EP0570911A1 - High strength aluminum alloy - Google Patents
High strength aluminum alloy Download PDFInfo
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- EP0570911A1 EP0570911A1 EP93108092A EP93108092A EP0570911A1 EP 0570911 A1 EP0570911 A1 EP 0570911A1 EP 93108092 A EP93108092 A EP 93108092A EP 93108092 A EP93108092 A EP 93108092A EP 0570911 A1 EP0570911 A1 EP 0570911A1
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- aluminum alloy
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- intermetallic compound
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
- C22C45/08—Amorphous alloys with aluminium as the major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
Definitions
- the present invention relates to a high strength aluminum alloy, and particularly, to an aluminum alloy including an aluminum matrix and a particular intermetallic compound.
- the quenched and solidified aluminum alloys have a problem that they have a high strength, but have a low toughness, on the other hand.
- an object of the present invention to provide an aluminum alloy of the type described above, which has a high strength with an increased toughness achieved.
- an high strength aluminum alloy comprising an aluminum matrix, and an intermetallic compound Al8REFe4 (wherein RE is at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd and Dy) having a grain size equal to or less than 1.0 ⁇ m and dispersed in said aluminum matrix, the volume fraction Vf of Al8REFe4 being in a range of 13% ⁇ Vf ⁇ 38%.
- the hardness of the aluminum alloy can be increased to provide an increased strength and to achieve an increase in toughness.
- Vf of Al8REFe4 is less than 13% (Vf ⁇ 13%), the degree of increase in hardness of the aluminum alloy is low, resulting in a failure to provide an increase in strength.
- Vf > 38% the breaking strain ⁇ f of the aluminum alloy is extremely low, resulting in a failure to achieve an increase in toughness.
- An aluminum alloy according to the present invention is represented by the chemical formula: Al a Fe b RE c wherein a, b and c are atomic percentages defined within the following ranges: 85 ⁇ a ⁇ 95, 3 ⁇ b ⁇ 9, and 1 ⁇ c ⁇ 6.
- RE is at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd and Dy.
- a process which comprises preparing an aluminum alloy blank having a metallographic structure including an amorphous single-phase texture, or a mixed-phase texture consisting of an amorphous phase and a crystalline phase, and then subjecting the aluminum alloy blank to a thermal treatment.
- An intermetallic compound Al8REFe4 is precipitated during this thermal treatment step, and dispersed in an aluminum matrix.
- a further aluminum alloy according to the present invention is represented by the formula Al a Fe b RE c Mn d wherein a, b, c and d are atomic percentages defined within the following ranges: 85 ⁇ a ⁇ 95, 2 ⁇ b ⁇ 8, 1 ⁇ c ⁇ 6, and 0.5 ⁇ d ⁇ 6.
- an intermetallic compound contributing to an increase in strength of the aluminum alloy is Al8RE(FeMn)4 and has a structure in which a portion of Fe is replaced by Mn.
- a molten metal having a composition represented by Al92Fe5Dy3 (each of these numerical values represent atomic percentages) in which Dy is selected as RE was prepared in a high frequency melting furnace. Then, the molten metal was used to produce a ribbon-like aluminum alloy blank having a width of 2 mm and a thickness of about 20 ⁇ m by application of a single roll process.
- Conditions for the single roll process were as follows: the diameter of a roll of copper was 250 mm; the number of revolutions of the roll was 4,000 rpm; the diameter of an injection bore in a quartz nozzle was 0.5 mm; a gap between the quartz nozzle and the roll was 0.3 mm; the pressure under which the molten metal was injected was 0.4 kgf/cm2; and the atmosphere was an argon atmosphere under -40 cmHg.
- Fig. 1 is an X-ray diffraction pattern for the aluminum alloy blank
- Fig .2 is a thermocurve diagram of a differential thermal analysis (DSC) for the aluminum alloy blank. It can be seen from Figs. 1 and 2 that the aluminum alloy has a mixed-phase texture consisting of an amorphous phase and a crystalline phase. The temperature Tx for crystallization of the amorphous phase is 624.2 K.
- the ribbon-like aluminum alloy blank was cut to fabricate a plurality of thin aluminum alloy blank pieces having a length of about 50 mm. These pieces were subjected to a thermal treatment to provide various aluminum alloys.
- Fig. 3 shows a thermal treatment process.
- This process comprises a primary temperature-rising stage P1 in which the temperature is raised from about 298 K to 590 K at a rate of about 15 K/minute; a primary constant-temperature maintaining stage P2 in which the temperature is maintained at 590 K for A minutes; a secondary temperature-raising stage P3 in which the temperature is raised from 590 K to 723 K at a rate of about 9 K/minute; a secondary constant-temperature maintaining stage P4 in which the temperature is maintained at 723 K for one hour; and a quenching stage P5 in which the blank is quenched from 723 K.
- the time for the primary constant-temperature maintaining stage, i.e., A was varied for every aluminum alloy blank.
