EP0515414B1 - Web cleaning apparatus - Google Patents

Web cleaning apparatus Download PDF

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Publication number
EP0515414B1
EP0515414B1 EP91903320A EP91903320A EP0515414B1 EP 0515414 B1 EP0515414 B1 EP 0515414B1 EP 91903320 A EP91903320 A EP 91903320A EP 91903320 A EP91903320 A EP 91903320A EP 0515414 B1 EP0515414 B1 EP 0515414B1
Authority
EP
European Patent Office
Prior art keywords
web
particles
air
corona discharge
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP91903320A
Other languages
German (de)
French (fr)
Other versions
EP0515414A1 (en
Inventor
Roger Arthur Whitney
Raymond John Cox
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kodak Ltd
Eastman Kodak Co
Original Assignee
Kodak Ltd
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kodak Ltd, Eastman Kodak Co filed Critical Kodak Ltd
Publication of EP0515414A1 publication Critical patent/EP0515414A1/en
Application granted granted Critical
Publication of EP0515414B1 publication Critical patent/EP0515414B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B6/00Cleaning by electrostatic means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B5/00Cleaning by methods involving the use of air flow or gas flow
    • B08B5/02Cleaning by the force of jets, e.g. blowing-out cavities
    • B08B5/023Cleaning travelling work
    • B08B5/026Cleaning moving webs

