EP0396267A1 - Verfahren und Vorrichtung zum Behandeln von Metallschmelzen - Google Patents

Verfahren und Vorrichtung zum Behandeln von Metallschmelzen Download PDF

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Publication number
EP0396267A1
EP0396267A1 EP90303889A EP90303889A EP0396267A1 EP 0396267 A1 EP0396267 A1 EP 0396267A1 EP 90303889 A EP90303889 A EP 90303889A EP 90303889 A EP90303889 A EP 90303889A EP 0396267 A1 EP0396267 A1 EP 0396267A1
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EP
European Patent Office
Prior art keywords
shaft
gas
rotor
treatment agent
rotary device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP90303889A
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English (en)
French (fr)
Inventor
Josef Schiffarth
Helmut Jaunich
Wolfgang Paul Kaettlitz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foseco International Ltd
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Foseco International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foseco International Ltd filed Critical Foseco International Ltd
Publication of EP0396267A1 publication Critical patent/EP0396267A1/de
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0037—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00—Obtaining aluminium
    • C22B21/06—Obtaining aluminium refining
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28—Manufacture of steel in the converter
    • C21C5/42—Constructional features of converters
    • C21C5/46—Details or accessories
    • C21C5/4606—Lances or injectors
    • C21C5/4613—Refractory coated lances; Immersion lances
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00—Obtaining aluminium
    • C22B21/06—Obtaining aluminium refining
    • C22B21/064—Obtaining aluminium refining using inert or reactive gases
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/05—Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ

Definitions

  • This invention relates to a method and apparatus for the treatment of molten metals.
  • the device consists of a hollow shaft and a hollow rotor attached to the shaft.
  • the rotor has a plurality of vanes extending from the shaft towards the periphery of the rotor and dividing the hollow interior of the rotor into a plurality of compartments.
  • Each compartment has an inlet adjacent the shaft and an outlet adjacent the periphery of the rotor.
  • the bottom end of the shaft opens into a manifold in the rotor and the inlets for the compartments are located in the wall of the manifold.
  • the gas bubbles are dispersed in the molten metal, and the dispersion flows into the compartments through the inlets in the manifold wall, through the compartments and out of the rotor through the peripheral outlets.
  • the gas is thus dispersed through the whole body of molten metal.
  • United States Patent No. 4802656 describes an apparatus for dissolving alloying elements and dispersing gas in an aluminium bath. That patent refers in its preamble to known gas dispersers and states that they cannot be used as apparatus for dissolving alloying elements in molten metal.
  • the apparatus described in the patent consists of a vertical shaft pierced along its axis by a duct, and connected to a gas source and a drive motor, and a rotor or disc having the same axis as the shaft.
  • the disc is provided with blades which extend along the generatrices of a right prism of parallelagrammatic section, with its axis passing through the centre of the disc, the ends of which result from the intersection of the said prism with a cylinder of the same axis as that bearing against the side wall of the disc, the large faces of the prism forming an angle of at most 45 degrees to the horizontal and the small faces being disposed respectively in the planes of the upper and lower faces of the disc, and the blades being provided with at least one orifice connected to the duct of the shaft by a tubular passage.
  • the disc is immersed in a bath of molten metal and rotated and gas is introduced into the shaft duct. Alloying additions are fed into the molten metal adjacent the shaft from a hopper disposed above the bath.
  • a method for the treatment of molten metal with a particulate treatment agent and a gas comprising providing a rotary device comprising a hollow shaft having a discharge end and a hollow rotor attached to the shaft, the rotor having a plurality of vanes each extending from the shaft or from a location adjacent the shaft towards the periphery of the rotor so that the hollow interior of the rotor is divided into a plurality of compartments, each compartment having an inlet adjacent the shaft and an outlet adjacent the periphery of the rotor, and the rotor having means for passing the particulate treatment agent and gas from the discharge end of the shaft to the compartments, immersing the rotary device in molten metal contained in a vessel, rotating the device so that molten metal enters the compartments through the inlets, and supplying a particulate treatment agent for the molten metal and a gas to the shaft so that the particulate treatment agent and gas emerge from the discharge end of the shaft and pass into
  • apparatus for the treatment of molten metal with a particulate treatment agent and a gas comprising a vessel, a rotary device for dispersing particulate treatment agent and a gas in molten metal contained in the vessel and means for supplying the particulate treatment agent and gas to the rotary device, wherein the rotary device comprises a hollow shaft having a discharge end and a hollow rotor attached to the shaft, the rotor having a plurality of vanes each extending from the shaft or from a location adjacent the shaft towards the periphery of the rotor so that the hollow interior of the rotor is divided into a plurality of compartments, each compartment having an inlet adjacent the shaft and an outlet adjacent the periphery of the rotor, and the rotor having means for passing the particulate treatment agent and gas from the discharge end of the hollow shaft of the device to the compartments.
  • the rotary device may be as described in European Patent Application Publication No. 0332292A and have a rotor having a manifold and inlets for the compartments in the walls of the manifold and a shaft whose lower end opens into the manifold.
  • the rotor of the rotary device may be formed separately from and be fixed to the shaft or the rotor may be formed integrally with the shaft.
  • the rotor is preferably circular in transverse cross-section in order to reduce drag in the molten metal when the device rotates and in order that the overall weight of the rotor may be as low as possible.
  • the rotor may have two or more vanes and hence two or more compartments. At least three vanes and three compartments are preferred and four has been found to be a convenient number in practice, Preferably the vanes extend from the shaft, to which they may be joined or with which they may be integrally formed, to the periphery of the rotor. The vanes may extend radially or be tangential to the shaft.
  • the shaft is connected to drive means, either through a drive shaft or directly at the top of the shaft, or through the base of the rotor at the bottom of the shaft.
  • molten metal is drawn into the manifold of the rotor when the device rotates in the molten metal, and in the manifold the metal breaks up the stream of particulate treatment agent and gas leaving the outlet of the shaft.
  • the gas in the form of very small bubbles and the particulate treatment agent are intimately mixed with the molten metal and the dispersion formed flows into the compartments through the inlets in the manifold wall and out through the peripheral outlet, and is dispersed through the whole body of molten metal.
  • the flow pattern of the molten metal and gas/particulate treatment agent mixture emerging from the rotor into the body of molten metal is determined by the geometry of the interior of the rotor. In practice it is preferred to locate the device as near to the bottom of the vessel as possible and to cause the molten metal, gas and particulate treatment to emerge from the rotor in a substantially horizontal direction. This may be achieved, for example, by making the edge or the whole of the upper surface of the bottom of the rotor, and optionally the edge of the underside of the top of the rotor, horizontal.
