EP0506807B1 - Flexibles, reiss- und berstbeständiges blatt mit geringem flüssigkeitsabsorptionsvermögen und kontrollierter porosität - Google Patents

Flexibles, reiss- und berstbeständiges blatt mit geringem flüssigkeitsabsorptionsvermögen und kontrollierter porosität Download PDF

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Publication number
EP0506807B1
EP0506807B1 EP91901826A EP91901826A EP0506807B1 EP 0506807 B1 EP0506807 B1 EP 0506807B1 EP 91901826 A EP91901826 A EP 91901826A EP 91901826 A EP91901826 A EP 91901826A EP 0506807 B1 EP0506807 B1 EP 0506807B1
Authority
EP
European Patent Office
Prior art keywords
fact
sheet
resistant
sheet according
moisture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP91901826A
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English (en)
French (fr)
Other versions
EP0506807A1 (de
Inventor
Jean-Yves Escabasse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ArjoWiggins SAS
Original Assignee
ArjoWiggins SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ArjoWiggins SAS filed Critical ArjoWiggins SAS
Publication of EP0506807A1 publication Critical patent/EP0506807A1/de
Application granted granted Critical
Publication of EP0506807B1 publication Critical patent/EP0506807B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1303Paper containing [e.g., paperboard, cardboard, fiberboard, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249994Composite having a component wherein a constituent is liquid or is contained within preformed walls [e.g., impregnant-filled, previously void containing component, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/253Cellulosic [e.g., wood, paper, cork, rayon, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/268Monolayer with structurally defined element
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/269Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/27Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y10T428/273Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
    • Y10T428/277Cellulosic substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2402Coating or impregnation specified as a size
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2484Coating or impregnation is water absorbency-increasing or hydrophilicity-increasing or hydrophilicity-imparting

Definitions

  • the present invention relates to a flexible sheet which can be used especially for sterilizable packaging.
  • a first property is that the sheet must be flexible to ability to form sachets into which objects of various shapes and sizes.
  • a second property is that the sheet must be resistant to tearing as well as bursting. Indeed, it is intended for contain objects which may be heavy and blunt or sharp. In addition, it is intended in the form of a sachet, during sterilization with gases, for example ethylene oxide, to be subjected to pressure during gas injection and strong posterior depression during the evacuation of gases, which must be complete.
  • gases for example ethylene oxide
  • a third property is that the sheet must be slightly absorbent especially with regard to water, so that water or other products liquids do not penetrate through the sachet formed by the sheet, from outside to inside, by defiling the wrapped object, in the bag.
  • Such sheets of paper are sold to manufacturers of sterilizable sachets or packaging that make up the sachet having a layer of lacquer which ensures the connection between the edges of the sheet and a transparent film.
  • processors apply heat-sealable lacquer, aqueous or solvent medium, so as to preserve a certain gas permeability of paper.
  • the bags or pouches are then heat-sealed with plastic films.
  • Sheets have also been made of the dry non-woven type, that is to say that a mattress of synthetic fibers, for example polyethylene, is made, which is bonded together, when hot. These sheets are manufactured by the company DU PONT DE NEMOURS and sold under the name of TYVEK R. These sheets are resistant to tearing and bursting. In addition, they are flexible. However, a major drawback of these sheets is that their thickness is very heterogeneous, that is to say that the distribution of the fibers per unit area is irregular, which means that the porosity of the sheet is not uniform. Thus, in certain places, the sheet will have pores of too large diameter, which will have the effect that the microorganisms will be able to penetrate inside the packaging produced using this sheet. On the contrary, in certain places, the sheet will have pores of too small diameter, which will hinder the penetration of the molecules of sterilizing gas. In addition, these sheets are absolutely permanent, that is to say non-biodegradable.
  • the invention is remarkable in that, according to a person skilled in the art, it it is difficult to combine the requisite qualities simultaneously. Indeed, the products that improve mechanical characteristics increase the rigidity, therefore decrease flexibility.
  • the first fabric softeners mentioned destroy connections interfibers, so they decrease the mechanical characteristics.
  • the second cited do not have this disadvantage but they oppose the action of the bonding agents which give the barrier properties leaf.
  • the invention relates to a flexible sheet, resistant to tearing and bursting, very little absorbent with water or other liquid, with controlled porosity, printable, comprising a support based on cellulose fibers of which at least one of the faces is impregnated with a composition comprising at least one binder, characterized in that the composition contains at least one moisture-retaining agent and at least one bonding agent, such as the measured COBB 60 bonding according to ISO535 standard, is less than 20 g / m 2 , that the TABER stiffness, measured according to ISO 2493 standard is less than 2.5 and that the amount of moisture-retaining agent is less than about 20% by weight dry leaf.
  • the sheet preferably contains at least 1% moisture-retaining agent.
  • the humidity-retaining agent is preferably chosen from the group formed by urea, a nitrate salt or their mixtures.
  • urea-nitrate mixture the mixture can preferably be used in a urea / sodium nitrate ratio of 2: 1.
  • the bonding agent is chosen from the group formed by wax or paraffin dispersions, alkyl ketene dimers, alkylene succinic anhydrides, stearic anhydrides and their mixtures.
  • the binder is chosen from the group formed by polyvinyl alcohol, native starch or its derivatives, cellulose ethers or esters, alginates, guaranates or mixtures thereof.
  • the impregnation composition is preferably carried out in the medium aqueous.
  • the fibrous support is preferably a support formed mainly cellulose fibers.
  • This support is preferably not bonded en masse; it can contain at least one wet resistance.
  • the sheet is produced by a papermaking process.
  • the support can be impregnated with the composition according to the invention, using a sizing press. Any other means of impregnation or bedding usually used in stationery may be suitable.
  • the invention makes it possible to provide printable sheets, preferably by heliographic printing, offset or flexographic.
  • the invention makes it possible to provide sheets whose physical characteristics are homogeneous, i.e. substantially the same in the cross direction as in the running direction.
  • the invention makes it possible to provide sheets which are the more easily biodegradable after use and the cost of manufacturing is competitive.
  • the invention is remarkable in that a sheet is obtained having a COBB of less than 20 g / m2 and up to 12 g / m2, and having a TABER stiffness of less than 2.5 and having an index of tear greater than 80 cNm2 / g.
  • the following examples are carried out on a paper machine of laboratory. We impregnate, using a sizing press, a support based on cellulose fibers, not mass bonded. The compositions for the impregnation bath are carried out in medium aqueous.
  • the tear index is measured according to ISO standard 1974.
  • the dry burst index is measured according to the ISO 2758 measurement.
  • the wet burst index is measured according to ISO standard 3686 (after immersion in water for ten minutes). (after immersion in water for ten minutes). Burst REH (wet strength) is the ratio of the wet burst and dry burst indices, multiplied by 100.
  • TABER stiffness is measured according to ISO 2493.
  • BENDTSEN porosity is measured according to ISO 5636/3.
  • the dry recovery expresses the quantity of sauce by dry weight absorbed per sheet per square meter.
  • the sheets obtained are sterilizable. They are sealable and peelable.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Paper (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Laminated Bodies (AREA)
  • Materials For Medical Uses (AREA)
  • Packages (AREA)
  • Wrappers (AREA)

