EP0380630A4 - High damping capacity, two-phase fe-mn-al-c alloy - Google Patents

High damping capacity, two-phase fe-mn-al-c alloy

Info

Publication number
EP0380630A4
EP0380630A4 EP19890908610 EP89908610A EP0380630A4 EP 0380630 A4 EP0380630 A4 EP 0380630A4 EP 19890908610 EP19890908610 EP 19890908610 EP 89908610 A EP89908610 A EP 89908610A EP 0380630 A4 EP0380630 A4 EP 0380630A4
Authority
EP
European Patent Office
Prior art keywords
alloy
cast iron
alloys
phase
damping capacity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19890908610
Other versions
EP0380630A1 (en
EP0380630B1 (en
Inventor
Chi-Meen Wan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Famcy Steel Corp
Original Assignee
Famcy Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/218,695 external-priority patent/US4875933A/en
Application filed by Famcy Steel Corp filed Critical Famcy Steel Corp
Publication of EP0380630A1 publication Critical patent/EP0380630A1/en
Publication of EP0380630A4 publication Critical patent/EP0380630A4/en
Application granted granted Critical
Publication of EP0380630B1 publication Critical patent/EP0380630B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese

Definitions

  • Figure 1 depicts the damping capacity curve for an alloy of the invention
  • Figure 2 depicts the damping capacity curve for ductile iron.
  • Fe-Mn-Al-C alloys manganese ⁇ •- ⁇ tnd carbon are gamma- phase formers andaluminum is an alpha-phase former.
  • Fe-Mn-Al-C alloys canbe disigned to be fully gamma phase, such as Fe-29Mn-7Al-lC. Reduction of the manganese or carbon or both of them and the increase of aluminum can promote the appearance of alpha phase, and make the alloy an alpha+gamma to-phase steel.
  • the volume fraction of alpha phase can be controlled bychanging the amount of manganese or aluminum or carbon or other ferrite-forming elements.
  • Alloys according to the invention contain, in weight percent, 107. to 457 0 manganese, 47, to 127. aluminum, up to 127, chromium, 0.01% to 0.77o carbon, balance essentially iron, and are charac ⁇ terized by a microstructure containing about 257. to 757,ferrite, with the remainder austenite and bya high damping capacity on the order of a cast iron. Minor amounts of Ni,Mo,Cb,Co,Si, etc. may be included in the allov.
  • This example illustrates the effect of the element compositions on the change of ⁇ volume fraction in the Fe-Mn-Al-C based alloys.
  • Manganese and carbon are austenite phase stabilizers and aluminum is a ferrite phase former.
  • the effect of the carbon content on the ferrite fraction of the Fe-Mn-Al-C based alloys is shown in
  • Table I in which the chemical composition of aluminum and manganese are essentially constant and the carbon content decreases from 0.5 wt% to 0.11 wt%.
  • the ferrite phase volume fractions of the alloys increases from 0% to 36%.
  • the volume fractions of ferrite phase and balanced ⁇ phase is controlled to be from 25% to 75%. Within this ferrite fraction range, excellent damping capacity is always found in the Fe-Mn-Al-C based alloy.
  • This example illustrates the good damping capacity of the said ⁇ -- ⁇ two-phase Fe-Mn-Al-C based alloys which have been measured and determined with comparison to ductile cast iron.
  • the test sample of the invention contained 19.7Mn-5.84Al-5.74Cr-0.19C.
  • the ferrite volume fraction is about 65% balanced with ⁇ phase.
  • the damping capacity curves of the damping capacity tests of the Fe-Mn-Al-C based alloy and ductile cast iron are shown in Fig. 1 and Fig. 2. It is seen that the damping capacities of the two alloys are almost equivalent.
  • This example illustrates the good workability of ⁇ + ⁇ two-phase Fe-Mn-Al-C based alloys.
  • the alloys listed in Table II were cast into ingot; homogenized at 1200°C; cut and hot forged at 1200°C; further annealed at 1150°C and descaled.
  • the alloys were cold rolled ' into 2.0 mm thick strip and annealed.
  • the ferrite volume percentages of these strips were measured and are listed in Table III.
  • the mechanical properties of these annealed strips are also listed in Table III. It is seen that the alloys of the invention have good workablility and excellent mechanical properties.

Abstract

Carbon steels and other hot-and cold-workable ferrous alloys generally have poor damping capacity as compared to that cast iron (gray cast iron, malleable cast iron and ductile cast iron). This is because the graphite in cast irons helps to absorb the damping force and depresses the damping wave. But cast iron can not be rolled into strip of sheet. By controlling the correlated concentrations of manganese, aluminum and carbon, Fe-Mn-Al-C based alloys are made to be alpha + gamma two-phase alloy steel with different alpha and gamma volume fractions. With particular ferrite volumes, workable Fe-Mn-Al-C based alloys have equivalent and better damping capacity than that of cast irons especially in the high frequency side. Such alloys suppress the vibration noise that comes from machine rooms, motors, air conditioners, and etc. Chromium and other minor amount of elements can be added to this alloy system to improve the corrosion resistance.

