EP0378259B1 - Fil de connexion à haute tension - Google Patents

Fil de connexion à haute tension Download PDF

Info

Publication number
EP0378259B1
EP0378259B1 EP90200017A EP90200017A EP0378259B1 EP 0378259 B1 EP0378259 B1 EP 0378259B1 EP 90200017 A EP90200017 A EP 90200017A EP 90200017 A EP90200017 A EP 90200017A EP 0378259 B1 EP0378259 B1 EP 0378259B1
Authority
EP
European Patent Office
Prior art keywords
insulation sheath
connection wire
copolymer
voltage
sheath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP90200017A
Other languages
German (de)
English (en)
Other versions
EP0378259A1 (fr
Inventor
Peter Hubertus Van Buggenum
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Belden Wire and Cable Co
Original Assignee
Philips Gloeilampenfabrieken NV
Koninklijke Philips Electronics NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Philips Gloeilampenfabrieken NV, Koninklijke Philips Electronics NV filed Critical Philips Gloeilampenfabrieken NV
Publication of EP0378259A1 publication Critical patent/EP0378259A1/fr
Application granted granted Critical
Publication of EP0378259B1 publication Critical patent/EP0378259B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds

Definitions

  • the invention relates to a high-voltage connection wire for use in display devices such as, in particular, TV receivers and monitors for computers.
  • the known high-voltage connection wires comprise an insulating sheath which is provided about the central conductor, said sheath being manufactured from polyethylene which, if desirable, is made to be flame-extinguishing by the addition of additives such as a bromine compound, crosslinked polyethylene, polyvinyl chloride, irradiated polyvinyl chloride, tetrafluoroethylene, polyvinylidene fluoride, copolymer of ethylene and tetrafluoroethylene or silicone rubber.
  • additives such as a bromine compound, crosslinked polyethylene, polyvinyl chloride, irradiated polyvinyl chloride, tetrafluoroethylene, polyvinylidene fluoride, copolymer of ethylene and tetrafluoroethylene or silicone rubber.
  • connection wires Both the electrical and the mechanical properties of the special high-voltage connection wires mentioned above must meet high requirements as regards, for example, the flame-extinguishing character, temperature resistance, moisture resistance, flexibility, permissible voltage and variation of the permissible voltage as a function of the stress present or developed in the wire. Since the wires, as stated above, are applied in displays which are used indoors in very large numbers, international research institutes keep a close check on the quality of the connection wires, both when a novel type of wire is introduced and in the subsequent period of use. It should be kept in mind that the connection wires in said display devices bring about the electric connection between the high-voltage unit and the display tube present therein. The temperature may vary substantially in this type of apparatus; besides, the wires must be passed between a variety of components, so that sharp curves are formed which bring about mechanical stress in the connection wire.
  • the fluorine-containing insulation materials used so far have the advantage of a favourable temperature resistance but they are very expensive.
  • polyethylene is anything but flame-extinguishing or fire-retardant.
  • the polyvinyl chloride insulation material used has a low temperature resistance.
  • connection wire in which the conductor is surrounded by a first insulation sheath having a thickness between 0.3 and 1.5 mm and comprising a copolymer of propene and at least one other alkene, said first insulation sheath being coated with a non-crosslinked second insulation sheath having a thickness between 1.0 and 3.0 mm and comprising polyvinyl chloride or a copolymer thereof, said second insulation sheath being further provided with flame-extinguishing additives.
  • connection wire is of exceptional quality and is completely safe for use.
  • the connection wire is, in particular, highly resistant to varying climatological conditions such as temperature, humidity and the like. A relatively high electric voltage load is permissible for a long period of use and at varying mechanical stresses as a result of bending.
  • the first insulation sheath is important to obtain suitable dielectric properties. In particular, the first insulation sheath provides a sufficient insulation resistance.
  • United States Patent US-4310597 discloses a low-voltage electrical wire consisting of an electrical conductor which is successively coated by an inner layer of polyolefin insulating material and an outer layer of irradiation-crosslinked insulating material made essentially of polyvinyl chloride, acrylic monomers and plasticiser, the combined thickness of the inner and outer layers being around 0.2 mm.
  • the disclosed wire is intended for use in low-voltage telecommunications equipment, where a plurality of such wires are interwoven over tortuous paths, and are very frequently re-routed, kinked, and abraded during routine maintenance work.
  • connection wire comprising a first insulation sheath of polypropylene has a favourable insulation resistance in the straight condition of the wire.
  • Tests have been carried out using connection wires comprising a tin-plated copper conductor having a diameter of 0.8 mm and a first insulation sheath of polypropylene.
  • the layer thickness of the first insulation sheath differs, the diameter of the first insulation sheath being 1.9 mm; 2.1 mm and 2.3 mm, respectively.
  • connection wires can suitably be used with voltage loads of 20 kV, 30 kV and 40 kV, respectively, at temperatures up to 105°C. However, these values apply to a straight connection wire.
  • connection wire is bent to a radius of curvature which is approximately 10 times the wire diameter or less, the permissible voltage load is reduced by 40-60%.
  • polypropylene is substituted by a copolymer of polypropylene and at least one other alkene, bending and, hence, mechanical tensile stress, does not lead to a reduction of the voltage load. Consequently, also when the wire is bent, a voltage load of at least 20 kV,30 kV and 40 kV, respectively, is permissible for the above-mentioned diameters of the first insulation sheath of the high-voltage connection wire.