Claims (8)

  1. Reiß- und berstfeste weiche Folie mit kontrollierter (gesteuerter) Porosität, die bedruckbar ist und sehr wenig Wasser oder sonstige Flüssigkeit absorbiert, die umfaßt einen Träger auf Basis von Cellulosefasern, bei dem mindestens eine der Oberflächen mit einer mindestens ein Bindemittel enthaltenden Zusammensetzung imprägniert ist, dadurch gekennzeichnet,
    daß die Zusammensetzung mindestens ein Feuchthaltemittel in einer Menge von weniger als etwa 20 %, bezogen auf das Trockengewicht der Folie, und mindestens ein Klebemittel in einer solchen Menge enthält, daß die Klebekraft COBB60, bestimmt nach der Norm ISO 535, unter 20 g/m2 liegt, und daß die TABER-Steifheit, bestimmt nach der Norm ISO 2493,unter 2,5 liegt.
  2. Folie nach Anspruch 1, dadurch gekennzeichnet, daß sie mindestens 1 % Feuchthaltemittel enthält.
  3. Folie nach einem der Ansprüche 1 und 2, dadurch gekennzeichnet, daß es sich bei dem Feuchthaltemittel um Harnstoff, ein Nitratsalz oder Mischungen davon handelt.
  4. Folie nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß es sich bei dem Feuchthaltemittel um ein Harnstoff/Natriumnitrat-Gemisch im Verhältnis 2:1 handelt.
  5. Folie nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß das Klebemittel ausgewählt wird aus der Gruppe, die besteht aus Wachs- oder Paraffin-Dispersionen, Alkylketendimeren, Alkylenbernsteinsäureanhydriden, Stearinsäureanhydriden und Mischungen davon.
  6. Folie nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß das Bindemittel ausgewählt wird aus der Gruppe, die besteht aus Polyvinylalkohol, nativer Stärke oder ihren Derivaten, Celluloseethern oder -estern, Alginaten, Guaranaten oder Mischungen davon.
  7. Folie nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, daß sie ein feuchtigkeitsbeständig machendes Mittel enthält.
  8. Sterilisationsverpackung, dadurch gekennzeichnet, daß sie mindestens eine Folie nach einem der Ansprüche 1 bis 7 umfaßt.
EP91901826A 1989-12-22 1990-12-21 Flexibles, reiss- und berstbeständiges blatt mit geringem flüssigkeitsabsorptionsvermögen und kontrollierter porosität Expired - Lifetime EP0506807B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR8917147A FR2656346B1 (fr) 1989-12-22 1989-12-22 Feuille souple, resistant a la dechirure et l'eclatement, peu absorbante aux liquides et a porosite controlee.
FR8917147 1989-12-22
PCT/FR1990/000940 WO1991010011A1 (fr) 1989-12-22 1990-12-21 Feuille souple, resistant a la dechirure et l'eclatement, peu absorbante aux liquides et a porosite controlee