Definitions

  • This invention relates to web cleaning apparatus, and is more particularly concerned with non-contact web cleaning apparatus.
  • non-contact web cleaners clean air at high velocity is passed over the surface of the web to remove debris. It is also known to utilise electrostatic charges to neutralise the charge which may be attracting the debris or dirt to the surface of the web.
  • US Patent Specification US-A-2920987 describes an arrangement which can be used to clean the surface of a non-conducting material.
  • a high alternating voltage supply is applied to the material by means of an electrode positioned adjacent one surface of the web. This alternating voltage damps out the static charge present on the surface of the material due to a previous operation, for example, a grinding operation.
  • Arranged on the opposite side of the material to the electrode is a series of projections which contact the material. Particles on the material after the grinding operation, say, are removed due to the electrostatic effect produced by the electrode and the physical contact of the projections with the material itself. Loosened particles are removed from the surface of the material by suction.
  • US Patent Specification US-A-4213167 discloses an arrangement in which both surfaces of a web are cleaned by causing air to flow over both surfaces, and introducing ions into the air flow to neutralise static charge on the web.
  • Other examples of the use of ionised air streams to remove dust are disclosed in US Patent Specifications US-A-4454621 and US-A-4241377.
  • US Patent Specification US-A-4835808 discloses an arrangement which utilises both suction and blowing to remove particles from the surface of a web. A field plate is also used to charge the web and an electrode is used to discharge the web thereby removing the particles. US Patent Specification US-A-3536528 also discloses the use of suction and blowing to remove particles from the surface of a web, but in this case, the charge on the web is neutralised after cleaning.
  • French Patent Application FR-A-2179707 discloses apparatus and method for cleaning glass sheets. Electrostatic charge is generated on the sheet by means of corona discharge as it passes between two electrode strips arranged transverse to the direction of motion of the glass sheets, each strip having a plurality of needle electrodes arranged along its length. These electrode strips are used to discharge particles adhering to the glass sheet and once discharged, the particles are removed using an airstream.
  • Web cleaners which use ions to discharge the electrostatic charges holding particles against the surface of the web are only effective at low web speeds. However, this may prevent particles being re-attracted to the web after they have been loosened.
  • a method of cleaning web material comprising, passing the web through an air gap, the air gap being defined by a first surface over which the web passes, the web being supported by the first surface, and a second surface spaced from the first surface, producing a corona discharge across the air gap to generate electrostatic forces on the web and on the particles to cause at least some of the particles to lift off the surface of the web, and removing particles from the web.
  • the corona discharge is produced by an alternating voltage supply.
  • a web cleaning apparatus for use in a method as described above which comprises:- means for defining an air gap, comprising a first surface over which the web passes, the web being supported by the first surface, and a second surface spaced from the first surface, generator means for producing a corona discharge in the air gap, and means for removing particles loosened by the corona discharge.
  • At least one of the first and second surfaces is an insulating surface so that the corona discharge does not only occur at a single point.
  • the generator means may be a high voltage alternating supply.
  • the particles Once the particles have been loosened, they can be removed using a high velocity air stream. Additionally, or alternatively, suction means can be used to remove the loosened particles.
  • the generator means operates at a frequency between 1 to 5kHz.
  • the present invention aims to deposit a significant charge of one sign on the web and then subject it to an electric field of the opposite sign to produce a force to dislodge particles from the surface of the web. Particles so dislodged can then be removed by an air stream passing over the surface of the web, or by suction applied to the web surface.