  • connection wires according to the invention were bent substantially at increased temperatures and subjected to an additional mechanical tensile stress. Even under such extreme conditions, the connection wire according to the invention remains suitable for a high voltage load. Also at an increased temperature and under tensile stress, a connection wire according to the invention comprising a conductor having a diameter of 0.8 mm, a first insulation sheath having a diameter of 1.9 mm and a non-crosslinked second insulation sheath having a diameter of 3.2 mm, can be used at a voltage of at least 30 kV.
  • a similar wire comprising the same conductor, a first insulation sheath with a diameter of 2.1 mm and a non-crosslinked second insulation sheath with a diameter of 3.5 mm can suitably be used for a voltage load of at least 45 kV at an increased temperature and under mechanical stress.
  • a service voltage of at least 60 kV is obtained by means of a high-voltage connection wire according to the invention, which comprises a conductor with a diameter of 0.8 mm, a first insulation sheath with a diameter of 2.3 mm and a non-crosslinked second insulation sheath with a diameter of 4.2 mm.
  • the copolymer is, for example, a copolymer of propene and butene or of propene and hexene.
  • a very suitable copolymer is the copolymer of propene and ethene. Both block copolymers and random copolymers can be used.
  • the ethene content is 2-60% by weight. In the case of block copolymers the ethene content is preferably 10-30% by weight. In the case of random copolymers the ethene content is preferably 2-40% by weight.
  • the durability of the copolymer can be extended by adding auxiliary agents such as stabilizers, antioxidants and similar additives in a customary manner.
  • the non-crosslinked second insulation sheath of the high-voltage connection wire ensures that the connection wire has a flame-extinguishing character.
  • the polymer basic material of the second insulation sheath is polyvinyl chloride or a copolymer of vinyl chloride.
  • a suitable copolymer is the copolymer of vinyl chloride and ethylene vinylacetate.
  • a mixture of polyvinyl chloride and another polymer substance can be used such as, for example, a mixture of polyvinyl chloride and polyethylene vinylacetate.
  • Polyvinyl chloride or a copolymer thereof already has fire-retardant properties in itself.
  • the material of the second insulation sheath is additionally provided with flame-extinguishing additives which are known per se such as bromine compounds, in particular aromatic bromine compounds, for example, decabromine diphenyl or decabromine diphenyl oxide.
  • flame-extinguishing additives which are known per se such as bromine compounds, in particular aromatic bromine compounds, for example, decabromine diphenyl or decabromine diphenyl oxide.
  • inorganic oxides or sulphides can be used such as antimony oxide or antimony sulphide.
  • the second insulation sheath may be provided with customary additives such as a filler, for example, calcium carbonate, stabilizers, antioxidants and lubricants.
  • the flame-extinguishing properties are established in the so-called vertical-wire flame test.
  • a Tirrill gas burner is used (a Bunsen burner in which the gas and air supply can be adjusted) as well as a metal housing comprising three wall portions, i.e. a bottom plate and two parallel side plates which are arranged perpendicularly on the bottom plate.
  • a specimen of the high-voltage connection wire to be investigated is arranged in the centre of the housing, perpendicularly to the bottom plate and equidistantly from the side plates.
  • the Tirrill gas burner is directed at the specimen, such that the fire tube of the burner is at an angle of 20° to the vertically arranged specimen.
  • Said specimen is subjected to a flame process in which it is heated by the gas flame of the Tirrill burner for 5 periods of 15 seconds each. These active periods are alternated with rest periods of 15 seconds also, during which no heating takes place.
  • the gas flame has a length of 100-125 mm and has a blue, conical flame zone having a length of 38 mm.
  • the temperature at the tip of the blue conical flame zone is approximately 800° C.
  • the tip of said blue flame zone touches the specimen. After the last active heating period, it was found that the specimen stopped flaming within one minute. Moreover, in the test period, no glowing or flaming particles have formed and/or come off the specimen.
  • the high-voltage connection wire according to the invention can be provided with one or more reinforcement layers which are applied to the second insulation sheath, such as a layer of a metal braid which in turn is covered with a PVC sheath.
  • reference numeral 1 denotes a conductor.
  • Said conductor is manufactured from, for example, Cu or Cu provided with a layer of Sn.
  • the diameter of the conductor is not of essential importance. A suitable diameter ranges from, for example, 0.5 to 1.5 mm.
  • the conductor may be solid or composed of a number of interwoven elementary wires, a so-called litz wire.
  • a first insulation sheath 2 is provided around the conductor 1.
  • a suitable method for doing this is an extrusion process.
  • the thickness of the sheath 2 is determined by the voltage required during operation of the connection wire. Thus, the thickness may vary between, for example, 0.3 and 1.5 mm for service voltages of 10 kV to, for example, 100 kV or higher.
  • the insulation sheath is manufactured from a copolymer of propene and ethene containing 20% by weight of ethene.
  • a non-crosslinked second insulation sheath 3 is provided around the first insulation sheath 2 by means of an extrusion process.
  • the sheath 3 provides the high-voltage connection wire with flame-extinguishing properties.
  • the thickness of the sheath 3 is adapted and attuned to that of the sheath 2, in such a manner that a larger layer thickness of sheath 2 leads to a larger thickness of sheath 3.
  • a suitable layer thickness ranges from 1.0 to 3.0 mm.
  • the sheath 3 has the following composition:

Landscapes

  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Insulated Conductors (AREA)
  • Organic Insulating Materials (AREA)

Claims (3)

  1. Fil de connexion à haute tension qui s'utilise dans des dispositifs de visualisation, ledit fil de connexion comporte un conducteur isolé (1), caractérisé en ce que le conducteur est entouré d'une première gaine d'isolation (2) présentant une épaisseur comprise entre 0,3 et 1,5 mm et comportant un copolymère de propène et au moins un autre alkène, ladite première gaine d'isolation étant revêtue d'une deuxième gaine d'isolation non réticulée (3) présentant une épaisseur comprise entre 1,0 et 3,0 mm et comportant du chlorure de polyvinyle ou un copolymère dudit chlorure, ladite deuxième gaine d'isolation comportant encore des additifs pour éteindre les flammes.
  2. Fil de connexion à haute tension selon la revendication 1, caractérisé en ce que la première gaine d'isolation (2) comporte un copolymère de propène et d'éthène dont la teneur en poids est compris entre 2 et 60%.
  3. Fil de connexion à haute tension selon la revendication 1 ou 2, caractérisé en ce que la deuxième gaine d'isolation (3) comporte un copolymère de chlorure de vinyle et de vinylacétate d'éthylène ou un mélange de chlorure de polyvinyle et de vinylacétate de polyéthylène.
EP90200017A 1989-01-10 1990-01-04 Fil de connexion à haute tension Expired - Lifetime EP0378259B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL8900044A NL8900044A (nl) 1989-01-10 1989-01-10 Hoogspanning-verbindingsdraad.
NL8900044 1989-01-10

Publications (2)

Publication Number Publication Date
EP0378259A1 EP0378259A1 (fr) 1990-07-18
EP0378259B1 true EP0378259B1 (fr) 1994-08-24

Family

ID=19853922

Family Applications (1)