- Table 1 shows the time A for the primary constant-temperature maintaining stage P2 for various aluminum alloys (1) to (6); the metallographic structure at the completion of the primary constant-temperature maintaining stage P2 (i.e., the intermediate metallographic structure); and the metallographic structure at the completion of the quenching stage P5 (i.e., the final metallographic structure).
- X-ray diffraction was primarily used to observe these metallographic structures. However, a transmission electron microscope and fluorescent X-ray analysis were also used.
- "amo” means an amorphous phase
- fcc means an aluminum crystal
- IMC means an intermetallic compound
- a " ⁇ " mark indicates that an unidentified AlFe and the like are present.
- Fig. 4 shows the relationship between the time A and the Vickers hardness Hv, wherein characters (1) to (6) correspond to the aluminum alloys (1) to (6).
- volume fractions Vf and Vf1 of Al8DyFe4 and Al3Dy in each of the aluminum alloys (1) to (6) were determined from a scanning electron microscope photomicrograph (a transmission electron microscope photomicrograph and a fluorescent X-ray analysis photograph were also partially used) to provide the results given in Table 2.
- Table 2 Al alloy Vf1 of Al3Dy (%) Vf of Al8DyFe4 (%) (1) 13.5 -- (2) 13.5 -- (3) 11 9 (4) 9 16 (5) 8 19 (6) 7 20
- Fig. 5 shows the relationship between the volume fraction Vf1 of Al3Dy and the Vickers hardness of each of the aluminum alloys (1), (3) to (6)
- Fig. 6 shows the relationship between the volume fraction Vf of Al8DyFe4 and the Vickers hardness of each of the aluminum alloys (1), (3) to (6).
- Characters (1), (3) to (6) in Figs. 5 and 6 correspond to the aluminum alloys (1), (3) to (6), respectively. It can be seen from Figs. 5 and 6 that the Vickers hardness of the aluminum alloy is increased by a decrease in volume fraction Vf1 of the Al3Dy and by an increase in volume fraction Vf of Al8DyFe4. In this case, the grain size of Al8DyFe4 was in a range of 100 to 300 nm.
- Fig. 7 shows a scanning electron microscope photomicrograph (72,000X magnification) of the metallographic structure of the aluminum alloy (6).
- Fig. 8 is a diagram traced from Fig. 8. In Figs. 7 and 8, the number of Al3Dy is 19, and the remaining is Al8DyFe4. It can be seen from both of Figs. 7 and 8 that these Al8DyFe4 are dispersed in the aluminum matrix M.
- Table 3 shows the composition of the various aluminum alloys (7) to (15) and the time A taken for the primary constant-temperature maintaining stage P2.
- Table 3 Al alloy Composition (by atomic %) Time A (minute) (7) Al91Fe6Dy3 60 (8) Al91Fe6Dy3 90 (9) Al91Fe6Dy3 120 (10) Al90Fe7Dy3 60 (11) Al90Fe7Dy3 90 (12) Al90Fe7Dy3 120 (13) Al89Fe8Dy3 90 (14) Al89Fe8Dy3 120 (15) Al90Fe8Dy2 90
- Fig. 9 shows their relationship between the volume fraction Vf1 of Al3Dy and the Vickers hardness Hv of each of the aluminum alloys (7) to (15)
- Fig. 10 shows the relationship between the volume fraction Vf of Al8DyFe4 and the Vickers hardness of each of the aluminum alloys (7) to (15).
- Characters (7) to (15) in Figs. 9 and 10 correspond to the aluminum alloys (7) to (15), respectively.
- Table 4 shows the composition of each of the various aluminum alloys (16) to (25), the time A taken for the primary constant-temperature maintaining stage P2 and intermetallic compounds represented by Al8REFe4.
- Table 4 Al alloy Composition (by atomic %) Time A (minute) Al8REFe4 (16) Al92Fe5Y3 60 Al8YFe4 (17) Al92Fe5Y3 120 Al8YFe4 (18) Al90Fe6La2Ce2 90 Al8(LaCe)Fe4 (19) Al90Fe6La2Ce2 120 Al8(LaCe)Fe4 (20) Al91Fe5Nd2Pr2 90 Al8(NdPr)Fe4 (21) Al91Fe5Nd2Pr2 120 Al8(NdPr)Fe4 (22) Al90Fe6Sm2Gd2 90 Al8(SmGd)Fe4 (23) Al90Fe6Sm2Gd2 120 Al8(SmGd)Fe4 (24) Al89
- Fig. 11 shows the relationship between the volume fraction Vf of Al8REFe4 and the Vickers hardness Hv in each of the various aluminum alloys (16) to (25) and the above-described aluminum alloys (1) to (15). Characters (1) to (25) in Fig. 11 correspond to the aluminum alloys (1) to (25), respectively.
- Fig. 12 shows the relationship between the volume fraction Vf of Al8REFe4 and the breaking strain ⁇ f in each of the various aluminum alloys (1) to (25). Characters (1) to (25) in Fig. 12 correspond to the aluminum alloys (1) to (25), respectively.
- Conditions established for the other stages P1, P3 and P5 were the same as those described with reference to Fig. 3.
