EP0503221B1 - Konzentrierte Textilweichmacherzusammensetzungen - Google Patents
Konzentrierte Textilweichmacherzusammensetzungen Download PDFInfo
- Publication number
- EP0503221B1 EP0503221B1 EP19910870187 EP91870187A EP0503221B1 EP 0503221 B1 EP0503221 B1 EP 0503221B1 EP 19910870187 EP19910870187 EP 19910870187 EP 91870187 A EP91870187 A EP 91870187A EP 0503221 B1 EP0503221 B1 EP 0503221B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- fabric softening
- composition
- composition according
- concentrated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
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- 239000000203 mixture Substances 0.000 title claims description 117
- 239000004744 fabric Substances 0.000 title claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 150000002191 fatty alcohols Chemical class 0.000 claims description 15
- 229920006294 polydialkylsiloxane Polymers 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- -1 imidazoline ester Chemical class 0.000 claims description 9
- 125000002091 cationic group Chemical group 0.000 claims description 8
- 238000010790 dilution Methods 0.000 claims description 7
- 239000012895 dilution Substances 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 claims description 5
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 5
- SJHPCNCNNSSLPL-CSKARUKUSA-N (4e)-4-(ethoxymethylidene)-2-phenyl-1,3-oxazol-5-one Chemical compound O1C(=O)C(=C/OCC)\N=C1C1=CC=CC=C1 SJHPCNCNNSSLPL-CSKARUKUSA-N 0.000 claims description 4
- 238000007046 ethoxylation reaction Methods 0.000 claims description 4
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 claims description 3
- 229920001477 hydrophilic polymer Polymers 0.000 claims description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 2
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- 230000000063 preceeding effect Effects 0.000 claims 1
- 239000002304 perfume Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 239000002979 fabric softener Substances 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 239000001110 calcium chloride Substances 0.000 description 3
- 229910001628 calcium chloride Inorganic materials 0.000 description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- QTJISTOHDJAKOQ-UHFFFAOYSA-N 2-hydroxyethylazanium;methyl sulfate Chemical compound [NH3+]CCO.COS([O-])(=O)=O QTJISTOHDJAKOQ-UHFFFAOYSA-N 0.000 description 2
- 229920004511 Dow Corning® 200 Fluid Polymers 0.000 description 2
- 239000004353 Polyethylene glycol 8000 Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229940057838 polyethylene glycol 4000 Drugs 0.000 description 2
- 229940085678 polyethylene glycol 8000 Drugs 0.000 description 2
- 235000019446 polyethylene glycol 8000 Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- YWKSINPSASCIMZ-UHFFFAOYSA-N 4,5-dimethyl-4,5-dihydro-1h-imidazole Chemical compound CC1NC=NC1C YWKSINPSASCIMZ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 206010034759 Petit mal epilepsy Diseases 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- VKKVMDHHSINGTJ-UHFFFAOYSA-M di(docosyl)-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCCCCCC VKKVMDHHSINGTJ-UHFFFAOYSA-M 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3734—Cyclic silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
- C11D3/202—Monohydric alcohols branched fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/58—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Definitions
- the present invention relates to fabric softeners.
- the compositions according to the invention are concentrated aqueous fabric softening compositions which retain viscosity upon dilution.
- Concentrated aqueous fabric softening compositions have been extensively described in the art, and one aspect which has often been discussed is the viscosity of these concentrated compositions; indeed these concentrated compositions are typically extremely viscous and the prior art has often described means by which the viscosity of these concentrated compositions could be controlled or decreased.
- One aspect which has been much less dealt with is the viscosity of these concentrated compositions upon dilution; indeed it has been observed that the viscosity of such concentrated compositions dramatically drops upon dilution, and this viscosity loss is clearly undesirable, essentially in terms of consumer acceptance.
- Concentrated aqueous fabric softeners have been described for instance in EP 56 695, EP 13 780, DE 26 31 114 and EP 60 003, and a process for the preparation of concentrated fabric softening compositions is disclosed in EP-A-316 996.