Description

HIGH DAMPING CAPACITY, TWO-PHASE Fe-Mn-Al-C ALLOY
BACKGROUND:
For the past years alpha-gamma two-phasealloys have been developed by adding molybdenum and cobalt to the Fe-Ni-Cr alloy system for the purpose of making alloys having both better stress corrosion and hydrogen embrittlement resistance. But none of these alloys was designed for the purpose of higher damping: capacity. The iron-base materials that have been used for high damping capacity are the cast irons. The graphite in gray cast irons is the most important factor for absorbing the high frequency vibration wave. But cast irons generally are not workable, making them of limited value in highdamping applicactions.
DESCRIPTION OF THE DRAWING
In the drawing: Figure 1 depicts the damping capacity curve for an alloy of the invention; and Figure 2 depicts the damping capacity curve for ductile iron.
DETAILED DESCRIPTION OF THE INVENTION;
In Fe-Mn-Al-C alloys, manganese •-■tnd carbon are gamma- phase formers andaluminum is an alpha-phase former. By suitable compositional arrangement, Fe-Mn-Al-C alloys canbe disigned to be fully gamma phase, such as Fe-29Mn-7Al-lC. Reduction of the manganese or carbon or both of them and the increase of aluminum can promote the appearance of alpha phase, and make the alloy an alpha+gamma to-phase steel. The volume fraction of alpha phase can be controlled bychanging the amount of manganese or aluminum or carbon or other ferrite-forming elements.
Alloys according to the invention contain, in weight percent, 107. to 4570manganese, 47, to 127. aluminum, up to 127, chromium, 0.01% to 0.77o carbon, balance essentially iron, and are charac¬ terized by a microstructure containing about 257. to 757,ferrite, with the remainder austenite and bya high damping capacity on the order of a cast iron. Minor amounts of Ni,Mo,Cb,Co,Si, etc. may be included in the allov. Example I. "2-
This example illustrates the effect of the element compositions on the change of α volume fraction in the Fe-Mn-Al-C based alloys. Manganese and carbon are austenite phase stabilizers and aluminum is a ferrite phase former. The effect of the carbon content on the ferrite fraction of the Fe-Mn-Al-C based alloys is shown in
Table I. in which the chemical composition of aluminum and manganese are essentially constant and the carbon content decreases from 0.5 wt% to 0.11 wt%.
With the decreasing of carbon content, the ferrite phase volume fractions of the alloys increases from 0% to 36%. With the change of manganese, carbon and aluminum contents, the volume fractions of ferrite phase and balanced γ phase is controlled to be from 25% to 75%. Within this ferrite fraction range, excellent damping capacity is always found in the Fe-Mn-Al-C based alloy.
Table I
Example 2.
This example illustrates the good damping capacity of the said α--γ two-phase Fe-Mn-Al-C based alloys which have been measured and determined with comparison to ductile cast iron. The test sample of the invention contained 19.7Mn-5.84Al-5.74Cr-0.19C. The ferrite volume fraction is about 65% balanced with γ phase. The damping capacity curves of the damping capacity tests of the Fe-Mn-Al-C based alloy and ductile cast iron are shown in Fig. 1 and Fig. 2. It is seen that the damping capacities of the two alloys are almost equivalent.
xamp e .
This example illustrates the good workability of α+γ two-phase Fe-Mn-Al-C based alloys. The alloys listed in Table II were cast into ingot; homogenized at 1200°C; cut and hot forged at 1200°C; further annealed at 1150°C and descaled. The alloys were cold rolled' into 2.0 mm thick strip and annealed. The ferrite volume percentages of these strips were measured and are listed in Table III. The mechanical properties of these annealed strips are also listed in Table III. It is seen that the alloys of the invention have good workablility and excellent mechanical properties.
Table II.
sample no. 0.2% proof ultimate teπsi % elongation hardness ferrite stress(ksi) stress (ksi) (Rb) %
#109 45 103 42 84 45 #108 39 94 44 80 28 #320 41 98 43 82 67 #317 44 101 41 83 75 #129 61 112 38 86 65 #1 16 59 109 37 85 73