- Table 5 shows the volume fractions Vf of Al8DyFe4 in the various aluminum alloys (26) to (30).
- Table 5 Al alloy Vf of Al8DyFe4 (%) (26) 20 (27) 19 (28) 19 (29) 20 (30) 20
- Fig. 13 shows the relationship between the grain size of Al8DyFe4 and the Vickers hardness Hv of each of the aluminum alloys (26) to (30). Characters (26) to (30) in Fig. 13 correspond to the aluminum alloys (26) to (30), respectively. As is apparent from Fig. 13, the Vickers hardness Hv of the aluminum alloy can be increased by setting the grain size of Al8DyFe4 less than 1.0 ⁇ m, thereby increasing the strength of the aluminum alloy.
- Table 6 shows the compositions of the various aluminum alloy blanks (31) to (35).
- Table 6 Al alloy blank Composition (by atomic %) (31) Al92Fe4Dy3Mn1 (32) Al92Fe3Dy3Mn2 (33) Al92Fe2Dy3Mn3 (34) Al92Fe1Dy3Mn4 (35) Al92Dy3Mn5
- each of the aluminum alloy blanks (31) to (34) had a mixed-phase texture consisting of an amorphous phase and a crystalline phase, but the aluminum alloy blank (35) had a crystalline single-phase texture due to its composition.
- each of the aluminum alloy blanks (31) to (34) was formed into a ribbon-like configuration and exhibited a toughness, whereas the aluminum alloy blank (35) was also formed into a ribbon-like configuration, but was very brittle.
- the other aluminum alloy blanks (31) to (34) were subjected to a thermal treatment to produce aluminum alloys (31) to (34) (for convenience, the same characters are used for the aluminum alloys corresponding to the aluminum alloy blanks).
- Conditions for the thermal treatment are similar to those described with reference to Fig. 3, except for the time A set at 120 minutes for the primary constant-temperature maintaining stage P2.
- Intermetallic compounds in the aluminum alloys (31) to (34) are Al3Dy and Al8Dy(FeMn)4, and the volume fractions Vf3 of Al8Dy(FeMn)4 in the aluminum alloys (31) to (34) are as shown in Table 7.
- Table 7 Al alloy blank Vf3 of Al8Dy(FeMn)4 (%) (31) 19 (32) 19 (33) 20 (34) 19
- Fig. 14 shows the relationship between the amount of added Mn and the Vickers hardness Hv in each of the aluminum alloys (31) to (34). Characters (31) to (34) in Fig. 14 correspond to the aluminum alloys (31) to (34), respectively. A character (5) corresponds to the above-described aluminum alloy (5).
- each of the aluminum alloys (31) to (34) having compositions obtained by replacement of all or a portion of Fe in Al8DyFe4 has an increased Vickers hardness Hv and thus an increased strength, as compared with those of the aluminum alloy (5) free from Mn. This is believed to be attributable to an increased resistance to deformation in a crystal grain boundary as a result of addition of Mn.
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Abstract
An aluminum alloy includes an aluminum matrix, and an intermetallic compound Al₈REFe₄ (wherein RE is at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd and Dy) having a grain size of at most 1.0 µm and dispersed in the aluminum matrix. The volume fraction Vf of Al₈REFe₄ is in a range of 13% ≦ Vf ≦ 38%. In this way, if the volume fraction Vf of Al₈REFe₄ is set at a value equal to or more than 13% (13% ≦ Vf), the Vickers hardness Hv of the aluminum alloy can be increased to increase the strength. In addition, an increase in toughness of the aluminum alloy can be achieved by setting the volume fraction Vf of Al₈REFe₄ at a value equal to or less than 38% (Vf ≦ 38%).
Description
- The present invention relates to a high strength aluminum alloy, and particularly, to an aluminum alloy including an aluminum matrix and a particular intermetallic compound.
- There are conventionally known quenched and solidified aluminum alloys as aluminum alloys of this type (for example, see Japanese Patent Application Laid-open No. 275732/89 and U.S. Patent No. 5,053,085).
- However, the quenched and solidified aluminum alloys have a problem that they have a high strength, but have a low toughness, on the other hand.
- Accordingly, it is an object of the present invention to provide an aluminum alloy of the type described above, which has a high strength with an increased toughness achieved.
- To achieve the above object, according to the present invention, there is provided an high strength aluminum alloy, comprising an aluminum matrix, and an intermetallic compound Al₈REFe₄ (wherein RE is at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd and Dy) having a grain size equal to or less than 1.0 µm and dispersed in said aluminum matrix, the volume fraction Vf of Al₈REFe₄ being in a range of 13% ≦ Vf ≦ 38%.
- If Al₈REFe₄ is dispersed in the aluminum matrix as described above, the hardness of the aluminum alloy can be increased to provide an increased strength and to achieve an increase in toughness.
- However, if the volume fraction Vf of Al₈REFe₄ is less than 13% (Vf < 13%), the degree of increase in hardness of the aluminum alloy is low, resulting in a failure to provide an increase in strength. On the other hand, if Vf > 38%, the breaking strain εf of the aluminum alloy is extremely low, resulting in a failure to achieve an increase in toughness.