- EP 0,309,052 discloses concentrated aqueous fabric softening compositions comprising a fabric softener component and a linear fatty ethoxylated alcohol.
- a concentrated aqueous fabric softening composition comprising from 10% to 35% by weight of a cationic fabric softening active or mixtures thereof, said composition further comprising:
- the present invention also encompasses a method for the softening of fabrics, wherein the above concentrated compositions are diluted in water before they are contacted with said fabrics in the rinse water.
- compositions according to the invention are concentrated fabric softeners; by concentrated, it is meant that the compositions comprise from 10% to 35% by weight of the total composition of a cationic fabric softening active or mixtures thereof, preferably 15% to 25%.
- cationic it is meant any softening compound which is in cationic form in the concentrated softening composition.
- Suitable cationic fabric softening actives include
- Component (i) are the well-known dialkyldimethylammonium salts such as ditallowdimethylammonium chloride (DTDMAC), ditallowdimethylammonium methylsulfate, di(hydrogenated tallow) dimethylammonium chloride, dibehenyldimethylammonium chloride.
- DTDMAC ditallowdimethylammonium chloride
- ditallowdimethylammonium methylsulfate di(hydrogenated tallow) dimethylammonium chloride
- dibehenyldimethylammonium chloride ditallowdimethylammonium chloride
- Component (ii) and (iii) are methylbis(tallowamidoethyl) (2-hydroxyethyl) ammonium methylsulfate and methylbis(hydrogenated tallowamidoethyl) (2-hydroxyethyl) ammonium methylsulfate, wherein R 1 is an acyclic aliphatic C 15 -C 17 hydrocarbon group, R 2 is an ethylene group, R 5 is a methyl group, R 8 is a hydroxyalkyl group and A is a methylsulfate anion; these materials are available from Sherex Chemical Company under the trade names Varisoft 222 R and Varisoft 110 R, respectively.
- Component (iv) are l-methyl-1-tallowamido-ethyl-2-tallowimidazolinium methylsulfate and 1-methyl-1-(hydrogenated tallowamidoethyl)-methylsulfate.
- Suitable fabric softening actives include the following amines, provided they are present in the concentrated softening composition in a protonated form; such amines are of the formula : wherein n is 2 or 3, preferably 2; R 1 and R 2 are, independently, a C 8 -C 30 alkyl or alkenyl, preferably C 12 -C 20 alkyl, more preferably C 15 -C 18 alkyl, or mixtures of such alkyl radicals. Examples of such mixtures are the alkyl radicals obtained from coconut oil, "soft" (non-hardened) tallow, and hardened tallow.
- Q is CH 2 or N, preferably N
- X is wherein T is O or NR 5 , R 5 being H or C 1 -C 4 alkyl, preferably H, and R 4 is a divalent C 1 -C 3 alkylene group or (C 2 H 4 O)m, wherein m is an integer of from 1 to 8; or X is R 4 .
- Most preferred softening agents according to the above formula are imidazolines of the following formula : wherein R1 is a tallow group.
- the softening amines described herein above are suitable for the purpose of the present invention provided they are present in the concentrated softening composition in a protonated form; a suitable means to protonate these amines is described for instance in EP 199 383.
- a preferred softening active mixture for use herein is a mixture of 20% to 70% by weight of the softening active of ditallow dimethyl ammonium chloride (DTDMAC) and 30% to 80% ditallow imidazoline.
- DTDMAC ditallow dimethyl ammonium chloride
- the concentrated compositions according to the invention comprise from 15% to 25% by weight of the finished product of such a mixture.
- the softening active comprises a ditallow imidazoline ester such as described herein above (i.e. when T is O and R 1 and R 2 are both tallow in the formula above). This embodiment is particularly preferred for environmental reasons.
- compositions according to the invention further comprise from 0.3% to 3% by weight of the total composition of a linear fatty alcohol ethoxylate of the formula RO(Etox) n , wherein R is a linear C 8 - 18 alkyl chain, and n representing the weighted average ethoxylation degree is of from 3 to 35, or mixtures thereof.
