EP0369674A1 - Additif à fonctions multiples d'amélioration de l'indice de viscosité - Google Patents

Additif à fonctions multiples d'amélioration de l'indice de viscosité Download PDF

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Publication number
EP0369674A1
EP0369674A1 EP89311572A EP89311572A EP0369674A1 EP 0369674 A1 EP0369674 A1 EP 0369674A1 EP 89311572 A EP89311572 A EP 89311572A EP 89311572 A EP89311572 A EP 89311572A EP 0369674 A1 EP0369674 A1 EP 0369674A1
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EP
European Patent Office
Prior art keywords
butene
poly
ethylene
oil
reaction product
Prior art date
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EP89311572A
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German (de)
English (en)
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EP0369674B1 (fr
Inventor
Frank Joung-Yei Chen
David Yen-Lung Chung
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/36—Release agents or mold release agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/38—Conveyors or chain belts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/40—Generators or electric motors in oil or gas winning field
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/42—Flashing oils or marking oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/44—Super vacuum or supercritical use
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/50—Medical uses
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Definitions

  • U.S. Pat. No. 3,316,177 teaches ethylene copolymers such as ethylene-propylene, or ethylene-propylene-diene, which are heated to elevated temperatures in the presence of oxygen so as to oxidize the polymer and cause its reaction with maleic anhydride which is present during the oxidation. The resulting polymer can then be reacted with alkylene polyamines.
  • U.S. Pat. No. 3,326,804 teaches reacting ethylene copolymers with oxygen or ozone, to form a hydroperoxidized polymer, which is grafted with maleic anhydride followed by reaction with polyalkylene polyamines.
  • U.S. Pat. No. 4,089,794 teaches grafting the ethylene copolymer with maleic anhydride using peroxide in a lubricating oil solution, wherein the grafting is preferably carried out under nitrogen, followed by reaction with polyamine.
  • U.S. Pat. No. 4,137,185 teaches reacting C1 to C30 mono carboxylic acid anhydrides, and dicarboxylic acid anhydrides, such as acetic anhydride, succinic anhydride, etc. with an ethylene copolymer reacted with maleic anhydride and a polyalkylene polyamine to inhibit cross linking and viscosity increase due to further reaction of any primary amine groups which were initially unreacted.
  • U.S. Pat. No. 4,144,181 is similar to 4,137,185 in that it teaches using a sulfonic acid to inactivate the remaining primary amine groups when a maleic anhydride grafted ethylene-propylene copolymer is reacted with a polyamine.
  • U.S. Pat. No. 4,169,063 reacts an ethylene copolymer in the absence of oxygen and chlorine at temperatures of 150°C to 250°C with maleic anhydride followed by reaction with polyamine.
  • a number of prior disclosures teach avoiding the use of polyamine having two primary amine groups to thereby reduce cross-linking problems which become more of a problem as the number of amine moieties added to the polymer molecule is increased in order to increase dispersancy.
  • German Published Application No. P3025274.5 teaches an ethylene copolymer reacted with maleic anhydride in oil using a long chain alkyl hetero or oxygen containing amine.
  • U.S. Pat. No. 4,132,661 grafts ethylene copolymer, using peroxide and/or air blowing, with maleic anhydride and then reacts with a primary-tertiary diamine.
  • U.S. Pat. No. 4,160,739 teaches an ethylene copolymer which is grafted, using a free radical technique, with alternating maleic anhydride and a second polymerizable monomer such as methacrylic acid, which materials are reacted with an amine having a single primary, or a single secondary, amine group.
  • U.S. Pat. No. 4,171,273 reacts an ethylene copolymer with maleic anhydride in the presence of a free radical initiator and then with mixtures of C4 to C12 n-alcohol and amine such as N-aminopropylmorpholine or dimethylamino propyl amine to form a V.I. dispersant pour depressant additive.
  • U.S. Pat. No. 4,219,432 teaches maleic anhydride grafted ethylene copolymer reacted with a mixture of an amine having only one primary group together with a second amine having two or more primary groups.
  • German published application No. 2753569.9 shows an ethylene copolymer reacted with maleic anhydride by a free radical technique and then reacted with an amine having a single primary group.