- The above and other objects, features and advantages of the invention will become apparent from the following detailed description of preferred embodiments, taken in conjunction with the accompanying drawings.
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- Fig. 1 is an X-ray diffraction pattern for an aluminum alloy;
- Fig. 2 is a thermocurve diagram of a differential thermal analysis for the aluminum alloy;
- Fig. 3 is a graph illustrating the relationship between the time and the temperature in a thermal treatment;
- Fig. 4 is a graph illustrating the relationship between the time A and the Vickers hardness Hv;
- Fig. 5 is a graph illustrating the relationship between the volume fraction Vf₁ of Al₃Dy and the Vickers hardness Hv;
- Fig. 6 is a graph illustrating the relationship between the volume fraction Vf of Al₈DyFe₄ and the Vickers hardness Hv;
- Fig. 7 is a photomicrograph showing the metallographic structure of an aluminum alloy;
- Fig. 8 is a diagram traced from Fig. 7;
- Fig. 9 is a graph illustrating the relationship between the volume fraction Vf₁ of Al₃Dy and the Vickers hardness Hv;
- Fig. 10 is a graph illustrating the relationship between the volume fraction Vf of Al₈DyFe₄ and the Vickers hardness Hv;
- Fig. 11 is a graph illustrating the relationship between the volume fraction Vf of Al₈REFe₄ and the Vickers hardness Hv;
- Fig. 12 is a graph illustrating the relationship between the volume fraction Vf of Al₈REFe₄ and the breaking strain εf.
- Fig. 13 is a graph illustrating the relationship between the grain size of Al₈DyFe₄ and the Vickers hardness Hv;
- Fig. 14 is a graph illustrating the relationship between the Mn content and the Vickers hardness Hv.
- An aluminum alloy according to the present invention is represented by the chemical formula: Ala Feb REc wherein a, b and c are atomic percentages defined within the following ranges: 85 ≦ a ≦ 95, 3 ≦ b ≦ 9, and 1 ≦ c ≦ 6. RE is at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd and Dy.
- In producing the aluminum alloy, a process is employed which comprises preparing an aluminum alloy blank having a metallographic structure including an amorphous single-phase texture, or a mixed-phase texture consisting of an amorphous phase and a crystalline phase, and then subjecting the aluminum alloy blank to a thermal treatment. An intermetallic compound Al₈REFe₄ is precipitated during this thermal treatment step, and dispersed in an aluminum matrix.
- A further aluminum alloy according to the present invention is represented by the formula Ala Feb REc Mnd wherein a, b, c and d are atomic percentages defined within the following ranges: 85 ≦ a ≦ 95, 2 ≦ b ≦ 8, 1 ≦ c ≦ 6, and 0.5 ≦ d ≦ 6. In this case, an intermetallic compound contributing to an increase in strength of the aluminum alloy is Al₈RE(FeMn)₄ and has a structure in which a portion of Fe is replaced by Mn.
- A molten metal having a composition represented by Al₉₂Fe₅Dy₃ (each of these numerical values represent atomic percentages) in which Dy is selected as RE was prepared in a high frequency melting furnace. Then, the molten metal was used to produce a ribbon-like aluminum alloy blank having a width of 2 mm and a thickness of about 20 µm by application of a single roll process. Conditions for the single roll process were as follows: the diameter of a roll of copper was 250 mm; the number of revolutions of the roll was 4,000 rpm; the diameter of an injection bore in a quartz nozzle was 0.5 mm; a gap between the quartz nozzle and the roll was 0.3 mm; the pressure under which the molten metal was injected was 0.4 kgf/cm²; and the atmosphere was an argon atmosphere under -40 cmHg.
- Fig. 1 is an X-ray diffraction pattern for the aluminum alloy blank, and Fig .2 is a thermocurve diagram of a differential thermal analysis (DSC) for the aluminum alloy blank. It can be seen from Figs. 1 and 2 that the aluminum alloy has a mixed-phase texture consisting of an amorphous phase and a crystalline phase. The temperature Tx for crystallization of the amorphous phase is 624.2 K.
- The ribbon-like aluminum alloy blank was cut to fabricate a plurality of thin aluminum alloy blank pieces having a length of about 50 mm. These pieces were subjected to a thermal treatment to provide various aluminum alloys.
- Fig. 3 shows a thermal treatment process. This process comprises a primary temperature-rising stage P₁ in which the temperature is raised from about 298 K to 590 K at a rate of about 15 K/minute; a primary constant-temperature maintaining stage P₂ in which the temperature is maintained at 590 K for A minutes; a secondary temperature-raising stage P₃ in which the temperature is raised from 590 K to 723 K at a rate of about 9 K/minute; a secondary constant-temperature maintaining stage P₄ in which the temperature is maintained at 723 K for one hour; and a quenching stage P₅ in which the blank is quenched from 723 K. The time for the primary constant-temperature maintaining stage, i.e., A, was varied for every aluminum alloy blank.
