EP0448572A1 - Hard metal composite body and process for producing it. - Google Patents
Hard metal composite body and process for producing it.Info
- Publication number
- EP0448572A1 EP0448572A1 EP89913058A EP89913058A EP0448572A1 EP 0448572 A1 EP0448572 A1 EP 0448572A1 EP 89913058 A EP89913058 A EP 89913058A EP 89913058 A EP89913058 A EP 89913058A EP 0448572 A1 EP0448572 A1 EP 0448572A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composite body
- reinforcing material
- sintering
- hard
- body according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
- C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/02—Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
- C22C49/08—Iron group metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
Definitions
- the invention relates to a hard metal composite body consisting of hard material phases such as tungsten carbide and / or carbides or nitrides or elements of the IVa or Va group of the periodic table, of reinforcing materials and of a binder metal phase such as cobalt and / or iron and / or nickel . Furthermore, the invention relates to a method for producing a hard metal composite material by powder metallurgy.
- the single crystals known in principle from the prior art have excellent mechanical properties, such as great tensile and shear strength.
- DE-PS 259249 describes a sintered hard metal consisting of hard materials and binders, which hard materials in the form of needle-shaped single crystals in an amount of at least 0.1%, preferably 0.5 to 1.5% of the contains total hard material.
- WC in the form of acicular single crystals is added to the hard material before grinding, after the addition of a binding metal to the iron group, the hard metal batch is pressed and sintered to form a liquid phase.
- the monocrystalline WC portion largely dissolves in the binding phase (cf. DE-Z "Metall", July 1974, issue 7).
- the proposed hard single crystals do not suffice to obtain a noticeable improvement in the wear properties, in particular also not because only as many hard single crystals should be added until the hard grain fraction (grains with an average diameter below 2 ⁇ m) is replaced. It is an object of the present invention to provide a hard metal composite body which, compared to the previously known hard metal composite bodies, has a higher toughness resistance, greater hardness, even when the hard metal composite body is subjected to high thermal loads, and less susceptibility to breakage. It is also an object of the present invention to provide a method for producing such a hard metal composite body.
- EP-0067584 B1 describes a process for producing a composite material from a metallic, ceramic glass or plastic base material and therein substantially homogeneously and uniformly distributed deagglomerated silicon carbide whiskers for reinforcing the base material, in which silicon carbide whiskers are used in a polar solvent stirring to form a slurry and then grinding the slurry to form a slurry of deagglomerated silicon carbide whiskers, mixing the slurry therefrom with a base material to form a homogeneous mixture, then drying and shaping into a blank.
- composite materials are known from EP-0213615 A2, in which silicon carbide and silicon nitride whiskers are contained in a metal matrix.
- a particular advantage of an inert whisker coating is, however, that a targeted strength of the bond with the matrix can be set.
- the storage of coated whiskers leads to an increase in hardness with a simultaneous increase in toughness, even under high-temperature loads, such as those e.g. take place at Schneidtechnik ⁇ . This is advantageously also achieved in the case of hard metals which have a low binder content (less than 8% by volume).
- the inert coating has a certain protective function for the coated single crystals, i.e. the single crystals cannot be dissolved in the binder; in particular, WC single crystals can be used for the first time in a proportion which is effective in relation to the hard metal composition.
- the part of the task relating to the method known from the prior art is achieved by the features specified in claim 11, in particular with contents of up to 20 volume -3.
- the normal sintering process, the combined sintering / HIP process or the sintering with a subsequent hot isostatic pressing in a separate plant and, in the case of higher reinforcing material contents, the hot pressing is preferred.
- the production of whisker hard metal composites is basically based on known powder metallurgical process steps.
- the reinforcing materials whiskers, platelets
- the reinforcing materials are first prepared, deagglomerated and classified and preferably coated using a CVD or PVD process before they are subjected to the further process steps.
- the hard metal composite material according to the invention has greater hardness and higher strength values than composite materials known from the prior art.
- the toughness resilience is higher with a reduced risk of breakage, without having to set higher binding contents.