  • the rotary device of the apparatus of the invention provides an efficient means for dispersing a particulate treatment agent and a gas in molten metal and for distributing them throughout a large body of the molten metal.
  • the rotary device may be made from graphite, silicon carbide or a ceramic material which is inert to the molten metal.
  • the vessel used to carry out the method of the invention may be for example a ladle which may be used for the treatment of the molten metal by a batch process or the vessel may be a special construction in which the molten metal may be treated by a continuous process for example as described in a European Patent No. 0183402.
  • the means used for supplying the particulate treatment agent and gas to the rotary device will depend on the particle size of the particulate treatment agent being used.
  • the means may be a hopper fitted with gas injection nozzles.
  • the preferred means is an apparatus in which the particulate treatment agent is fluidised by the gas to produce a dispersion, and which is connected by a pipe to the bore of the shaft of the rotary device.
  • Such an apparatus may comprise a container having a closable inlet at its top end for admitting the particulate treatment agent, a primary inlet for introducing a gas such as argon or nitrogen adjacent its bottom end, such as a plurality of jets, through which the gas passes in order to fluidise the particulate treatment agent, and a valve at its bottom end through which the dispersion passes into the pipe connecting the apparatus with the rotary device.
  • the apparatus may also have a secondary inlet for gas which is introduced into the dispersion so as to reduce the concentration of particulate treatment agent in the dispersion, and an outlet adjacent the top end through which excess gas leaves the container and which is connected to the pipe connecting the apparatus with the rotary device.
  • the flow rate of particulate treatment agent may be controlled by the flow rate of gas passing through the secondary inlet and can be controlled by locating the container on a weighing device on a platform.
  • the particulate treatment agent preferably consists of particles of a size less than 1 mm, and more preferably particles of a size 0.15 mm to 0.8 mm.
  • the length to width ratio of the particles is preferably no more than 2.0:1, and is more preferably from 1:1 to 1.75:1.
  • Particles of the desired shape and size may be made by forming tablets of the treatment agent and milling the tablets.
  • treatment agent for example alloys such as so-called master alloys which are used for grain refining aluminium and its alloys the production of particles of the above shape and size is difficult and inconvenient. It is therefore desirable to use such treatment agents in the form of larger particles of a size greater than 5 mm, preferably of the order of 6 - 10 mm, and having a droplet like shape.
  • the means used for introducing these relatively large particles into the rotary device is preferably a hopper of special construction connected to the bore of the shaft of the rotary device.
  • the hopper which is mounted above the rotary device which preferably has the shape of an inverted cone has a sealed top having a closable inlet for the particles of treatment agent, and an aperture in its base communicating with a tube having one or more apertures therein for the introduction of gas and located inside the bore of the shaft of the rotary device.
  • the sidewall of the hopper, adjacent the base has at least one series of apertures spaced apart around its perimeter, and each aperture has projecting through it into the inside of the hopper a sliding member connected to means such as compressed air cylinders located outside the hopper to cause the member to slide forwards and backwards towards and away from the vertical axis of the hopper.
  • the hopper preferably has two or more series of apertures and sliding members spaced apart around the perimeter of the hopper, and the apertures and sliding members are preferably located so that the apertures and sliding members in one series are positioned above and between the apertures and sliding members of another series.
  • each series consists of three apertures and sliding members.
  • the sliding members are operated in such a manner that each series operates in succession so that they alternatively open and close the space above and below each sliding member. As a result they accelerate the large particles of treatment agent so that the particles always enter the rotor one at a time.
  • the frequency of operation of the sliding members can be varied depending on the size or density of the particles being used.
  • the tube connected to the base of the hopper passes through a block beneath on the base of the hopper into the bore of the shaft of the rotary device.
  • the block has a plurality of ducts preferably angled downwardly towards the rotary device, and the ducts communicate via apertures in the wall of the tube with the inside of the tube.
  • gas is injected into the tube via the ducts and the effect of the gas is to produce a positive pressure which prevents molten metal entering the rotor of the rotary device and ensures that the particles of treatment agent always fall into a gas pocket.
  • the apparatus also has means for introducing and controlling the flow of gas into the shaft of the rotary device in the space surrounding the tube from the hopper, and means such as a wheel driven by a fan belt for driving the shaft of the rotary device either directly or via a drive shaft.
  • the metal When the rotary device is rotated in molten metal the metal is pumped through the rotor and particles of treatment agent and gas are mixed with the metal inside the rotor.
  • the method and apparatus of the invention may be used to treat a variety of molten metals with a particulate treatment agent, for example aluminium and its alloys, magnesium and its alloys, copper and its alloys, or ferrous metals such as iron or steel.