- Table 1 shows the time A for the primary constant-temperature maintaining stage P₂ for various aluminum alloys (1) to (6); the metallographic structure at the completion of the primary constant-temperature maintaining stage P₂ (i.e., the intermediate metallographic structure); and the metallographic structure at the completion of the quenching stage P₅ (i.e., the final metallographic structure). X-ray diffraction was primarily used to observe these metallographic structures. However, a transmission electron microscope and fluorescent X-ray analysis were also used. In table 1, "amo" means an amorphous phase; "fcc" means an aluminum crystal; and "IMC" means an intermetallic compound, and a " ⃝" mark indicates that an unidentified AlFe and the like are present.
Table 1 Al alloy Primary constant-temperature maintaining stage P₂ Final metallographic structure (Dispersed in a Al matrix) A (minute) I.M.S. UNID.AlFe Al₃DY Al₈byFe₄ (1) 10 amo + fcc ⃝ ⃝ - (2) 30 amo + fcc ⃝ ⃝ - (3) 60 fcc + IMC ⃝ ⃝ ⃝ (4) 90 fcc + IMC ⃝ ⃝ ⃝ (5) 120 fcc + IMC - ⃝ ⃝ (6) 150 fcc + INC - ⃝ ⃝ I.M.S. = intermediate metallographic structure
UNID = unidentified - The following can be seen from Table 1: In the aluminum alloys (1) and (2), produced with the time A set at 10 and 30 minutes and having the intermediate metallographic structure of "amo + fcc", no Al₈DyFe₄ was present in the final metallographic structure. In the aluminum alloys (3) and (4), produced with the time A set at 60 and 90 minutes and having the intermediate metallographic structure of "fcc + IMC", unidentified AlFe, Al₃Dy and Al₈DyFe₄ were observed in the final metallographic structure. Further, in the aluminum alloys (5) and (6), produced with the time A set at 120 and 150 minutes and having the intermediate metallographic structure of "fcc + IMC", Al₃Dy and Al₈DyFe₄ were observed in the final metallographic structure. These facts indicate that the configuration of the final metallographic structure is varied depending upon the intermediate metallographic structure.
- Fig. 4 shows the relationship between the time A and the Vickers hardness Hv, wherein characters (1) to (6) correspond to the aluminum alloys (1) to (6).
- It can be seen from Fig. 4 that the longer the time A is, the higher the hardness is. This phenomenon is attributable to the difference in IMC and the amount of IMC present, because there is less difference in size of the metallographic structure between the aluminum alloys (1) to (6).
- Thereupon, the volume fractions Vf and Vf₁ of Al₈DyFe₄ and Al₃Dy in each of the aluminum alloys (1) to (6) were determined from a scanning electron microscope photomicrograph (a transmission electron microscope photomicrograph and a fluorescent X-ray analysis photograph were also partially used) to provide the results given in Table 2.
Table 2 Al alloy Vf₁ of Al₃Dy (%) Vf of Al₈DyFe₄ (%) (1) 13.5 -- (2) 13.5 -- (3) 11 9 (4) 9 16 (5) 8 19 (6) 7 20 - It can be seen from Table 2, that if the volume fraction Vf₁ of Al₃Dy is decreased, the volume fraction Vf of the Al₈DyFe₄ is increased.
- Fig. 5 shows the relationship between the volume fraction Vf₁ of Al₃Dy and the Vickers hardness of each of the aluminum alloys (1), (3) to (6), and Fig. 6 shows the relationship between the volume fraction Vf of Al₈DyFe₄ and the Vickers hardness of each of the aluminum alloys (1), (3) to (6). Characters (1), (3) to (6) in Figs. 5 and 6 correspond to the aluminum alloys (1), (3) to (6), respectively. It can be seen from Figs. 5 and 6 that the Vickers hardness of the aluminum alloy is increased by a decrease in volume fraction Vf₁ of the Al₃Dy and by an increase in volume fraction Vf of Al₈DyFe₄. In this case, the grain size of Al₈DyFe₄ was in a range of 100 to 300 nm.
- Fig. 7 shows a scanning electron microscope photomicrograph (72,000X magnification) of the metallographic structure of the aluminum alloy (6). Fig. 8 is a diagram traced from Fig. 8. In Figs. 7 and 8, the number of Al₃Dy is 19, and the remaining is Al₈DyFe₄. It can be seen from both of Figs. 7 and 8 that these Al₈DyFe₄ are dispersed in the aluminum matrix M.
- Various aluminum alloys (7) to (15) of the same type as the above-described aluminum alloys were produced in the same manner as described above.
- Table 3 shows the composition of the various aluminum alloys (7) to (15) and the time A taken for the primary constant-temperature maintaining stage P₂.