Abstract
Corps composite de métal dur consistant en une substance dure, un liant et un matériau de renforcement intercalé, et procédé pour produire un corps composite de métal dur par métallurgie des poudres. Pour obtenir un corps composite de métal dur, qui supporte de fortes contraintes d'endurance en étant à la fois très dur et peu sujet à la rupture, on y intercale des matériaux de renforcement monocristallins cristallisés en aiguilles et/ou en lamelles, dotés de préférence d'un revêtement inerte par rapport à la phase de métal liant, et composés de borures et/ou carbures et/ou nitrures et/ou carbonitrures, éléments de la colonne IVa ou Va, ou de mélanges de ces derniers, et/ou un matériau de renforcement monocristallin en SiC, Si3N4, Si2N2O, Al2O3, ZrO2, AlN et/ou BN. Ce corps composite de métal dur est obtenu par des procédés de métallurgie des poudres, le matériau de renforcement, doté par dépôt en phase gazeuse par procédé chimique ou physique (CVD ou PVD) d'un revêtement inerte par rapport à la phase de métal liant, étant mélangé, sous forme désagglomérée et classifiée, avec le mélange broyé de substances dures et de liants, puis séché, granulé, pressé par compression uniaxiale et isostatique à basse température, et soumis à une opération de frittage ou à un procédé combiné ou séparé de frittage/compression isostatique à température élevée ou à une compression axiale à chaud. On optera de préférence pour la compression axiale à chaud lorsque la teneur en matériau de renforcement est supérieure à 20 % en volume, sinon il est préférable de recourir aux autres modes de traitement.Hard metal composite body consisting of a hard substance, a binder and an interleaved reinforcing material, and method for producing a hard metal composite body by powder metallurgy. To obtain a hard metal composite body, which withstands high endurance constraints while being both very hard and not very subject to breakage, there are interposed monocrystalline reinforcing materials crystallized in needles and / or in lamellae, provided with preferably an inert coating with respect to the binder metal phase, and compounds of borides and / or carbides and / or nitrides and / or carbonitrides, elements of column IVa or Va, or mixtures of the latter, and / or a monocrystalline reinforcing material in SiC, Si3N4, Si2N2O, Al2O3, ZrO2, AlN and / or BN. This hard metal composite body is obtained by powder metallurgy processes, the reinforcing material, provided by deposition in the gas phase by chemical or physical process (CVD or PVD) of an inert coating with respect to the binder metal phase. , being mixed, in disaggregated and classified form, with the crushed mixture of hard substances and binders, then dried, granulated, pressed by uniaxial and isostatic compression at low temperature, and subjected to a sintering operation or to a combined or separate process isostatic sintering / compression at high temperature or hot axial compression. Preferably, hot axial compression will be used when the content of reinforcing material is greater than 20% by volume, otherwise it is preferable to use other treatment methods.
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89913058T ATE90399T1 (en) | 1988-12-16 | 1989-11-27 | CARBIDE COMPOSITE AND PROCESS FOR ITS MANUFACTURE. |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19883842439 DE3842439A1 (en) | 1988-12-16 | 1988-12-16 | Hard cemented composite and process for the production thereof |
DE3842439 | 1988-12-16 | ||
DE19883843219 DE3843219A1 (en) | 1988-12-22 | 1988-12-22 | Hard cemented composite and process for the production thereof |
DE3843219 | 1988-12-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0448572A1 true EP0448572A1 (en) | 1991-10-02 |
EP0448572B1 EP0448572B1 (en) | 1993-06-09 |
Family
ID=25875237
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89913058A Expired - Lifetime EP0448572B1 (en) | 1988-12-16 | 1989-11-27 | Hard metal composite body and process for producing it |
Country Status (5)
Country | Link |
---|---|
US (1) | US5173107A (en) |
EP (1) | EP0448572B1 (en) |
JP (1) | JPH04502347A (en) |
DE (1) | DE58904666D1 (en) |
WO (1) | WO1990007017A1 (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5436080A (en) * | 1991-09-13 | 1995-07-25 | Tsuyoshi Masumoto | High strength structural member and process for producing the same |
US5376466A (en) * | 1991-10-17 | 1994-12-27 | Mitsubishi Materials Corporation | Cermet blade member |
US5579532A (en) * | 1992-06-16 | 1996-11-26 | Aluminum Company Of America | Rotating ring structure for gas turbine engines and method for its production |