  • German published application No. 2845288 grafts maleic anhydride on an ethylene-propylene copolymer by thermal grafting at high temperatures and then reacts with amine having one primary group.
  • French published application No. 2423530 teaches the thermal reaction of an ethylene copolymer with maleic anhydride at 150°C to 210°C followed by reaction with an amine having one primary or secondary group.
  • U.S. Patent No. 4,517,104 represents a further improvement over the art in that it permits the utilization of the generally less expensive polyalkylene polyamines having two reactive amine groups such as primary and/or secondary amine groups, while achieving good dispersancy levels, inhibiting cross-linking and allowing initiator, e.g. peroxide, grafting in oil.
  • This can be obtained by reacting the polymer grafted with the maleic anhydride and an acid component, such as an alkenyl succinic anhydride, e.g., polyisobutenyl succinic anhydride, with the polyalkylene polyamine, e.g.
  • the present invention is directed to multifunctional viscosity index improvers comprising the reaction products of (i) ethylene copolymers grafted with ethylenically unsaturated carboxylic acid moieties, (ii) polyamines or polyols, and (iii) poly-n-butene substituted dicarboxylic acid material containing a poly-n-butene of from about 300 to about 3,000 number average molecular weight.
  • oil soluble viscosity index improver-dispersant additives comprising the reaction products of (i) ethylene copolymers, such as copolymers of ethylene and propylene, grafted with ethylenically unsaturated carboxylic acid moieties, preferably maleic anhydride moieties; (ii) polyamines having two or more reactive amine groups selected from primary and secondary amine groups, or polyols; and (iii) poly-n-butene substituted carboxylic acid material wherein the poly-n-butene has a number average molecular weight of from about 300 to about 3,000.
  • V.I.-dispersants exhibiting improved low temperature viscometric properties are provided.
  • Oil soluble ethylene copolymers used in the invention generally will have a number average molecular weight ( M n ) of from above about 5000 to about 500,000; preferably 10,000 to 200,000 and optimally from about 20,000 to 100,000.
  • M n number average molecular weight
  • polymers useful as V.I. improvers will be used. These V.I. improvers will generally have a narrow range of molecular weight, as determined by the ratio of weight-average molecular weight ( M w ) to number-average molecular weight ( M n ). Polymers having a M w / M n of less than 10, preferably less than 7, and more preferably 4 or less are most desirable.
  • ( M n ) and ( M w ) are measured by the well known techniques of vapor phase osmometry (VPO), membrane osmometry and gel permeation chromatography.
  • VPO vapor phase osmometry
  • polymers having a narrow range of molecular weight may be obtained by a choice of synthesis conditions such as choice of principal catalyst and cocatalyst combination, addition of hydrogen during the synthesis, etc.
  • Post synthesis treatment such as extrusion at elevated temperature and under high shear through small orifices, mastication under elevated temperatures, thermal degradation, fractional precipitation from solution, etc. may also be used to obtain narrow ranges of desired molecular weights and to break down higher molecular weight polymer to different molecular weight grades for V.I. use.
  • These polymers are prepared from ethylene and ethylenically unsaturated hydrocarbons including cyclic, alicyclic and acyclic, containing from 3 to 28 carbons, e.g. 3 to 18 carbons.
  • These ethylene copolymers may contain from 15 to 90 wt. % ethylene, preferably 30 to 80 wt. % of ethylene and 10 to 85 wt. %, preferably 20 to 70 wt. % of one or more C3 to C28, preferably C3 to C18 more preferably C3 to C8, alpha olefins. While not essential, such copolymers preferably have a degree of crystallinity of less than 25 wt.
  • Copolymers of ethylene and propylene are most preferred.
  • Other alpha-olefins suitable in place of propylene to form the copolymer, or to be used in combination with ethylene and propylene to form a terpolymer, tetrapolymer, etc. include 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, etc.; also branched chain alpha-ole­fins, such as 4-methyl-1-pentene, 4-methyl-1-hexene, 4,4-dimethyl-1-pentene, and 6-methylheptene-1, etc., and mixtures thereof.