Application Number Title Priority Date Filing Date
EP90200017A Expired - Lifetime EP0378259B1 (fr) 1989-01-10 1990-01-04 Fil de connexion à haute tension

Country Status (4)

Country Link
EP (1) EP0378259B1 (fr)
JP (1) JPH02227915A (fr)
DE (1) DE69011695T2 (fr)
NL (1) NL8900044A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03126309U (fr) * 1990-04-04 1991-12-19
DE60108796T2 (de) 2000-02-21 2006-01-12 Cables Pirelli Feuerbeständige und wasserfeste, halogenfreie Niederspannungskabel

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4310597A (en) * 1978-07-10 1982-01-12 Northern Telecom Limited Low voltage electrical wire

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ENCYCLOPAEDIA OF POLYMER SCIENCE AND ENGINEERING, publ. WILEY, 1986, Vol. 17, p. 835 and Vol. 6, pp. 522-526 *
ENCYCLOPAEDIA OF PVC, Ed. Nass,publ. Marcel Dekker Inc., New York,1977, pp.1713-1717 *

Also Published As

Publication number Publication date
EP0378259A1 (fr) 1990-07-18
NL8900044A (nl) 1990-08-01
JPH02227915A (ja) 1990-09-11
DE69011695D1 (de) 1994-09-29
DE69011695T2 (de) 1995-03-16

Similar Documents

Publication Publication Date Title
US8410789B2 (en) High voltage electric cable
EP0224281B1 (fr) Revêtement ignifugé
EP0440118A2 (fr) Fil électrique isolé et câble l'utilisant
US6207277B1 (en) Multiple insulating layer high voltage wire insulation
EP2582751A2 (fr) Isolants contenant des copolymères du styrène
US5462803A (en) Dual layer fire-resistant plenum cable
US3772455A (en) Flame and moisture resisting impregnating composition for fibrous materials, and products thereof
EP0378259B1 (fr) Fil de connexion à haute tension
EP0211505A2 (fr) Bande Isolante
CA1118855A (fr) Cables electriques gaines a bonne tenue au feu
KR20190096889A (ko) 고내화 절연 조성물
WO1993007627A1 (fr) Cable electrique
KR20190121998A (ko) 내화 케이블
CA2192380C (fr) Cable de communication a installer en caisson de distribution d'air
EP0373669B1 (fr) Brin pour courant continu à haute tension
CA1307837C (fr) Cable mural double a gaines isolantes en polyester et en polymere fluore
JP3092294B2 (ja) 耐熱性直流用高圧リード線
CN111349282A (zh) 包括容易剥离的半导电层的线缆
JP2009245927A (ja) 高耐熱性絶縁材製造用組成物及びこれを用いて製造された高耐熱絶縁電線
JPS6140021Y2 (fr)
KR100930438B1 (ko) 유연성과 난연성 및 내마모성이 우수한 전선용 절연체조성물과 이를 이용한 전선
JP2001052535A (ja) 耐トラッキング性絶縁電線、及び耐トラッキング性絶縁ケーブル
JPS6356647B2 (fr)
WO1989000760A1 (fr) Fil
GB2096151A (en) Insulated electric cables, and composition therefor

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE FR GB IT NL

17P Request for examination filed

Effective date: 19901219

17Q First examination report despatched

Effective date: 19921119

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE FR GB IT NL

REF Corresponds to:

Ref document number: 69011695

Country of ref document: DE

Date of ref document: 19940929

ITF It: translation for a ep patent filed

Owner name: ING. C. GREGORJ S.P.A.

ET Fr: translation filed
ITPR It: changes in ownership of a european patent

Owner name: CAMBIO RAGIONE SOCIALE;PHILIPS ELECTRONICS N.V.

REG Reference to a national code

Ref country code: FR

Ref legal event code: CD

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

NLT1 Nl: modifications of names registered in virtue of documents presented to the patent office pursuant to art. 16 a, paragraph 1

Owner name: PHILIPS ELECTRONICS N.V.

26N No opposition filed
REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19960109

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19960115

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19960125

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19960130

Year of fee payment: 7

NLS Nl: assignments of ep-patents

Owner name: BELDEN WIRE & CABLE COMPANY

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19970104

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19970801

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19970104

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Effective date: 19970930

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 19970801

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19971001

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050104