EP0533652A1 - Process and device for operating a gas turbine with introduction of additives. - Google Patents
Process and device for operating a gas turbine with introduction of additives.Info
- Publication number
- EP0533652A1 EP0533652A1 EP89901457A EP89901457A EP0533652A1 EP 0533652 A1 EP0533652 A1 EP 0533652A1 EP 89901457 A EP89901457 A EP 89901457A EP 89901457 A EP89901457 A EP 89901457A EP 0533652 A1 EP0533652 A1 EP 0533652A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- magnesium compound
- burner
- combustion chamber
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J7/00—Arrangement of devices for supplying chemicals to fire
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/002—Supplying water
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/002—Supplying water
- F23L7/005—Evaporated water; Steam
Definitions
- the present invention relates to a method for operating a gas turbine according to the preamble of claim 1 and a corresponding device according to the preamble of claim 7.
- magnesium orthovanadate g, V 2 0g
- the magnesium has been mixed into the fuel either in the form of oil-soluble compounds, colloidal suspensions or in the form of water-soluble salts which have to be emulsified.
- the object of the present invention to create a method and an associated device which enable a reliable and inexpensive admixture of magnesium in the combustion process while avoiding the aforementioned problems.
- the admixture of magnesium sulfate dissolved in the water in the combustion process of fuels containing vanadium should be made easier and cheaper.
- the concentration of the water-soluble magnesium compound in the water can be adjusted such that about one tenth of the volume of water with dissolved magnesium compound has to be injected per part by volume of fuel. From a technical point of view, this is not a problem because the injection of much larger amounts of water is already solved in another context.
- a burner was selected as an example, as is described in detail in EP-A-0 193 838. There is no explanation of the structural details of the burner itself. It is only important that the burner 1 has devices for injecting water 2 and / or steam 3. It is not decisive whether it is a premix burner, a diffusion burner or a so-called hybrid burner. According to the invention, such a burner is assigned at least one storage container 4, which is connected via a metering device 5 to the injection devices 2, 3 for water and / or steam.
- the present invention is particularly suitable for gas turbine plants in which vanadium-containing fuel is to be burned always or temporarily.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
Abstract
Procédé, nécessitant au moins un brûleur dans une chambre de combustion, avec lequel, pour éviter que les éléments de la turbine à gaz soient détériorés par le vanadium présent dans le combustible, un composé du magnésium dissous dans l'eau est injecté séparément dans la chambre de combustion. Un dispositif pour la mise en oeuvre du procédé se compose d'un brûleur (1) d'un modèle connu avec des dispositifs pour l'injection d'eau (2) ou de vapeur (3), ces dispositifs étant reliés à un réservoir (4) par l'intermédiaire d'un doseur (5). L'invention permet de substituer à l'emploi de composés du magnésium onéreux et solubles dans l'huile des sels de magnésium solubles dans l'eau d'une bien plus grande facilité d'emploi et d'un prix de revient avantageux.A process, requiring at least one burner in a combustion chamber, with which, to prevent the elements of the gas turbine from being damaged by the vanadium present in the fuel, a magnesium compound dissolved in water is separately injected into the gas turbine. combustion chamber. A device for carrying out the method consists of a burner (1) of a known model with devices for injecting water (2) or steam (3), these devices being connected to a tank (4) via a metering device (5). The invention makes it possible to replace the use of expensive and oil-soluble magnesium compounds with water-soluble magnesium salts which are much easier to use and at an advantageous cost.