- a linear fatty alcohol ethoxylate of the formula RO(Etox) n wherein R is a linear C 8 - 18 alkyl chain, and n representing the weighted average ethoxylation degree is of from 3 to 35, or mixtures thereof.
- Preferred are linear fatty alcohol ethoxylates wherein R is a linear chain having from 10 to 13 carbon atoms, and wherein n is from 5 to 10, preferably 8.
- these compounds, or mixtures thereof are present at levels of from about 1 to about 1.5% by weight of the total composition.
- These compounds are commercially available from BASF under the trade name LUTENSOL TO®.
- compositions according to the present invention further comprise from 0.5% to 6% , preferably from 1.5% to 2.5% by weight of the composition of a nonionic hydrophylic polymer, or mixtures thereof.
- suitable polymers include polyethylene glycol, polypropylene glycol, polyvinylalcolhol and the like. Particularly preferred is a polyethylene glycol having a molecular weight of from 300 to 50000, preferably 2000 to 10000.
- the softening active is a mixture of DTDMAC and ditallow imidazoline
- the softening active comprises ditallow imidazoline ester
- compositions according to the present invention further comprise from 0% to 2%, preferably from 0% to 0.1% by weight of the total composition of a highly branched fatty alcohol having from 8 to 18 carbon atoms, preferably 12 to 14, or mixtures thereof, most preferably 13.
- Branched compounds similar to said highly branched fatty alcohols are often present in perfumes; thus, the level of said highly branched fatty alcohol to be added to the composition must be adjusted depending on the perfume which is used, if any.
- Such highly branched fatty alcohols suitable for use in the compositions according to the present invention are commercially available from EXXON under the trade name EXXAL®.
- compositions according to the invention may further comprise from 0% to 0.5% by weight of the total composition of a linear or cyclic polydialkylsiloxane of the formula: where R is a C 1 -C 5 alkyl group and m is an integer of 1 to 500, or mixtures thereof.
- Said polydialkylsiloxanes components are not essential ingredients in the compositions according to the invention, as the compositions will retain viscosity upon dilution even in the abscence of such polydialkylsiloxanes.
- several benefits can be obtained from these polydialkylsiloxanes, including improved stability of the finished product, improved water absorbancy of the treated fabrics.
- compositions according to the present invention comprise from 0.05% to 0.5%, most preferably from 0.1% to 0.3% by weight of the total composition of the above polydialkylsiloxanes, or mixtures thereof.
- the softening active comprises the ditallow imidazoline ester described herein above
- Suitable polydialkylsiloxanes are commercially available from DOW CORNING under the trade name 200 fluid, and the preferred polydialkylsiloxanes for use herein are DOW CORNING's 200 fluid 350 CS (R is methyl and m is 203) and 5 CS (R is methyl and m is 7).
- compositions according to the invention may additionally comprise such conventional ingredients as perfumes, preservatives, germicides, colorants, fungicides, stabilizers, brighteners, opacifiers and the like, at conventional levels, i.e. up to about 5% by weight of the composition.
- compositions in their concentrated form have a viscosity of from 40 to 400 mPa.s (cps) at 60 RPM shear rate.
- the compositions according to the invention can be used directly in the concentrated form, or they can preferably be diluted before they are used.
- the compositions according to the present invention are meant to be diluted in water, preferably in 2 to 3 times their weight of water.
- the compositions have a viscosity of from 20 to 60 mPa.s (cps) at 60 RPM shear rate, preferably 30 to 50 mPa.s (cps) at 6o RPM shear rate.
- the present invention also encompasses a method for the softening of fabrics wherein the concentrated fabric softening compositions described herein above are diluted in water before they are contacted with said fabrics.
- a concentrated softening composition as described hereinabove which has a viscosity of from 40 to 400 mPa.s (cps) at 60 RPM shear rate, is diluted in two times its weight of water so as to obtain a diluted fabric softening composition having a viscosity of from 20 to 60, preferably 30 to 50 mPa.s (cps) at 60 RPM shear rate, and said diluted fabric softening composition is contacted with said fabrics in the rinse water.
