either of Claims 2 and 3, characterized in that each element is cooled by the internal circulation of a coolant.
  9. Wall according to Claim 1, characterized in that the plate (31) is made of copper or a copper alloy.
  10. Wall according to Claim 1, characterized in that the frequency of the inductor current is from 50 Hz to 500 kHz.
  11. Wall according to Claim 1, characterized in that the plate 31 and the inductor 10 are concave.
  12. Twin-roll continuous casting plant, characterized in that it comprises two walls according to one of the preceding claims, the said rolls constituting the said moving walls.
EP93470020A 1992-09-23 1993-09-07 Side wall for a continuous cashing plkant for cashing metal between movable walls and apparatus Expired - Lifetime EP0589811B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9211507A FR2695846B1 (en) 1992-09-23 1992-09-23 Lateral closing wall of a continuous metal casting installation between movable walls and installation comprising such a wall.
FR9211507 1992-09-23

Publications (2)

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EP0589811A1 EP0589811A1 (en) 1994-03-30
EP0589811B1 true EP0589811B1 (en) 1999-01-13

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EP93470020A Expired - Lifetime EP0589811B1 (en) 1992-09-23 1993-09-07 Side wall for a continuous cashing plkant for cashing metal between movable walls and apparatus

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EP (1) EP0589811B1 (en)
AT (1) ATE175603T1 (en)
DE (2) DE69323021T2 (en)
DK (1) DK0589811T3 (en)
ES (1) ES2129075T3 (en)
FR (1) FR2695846B1 (en)
GR (1) GR3029545T3 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60261645A (en) * 1984-06-08 1985-12-24 Ishikawajima Harima Heavy Ind Co Ltd Twin roll type continuous casting machine
JPS6257746A (en) * 1985-09-06 1987-03-13 Daido Steel Co Ltd Continuous casting device for thin metallic sheet
JPS6264458A (en) * 1985-09-18 1987-03-23 Kawasaki Steel Corp Continuous casting method for thin ingot
JPS62259642A (en) * 1986-05-02 1987-11-12 Mitsubishi Heavy Ind Ltd Continuous casting apparatus for strip
JPH02155543A (en) * 1988-12-09 1990-06-14 Hitachi Ltd Apparatus for continuously casting cast strip
FR2670413B1 (en) * 1990-12-17 1993-04-09 Usinor Sacilor CONTINUOUS CASTING DEVICE FOR THIN STRIPS OF METAL, ESPECIALLY STEEL.

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Publication number Publication date
ES2129075T3 (en) 1999-06-01
DE69323021T2 (en) 1999-08-12
DK0589811T3 (en) 1999-09-06
DE4332220A1 (en) 1994-03-24
GR3029545T3 (en) 1999-06-30
EP0589811A1 (en) 1994-03-30
FR2695846A1 (en) 1994-03-25
FR2695846B1 (en) 1994-10-21
DE69323021D1 (en) 1999-02-25
ATE175603T1 (en) 1999-01-15

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