EP0447546A4 - Corrosion resistant feedthrough - Google Patents
Corrosion resistant feedthroughInfo
- Publication number
- EP0447546A4 EP0447546A4 EP19910900634 EP91900634A EP0447546A4 EP 0447546 A4 EP0447546 A4 EP 0447546A4 EP 19910900634 EP19910900634 EP 19910900634 EP 91900634 A EP91900634 A EP 91900634A EP 0447546 A4 EP0447546 A4 EP 0447546A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- titanium
- feedthrough
- glass
- sleeve
- terminal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000007797 corrosion Effects 0.000 title abstract description 9
- 238000005260 corrosion Methods 0.000 title abstract description 9
- 239000011521 glass Substances 0.000 claims abstract description 24
- 229910001069 Ti alloy Inorganic materials 0.000 claims abstract description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 12
- 239000010936 titanium Substances 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 239000010955 niobium Substances 0.000 claims description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- 239000012212 insulator Substances 0.000 claims 4
- JZLMRQMUNCKZTP-UHFFFAOYSA-N molybdenum tantalum Chemical compound [Mo].[Ta] JZLMRQMUNCKZTP-UHFFFAOYSA-N 0.000 claims 1
- 238000005336 cracking Methods 0.000 description 2
- 239000005486 organic electrolyte Substances 0.000 description 2
- 241000321453 Paranthias colonus Species 0.000 description 1
- SOZVEOGRIFZGRO-UHFFFAOYSA-N [Li].ClS(Cl)=O Chemical compound [Li].ClS(Cl)=O SOZVEOGRIFZGRO-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/24—Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metal; Glass solders
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/186—Sealing members characterised by the disposition of the sealing members
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C29/00—Joining metals with the aid of glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/14—Silica-free oxide glass compositions containing boron
- C03C3/145—Silica-free oxide glass compositions containing boron containing aluminium or beryllium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/19—Sealing members characterised by the material
- H01M50/191—Inorganic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/19—Sealing members characterised by the material
- H01M50/197—Sealing members characterised by the material having a layered structure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- Glass seals are used in various arrangements including batteries and other electrochemical cells .
- glass seals are used to seal the battery container while allowing one or more electrical terminals to extend through the seal for interior/exterior connection thereto .
- the term "feedthrough" shall be used herein to describe such arrangements in generic fashion.
- corrosion has been encountered.
- batteries which include various organic electrolyte systems give rise to corrosion and cracking of glass and metal feedthrough components.
- a special glass composition has developed by Sandia National Laboratories which exhibit improved corrosion resistance. It is generally referred to as CABAL-12 glass.
- the ' general purpose of this invention is to provide a combination of metal and CABAL-12 GLASS for improved feedthrough structures in battery and electrochemical cell applications.
- This invention relates to feedthrough structures which utilize CABAL-12 glass particularly for use in aggressive battery organic electrolyte environments e.g., a lithium thionyl chloride cell or cells of other active chemistries such as Mn0 2 , and CFX, for example. It has been discovered that this glass has a unique affinity for sealing to titanium and titanium alloys.
- the invention relates specifically to hermetic, corrosion resistant, compression-type sealed feedthroughs utilizing single or multiple terminals or pins of niobium, tantalum, molybdenum and titanium or alloy thereof, contained within a header or sleeve of titanium or a titanium alloy, Titanium-6A1-4V being preferred.
- FIG. 1 is a schematic cross-section of a battery header in accordance with the invention
- Fig. 2 is a schematic cross-section of a feedthrough with sleeve according to the invention combined with a metal container for use as an electrochemical cell.
- a header of typical construction is shown which includes a center pin or terminal 10, a glass seal member 12 and an outer member 14. This arrangement and that of Fig. 2 are typical feedthrough seal arrangements which may make use of the invention.
- the invention in a preferred form includes a terminal 10 extending through a glass seal 12 which is received into a sleeve or header 14.
- Sleeve 14 may be welded into an opening in a battery container 16 of, for example, stainless steel.
- the assembly requiring forming weights, is placed in an oven or furnace and heated causing the glass to wet the metallic components forming a he_rmetic seal between the glass and the metal components.
- Such a feedthrough may thereafter be welded if necessary, into any desirable container or the like.
- terminal 10 consists essentially of niobium, or titanium or an alloy thereof.