- compositions according to the present invention are illustrated by the following examples.
- composition according to the present invention is made, which comprises :
- the above composition was made by adding the HCl to a water seat at 60°C-65°C. To this solution, a molten permix of ditallow dimethyl ammonium chloride, ditallowimidazoline and Lutensol TO 8 is added at about 80°C-85°C, under agitation during about 10 minutes. An aqueous solution of CaCl 2 is then injected for about 5 minutes. A mixture of perfume and the silicone oil is then added. The composition is then cooled to room temperature. Finally a 50% solution of the polyethylene glycol 4000 MW is added. The composition thus obtained has a viscosity of about 65 mPa.s (cps) before dilution, and 50 mPa.s (cps) after dilution in 2 times its weight of water.
- a composition which contains:
- a composition which contains:
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Claims (15)
- Konzentrierte, wäßrige Textilweichmacherzusammensetzung, umfassend10 bis 35 Gew. -% eines kationischen Textilweichmacherwirkstoffs oder Mischungen hiervon0,3 bis 3 Gew. -% der gesamten Zusammensetzung eines linearen Fettalkoholethoxylats der Formel RO(Etox)n, worin R eine lineare C8-C18-Alkylkette ist und n, das den gewichtsmittleren Ethoxylierungsgrad darstellt, 3 bis 35 ist, oder Mischungen hiervon;0,5 bis 6 Gew.-% der gesamten Zusammensetzung eines nichtionischen hydrophilen Polymeren oder Mischungen hiervon;0 bis 2 Gew.-% der gesamten Zusammensetzung eines hochverzweigten Fettalkohols mit 8 bis 18 Kohlenstoffatomen und Mischungen hiervon;
- Zusammensetzung nach Anspruch 1, umfassend 15 bis 25 Gew.-% der gesamten Zusammensetzung des kationischen Textilweichmacherwirkstoffs oder Mischungen hiervon.
- Konzentrierte Textilweichmacherzusammensetzung nach den vorangehenden Ansprüchen, wobei der kationische Weichmacherwirkstoff eine Mischung aus Ditalgdimethylammoniumchlorid und Ditalgimidazolin ist.
- Konzentrierte Textilweichmacherzusammensetzung nach Anspruch 3, bestehend aus 20 bis 70 Gew.-% des Weichmacherwirkstoffs aus Ditalgdimethylammoniumchlorid und 30 bis 80 Gew.-% des Weichmacherwirkstoffs aus Ditalgimidazolin.
- Konzentrierte Textilweichmacherzusammensetzung nach den Ansprüchen 3 und 4, umfassend 1,5 bis 2,5 Gew. -% der gesamten Zusammensetzung eines Polyethylenglykols mit einem Molekulargewicht von 4.000.
- Konzentrierte Textilweichmacherzusammensetzung nach den Ansprüchen 1 und 2, wobei der Weichmacherwirkstoff Ditalgimidazolinester umfaßt.
- Konzentrierte Textilweichmacherzusammensetzung nach Anspruch 7, umfassend ein Polyethylenglykol mit einem Molekulargewicht von 8.000.
- Konzentrierte Textilweichmacherzusammensetzung nach den vorangehenden Ansprüchen, umfassend 1 bis 1,5 Gew.-% der gesamten Zusammensetzung des Fettalkoholethoxylats der Formel RO(Etox)n, worin R eine lineare C10-C13-Alkylkette ist, und n, das den gewichtsmittleren Ethoxylierungsgrad bedeutet, 5 bis 10, vorzugsweise 8, ist.
- Konzentrierte Textilweichmacherzusammensetzung nach den vorangehenden Ansprüchen, umfassend 0 bis 0,1 Gew.-% der gesamten Zusammensetzung des hochverzweigten Fettalkohols, wobei der hochverzweigte Fettalkohol 12 bis 14, vorzugsweise 13 Kohlenstoffatome aufweist.