Table 3 Al alloy Composition (by atomic %) Time A (minute) (7) Al₉₁Fe₆Dy₃ 60 (8) Al₉₁Fe₆Dy₃ 90 (9) Al₉₁Fe₆Dy₃ 120 (10) Al₉₀Fe₇Dy₃ 60 (11) Al₉₀Fe₇Dy₃ 90 (12) Al₉₀Fe₇Dy₃ 120 (13) Al₈₉Fe₈Dy₃ 90 (14) Al₈₉Fe₈Dy₃ 120 (15) Al₉₀Fe₈Dy₂ 90 - Fig. 9 shows their relationship between the volume fraction Vf₁ of Al₃Dy and the Vickers hardness Hv of each of the aluminum alloys (7) to (15), and Fig. 10 shows the relationship between the volume fraction Vf of Al₈DyFe₄ and the Vickers hardness of each of the aluminum alloys (7) to (15). Characters (7) to (15) in Figs. 9 and 10 correspond to the aluminum alloys (7) to (15), respectively.
- It was confirmed from Figs. 9 and 10 that even if the composition of the aluminum alloy was changed, the Vickers hardness Hv of the aluminum alloy is increased by a decrease in volume fraction Vf₁ of Al₃Dy and an increase in volume fraction Vf of Al₈DyFe₄.
- Further, various aluminum alloys (16) to (25) with the type of RE varied were produced by the same process as described above.
- Table 4 shows the composition of each of the various aluminum alloys (16) to (25), the time A taken for the primary constant-temperature maintaining stage P₂ and intermetallic compounds represented by Al₈REFe₄.
Table 4 Al alloy Composition (by atomic %) Time A (minute) Al₈REFe₄ (16) Al₉₂Fe₅Y₃ 60 Al₈YFe₄ (17) Al₉₂Fe₅Y₃ 120 Al₈YFe₄ (18) Al₉₀Fe₆La₂Ce₂ 90 Al₈(LaCe)Fe₄ (19) Al₉₀Fe₆La₂Ce₂ 120 Al₈(LaCe)Fe₄ (20) Al₉₁Fe₅Nd₂Pr₂ 90 Al₈(NdPr)Fe₄ (21) Al₉₁Fe₅Nd₂Pr₂ 120 Al₈(NdPr)Fe₄ (22) Al₉₀Fe₆Sm₂Gd₂ 90 Al₈(SmGd)Fe₄ (23) Al₉₀Fe₆Sm₂Gd₂ 120 Al₈(SmGd)Fe₄ (24) Al₈₉Fe₇La₂Ce₁Nd₁ 90 Al₈(LaCeNd)Fe₄ (25) Al₈₉Fe₇La₂Ce₁Nd₁ 120 Al₈(LaCeNd)Fe₄ - Fig. 11 shows the relationship between the volume fraction Vf of Al₈REFe₄ and the Vickers hardness Hv in each of the various aluminum alloys (16) to (25) and the above-described aluminum alloys (1) to (15). Characters (1) to (25) in Fig. 11 correspond to the aluminum alloys (1) to (25), respectively.
- As is apparent from Fig. 11, in the various aluminum alloys, the increase rate of the Vickers hardness Hv is increased at the volume fraction Vf of Al₈REFe₄ equal to or more than 13%. Therefore, the lower limit value of the volume fraction Vf of Al₈REFe₄ required for increasing the strength of the aluminum alloy is set at 13% (Vf = 13%).
- Then, the breaking strain εf of each of the aluminum alloys (1) to (25) was measured in order to examine the toughness of each of these aluminum alloys.
- Fig. 12 shows the relationship between the volume fraction Vf of Al₈REFe₄ and the breaking strain εf in each of the various aluminum alloys (1) to (25). Characters (1) to (25) in Fig. 12 correspond to the aluminum alloys (1) to (25), respectively.
- As is apparent from Fig. 12, if the volume fraction Vf of Al₈REFe₄ becomes more than 38%, the breaking strain εf is equal to or less than 0.01, resulting in a failure to achieve an increase in toughness of the aluminum alloy. Therefore, the upper limit value of the volume fraction Vf of Al₈REFe₄ is set at 38% (Vf = 38%).
- The grain size of Al₈REFe₄ will be described below.
- A plurality of thin aluminum alloy blank pieces having compositions similar to those described above, i.e., Al₉₂Fe₅Dy₃ (each numerical value represents an atomic %) were subjected to the primary constant-temperature maintaining stage P₂ with the time A set at 120 minutes (A = 120 minutes) and with the temperature likewise set at 590 K, thereby producing intermediate products which were then subjected to the secondary constant-temperature maintaining stage P₁ with the temperature likewise set at 723 to 823 K and with the time set at 1 to 30 hours, thereby producing various aluminum alloys (26) to (30) having different grain sizes of Al₈DyFe₄. Conditions established for the other stages P₁, P₃ and P₅ were the same as those described with reference to Fig. 3.
- Table 5 shows the volume fractions Vf of Al₈DyFe₄ in the various aluminum alloys (26) to (30).
Table 5 Al alloy Vf of Al₈DyFe₄ (%) (26) 20 (27) 19 (28) 19 (29) 20 (30) 20 - Fig. 13 shows the relationship between the grain size of Al₈DyFe₄ and the Vickers hardness Hv of each of the aluminum alloys (26) to (30). Characters (26) to (30) in Fig. 13 correspond to the aluminum alloys (26) to (30), respectively. As is apparent from Fig. 13, the Vickers hardness Hv of the aluminum alloy can be increased by setting the grain size of Al₈DyFe₄ less than 1.0 µm, thereby increasing the strength of the aluminum alloy.