  • the apparatus shown in Figure 1 comprises a cylinder 12 over which a web 10 to be cleaned is passed.
  • the surface of the cylinder 12 has a layer 14 of insulating material placed on it.
  • the rest of the apparatus is positioned above the cylinder 12, and is mounted in a housing 16.
  • An electrode 18 is positioned above the cylinder 12 so that the web 10 passes through a gap 20 formed between the cylinder 12 and the electrode 18.
  • the electrode 18 has an insulating surface 19, and is connected to a high voltage alternating supply (not shown) which causes a corona discharge to occur in the gap 20.
  • the insulating surface 19 and the layer 14 may not be required, the insulating surface being provided by the web itself.
  • An air supply arrangement 22 for supplying air to and removing air from the gap 20 is attached to an upper wall 24 of the housing 16 as shown.
  • the arrangement 22 comprises a blower section 26 and a suction section 28 positioned adjacent one another with a dividing wall 30 therebetween.
  • Each section 26, 28 has a respective opening 32, 34 which allows the passage of air into and out of that section.
  • the arrangement 22 also provides a means of positioning the electrode 18 above the surface of the cylinder 12.
  • An insulating support member 36 is attached at one end to the arrangement 22 and at the other to the electrode 18.
  • the support member 36 is positioned between the openings 32, 34 thereby forming two ducts 38, 40, with further walls 42, 44.
  • the walls 42, 44 are also made of insulating material so that the ducts 38, 40 so formed are non-conducting.
  • a member 46 is attached to the lower end 48 of wall 42 and extends perpendicularly to it.
  • the apparatus operates as follows:
  • An alternating high voltage is applied to the electrode 18. Charging of the web and the production of forces into and away from the surface of the web occurs each half cycle of the alternating applied voltage.
  • the strength of the electric field exceeds the breakdown strength for the air in the air gap 20, and a charge of the same sign as the applied electrode voltage is deposited on the surface of the web 10.
  • the electrostatic forces produced by the alternating voltage cause at least some of the particles attached thereto to lift off the surface of the web 10, so that they can then be removed by air supplied to the surface of the web through the air jet 50, and removed from that surface by the suction section 28 of the air supply arrangement 22.
  • the relationship between the alternating voltage waveform and the removal of particles from the surface of the web 10 is shown in Figure 2.
  • an alternating voltage waveform 100 is shown.
  • a regular sinusoidal waveform is shown but any other suitable alternating waveform can be used.
  • a current waveform 102 and a force 'waveform' 104 are also shown.
  • the waveforms 102 and 104 are depicted on the same time scale as the voltage waveform 100.
  • the alternating voltage supply (not shown) is chosen to have a voltage which produces an electric field to loosen the particles from the surface of the web, the voltage having a maximum value to produce an electric field exceeding the breakdown strength of the air in the air gap 20.
  • the electrode 18 is shaped so that breakdown occurs along the entire width of the web 10, and the corona discharge produced in the gap 20 is not concentrated at one point only.
  • the gap 20 is small, preferably less than 4mm, but any suitable value can be chosen according to the particular arrangement of the apparatus.
  • the size of the air gap is determined by known parameters which affect the production of a corona discharge.
  • the alternating high voltage supply is chosen to have a frequency which is of several kHz, preferably in the range of 1 to 5kHz, although other frequencies may be workable according to the particular embodiment of the apparatus.
  • the frequency of the alternating voltage is related to the speed of the web.
  • the web For the apparatus to work, the web must be under the electrode for at least half a cycle of the alternating voltage. However, it is preferred that the web is under the electrode for more than 2 cycles. With this in mind, lower frequencies can be used if the web is moving at a compatible speed.
  • the alternating voltage may have a regular sinusoidal waveform or it may have one of many other waveforms.
  • the voltage supplied to the electrode should have:
  • web cleaning apparatus according to the present invention is described with reference to a web which passes over a cylinder, the apparatus can be used equally well in an arrangement in which the web passes over a flat surface.