- Konzentrierte Textilweichmacherzusammensetzung nach mindestens einem der vorangehenden Ansprüche, wobei die Zusammensetzung eine Viskosität von 40 bis 400 mPa·s (cps) bei einer Scherrate von 60 UPM vor der Verdünnung aufweist, und wobei die Zusammensetzung eine Viskosität von 20 bis 60 mPa·s (cps) bei einer Scherrate von 60 UPM aufweist, nachdem sie mit dem zweifachen ihres Gewichts an Wasser verdünnt worden ist.
- Konzentrierte Textilweichmacherzusammensetzung nach Anspruch 12, welche eine Viskosität von 30 bis 50 mPa·s (cps) bei einer Scherrate von 60 UPM aufweist, nachdem sie mit dem zweifachen ihres Gewichts an Wasser verdünnt worden ist.
- Verfahren zum Weichmachen von Textilien, bei dem eine konzentrierte Textilweichmacherzusammensetzung nach den Ansprüchen 1 bis 10, welche eine Viskosität von 40 bis 400 mPa·s (cps) bei einer Scherrate von 60 UPM aufweist, mit dem zweifachen ihres Gewichts an Wasser verdünnt wird, um so eine verdünnte Textilweichmacherzusammensetzung mit einer Viskosität von 20 bis 60 mPa·s (cps) bei einer Scherrate von 60 UPM zu erzielen, und wobei die verdünnte Textilweichmacherzusammensetzung mit den Textilien im Spülwasser kontaktiert wird.
- Verfahren nach Anspruch 14, wobei die konzentrierte Textilweichmacherzusammensetzung mit einer Viskosität von 40 bis 400 mPa·s (cps) bei einer Scherrate von 60 UPM mit dem zweifachen ihres Gewichts an Wasser verdünnt wird, um so eine verdünnte Textilweichmacherzusammensetzung mit einer Viskosität von 30 bis 50 mPa·s (cps) bei einer Scherrate von 60 UPM zu erzielen.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CS931846A CZ184693A3 (en) | 1991-03-08 | 1992-01-30 | Concentrated textile plasticizing mixtures |
US08/178,243 US5484540A (en) | 1991-03-08 | 1992-01-30 | Concentrated fabric softening compositions |
AU14445/92A AU1444592A (en) | 1991-03-08 | 1992-01-30 | Concentrated fabric softening compositions |
PCT/US1992/000661 WO1992015745A1 (en) | 1991-03-08 | 1992-01-30 | Concentrated fabric softening compositions |
HU9302549A HUT66690A (en) | 1991-03-08 | 1992-01-30 | Concentrated fabric softening compositions |
MX9200990A MX9200990A (es) | 1991-03-08 | 1992-03-06 | Composiciones concentradas suavizadoras de telas. |
IE920735A IE920735A1 (en) | 1991-03-08 | 1992-03-06 | Concentrated fabric softening compositions |
NZ24186292A NZ241862A (en) | 1991-03-08 | 1992-03-06 | Concentrated aqueous fabric softener containing cationic active; linear fatty alcohol ethoxylate; nonionic hydrophilic polymer and optionally fatty alcohol or/and polydialkyl siloxane |
PT10021092A PT100210A (pt) | 1991-03-08 | 1992-03-06 | Composicoes aquosas concentradas de amaciamento de tecidos que compreendem ingredientes activos cationicos de amaciamento de tecidos bem assim uma combinacao espacifica de agentes emulsionantes e polimeros |
CN 92102202 CN1046774C (zh) | 1991-03-08 | 1992-03-07 | 浓缩的织物柔软组合物 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP91200507 | 1991-03-08 | ||
EP91200507 | 1991-03-08 | ||
EP91870105 | 1991-07-03 | ||
EP91870105.3A EP0503218A1 (de) | 1991-03-08 | 1991-07-03 | Konzentrierte Textilweichmacherzusammensetzungen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0503221A1 EP0503221A1 (de) | 1992-09-16 |
EP0503221B1 true EP0503221B1 (de) | 1998-02-11 |