Claims

Claim:
(1) A ferrite-austenite two-phase alloy of high damping capacity having composition consisting essentially of 10 to 45 wt% manganese, 4 to 15 wt aluminum, up to 12 wt% chromium, 0.01 to 0.7 wt% carbon and the balanc essentially iron, with the ferrite phase of said alloy having about 25% to 75% b volume, the remainder being essentially austenite, said alloy having a dampin capacity of about the same level as that of ductile iron.
(2) The alloy of claim 1 containing 0 to 4.0. wt% molybdenum.
(3) The alloy of claim 1 containing 0 to 4.0 wt% copper.
(4) The alloy of claim 1 containing 0 to 2.0 wt% nickel.
(5) The alloy of claim 1 containing 0 to 3.5 wt% niobium.
(6) The alloy of claim 1 containing up to 500 ppm boron.
(7) The alloy of claim 1 containing up to 0.2 wt% nitrogen.
(8) The alloy of claim 1 containing 0 to 3.5 wt% titanium.
(9) The alloy of claim 1 containing 0 to 2.0 wt% cobalt.
(10) The alloy of claim 1 containing 0 to 3.5 wt% vanadium.
(11) The alloy of claim 1 containing 0 to 3.5 wt% tungsten.
(12) The alloy of claim 1 containing 0 to 2.0 wt% zirconium.
(13) The alloy of claim 1 containing up to 2.5 wt% silicon.
EP89908610A 1988-07-08 1989-07-06 Use of a high damping capacity, two-phase fe-mn-al-c alloy Expired - Lifetime EP0380630B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US218695 1988-07-08
US07/218,695 US4875933A (en) 1988-07-08 1988-07-08 Melting method for producing low chromium corrosion resistant and high damping capacity Fe-Mn-Al-C based alloys
US341117 1989-04-20
US07/341,117 US4966636A (en) 1988-07-08 1989-04-20 Two-phase high damping capacity F3-Mn-Al-C based alloy
PCT/US1989/002950 WO1990000629A1 (en) 1988-07-08 1989-07-06 High damping capacity, two-phase fe-mn-al-c alloy

Publications (3)

Publication Number Publication Date
EP0380630A1 EP0380630A1 (en) 1990-08-08
EP0380630A4 true EP0380630A4 (en) 1990-12-27
EP0380630B1 EP0380630B1 (en) 1994-11-30

Family

ID=26913151

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89908610A Expired - Lifetime EP0380630B1 (en) 1988-07-08 1989-07-06 Use of a high damping capacity, two-phase fe-mn-al-c alloy

Country Status (7)

Country Link
EP (1) EP0380630B1 (en)
JP (1) JPH03500305A (en)
AT (1) ATE114736T1 (en)
AU (1) AU610429B2 (en)
CA (1) CA1336364C (en)
DE (1) DE68919672T2 (en)
WO (1) WO1990000629A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR960006453B1 (en) * 1993-10-22 1996-05-16 최종술 Making method of vibration decrease alloy steel & the manufacturing process
DE10259230B4 (en) * 2002-12-17 2005-04-14 Thyssenkrupp Stahl Ag Method for producing a steel product
RU2401877C2 (en) * 2005-02-02 2010-10-20 Корус Стал Бв Austenite steel of high strength, procedure for production of said steel and its application
KR20080111032A (en) 2006-04-20 2008-12-22 아사히 가라스 가부시키가이샤 Core-shell silica and method for producing same
WO2013064202A1 (en) * 2011-11-03 2013-05-10 Tata Steel Nederland Technology B.V. Method of manufacturing a duplex steel sheet having enhanced formability
WO2013178887A1 (en) 2012-05-31 2013-12-05 Arcelormittal Investigación Desarrollo Sl Low-density hot- or cold-rolled steel, method for implementing same and use thereof
CN104674109B (en) * 2015-03-11 2017-01-18 北京科技大学 Low-density Fe-Mn-Al-C system cold-rolled automobile steel plate and preparation method
KR101910744B1 (en) * 2017-07-26 2018-10-22 포항공과대학교 산학협력단 Medium-entropy alloys with excellent cryogenic properties

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB949786A (en) * 1959-06-23 1964-02-19 United States Steel Corp Austenitic stainless steel

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA655825A (en) * 1963-01-15 Ciba Limited Unsaturated aliphatic amino-diols and process for their manufacture
AU8261182A (en) * 1981-04-22 1982-10-28 Unisearch Limited Oxidation and corrosion-resistant febase-al-mn alloys
JPS60248866A (en) * 1984-05-24 1985-12-09 Yamato Metal Kogyo Kk Stainless steel for cryogenic service having excellent sea water resistance

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB949786A (en) * 1959-06-23 1964-02-19 United States Steel Corp Austenitic stainless steel

Also Published As

Publication number Publication date
AU3981589A (en) 1990-02-05
WO1990000629A1 (en) 1990-01-25
EP0380630A1 (en) 1990-08-08
DE68919672T2 (en) 1995-04-06
JPH03500305A (en) 1991-01-24
AU610429B2 (en) 1991-05-16
EP0380630B1 (en) 1994-11-30
ATE114736T1 (en) 1994-12-15
DE68919672D1 (en) 1995-01-12
CA1336364C (en) 1995-07-25

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