Abstract

In known non-contact web cleaners, clean air at high velocity is passed over the surface of the web to remove debris. However, these web cleaners can only remove particles down to a certain size due to the boundary layer produced over the surface of the web by the high velocity air stream. Electrostatic charges are also used to neutralise the charge which may be attracting the debris or dirt to the surface of the web. Electrostatic cleaning is only effective at low web speeds. Described herein is a method and apparatus which produces alternating electrostatic forces to separate particles from the surface of the web in the region of the boundary layer. The apparatus utilises an electrode (18) to produce a corona discharge in a gap (20) formed between the electrode (18) itself and the surface of the web (10) being treated. An air supply arrangement (22) is provided to supply air to and remove air from the gap (20) to remove the particles which have been lifted from the surface of the web (10) due to the corona discharge.

Description

  • This invention relates to web cleaning apparatus, and is more particularly concerned with non-contact web cleaning apparatus.
  • In known non-contact web cleaners, clean air at high velocity is passed over the surface of the web to remove debris. It is also known to utilise electrostatic charges to neutralise the charge which may be attracting the debris or dirt to the surface of the web.
  • US Patent Specification US-A-2920987 describes an arrangement which can be used to clean the surface of a non-conducting material. A high alternating voltage supply is applied to the material by means of an electrode positioned adjacent one surface of the web. This alternating voltage damps out the static charge present on the surface of the material due to a previous operation, for example, a grinding operation. Arranged on the opposite side of the material to the electrode is a series of projections which contact the material. Particles on the material after the grinding operation, say, are removed due to the electrostatic effect produced by the electrode and the physical contact of the projections with the material itself. Loosened particles are removed from the surface of the material by suction.
  • Another arrangement in which alternating voltages are used to assist in the removal of particles from the surface of a web is described in US Patent Specification US-A-2980933. In this arrangement, the web is passed through two static electrostatic fields of opposite charge, an air stream being used to remove the particles loosened by the oppositely charged electrostatic fields.
  • US Patent Specification US-A-4213167 discloses an arrangement in which both surfaces of a web are cleaned by causing air to flow over both surfaces, and introducing ions into the air flow to neutralise static charge on the web. Other examples of the use of ionised air streams to remove dust are disclosed in US Patent Specifications US-A-4454621 and US-A-4241377.
  • US Patent Specification US-A-4835808 discloses an arrangement which utilises both suction and blowing to remove particles from the surface of a web. A field plate is also used to charge the web and an electrode is used to discharge the web thereby removing the particles. US Patent Specification US-A-3536528 also discloses the use of suction and blowing to remove particles from the surface of a web, but in this case, the charge on the web is neutralised after cleaning.
  • In arrangements which utilise air at high velocity to remove loosened particles from the surface of a web, there is a lower limit to the size of particle which can be removed. This limit is due to the thickness of the boundary layer produced over the surface of the web by the high velocity air stream. The thickness of the boundary layer can be reduced by increasing the air velocity, but a practical limit is approximately 30»m on a smooth surface and more than this on a rough one.
  • French Patent Application FR-A-2179707 discloses apparatus and method for cleaning glass sheets. Electrostatic charge is generated on the sheet by means of corona discharge as it passes between two electrode strips arranged transverse to the direction of motion of the glass sheets, each strip having a plurality of needle electrodes arranged along its length. These electrode strips are used to discharge particles adhering to the glass sheet and once discharged, the particles are removed using an airstream.
  • Web cleaners which use ions to discharge the electrostatic charges holding particles against the surface of the web are only effective at low web speeds. However, this may prevent particles being re-attracted to the web after they have been loosened.
  • It is therefore an object of the present invention to provide an improved web cleaning apparatus and method in which sufficient force is produced using alternating electrostatic fields to separate particles from the surface of the web, in the boundary layer region, so that they can be removed from the surface of the web.
  • According to one aspect of the present invention, there is provided a method of cleaning web material comprising,
       passing the web through an air gap, the air gap being defined by a first surface over which the web passes, the web being supported by the first surface, and a second surface spaced from the first surface,
       producing a corona discharge across the air gap to generate electrostatic forces on the web and on the particles to cause at least some of the particles to lift off the surface of the web, and
       removing particles from the web.
  • Preferably, the corona discharge is produced by an alternating voltage supply.
  • According to a second aspect of the present invention, there is provided a web cleaning apparatus for use in a method as described above which comprises:-
       means for defining an air gap, comprising a first surface over which the web passes, the web being supported by the first surface, and a second surface spaced from the first surface,
       generator means for producing a corona discharge in the air gap, and
       means for removing particles loosened by the corona discharge.
  • At least one of the first and second surfaces is an insulating surface so that the corona discharge does not only occur at a single point.
  • The generator means may be a high voltage alternating supply.
  • Once the particles have been loosened, they can be removed using a high velocity air stream. Additionally, or alternatively, suction means can be used to remove the loosened particles.
  • In a preferred arrangement, the generator means operates at a frequency between 1 to 5kHz.