  • copolymer as used herein includes terpolymers, tetrapolymers, etc., of ethylene, said C3-28 alpha-olefin and/or a non-conjugated diolefin or mixtures of such diolefins which may also be used.
  • the amount of the non-conjugated diolefin will generally range from about 0.5 to 20 mole percent, preferably about 1 to about 7 mole percent, based on the total amount of ethylene and alpha-olefin present.
  • non-conjugated dienes that may be used as the third monomer in the terpolymer include:
  • These materials which are grafted onto the ethylene copolymer to make the acid grafted ethylene copolymer are (i) monounsaturated C4 to C10 dicarboxylic acid wherein (a) the carboxyl groups are vicinyl, (i.e. located on adjacent carbon atoms) and (b) are at least one, preferably both, of said adjacent carbon atoms are part of said mono unsaturation; or with (ii) derivatives of (i) such as anhydrides or C1 to C5 alcohol derived mono-or diesters of (i).
  • the monounsaturation of the dicarboxylic acid, anhydride, or esters becomes saturated.
  • maleic anhydride becomes succinic anhydride.
  • Exemplary of such unsaturated mono and dicarboxylic acids, or anhydrides and esters thereof ar fumaric acid, itaconic acid, maleic acid, maleic anhydride, chloromaleic acid, chloromaleic anhydride, acrylic acid, methacrylic acid, crotonic acid, cinnamic acid, etc.
  • Maleic anhydride or a derivative thereof is preferred as it does not appear to homopolymerize appreciably but grafts onto the ethylene copolymer to give two carboxylic acid functionalities.
  • Such preferred materials have the generic formula wherein R1 and R2 are independently hydrogen or chlorine.
  • various unsaturated comonomers may be grafted on the olefin copolymer together with the unsaturated acid component, e.g. maleic anhydride.
  • Such graft monomer systems may comprise one or a mixture of comonomers different from the unsaturated acid component and which contain only one copolymerizable double bond and are copolymerizable with said unsaturated acid component.
  • such comonomers do not contain free carboxylic acid groups and are esters containing alpha, beta-ethylenic unsaturation in the acid or alcohol portion; hydrocarbons, both aliphatic and aromatic, containing alpha, beta-ethylenic unsaturation, such as the C4-C12 alpha olefins, for example isobutylene, hexene, nonene, dodecene, etc.; styrenes, for example styrene, alpha-methyl styrene, p-methyl styrene, p-sec.
  • butyl styrene, etc. and vinyl monomers, for example vinyl acetate, vinyl chloride, vinyl ketones such as methyl and ethyl vinyl ketone, etc.
  • Comonomers containing functional groups which may cause crosslinking, gelation or other interfering reactions should be avoided, although minor amounts of such comonomers (up to about 10% by weight of the comonomer system) often can be tolerated.
  • the components of the graft copolymerizable system are used in a ratio of unsaturated acid monomer component to comonomer component of about 1:4 to 4:1, preferably about 1.2 to 2:1 by weight.
  • the grafting of the ethylene copolymer with the ethylenically unsaturated carboxylic acid material may be by any suitable method, such as thermally by the "ene” reaction, using copolymers containing unsaturation, such as ethylene-propylene-diene polymers either chlorinated or unchlorinated, extruder or masticator grafting, or more preferably it is by free-radical induced grafting in solvent, preferably in a mineral lubricating oil as solvent.
  • the free-radical induced grafting of ethylenically unsaturated carboxylic acid materials in solvents, such as benzene, is known in the art and disclosed, inter alia, in U.S. Patent No. 2,236,917, incorporated herein by reference.
  • the free-radical grafting is preferably carried out using free radical initiators such as peroxides and hydroperoxides, and nitrile compounds, preferably those which have a boiling point greater than about 100°C and which decompose thermally within the grafting temperature range to provide said free radicals.
  • free-radical initiators are azobutyro-nitrile, 2,5-dimethyl-hex-3-yne-2, 5 bis-tertiary-butyl peroxide (sold as Luperso 130) or its hexane analogue, di-tertiary butyl peroxide and dicumyl peroxide.
  • the initiator is generally used at a level of between about 0.005% and about 1%, based on the total weight of the polymer solution , and temperatures of about 150 to 220°C.