- Various molten metals having compositions obtained by replacement of all or a portion of Fe in Al₉₂Fe₅Dy₃ (each numerical value represents an atomic %) by Mn were prepared in a high frequency melting furnace and then subjected to a single-roll process under the same conditions as in Example 1 to produce various aluminum alloy blanks.
- Table 6 shows the compositions of the various aluminum alloy blanks (31) to (35).
Table 6 Al alloy blank Composition (by atomic %) (31) Al₉₂Fe₄Dy₃Mn₁ (32) Al₉₂Fe₃Dy₃Mn₂ (33) Al₉₂Fe₂Dy₃Mn₃ (34) Al₉₂Fe₁Dy₃Mn₄ (35) Al₉₂Dy₃Mn₅ - An X-ray diffraction and a differential thermal analysis (DSC) showed that each of the aluminum alloy blanks (31) to (34) had a mixed-phase texture consisting of an amorphous phase and a crystalline phase, but the aluminum alloy blank (35) had a crystalline single-phase texture due to its composition. In addition, each of the aluminum alloy blanks (31) to (34) was formed into a ribbon-like configuration and exhibited a toughness, whereas the aluminum alloy blank (35) was also formed into a ribbon-like configuration, but was very brittle.
- Then, except for the aluminum alloy blank (35), the other aluminum alloy blanks (31) to (34) were subjected to a thermal treatment to produce aluminum alloys (31) to (34) (for convenience, the same characters are used for the aluminum alloys corresponding to the aluminum alloy blanks). Conditions for the thermal treatment are similar to those described with reference to Fig. 3, except for the time A set at 120 minutes for the primary constant-temperature maintaining stage P₂.
- Intermetallic compounds in the aluminum alloys (31) to (34) are Al₃Dy and Al₈Dy(FeMn)₄, and the volume fractions Vf₃ of Al₈Dy(FeMn)₄ in the aluminum alloys (31) to (34) are as shown in Table 7.
Table 7 Al alloy blank Vf₃ of Al₈Dy(FeMn)₄ (%) (31) 19 (32) 19 (33) 20 (34) 19 - It can be seen from Table 7 that the volume fractions Vf₃ of Al₈Dy(FeMn)₄ in the aluminum alloys (31) to (34) are in a range of 13% ≦ Vf₃ ≦ 38%.
- Fig. 14 shows the relationship between the amount of added Mn and the Vickers hardness Hv in each of the aluminum alloys (31) to (34). Characters (31) to (34) in Fig. 14 correspond to the aluminum alloys (31) to (34), respectively. A character (5) corresponds to the above-described aluminum alloy (5).
- As is apparent from Fig. 14, each of the aluminum alloys (31) to (34) having compositions obtained by replacement of all or a portion of Fe in Al₈DyFe₄ has an increased Vickers hardness Hv and thus an increased strength, as compared with those of the aluminum alloy (5) free from Mn. This is believed to be attributable to an increased resistance to deformation in a crystal grain boundary as a result of addition of Mn.
Claims (10)
- A high strength aluminum alloy, comprising an aluminum matrix, and an intermetallic compound Al₈REFe₄, wherein:a. RE is at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, and Dy;b. said intermetallic compound has a grain size less than or equal to 1.0 µm;c. said intermetallic compound is dispersed in said aluminum matrix; andd. the volume fraction Vf of said intermetallic compound is in the following range: 13% ≦ Vf ≦ 38%.
- A high strength aluminum alloy, comprising an aluminum matrix, and an intermetallic compound Al₈RE(FeMn)₄, wherein:a. RE is at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, and Dy;b. said intermetallic compound has a grain size less than or equal to 1.0 µm;c. said intermetallic compound is dispersed in said aluminum matrix; andd. the volume fraction Vf of said intermetallic compound is in the following range: 13% ≦ Vf₃≦ 38%.
- A method for producing a high strength aluminum alloy having an intermetallic compound Al₈REFe₄ dispersed in an aluminum matrix, wherein RE is at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, and Dy; the grain size of the intermetallic compound is equal to or less than 1.0 µm; and the volume fraction Vf of the intermetallic is in a range of 13% ≦ Vf ≦ 38%, said method comprising:a. producing an aluminum alloy blank having a metallographic structure selected from the group consisting of an amorphous single phase texture an a mixed-phase texture consisting of an amorphous phase and a crystalline phase;b. subjecting said aluminum alloy blank to a thermal treatment to precipitate the intermetallic compound.