- Sleeve 14 is of titanium or a titanium alloy Ti-6A1-4V
- the glass 12 is CABAL-12, which is of the following composition:
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Connection Of Batteries Or Terminals (AREA)
- Glass Compositions (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41988189A | 1989-10-11 | 1989-10-11 | |
| US419881 | 1989-10-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0447546A1 EP0447546A1 (fr) | 1991-09-25 |
| EP0447546A4 true EP0447546A4 (en) | 1992-10-28 |
Family
ID=23664141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19910900634 Withdrawn EP0447546A4 (en) | 1989-10-11 | 1990-10-03 | Corrosion resistant feedthrough |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0447546A4 (fr) |
| JP (1) | JPH04502231A (fr) |
| AU (1) | AU637221B2 (fr) |
| CA (1) | CA2042036A1 (fr) |
| WO (1) | WO1991006129A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6759163B2 (en) | 2000-05-04 | 2004-07-06 | Wilson Greatbatch Ltd. | Mismatched compression glass-to-metal seal |
| US7966070B2 (en) | 2003-09-12 | 2011-06-21 | Medtronic, Inc. | Feedthrough apparatus with noble metal-coated leads |
| US7725999B2 (en) | 2005-07-29 | 2010-06-01 | Medtronic, Inc. | Method for positioning an eyelet in a feed-through assembly |
| DE112012000871A5 (de) * | 2011-02-18 | 2013-11-14 | Schott Ag | Durchführung, insbesondere für Batterien, und Verfahren zum Einbringen der Durchführung mittels Ultraschallschweißen in ein Gehäuse |
| US9208929B2 (en) * | 2013-09-20 | 2015-12-08 | Schott Corporation | GTMS connector for oil and gas market |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3803875A (en) * | 1973-02-05 | 1974-04-16 | Bendix Corp | Method of forming titanium metal-glass hermetic seals |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US455613A (en) * | 1891-07-07 | Stove | ||
| US4421947A (en) * | 1977-10-11 | 1983-12-20 | James C. Kyle | Polycrystalline insulating material seals between spaced members such as a terminal pin and a ferrule |
| US4180700A (en) * | 1978-03-13 | 1979-12-25 | Medtronic, Inc. | Alloy composition and brazing therewith, particularly for _ceramic-metal seals in electrical feedthroughs |
| US4271278A (en) * | 1978-10-16 | 1981-06-02 | Medtronic, Inc. | Cathode materials |
| US4678868A (en) * | 1979-06-25 | 1987-07-07 | Medtronic, Inc. | Hermetic electrical feedthrough assembly |
| US4307162A (en) * | 1980-09-25 | 1981-12-22 | Medtronic, Inc. | Lithium alloy coating for anode collector in lithium batteries |
| EP0269007A1 (fr) * | 1986-11-28 | 1988-06-01 | Siemens Aktiengesellschaft | Assemblage céramique-métal, en particulier pour stimulateur cardiaque ou neurologique, et procédé de fabrication |
-
1990
- 1990-10-03 JP JP3500755A patent/JPH04502231A/ja active Pending
- 1990-10-03 EP EP19910900634 patent/EP0447546A4/en not_active Withdrawn
- 1990-10-03 CA CA002042036A patent/CA2042036A1/fr not_active Abandoned
- 1990-10-03 AU AU75887/91A patent/AU637221B2/en not_active Expired - Fee Related
- 1990-10-03 WO PCT/US1990/005623 patent/WO1991006129A1/fr not_active Application Discontinuation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3803875A (en) * | 1973-02-05 | 1974-04-16 | Bendix Corp | Method of forming titanium metal-glass hermetic seals |
Non-Patent Citations (4)
| Title |
|---|
| CHEMICAL ABSTRACTS, vol. 112, no. 14, 2 April 1990, Columbus, Ohio, US; abstract no. 123996T, BROW, RICHARD K. ET ALL: 'Sealing glass compositions for titanium and its alloys' page 328 ; & US Pat. Appl. US 146507 (UNITED STATES DEPT . OF ENERGY) (01-11-1989) * |
| PROC. INTERSOC. ENERGY CONVERS. ENG. CONF. 22ND vol. 2, 1987, pages 1113 - 1118; RANDALL D WATKINS ET ALL: 'CORROSION RESISTANT GLASSES FOR USE IN LITHIUM AMBIENT-TEMPERATURE BATTERIES' * |
| REPORT SAND-87-0393 1987, pages 7 - 22; WATKINS R. D.: 'Development of CABAL glasses for use in lithium ambient-temperature batteries' * |
| See also references of WO9106129A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2042036A1 (fr) | 1991-04-12 |
| AU637221B2 (en) | 1993-05-20 |
| EP0447546A1 (fr) | 1991-09-25 |
| AU7588791A (en) | 1991-05-16 |
| WO1991006129A1 (fr) | 1991-05-02 |
| JPH04502231A (ja) | 1992-04-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 19910705 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB IT LI LU NL SE |
|
| A4 | Supplementary search report drawn up and despatched |
Effective date: 19920909 |
|
| AK | Designated contracting states |
Kind code of ref document: A4 Designated state(s): AT BE CH DE DK ES FR GB IT LI LU NL SE |
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19940503 |