  • a particulate treatment agent for example aluminium and its alloys, magnesium and its alloys, copper and its alloys, or ferrous metals such as iron or steel.
  • the gas which is used in conjunction with the particulate treatment agent may be inert or it may be reactive to the metal being treated.
  • gases which may be used are chlorine, argon and nitrogen.
  • treatment agents which may be used in particulate form include fluxing agents, such as mixtures of alkali metal chlorides and simple or complex alkali metal fluorides, for treating aluminium or aluminium alloys, grain refiners, such as mixtures of potassium borofluoride and potassium titanium fluoride salts or alloys for refining the grain structure of aluminium or its alloys, alloying additions for ferrous or non-ferrous metals, desulphurising agents such as a mixture of lime and calcium carbide or magnesium for desulphurising iron, or calcium silicide for desulphurising steel, and compositions to modify the structure of graphite in cast iron, such as compositions to produce spheroidal graphite iron or to produce vermicular graphite iron.
  • fluxing agents such as mixtures of alkali metal chlorides and simple or complex alkali metal fluorides, for treating aluminium or aluminium alloys
  • grain refiners such as mixtures of potassium borofluoride and potassium titanium fluoride salts or alloys for ref
  • the method and apparatus are particularly useful for adding grain refiners or modifying agents to aluminium or aluminium alloys, and enable materials which would not normally be useful in other processes to be used as treatment agents.
  • strontium metal milled to particulate form, can be used as a modifying agent instead of the commonly used strontium containing alloys, and alloys containing higher concentrations of titanium and boron than are normally used for example, 15% by weight titanium and 2% by weight boron, can be used as grain refiners.
  • the size of rotor, the rotor speed and the gas flow rate will usually be as described in European Patent Publication No. 0332292A and the flow rate of the particulate treatment agent will usually be from about 0.5 kg to 2 kg per minute depending on the size of the vessel containing the metal to be treated.
  • a rotary device for treating molten metal with a dispersion of a particulate treatment agent in a gas comprises a shaft 1 and a rotor 2.
  • the shaft 1 has a throughbore 3 and is internally threaded to receive a longitudinal portion of a threaded tubular connection piece 4 which has external threads.
  • the rotor 2 comprises a generally disc- or saucer-like body having an annular top 5 from which extends an underlying circular wall 6.
  • the centre of the top 5 contains an internally threaded socket 7 to receive a threaded length of the lower part of the connection piece 4.
  • the area below the socket 7 is open to define a manifold chamber 8 and the connection piece 4 has a bore 9 whose diameter is the same as that of the shaft bore 3 and which opens into the manifold 8.
  • the wall 6 contains four compartments 10 which extend from the inside of the wall 6A to the outside of the wall 6B which defines the rim of the rotor body. Each compartment 10 has an inlet aperture 11 in the wall 6A and an outlet in the form of an elongate slot 12 at the rim of the rotor. Adjacent compartments 10 are separated by vanes 13.
  • the wall 6 defines the wall of the manifold chamber 8.
  • the shaft 1 is connected to the lower end of a hollow drive shaft (not shown) whose upper end is connected to drive means, such as an electric motor (not shown) and the bore 3 is connected through the hollow drive shaft to a source of gas and particulate treatment agent (not shown).
  • drive means such as an electric motor (not shown)
  • the bore 3 is connected through the hollow drive shaft to a source of gas and particulate treatment agent (not shown).
  • the rotary device In use the rotary device is located inside a ladle or other vessel containing molten metal. The device is rotated and particulate treatment agent and gas are passed down the bore 3 of the shaft 1 to emerge via the bore 9 at the top of the manifold 8. As the device rotates molten metal is drawn into the manifold 8 through the lower open mouth and in the manifold 8 the metal breaks up the stream of particulate treatment agent and gas leaving the shaft 1 so that very small gas bubbles and particles of treatment agent are intimately mixed with molten metal. The dispersion formed flows into the compartments 10 via the inlets 11, through the compartments 10 and out of the peripheral outlet 12, and is dispersed through the whole body of the molten metal.
  • an apparatus for treating molten metal with a dispersion of particulate treatment agent in a gas consists of a ladle 21, a rotary device 22 and apparatus 23 for producing and providing the dispersion of particulate treatment agent in a gas.
  • the apparatus 23 consists of a pressurised container 24 having a closable inlet 25 at its top end for admitting the particulate treatment agent and at its bottom end a valve 26 and a primary inlet 27 for a gas such as argon or nitrogen.
  • a plurality of jets 28 are arranged around the container 24 adjacent its inner surface at its bottom end.
  • a secondary inlet for gas consists of a pipe 29 and the container 25 also has an outlet 30 adjacent its top end.
  • the valve 26 and the outlet 30 are both connected by pipes 31 and 32 to pipe 33 which is in turn connected to the rotary device 22.
  • the container 24 is located on a weighing device 34 on platform 35.
  • the rotary device 22 consists of a hollow shaft 36 and a rotor 37 which may be for example of the type shown in Figures 1 and 2.
  • the top of the hollow shaft 36 is connected by means of a snap lock system 38 to the lower end of a hollow drive shaft 39 whose inner diameter corresponds to the inner diameter of pipe 33.
  • the drive shaft 39 is driven by electric motor 40 housed in housing 41.
  • the rotary device 22, drive shaft 39 and motor housing 41 are lifted by a lever system 42 and lowered into the ladle 21 by a chain or screw driven cylinder 43, all located on a movable platform 44,
  • a buffer plate 45 is fixed to the bottom of the housing 41 parallel to the shaft 36.