CH686888A5 (en) * | 1993-11-01 | 1996-07-31 | Ufec Universal Fusion Energy C | composite metal-ceramic high tenacity and process for its manufacture. |
US5672435A (en) * | 1994-12-12 | 1997-09-30 | The Dow Chemical Company | Hard disk drive components and methods of making same |
US5580666A (en) * | 1995-01-20 | 1996-12-03 | The Dow Chemical Company | Cemented ceramic article made from ultrafine solid solution powders, method of making same, and the material thereof |
US5842107A (en) * | 1995-08-31 | 1998-11-24 | National Science Council | Sintering process for AIN powder coated with Al film |
WO1998040525A1 (en) | 1997-03-10 | 1998-09-17 | Widia Gmbh | Hard metal or cermet sintered body and method for the production thereof |
JP4945814B2 (en) * | 1997-05-13 | 2012-06-06 | アロメット コーポレイション | Tough-coated hard powder and its sintered product |
US20040052984A1 (en) | 1997-05-13 | 2004-03-18 | Toth Richard E. | Apparatus and method of treating fine powders |
WO2003042419A1 (en) * | 2001-11-13 | 2003-05-22 | Fundacion Inasmet | Method of producing products made from carbide-reinforced, structural metal materials |
CA2570671C (en) * | 2004-06-10 | 2013-01-08 | Allomet Corporation | Method for consolidating tough coated hard powders |
US7682557B2 (en) * | 2006-12-15 | 2010-03-23 | Smith International, Inc. | Multiple processes of high pressures and temperatures for sintered bodies |
CA2640206A1 (en) * | 2008-10-02 | 2010-04-02 | Hydro-Quebec | Composite materials for wettable cathodes and use of same for aluminum production |
US20100104874A1 (en) * | 2008-10-29 | 2010-04-29 | Smith International, Inc. | High pressure sintering with carbon additives |
CN102373357B (en) * | 2010-08-19 | 2013-09-18 | 比亚迪股份有限公司 | Composition composed of metal and ceramic and its preparation method, cermet and Raymond mill |
CN111471942A (en) * | 2020-03-25 | 2020-07-31 | 成都美奢锐新材料有限公司 | Nanocrystalline composite material for 3C product and preparation method thereof |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3139672A (en) * | 1961-02-10 | 1964-07-07 | Bendix Corp | Rocket nozzles and the like |
AT259242B (en) * | 1964-11-23 | 1968-01-10 | Boehler & Co Ag Geb | Sintered carbide consisting of hard materials and binding metal and process for its production |
US4007049A (en) * | 1968-08-06 | 1977-02-08 | The United States Of America As Represented By The Secretary Of The Air Force | Thermal shock resistant ceramic composite |
DE2461801C3 (en) * | 1974-12-30 | 1979-01-04 | Fisitscheskij Institut Imeni P.N. Lebedeva Akademii Nauk Ssr | Refractory material |
US4259112A (en) * | 1979-04-05 | 1981-03-31 | Dwa Composite Specialties, Inc. | Process for manufacture of reinforced composites |
JPS6031799B2 (en) * | 1979-11-30 | 1985-07-24 | 黒崎窯業株式会社 | SiC-Si↓3N↓4-based composite heat-resistant ceramic material and its manufacturing method |
US4268314A (en) * | 1979-12-21 | 1981-05-19 | Union Carbide Corporation | High density refractory composites and method of making |
JPS57205364A (en) * | 1981-06-08 | 1982-12-16 | Ngk Spark Plug Co | Manufacture of cutting tool ceramics |
US4463058A (en) * | 1981-06-16 | 1984-07-31 | Atlantic Richfield Company | Silicon carbide whisker composites |
JPS59121196A (en) * | 1982-12-25 | 1984-07-13 | Tokai Carbon Co Ltd | Preparation of whisker preform for composite material |
SE451581B (en) * | 1984-04-06 | 1987-10-19 | Sandvik Ab | CERAMIC MATERIAL MAINLY BASED ON SILICON NITRIDE, ALUMINUM NITRIDE AND ALUMINUM OXIDE |
US4732779A (en) * | 1985-05-21 | 1988-03-22 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Fibrous material for composite materials, fiber-reinforced metal produced therefrom, and process for producing same |
DE3662782D1 (en) * | 1985-06-10 | 1989-05-18 | Ngk Spark Plug Co | Fiber-reinforced compositie material for tools |
CA1285582C (en) * | 1986-08-04 | 1991-07-02 | Joseph G. Ii Baldoni | Ceramic based composites with improved fracture toughness |
US4756791A (en) * | 1986-08-25 | 1988-07-12 | Gte Laboratories Incorporated | Chemical vapor deposition process for producing metal carbide or nitride whiskers |
DE3706000A1 (en) * | 1987-02-25 | 1988-09-08 | Feldmuehle Ag | Cutting tip (cutting insert, cutting tool) |
SE8701791D0 (en) * | 1987-04-29 | 1987-04-29 | Sandvik Ab | CEMENTED CARBONITRIDE ALLOY WITH IMPROVED TOUGHNESS BEHAVIOUR |
EP0295228B1 (en) * | 1987-06-09 | 1992-03-25 | Sandvik Aktiebolag | Whisker reinforced ceramic cutting tool |
JPH01103205A (en) * | 1987-10-15 | 1989-04-20 | Toshiba Ceramics Co Ltd | Tool for working carbon |
-
1989