  • For a better understanding of the present invention, reference will now be made, by way of example only, to the accompanying drawings in which:-
    • Figure 1 illustrates one embodiment of web cleaning apparatus according to the present invention; and
    • Figure 2 shows graphically the relationship between an alternating voltage waveform, electrode current, and force on the surface of a web.
  • The present invention aims to deposit a significant charge of one sign on the web and then subject it to an electric field of the opposite sign to produce a force to dislodge particles from the surface of the web. Particles so dislodged can then be removed by an air stream passing over the surface of the web, or by suction applied to the web surface.
  • The apparatus shown in Figure 1 comprises a cylinder 12 over which a web 10 to be cleaned is passed. The surface of the cylinder 12 has a layer 14 of insulating material placed on it. The rest of the apparatus is positioned above the cylinder 12, and is mounted in a housing 16. An electrode 18 is positioned above the cylinder 12 so that the web 10 passes through a gap 20 formed between the cylinder 12 and the electrode 18. The electrode 18 has an insulating surface 19, and is connected to a high voltage alternating supply (not shown) which causes a corona discharge to occur in the gap 20.
  • In other applications, the insulating surface 19 and the layer 14 may not be required, the insulating surface being provided by the web itself.
  • An air supply arrangement 22 for supplying air to and removing air from the gap 20 is attached to an upper wall 24 of the housing 16 as shown. The arrangement 22 comprises a blower section 26 and a suction section 28 positioned adjacent one another with a dividing wall 30 therebetween. Each section 26, 28 has a respective opening 32, 34 which allows the passage of air into and out of that section.
  • The arrangement 22 also provides a means of positioning the electrode 18 above the surface of the cylinder 12. An insulating support member 36 is attached at one end to the arrangement 22 and at the other to the electrode 18. The support member 36 is positioned between the openings 32, 34 thereby forming two ducts 38, 40, with further walls 42, 44. The walls 42, 44 are also made of insulating material so that the ducts 38, 40 so formed are non-conducting.
  • A member 46 is attached to the lower end 48 of wall 42 and extends perpendicularly to it. The member 46, in conjunction with the electrode 18, forms an air jet 50 through which air is directed towards the gap 20.
  • The apparatus operates as follows:
  • An alternating high voltage is applied to the electrode 18. Charging of the web and the production of forces into and away from the surface of the web occurs each half cycle of the alternating applied voltage.
  • As the voltage approaches its maximum absolute value, the strength of the electric field exceeds the breakdown strength for the air in the air gap 20, and a charge of the same sign as the applied electrode voltage is deposited on the surface of the web 10.
  • While the applied electrode voltage decreases from its maximum absolute value, a force is produced into the web.
  • When the applied voltage starts to increase (having changed sign), a force away from the surface of the web is produced. This force continues until enough charge has been deposited on the surface of the web to neutralise the previously deposited charge. Charging continues until the next maximum absolute value of applied voltage is reached. This charging provides the charge necessary to produce the forces into and away from the surface of the web during the next half cycle.
  • The electrostatic forces produced by the alternating voltage cause at least some of the particles attached thereto to lift off the surface of the web 10, so that they can then be removed by air supplied to the surface of the web through the air jet 50, and removed from that surface by the suction section 28 of the air supply arrangement 22. The relationship between the alternating voltage waveform and the removal of particles from the surface of the web 10 is shown in Figure 2.
  • In Figure 2, an alternating voltage waveform 100 is shown. In this case, a regular sinusoidal waveform is shown but any other suitable alternating waveform can be used. A current waveform 102 and a force 'waveform' 104 are also shown. The waveforms 102 and 104 are depicted on the same time scale as the voltage waveform 100.
  • There are periods, indicated as 106, which due to the electrostatic forces acting away from the surface of the web, cause the particles to lift off the surface of the web 10.
  • The alternating voltage supply (not shown) is chosen to have a voltage which produces an electric field to loosen the particles from the surface of the web, the voltage having a maximum value to produce an electric field exceeding the breakdown strength of the air in the air gap 20. The electrode 18 is shaped so that breakdown occurs along the entire width of the web 10, and the corona discharge produced in the gap 20 is not concentrated at one point only.
  • The gap 20 is small, preferably less than 4mm, but any suitable value can be chosen according to the particular arrangement of the apparatus. The size of the air gap is determined by known parameters which affect the production of a corona discharge.
  • The alternating high voltage supply is chosen to have a frequency which is of several kHz, preferably in the range of 1 to 5kHz, although other frequencies may be workable according to the particular embodiment of the apparatus. The frequency of the alternating voltage is related to the speed of the web. For the apparatus to work, the web must be under the electrode for at least half a cycle of the alternating voltage. However, it is preferred that the web is under the electrode for more than 2 cycles. With this in mind, lower frequencies can be used if the web is moving at a compatible speed.
  • The alternating voltage may have a regular sinusoidal waveform or it may have one of many other waveforms. In order for the apparatus to work effectively, the voltage supplied to the electrode should have:
    • a) a period of time when the voltage is suitable to allow the electrostatic forces (which cause the loosening of the particles) to take effect, and
    • b) a period of time when the voltage is suitable to produce a corona discharge thereby charging the surface of the web.
  • Because of these two requirements, an alternating square waveform cannot be used.
  • Although web cleaning apparatus according to the present invention is described with reference to a web which passes over a cylinder, the apparatus can be used equally well in an arrangement in which the web passes over a flat surface.