  • a three way spinning valve 46 connects the pipe 33 and a drive shaft 39 and also another pipe 47 which can be connected to a source of gas to enable the apparatus to be used for degassing alone.
  • the rotary device In use the rotary device is lowered into molten metal 48, for example molten aluminium alloy, in the ladle 21 and rotated so that molten metal is pumped through the rotor 37.
  • Particulate treatment agent is introduced into the pressurised container 24 through the inlet 25 and the inlet is closed.
  • Gas, such as nitrogen or argon from a source not shown is introduced into the container 24 through inlet 27 and passes through the jets 28 so as to fluidise the particulate treatment agent, and additional gas is also introduced into the container 24 through inlet pipe 29. Excess gas leaves the container 24 through outlet 30 and passes through pipe 32 into pipe 33, together with the fluidised dispersion of particulate treatment agent which passes through the valve 26 and pipe 31 into pipe 33.
  • the dispersion then flows through the valve 46, the drive shaft 39 and the shaft 36 of the rotary device into the rotor 37 where it is mixed with the molten metal being pumped through rotor 37.
  • a hopper 51 for introducing relatively large particles (i.e greater than 1 mm) of treatment agent into a rotary device has a sealed top 52 having a closable inlet 53 for adding the particles to the hopper 51 and an aperture 54 at its base 55.
  • the hopper 51 has adjacent the base 55 two series of three sliding members 56, 57 passing through apertures in the sidewall 58 and driven by compressed air in cylinders 59, 60.
  • the sliding members 56, 57 in each of the series are equally spaced apart around the perimeter of the hopper 51, and sliding members 56 are above and midway between sliding members 57.
  • the aperture 54 at the base 55 of the hopper 51 is connected to a tube 61 which extends downwardly inside the bore 62 of drive shaft 63.
  • the tube 61 passes through a block 64 mounted underneath the hopper 51 and the block 64 has a plurality of ducts 65 which communicate with the inside of the tube 61 via apertures 66.
  • the block 64 is connected to a three way sealed spinning valve 67 which contains a bearing and washer 68 for shaft 63 and which has an aperture 69 for admitting gas into the bore 62 of the shaft 63.
  • the drive shaft 63 is driven by a wheel 70 connected by a fan belt (not shown) to an electric motor (not shown) and at its bottom end is connected to the shaft (not shown) of a rotary device for example as shown in Figures 1 and 2.
  • the rotary device In use the rotary device is lowered into molten metal in a vessel and the hopper 51, block 64, three way spinning valve 67 and wheel 70 are supported on the top of the vessel by means of support 71 which is located on a frame (not shown). Particles of treatment agent are introduced into the hopper 51 through the inlet 53 and the inlet 53 is sealed. Gas from a source not shown is passed through the ducts 65 in block 64 into tube 61. The sliding members 56, 57 are operated alternately so that they move forwards and backwards towards and away from the vertical axis of the hopper 51 and so that they accelerate the particles in the hopper 51 and cause them to fall one by one into the tube 61. Gas from a source not shown is passed into the bore 62 of the drive shaft 63 through the aperture 69 in the valve 67.
  • the modifying agent used was particles of a size less then 1 mm produced by milling bonded tablets of sodium carbonate and magnesium containing approximately 50% of each component.
  • 80g of the particles were injected in argon gas into 20kg of the molten alloy held at 790°C at a flow rate of 10g per minute, and with the rotor rotating at 400 rpm.
  • Samples of the modified alloy were taken at various times and examined by a standard thermo-­analysis technique for assessing modification in which a depression parameter in °K is measured. Using this technique the higher the depression parameter then the finer is the crystal size of the silicon in the alloy and hence the greater the degree of modification.
  • aluminium-silicon alloy and modifying agent as in Example 1 40g of the particles were injected into 20kg of the alloy held at 770°C at a flow rate of 8g per minute, and with the rotor rotating at 400 rpm.
  • a sample taken 2 minutes after modification treatment had a depression parameter of 6.5°K and a sample taken after 10 minutes had a depression parameter of 7°K.
  • Apparatus of the type shown in Figure 4 and a rotary device as shown in Figures 1 and 2 was used to modify an aluminium-silicon alloy containing 9% silicon and 3% copper.
  • 350kg of the alloy which contained 2 parts per million sodium were degassed with nitrogen at 780°C with the apparatus operating at a rotor speed of 600 rpm and a nitrogen flow rate of 25 litres per minute, and droplet shaped particles of modifying agent containing approximately 50% by weight sodium carbonate were added over a period of 2 minutes at a rate of 642 grams per minute.
  • This treatment increased the sodium content of the alloy to 71 parts per million and gave a depression parameter measured by thermo-analysis of 7°K.
  • Apparatus of the type used in Example 3 was used to grain refine the alloy used in Example 3 with grain refining droplet-like particles of 6 mm diameter during degassing of the alloy.
  • 350kg of the alloy with 8 parts per million boron were degassed with nitrogen at 780°C with the apparatus operating at a rotor speed of 600 rpm and a nitrogen flow rate of 25 litres per minute.
  • the grain refiner particles which contained 5% titanium and 1% boron were added over a period of 7 minutes at a rate of approximately 136 grams per minute. This treatment increased the boron content of the alloy to 29 parts per million.
  • Thermo - analysis showed a shortening in primary solidification from 11.5 to 6.5 time units.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Continuous Casting (AREA)
EP90303889A 1989-05-05 1990-04-11 Verfahren und Vorrichtung zum Behandeln von Metallschmelzen Withdrawn EP0396267A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8910288 1989-05-05
GB898910288A GB8910288D0 (en) 1989-05-05 1989-05-05 Treatment of molten metals