Family
ID=26129188
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19910870187 Revoked EP0503221B1 (de) | 1991-03-08 | 1991-11-22 | Konzentrierte Textilweichmacherzusammensetzungen |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0503221B1 (de) |
DE (1) | DE69128915T2 (de) |
ES (1) | ES2112857T3 (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ286025A (en) * | 1995-03-01 | 1997-04-24 | Colgate Palmolive Co | Laundry detergent concentrates; contains nonionic surfactant and water insoluble oil with a hydrophilic polar group, converts to liquid crystal phase dispersion on dilution |
DE19645380B4 (de) * | 1996-11-04 | 2008-04-17 | Schill + Seilacher Ag | Zusammensetzung für die Permanenthydrophilierung von Polyolefinfasern, und Verwendung der Zusammensetzung |
DE19714044C1 (de) * | 1997-04-05 | 1998-04-16 | Henkel Kgaa | Hydrophile Avivagemittel sowie Verwendung von Mischungen, enthaltend Esterquats und Siliconverbindungen zur Herstellung derselben |
US6607637B1 (en) * | 1998-10-15 | 2003-08-19 | The Procter & Gamble Company | Soft tissue paper having a softening composition containing bilayer disrupter deposited thereon |
GB0014891D0 (en) † | 2000-06-16 | 2000-08-09 | Unilever Plc | Fabric softening compositions |
GB0021765D0 (en) | 2000-09-05 | 2000-10-18 | Unilever Plc | A method of preparing fabric conditioning compositions |
GB0021766D0 (en) | 2000-09-05 | 2000-10-18 | Unilever Plc | Fabric conditioning compositions |
EP2270123A1 (de) | 2009-06-30 | 2011-01-05 | The Procter and Gamble Company | Verpackte partikelförmige Bleichzusammensetzungen |
CA2803565A1 (en) | 2010-06-21 | 2012-01-12 | Basf Se | Surfactant component and a composition including the same |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2503026A1 (de) * | 1975-01-25 | 1976-07-29 | Hoechst Ag | Waescheweichspuelmittel mit desinfizierenden eigenschaften |
GR67665B (de) * | 1979-05-21 | 1981-09-02 | Unilever Nv | |
GB8416884D0 (en) * | 1984-07-03 | 1984-08-08 | Procter & Gamble | Liquid cleansing composition |
GB2177108B (en) * | 1985-07-10 | 1989-07-19 | Procter & Gamble | Shampoo compositions and method |
US4637890A (en) * | 1986-01-23 | 1987-01-20 | The Procter & Gamble Company | Detergent composition providing rinse cycle suds and turbidity control containing a soap, quaternary ammonium salt and a silicone |
ATE82770T1 (de) * | 1987-09-23 | 1992-12-15 | Procter & Gamble | Lineare alkoxylierte alkohole enthaltende stabile, biologisch abbaubare waescheweichspuelerzusammensetzungen. |
US4840738A (en) * | 1988-02-25 | 1989-06-20 | The Procter & Gamble Company | Stable biodegradable fabric softening compositions containing 2-hydroxypropyl monoester quaternized ammonium salts |
GB8823875D0 (en) * | 1988-10-12 | 1988-11-16 | Dow Corning Sa | Softening compositions |
-
1991
- 1991-11-22 DE DE1991628915 patent/DE69128915T2/de not_active Revoked
- 1991-11-22 ES ES91870187T patent/ES2112857T3/es not_active Expired - Lifetime
- 1991-11-22 EP EP19910870187 patent/EP0503221B1/de not_active Revoked
Also Published As
Publication number | Publication date |
---|---|
EP0503221A1 (de) | 1992-09-16 |
DE69128915D1 (de) | 1998-03-19 |
ES2112857T3 (es) | 1998-04-16 |
DE69128915T2 (de) | 1998-09-17 |
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