  • the ethylenically unsaturated carboxylic acid material preferably maleic anhydride
  • the aforesaid carboxylic acid material and free radical initiator are generally used in a weight percent ratio of ethylenically unsaturated carboxylic acid material to free radical initiator of about 1.0:1 to 30:1, preferably 3.0:1 to 6:1.
  • the initiator grafting is preferably carried out in an inert atmosphere, such as that obtained by nitrogen blanketing. While the grafting can be carried out in the presence of air, the yield of the desired graft polymer is generally thereby decreased as compared to grafting under an inert atmosphere substantially free of oxygen.
  • the grafting time will usually range from about 0.1 to 12 hours, preferably from about 0.5 to 6 hours, more preferably 0.5 to 3 hours.
  • the graft reaction will be usually carried out to at least approximately 4 times, preferably at least about 6 times the half-life of the free-radical initiator at the reaction temperature employed, e.g. with 2,5-dimethyl hex-3-yne-2, 5-bis(t-butyl peroxide) 2 hours at 160°C. and one hour at 170°C., etc.
  • the copolymer solution is first heated to grafting temperature and thereafter said unsaturated carboxylic acid material and initiator are added with agitation, although they could have been added prior to heating.
  • the excess acid material can be eliminated by an inert gas purge, e.g. nitrogen sparging.
  • the carboxylic acid material that is added is kept below its solubility limit in the polymer solution, e.g. below about 1 wt. %, preferably below 0.4 wt. % or less, of free maleic anhydride based on the total weight of polymer-solvent solution, e.g. ethylene copolymer mineral lubricating oil solution.
  • Continuous or periodic addition of the carboxylic acid material along with an appropriate portion of initiator, during the course of the reaction can be utilized to maintain the carboxylic acid below its solubility limits, while still obtaining the desired degree of total grafting.
  • the maleic anhydride or other carboxylic acid material used may be grafted onto both the polymer and the solvent for the reaction.
  • Many solvents such as dichlorobenzene are relatively inert and may be only slightly grafted, while mineral oil will tend to be more grafted.
  • the exact split of graft between the substrates present depends upon the polymer and its reactivity, the reactivity and type of solvent, the concentration of the polymer in the solvent, and also upon the maintenance of the carboxylic acid material in solution during the course of the reaction and minimizing the presence of dispersed, but undissolved acid, e.g. the maleic anhydride.
  • the undissolved acid material appears to have an increased tendency to react to form oil insoluble materials as opposed to dissolved acid material.
  • the split between grafted solvent and grafted polymer may be measured empirically from the infrared analyses of the product dialyzed into solvent and polymer fractions.
  • the grafting is preferably carried out in a mineral lubricating oil which need not be removed after the grafting step but can be used as the solvent in the subsequent reaction of the graft polymer with the amine material and as a solvent for the end product to form the lubricating additive concentrate.
  • the oil having attached, grafted carboxyl groups, when reacted with the amine material will also be converted to the corresponding derivatives.
  • the solution grafting step when carried out in the presence of a high temperature decomposable peroxide can be accomplished without substantial degradation of the chain length (molecular weight) of the ethylene containing polymer.
  • the amine component which may be reacted with the grafted ethylene copolymer will generally have two or more reactive amine groups selected from primary and secondary amine groups, preferably primary amine groups.
  • Preferred amines are aliphatic saturated amines, including those of the general formulae: wherein R IV , R′, R ⁇ and R′′′ are independently selected from the group consisting of hydrogen; C1 to C25 straight or branched chain alkyl radicals; C1 to C12 alkoxy C2 to C6 alkylene radicals; C2 to C12 hydroxy amino alkylene radicals; and C1 to C12 alkyl­amino C2 to C6 alkylene radicals; and wherein R ⁇ and R′′′ can additionally comprise a moiety of the formula wherein R′ is as defined above, and wherein each s and s′ can be the same or a different number of from 2 to 6, preferably 2 to 4; and t and t′ can be the same or dif­ferent and are each numbers of typically from 0 to 10, preferably about 2 to 7, most preferably about 3 to 7, with the proviso that t + t′ is not greater than 10.