Publications (1)

Publication Number Publication Date
EP0396267A1 true EP0396267A1 (de) 1990-11-07

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EP90303889A Withdrawn EP0396267A1 (de) 1989-05-05 1990-04-11 Verfahren und Vorrichtung zum Behandeln von Metallschmelzen

Country Status (9)

Country Link
EP (1) EP0396267A1 (de)
JP (1) JPH02303653A (de)
KR (1) KR900018397A (de)
AU (1) AU622318B2 (de)
BR (1) BR9002097A (de)
CA (1) CA2015341A1 (de)
GB (1) GB8910288D0 (de)
NZ (1) NZ233458A (de)
ZA (1) ZA903099B (de)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0495581A2 (de) * 1991-01-16 1992-07-22 Foseco International Limited Drehbares Rohr zum Fördern körniger Materialien
EP0753589A1 (de) * 1995-07-12 1997-01-15 Steven Stride Rotorkopf, Vorrichtung und Verfahren zur Behandlung von Schmelzen
DE19539621C1 (de) * 1995-10-16 1997-06-05 Bayer Ag Begasungsrührer für Leichtmetallschmelzen
EP0620285B1 (de) * 1993-04-14 2002-06-12 Norsk Hydro Asa Einbringevorrichtung
US6589313B2 (en) 2000-09-12 2003-07-08 Alcan International Limited Process and apparatus for adding particulate solid material to molten metal

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5234202A (en) * 1991-02-19 1993-08-10 Praxair Technology, Inc. Gas dispersion apparatus for molten aluminum refining

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0183402A2 (de) * 1984-11-29 1986-06-04 Foseco International Limited Drehkörper, Vorrichtung und Verfahren zur Behandlung von Metallschmelzen
EP0332292A1 (de) * 1988-02-24 1989-09-13 Foseco International Limited Drehkörper, Vorrichtung und Verfahren zur Behandlung von Metallschmelzen

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0183402A2 (de) * 1984-11-29 1986-06-04 Foseco International Limited Drehkörper, Vorrichtung und Verfahren zur Behandlung von Metallschmelzen
EP0332292A1 (de) * 1988-02-24 1989-09-13 Foseco International Limited Drehkörper, Vorrichtung und Verfahren zur Behandlung von Metallschmelzen

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0495581A2 (de) * 1991-01-16 1992-07-22 Foseco International Limited Drehbares Rohr zum Fördern körniger Materialien
EP0495581A3 (en) * 1991-01-16 1993-02-03 Foseco International Limited Rotary pipe conveyor apparatus for granular materials
EP0620285B1 (de) * 1993-04-14 2002-06-12 Norsk Hydro Asa Einbringevorrichtung
EP0753589A1 (de) * 1995-07-12 1997-01-15 Steven Stride Rotorkopf, Vorrichtung und Verfahren zur Behandlung von Schmelzen
DE19539621C1 (de) * 1995-10-16 1997-06-05 Bayer Ag Begasungsrührer für Leichtmetallschmelzen
US5804135A (en) * 1995-10-16 1998-09-08 Bayer Aktiengesellschaft Gassing agitator for light metal melts
US6589313B2 (en) 2000-09-12 2003-07-08 Alcan International Limited Process and apparatus for adding particulate solid material to molten metal
US6960239B2 (en) 2000-09-12 2005-11-01 Alcan International Limited Process and apparatus for adding particulate solid material to molten metal

Also Published As

Publication number Publication date
AU5479190A (en) 1990-11-08
NZ233458A (en) 1991-12-23
CA2015341A1 (en) 1990-11-05
BR9002097A (pt) 1991-08-13
KR900018397A (ko) 1990-12-21
JPH02303653A (ja) 1990-12-17
AU622318B2 (en) 1992-04-02
GB8910288D0 (en) 1989-06-21
ZA903099B (en) 1991-03-27

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