Publications (2)

Publication Number Publication Date
EP0506807A1 EP0506807A1 (de) 1992-10-07
EP0506807B1 true EP0506807B1 (de) 1998-05-20

Family

ID=9388929

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91901826A Expired - Lifetime EP0506807B1 (de) 1989-12-22 1990-12-21 Flexibles, reiss- und berstbeständiges blatt mit geringem flüssigkeitsabsorptionsvermögen und kontrollierter porosität

Country Status (7)

Country Link
US (1) US5180614A (de)
EP (1) EP0506807B1 (de)
AT (1) ATE166404T1 (de)
AU (1) AU7053891A (de)
DE (1) DE69032327D1 (de)
FR (1) FR2656346B1 (de)
WO (1) WO1991010011A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10272639B2 (en) 2015-03-23 2019-04-30 Emd Millipore Corporation Abrasion resistant film for biocontainers

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5663218A (en) * 1992-03-03 1997-09-02 Lafarge Materiaux De Specialites Protection from shocks, capable of deforming progressively and in an irreversible manner
FR2688239B1 (fr) * 1992-03-03 1995-03-31 Lafarge Nouveaux Materiaux Composition pour la fabrication d'un materiau utile comme protection contre les chocs et emballage protecteur realise grace a ce materiau.
US5667753A (en) * 1994-04-28 1997-09-16 Advanced Sterilization Products Vapor sterilization using inorganic hydrogen peroxide complexes
US6123811A (en) * 1998-12-14 2000-09-26 Ethicon, Inc. Method of manufacturing aqueous paper pulp for water soluble packages
US7282273B2 (en) * 2005-10-26 2007-10-16 Polymer Ventures, Inc. Grease resistance and water resistance compositions and methods
US20080003384A1 (en) * 2006-06-29 2008-01-03 Polymer Ventures, Inc. Multi-layer coatings to increase water and grease resistance of porous materials and materials having such protection
US20090098303A1 (en) * 2007-10-15 2009-04-16 Polymer Ventures, Inc. Coatings to increase water and grease resistance of porous materials and materials having such protection
US20110220126A1 (en) 2010-03-11 2011-09-15 Lebrette Laurent Biodegradable medical material

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2268674A (en) * 1939-09-09 1942-01-06 Richards Chemical Works Inc Process for softening paper
NL124069C (de) * 1959-03-13 1900-01-01
US4207367A (en) * 1970-03-30 1980-06-10 Scott Paper Company Nonwoven fabric
US4025354A (en) * 1973-05-08 1977-05-24 Plasmine Corporation Urea containing sizing compositions
US3916058A (en) * 1973-06-25 1975-10-28 Nalco Chemical Co Method of treating paper and textiles with organically modified sio' 2 'aquasols
US4247318A (en) * 1979-01-30 1981-01-27 E. I. Du Pont De Nemours And Company Process for making security paper from film-fibril sheets
US4235657A (en) * 1979-02-12 1980-11-25 Kimberly Clark Corporation Melt transfer web
DE3111936A1 (de) * 1981-03-26 1982-10-07 Cassella Ag, 6000 Frankfurt Verfestigte gebilde aus textilen materialien
DE3325826A1 (de) * 1983-07-18 1985-01-31 Dr. Werner Freyberg Chemische Fabrik Delitia Nachf., 6941 Laudenbach Beutel zur aufnahme ausgasungsfaehiger schaedlingsbekaempfungsmittel
FR2642430B1 (fr) * 1989-01-10 1991-05-17 Hoechst France Nouvelles resines aminoplastes destinees a l'ennoblissement des fibres cellulosiques et leur application

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10272639B2 (en) 2015-03-23 2019-04-30 Emd Millipore Corporation Abrasion resistant film for biocontainers
US10675836B2 (en) 2015-03-23 2020-06-09 Emd Millipore Corporation Abrasion resistant film for biocontainers
US11110684B2 (en) 2015-03-23 2021-09-07 Emd Millipore Corporation Abrasion resistant film for biocontainers

Also Published As

Publication number Publication date
FR2656346A1 (fr) 1991-06-28
FR2656346B1 (fr) 1992-04-10
US5180614A (en) 1993-01-19
WO1991010011A1 (fr) 1991-07-11
AU7053891A (en) 1991-07-24
DE69032327D1 (de) 1998-06-25
EP0506807A1 (de) 1992-10-07
ATE166404T1 (de) 1998-06-15

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