- A method for producing a high strength aluminum alloy according to claim 5, wherein said thermal treatment comprises:a. raising the temperature of said aluminum alloy blank from about ambient temperature to about 590 K at a rate of approximately 15 K/minute;b. maintaining the temperature of said aluminum alloy blank at a temperature of about 590 K for a period sufficient to precipitate the intermetallic compound, and thereby producing an intermediate microstructure;c. increasing the temperature of said aluminum alloy from about 590 K to a temperature in the range of about 723 K to 823 K at a rate of about 9 K/minute;d. maintaining the temperature of said aluminum alloy in the temperature range of about 723 K to about 823 K for a period of approximately 1 hour to at most the period of time required to increase the grain size of the intermetallic phase to 1.0 µm;e. quenching the aluminum alloy and thereby fixing a final metallographic structure in the aluminum alloy.
- A method for producing a high strength aluminum alloy having an intermetallic compound Al₈RE(FeMn)₄ dispersed in an aluminum matrix, wherein RE is at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, and Dy; the grain size of the intermetallic compound is equal to or less than 1.0 µm; and the volume fraction Vf of the intermetallic is in a range of 13% ≦ Vf ≦ 38%, said method comprising:a. producing an aluminum alloy blank having a metallographic structure selected from the group consisting of an amorphous single phase texture and a mixed-phase texture consisting of an amorphous phase and a crystalline phase;b. subjecting said aluminum alloy blank to a thermal treatment to precipitate the intermetallic compound.
- A method for producing a high strength aluminum alloy according to claim 8, wherein said thermal treatment comprises:a. raising the temperature of said aluminum alloy blank from about ambient temperature to about 590 K at a rate of approximately 15 K/minute;b. maintaining the temperature of said aluminum alloy blank at a temperature of about 590 K for a period sufficient to precipitate the intermetallic compound, and thereby producing an intermediate microstructure;c. Increasing the temperature of said aluminum alloy from about 590 K to a temperature in the range of about 723 K to 823 K at a rate of about 9 K/minute;d. maintaining the temperature of said aluminum alloy in the temperature range of about 723 K to about 823 K for a period of approximately 1 hour to at most the period of time required to increase the grain size of the intermetallic phase to 1.0 µm;e. quenching the aluminum alloy and thereby fixing a final metallographic structure in the aluminum alloy.
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JP15607092A JPH05320803A (en) | 1992-05-22 | 1992-05-22 | High-strength al alloy |
JP156070/92 | 1992-05-22 |
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EP93108092A Withdrawn EP0570911A1 (en) | 1992-05-22 | 1993-05-18 | High strength aluminum alloy |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0662524A1 (en) * | 1993-12-24 | 1995-07-12 | Tsuyoshi Masumoto | Aluminum alloy and method of preparing the same |
CN109295346A (en) * | 2017-07-24 | 2019-02-01 | 中南大学 | A kind of soft aluminium alloy of high conductivity and its preparation method and application |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0136508A2 (en) * | 1983-10-03 | 1985-04-10 | AlliedSignal Inc. | Aluminum-transition metal alloys having high strength at elevated temperatures |
EP0333216A1 (en) * | 1988-03-17 | 1989-09-20 | Tsuyoshi Masumoto | High strength, heat resistant aluminum-based alloys |
EP0339676A1 (en) * | 1988-04-28 | 1989-11-02 | Tsuyoshi Masumoto | High strength, heat resistant aluminum-based alloys |
EP0460887A1 (en) * | 1990-06-08 | 1991-12-11 | Tsuyoshi Masumoto | A particle-dispersion type amorphous aluminium-alloy having high strength |
EP0475101A1 (en) * | 1990-08-14 | 1992-03-18 | Ykk Corporation | High strength aluminum-based alloys |
-
1992
- 1992-05-22 JP JP15607092A patent/JPH05320803A/en active Pending
-
1993
- 1993-05-18 EP EP93108092A patent/EP0570911A1/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0136508A2 (en) * | 1983-10-03 | 1985-04-10 | AlliedSignal Inc. | Aluminum-transition metal alloys having high strength at elevated temperatures |
EP0333216A1 (en) * | 1988-03-17 | 1989-09-20 | Tsuyoshi Masumoto | High strength, heat resistant aluminum-based alloys |
EP0339676A1 (en) * | 1988-04-28 | 1989-11-02 | Tsuyoshi Masumoto | High strength, heat resistant aluminum-based alloys |
EP0460887A1 (en) * | 1990-06-08 | 1991-12-11 | Tsuyoshi Masumoto | A particle-dispersion type amorphous aluminium-alloy having high strength |
EP0475101A1 (en) * | 1990-08-14 | 1992-03-18 | Ykk Corporation | High strength aluminum-based alloys |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0662524A1 (en) * | 1993-12-24 | 1995-07-12 | Tsuyoshi Masumoto | Aluminum alloy and method of preparing the same |
US5532069A (en) * | 1993-12-24 | 1996-07-02 | Tsuyoshi Masumoto | Aluminum alloy and method of preparing the same |
CN109295346A (en) * | 2017-07-24 | 2019-02-01 | 中南大学 | A kind of soft aluminium alloy of high conductivity and its preparation method and application |
CN109295346B (en) * | 2017-07-24 | 2021-04-16 | 中南大学 | High-conductivity soft aluminum alloy and preparation method and application thereof |
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