- 1989-11-27 US US07/689,237 patent/US5173107A/en not_active Expired - Fee Related
- 1989-11-27 DE DE8989913058T patent/DE58904666D1/en not_active Expired - Fee Related
- 1989-11-27 WO PCT/DE1989/000740 patent/WO1990007017A1/en active IP Right Grant
- 1989-11-27 EP EP89913058A patent/EP0448572B1/en not_active Expired - Lifetime
- 1989-11-27 JP JP2500125A patent/JPH04502347A/en active Pending
Non-Patent Citations (1)
Title |
---|
See references of WO9007017A1 * |
Also Published As
Publication number | Publication date |
---|---|
US5173107A (en) | 1992-12-22 |
EP0448572B1 (en) | 1993-06-09 |
WO1990007017A1 (en) | 1990-06-28 |
DE58904666D1 (en) | 1993-07-15 |
JPH04502347A (en) | 1992-04-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0448572A1 (en) | Hard metal composite body and process for producing it. | |
DE60110237T2 (en) | METHOD FOR PRODUCING A DIAMOND-CONTAINING ABRASIVE PRODUCT | |
DE69531948T2 (en) | AMORPHOUS METAL COMPOSITE AND REINFORCEMENT | |
DD283368A5 (en) | PROCESS FOR THE PREPARATION OF A SELF-SUPPORTING BODY | |
DE3812266C1 (en) | ||
EP0531378B1 (en) | Reaction-bonded mullite-containing ceramic, its formation and use | |
EP0902771B1 (en) | Metal-ceramic shaped body and process for manufacturing the same | |
EP0433856A1 (en) | Mixed hard metal materials based on borides, nitrides and iron group matrix metals | |
DE3329250A1 (en) | FIREPROOF SILICON NITRIDE COMPOSITE | |
DE19623425A1 (en) | Reaction bonded mullite-based ceramic article | |
DE4133351C2 (en) | Sintered ceramic / metal composites and process for their manufacture | |
EP0247528B1 (en) | Polycrystalline sintered articles based on silicon nitride with high rupture strength and hardness | |
DE10133209A1 (en) | Non-oxide ceramic coating powder and layers made therefrom | |
DE3842420A1 (en) | Hard cemented composite and process for the production thereof | |
DE3603191C2 (en) | ||
DD295106A5 (en) | HARD METAL COMPOSITE BODY AND METHOD FOR THE PRODUCTION THEREOF | |
DE3843219A1 (en) | Hard cemented composite and process for the production thereof | |
DE3842439A1 (en) | Hard cemented composite and process for the production thereof | |
DE3714240C1 (en) | Sintered body made of silicon nitride with an outer ceramic wear layer based on aluminum nitride | |
US5352533A (en) | Ceramic composite body, process for producing a ceramic composite | |
DE3706000C2 (en) | ||
DE3603331A1 (en) | SILICON CARBIDE SINTER PRODUCT AND METHOD FOR THE PRODUCTION THEREOF | |
DE4136744C2 (en) | Reinforced materials, processes for their production and their use | |
JPS61113738A (en) | Low density whisker forming body for composite material, and its production | |
DE19806203C2 (en) | Composite material and method for its production |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT CH DE ES FR GB IT LI NL SE |
|
17P | Request for examination filed |
Effective date: 19910328 |
|
17Q | First examination report despatched |
Effective date: 19921103 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT CH DE ES FR GB IT LI NL SE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Effective date: 19930609 Ref country code: NL Effective date: 19930609 Ref country code: ES Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY Effective date: 19930609 |
|
REF | Corresponds to: |
Ref document number: 90399 Country of ref document: AT Date of ref document: 19930615 Kind code of ref document: T |
|
REF | Corresponds to: |
Ref document number: 58904666 Country of ref document: DE Date of ref document: 19930715 |
|
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 19930623 |
|
ET | Fr: translation filed | ||
ITF | It: translation for a ep patent filed |
Owner name: STUDIO JAUMANN |
|
NLV1 | Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Effective date: 19931127 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Effective date: 19931130 Ref country code: CH Effective date: 19931130 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
ITPR | It: changes in ownership of a european patent |
Owner name: CAMBIO RAGIONE SOCIALE;WIDIA GMBH |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: CD |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20011008 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20011129 Year of fee payment: 13 Ref country code: DE Payment date: 20011129 Year of fee payment: 13 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021127 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030603 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030731 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED. Effective date: 20051127 |