Claims (12)

  1. A method of cleaning web material (10) comprising,
       passing the web (10) through an air gap (20), the air gap (20) being defined by a first surface (12, 14) over which the web (10) passes, the web (10) being supported by the first surface (12, 14), and a second surface (18, 19) spaced from the first surface (12, 14),
       producing a corona discharge across the air gap (20) to generate electrostatic forces on the web (10) and on the particles to cause at least some of the particles to lift off the surface of the web (10), and
       removing particles from the web (10).
  2. A method according to claim 1, wherein the corona discharge is produced by an alternating voltage supply.
  3. A method according to claim 1 or 2, wherein loosened particles are removed from the web by an air stream.
  4. A method according to claim 3, wherein the air stream is generated by suction.
  5. A method according to any one of claims 1 to 4, wherein at least one of the first surface (12, 14) and second surface (18, 19) is an insulating surface.
  6. A method according to any one of claims 1 to 4, wherein the web (10) constitutes an insulating surface.
  7. Web cleaning apparatus for use in a method according to any one of the preceding claims, the apparatus comprising:-
       means for defining an air gap (20) comprising a first surface (12, 14) over which the web (10) passes, the web (10) being supported by the first surface (12, 14), and a second surface (18, 19) spaced from the first surface (12, 14),
       generator means for producing a corona discharge in the air gap (20), and
       means for removing particles loosened by the corona discharge.
  8. Apparatus according to claim 7, wherein at least one of the first and second surfaces (12, 14; 18, 19) is an insulating surface.
  9. Apparatus according to claim 7 or 8, wherein the generator means is a high voltage alternating supply.
  10. Apparatus according to any one of claims 7 to 9, wherein the means for removing loosened particles is a high velocity air stream.
  11. Apparatus according to any one of claims 7 to 9, wherein the means for removing loosened particles includes suction means.
  12. Apparatus according to any one of claims 7 to 11, wherein the generator means operates at a frequency between 1 to 5kHz.
EP91903320A 1990-02-14 1991-02-11 Web cleaning apparatus Expired - Lifetime EP0515414B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB909003283A GB9003283D0 (en) 1990-02-14 1990-02-14 Web cleaning apparatus
GB9003283 1990-02-14
PCT/EP1991/000283 WO1991012095A1 (en) 1990-02-14 1991-02-11 Web cleaning apparatus

Publications (2)

Publication Number Publication Date
EP0515414A1 EP0515414A1 (en) 1992-12-02
EP0515414B1 true EP0515414B1 (en) 1994-06-01

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Application Number Title Priority Date Filing Date
EP91903320A Expired - Lifetime EP0515414B1 (en) 1990-02-14 1991-02-11 Web cleaning apparatus

Country Status (6)

Country Link
EP (1) EP0515414B1 (en)
JP (1) JPH05504297A (en)
AT (1) ATE106284T1 (en)
DE (1) DE69102266T2 (en)
GB (1) GB9003283D0 (en)
WO (1) WO1991012095A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19525453A1 (en) * 1995-07-13 1997-01-16 Eltex Elektrostatik Gmbh Device for removing the gaseous laminar boundary layer
DE10018010C2 (en) * 2000-04-11 2003-10-16 Eltex Elektrostatik Gmbh Dust removal device and its use
DE10033839A1 (en) 2000-07-12 2002-01-24 Roland Man Druckmasch Dryer inside a sheetfed press
US6709623B2 (en) 2000-12-22 2004-03-23 Kimberly-Clark Worldwide, Inc. Process of and apparatus for making a nonwoven web
US7488441B2 (en) 2002-06-15 2009-02-10 Kimberly-Clark Worldwide, Inc. Use of a pulsating power supply for electrostatic charging of nonwovens
DE10236071A1 (en) * 2002-08-07 2004-02-19 Softal Electronic Erik Blumenfeld Gmbh & Co. Method and device for cleaning surfaces of moving material webs
DE10255382A1 (en) 2002-11-25 2004-06-03 Sipra Patententwicklungs- Und Beteiligungsgesellschaft Mbh Textile machine with at least one dedusting device
JP5138981B2 (en) * 2007-06-04 2013-02-06 株式会社Trinc Dust removal device for level sensor
DE102014003692B3 (en) * 2014-03-13 2015-06-03 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Cleaning device and method for cleaning
JP6402018B2 (en) * 2014-12-15 2018-10-10 花王株式会社 Nonwoven manufacturing method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5216354B2 (en) * 1972-04-10 1977-05-09
DE3662992D1 (en) * 1986-04-29 1989-06-01 Eltex Elektrostatik Gmbh Dust-removing probe for moving webs, especially for paper webs
US4727614A (en) * 1987-01-20 1988-03-01 Shape Inc. Ground corona comb

Also Published As

Publication number Publication date
GB9003283D0 (en) 1990-04-11
EP0515414A1 (en) 1992-12-02
DE69102266D1 (en) 1994-07-07
ATE106284T1 (en) 1994-06-15
WO1991012095A1 (en) 1991-08-22
DE69102266T2 (en) 1995-01-05
JPH05504297A (en) 1993-07-08

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