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3808016 | 1988-03-10 | ||
DE3808016 | 1988-03-10 | ||
PCT/DE1989/000026 WO1989008803A1 (en) | 1988-03-10 | 1989-01-19 | Process and device for operating a gas turbine with introduction of additives |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0533652A1 true EP0533652A1 (en) | 1993-03-31 |
EP0533652B1 EP0533652B1 (en) | 1995-03-29 |
Family
ID=6349401
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89901457A Expired - Lifetime EP0533652B1 (en) | 1988-03-10 | 1989-01-19 | Process and device for operating a gas turbine with introduction of additives |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0533652B1 (en) |
JP (1) | JP2977569B2 (en) |
DE (1) | DE58909147D1 (en) |
IN (1) | IN171209B (en) |
WO (1) | WO1989008803A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100234569B1 (en) * | 1991-04-25 | 1999-12-15 | 피터 토마스 | Burner arrangement especially for gas turbines for the low-pollutant combustion of coal gas and other fuels |
RU2133851C1 (en) * | 1993-09-08 | 1999-07-27 | Сименс АГ | Method of operation of gas turbine with supply of additive |
EP0735002A1 (en) * | 1995-03-31 | 1996-10-02 | Siemens Aktiengesellschaft | Method and apparatus for dissolving a magnesium compound in water |
JP2002372233A (en) * | 2001-06-14 | 2002-12-26 | Seiji Inoue | Auxiliary equipment of boiler |
EP1329614A1 (en) * | 2002-01-21 | 2003-07-23 | Siemens Aktiengesellschaft | Burner and Process for Operating a Burner, in particular for a gas turbine engine |
US8623799B2 (en) | 2008-07-08 | 2014-01-07 | The Lubrizol Corporation | Marine diesel cylinder lubricant |
DE102009014026A1 (en) * | 2008-12-03 | 2010-06-10 | Ernest Stangl | Method for generating thermal energy as e.g. electrical energy, in distributed power plant, involves burning fuel in container in heat- or power plant using oxygen source, and supplying carbon dioxide and oxygen mixture for burning fuel |
US8123821B2 (en) * | 2009-02-10 | 2012-02-28 | General Electric Company | Regulating vanadium inhibitor in a gas turbine |
EP2230458A1 (en) | 2009-03-17 | 2010-09-22 | Siemens Aktiengesellschaft | Burner assembly for fluid fuels and method for producing a burner assembly |
EP2264370B1 (en) * | 2009-06-16 | 2012-10-10 | Siemens Aktiengesellschaft | Burner assembly for a firing assembly for firing fluid fuels and method for operating such a burner assembly |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB731242A (en) * | 1950-06-28 | 1955-06-08 | Power Jets Res & Dev Ltd | Improvements in or relating to fuel oils and the combustion of fuel oils |
ES454017A1 (en) * | 1976-12-07 | 1977-11-16 | Alentorn Ricos S L R | Improvements in facilities for the treatment of combustión through metal oxides. (Machine-translation by Google Translate, not legally binding) |
AU496757B2 (en) * | 1977-02-03 | 1977-04-21 | The Percom Company, Inc | Compositions and methods for inhibiting corrosion and ash deposition in fossil fuel burning equipment |
DE2932676C2 (en) * | 1979-08-11 | 1983-01-27 | L. & C. Steinmüller GmbH, 5270 Gummersbach | Process for binding sulfur, chlorine and fluorine compounds during combustion |
US4375359A (en) * | 1979-11-02 | 1983-03-01 | Dearborn Chemical Company Limited | Water based fireside additive |
GB2095283B (en) * | 1981-02-09 | 1984-08-01 | Polarchem Ltd | Method for the prevention of deposits on or the removal ofdeposits from heating and ancillary surfaces |
DE3318374A1 (en) * | 1983-05-20 | 1984-11-22 | Günter 3000 Hannover Hackerodt | Process for the removal of sulphur oxides from combustion gases and apparatus for carrying out the process |
DE3444469C1 (en) * | 1984-12-06 | 1986-06-19 | L. & C. Steinmüller GmbH, 5270 Gummersbach | Process and round burner for injecting aqueous additive suspensions in the center of a round burner |
-
1989
- 1989-01-19 EP EP89901457A patent/EP0533652B1/en not_active Expired - Lifetime
- 1989-01-19 JP JP1501246A patent/JP2977569B2/en not_active Expired - Fee Related
- 1989-01-19 WO PCT/DE1989/000026 patent/WO1989008803A1/en active IP Right Grant
- 1989-01-19 DE DE58909147T patent/DE58909147D1/en not_active Expired - Fee Related
- 1989-03-29 IN IN241/CAL/89A patent/IN171209B/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO8908803A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE58909147D1 (en) | 1995-05-04 |
IN171209B (en) | 1992-08-15 |
WO1989008803A1 (en) | 1989-09-21 |
EP0533652B1 (en) | 1995-03-29 |
JP2977569B2 (en) | 1999-11-15 |
JPH03503303A (en) | 1991-07-25 |
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