  • R IV , R′, R ⁇ , R′′′, (s), (s′), (t) and (t′) be selected in a manner sufficient to provide the compounds of formula Ia with typically at least two primary amino groups. This can be achieved by selecting at least one of said R IV , R ⁇ , or R′′′ groups to be hydrogen or by letting (t) in formula Ia be at least one when R′′′ is H or when the (Ib) moiety possesses a primary a amino group.
  • Non-limiting examples of suitable amine compounds include: 1,2-diaminoethane; 1,3-diaminopropane; 1,4-diamino­butane; 1,6-diaminohexane; polyethylene amines such as diethylene triamine; triethylene tetramine; tetraethylene pentamine; polypropylene amines such as 1,2-propylene diamine; di-(1,2-propylene) triamine; di-(1,3-propylene) triamine; N,N-dimethyl-1, 3-diaminopropane; N,N-di-(2-amino­ethyl) ethylene diamine; N,N-di(2-hydroxyethyl)-1,3-­propylene diamine; N-dodecyl-1,3propane diamine; and mixtures thereof.
  • amine compounds include: alicyclic diamines such as 1,4-di(aminoethyl) cyclohexane, and N-aminoalkyl piperazines of the general formula: wherein p1 and p2 are the same or different and are each integers of from 1 to 4, and n1, n2 and n3 are the same or different and are each integers of from 1 to 3.
  • one process for preparing alkylene amines involves the reaction of an alkylene dihalide (such as ethylene dichloride or propylene dichloride) with ammonia, which results in a complex mixture of alkylene amines wherein pairs of nitrogens are joined by alkylene groups, forming such compounds as diethylene triamine, triethylenetetramine, tetraethylene pentamine and corresponding piperazines.
  • alkylene dihalide such as ethylene dichloride or propylene dichloride
  • ammonia such as ethylene triamine, triethylenetetramine, tetraethylene pentamine and corresponding piperazines.
  • Low cost poly(ethyleneamine) compounds averaging about 5 to 7 nitrogen atoms per molecule are available commercially under trade names such as "Polyamine H", “Polyamine 400", “Dow Polyamine E-100", etc.
  • Useful amines also include polyoxyalkylene polyamines such as those of the formulae: NH2-alkylene O-alkylene NH2 (III) where m has a value of about 3 to 70 and preferably 10 to 35; and R V alkylene O-alkylene NH2) a (IV) where n has a value of about 1 to 40, with the provision that the sum of all the n's is from about 3 to about 70, and preferably from about 6 to about 35, and R V is a substituted saturated hydrocarbon radical of up to 10 carbon atoms, wherein the number of substituents on the R V group is from 3 to 6, and "a" is a number from 3 to 6 which represents the number of substituents on R V .
  • the alkylene groups in either formula (III) or (IV) may be straight or branched chains containing about 2 to 7, and preferably about 2 to 4 carbon atoms.
  • Particularly preferred polyamine compounds are the polyoxyalkylene polyamines of formulae III and IV, and the alkylene polyamines represented by the formula H -alkylene - H (V) wherein x is an integer of about 1 to 10, preferably about 2 to 7, and the alkylene radical is a straight or branched chain alkylene radical having 2 to 7, preferably about 2 to 4 carbon atoms.
  • alkylene polyamines of formula (V) examples include methylene amines, ethylene amines, butylene amines, propylene amines, pentylene amines, hexylene amines, heptylene amines, octylene amines, other polymethylene amines, the cyclic and higher homologs of these amines such as the piperazines, the amino-alkyl-substituted piperazines, etc.
  • amines include, for example, ethylene diamine, diethylene triamine, triethylene tetramine, propylene diamine, di(-heptamethylene)triamine, tripropylene tetramine, tetraethylene pentamine, trimethylene diamine, pentaethylene hexamine, di(trimethylene)triamine, 2-heptyl-3-(2-aminopropyl)-­imidazoline, 4-methylimidazoline, 1,3-bis-(2-aminopropyl)-­imidazoline, pyrimidine, 1-(2-aminopropyl)piperazine, 1,4-bis(2-aminoethyl)piperazine, N,N′-dimethyaminopropyl amine, N,N′-dioctylethyl amine, N-octyl-N′-methylethylene diamine, 2-methyl-1-(2aminobutyl)piperazine, etc.
  • Other higher homologs which may be
  • ethylene amines which are particularly useful are described, for example, in the Encyclopedia of Chemical Technology under the heading of "Ethylene Amines” (Kirk and Othmer), Volume 5, pgs. 898-905; Interscience Publishers, New York (1950), incorporated herein by reference. These compounds are prepared by the reaction of an alkylene chloride with ammonia. This results in the production of a complex mixture of alkylene amines, including cyclic condensation products such as piperazines. While mixtures of these amines may be used for purposes of this invention, it is obvious that pure alkylene amines may be used with complete satisfaction.
  • the polyoxyalkylene polyamines of formulae III and IV may have average molecular weights ranging from about 200 to about 4000 and preferably from about 400 to about 2000.
  • the preferred polyoxyalkylene polyamines include the polyoxyethylene and the polyoxypropylene diamines and the polyoxypropylene triamines having average molecular weights ranging from about 200 to 2000.
  • the polyoxyalkylene polyamines are commercially available and may be obtained, for example, from the Jefferson Chemical Company, Inc. under the trade name "Jeffamines D-230, D-400, D-1000, D-2000, T-403 ⁇ , etc.
  • the grafted ethylene copolymer is reacted with a polyol instead of with a polyamine.
  • Suitable polyol compounds which can be used include aliphatic polyhydric alcohols containing up to about 100 carbon atoms and about 2 to about 10 hydroxyl groups. These alcohols can be quite diverse in structure and chemical composition, for example, they can be substituted or unsubstituted, hindered or unhindered, branched chain or straight chain, etc. as desired.
  • Typical alcohols are alkylene glycols such as ethylene glycol, propylene glycol, trimethylene glycol, butylene glycol, and polyglycols such as diethylene glycol, triethylene glycol, tetraethylene glycol, dipropylene glycol, tripropylene glycol, dibutylene glycol, tributylene glycol, and other alkylene glycols and polyalkylene glycols in which the alkylene radical contains from two to about eight carbon atoms.
  • alkylene glycols such as ethylene glycol, propylene glycol, trimethylene glycol, butylene glycol
  • polyglycols such as diethylene glycol, triethylene glycol, tetraethylene glycol, dipropylene glycol, tripropylene glycol, dibutylene glycol, tributylene glycol, and other alkylene glycols and polyalkylene glycols in which the alkylene radical contains from two to about eight carbon atoms.
  • polyhydric alcohols include glycerol, monomethyl ether of glycerol, pentaerythritol, dipent­aerythritol, tripentaerythritol, 9,10-dihydroxystearic acid, the ethyl ester of 9,10-dihydroxystearic acid, 3-chloro-1,2-propanediol, 1,2-butanediol, 1,4-butanediol, 2,3-hexanediol, pinacol, tetrahydroxy pentane, erythritol, arabitol, sorbitol, mannitol, 1,2-cyclohexanediol, 1,4-cyclohexanediol, 1,4-(2-hydroxyethyl)-cyclohexane, 1,4-dihydroxy-2-nitrobutane, 1,4-di-(2-hydroxyethyl)-benzene, and the carbohydrates
  • alkane polyols which contain ether groups such as polyethylene oxide repeating units, as well as those polyhydric alcohols containing at least three hydroxyl groups, at least one of which has been esterified with a mono-carboxylic acid having from eight to about 30 carbon atoms such as octanoic acid, oleic acid, stearic acid, linoleic acid, dodecanoic acid, or tall oil acid.
  • Examples of such partially esterified polyhydric alcohols are the mono-oleate of sorbitol, the mono-oleate of glycerol, the monostearate of glycerol, the di-stearate of sorbitol, and the di-dodecanoate of erythritol.
  • a preferred class of aliphatic alcohols are those containing up to 20 carbon atoms, and especially those containing three to 15 carbon atoms.
  • This class of alcohols includes glycerol, erythritol, pentaerythritol, dipentaerythritol, tripentaerythritol, gluconic acid, glyceraldehyde, glucose, arabinose, 1,7-heptanediol, 2,4-heptanediol, 1,2,3-hexanetriol, 1,2,4-hexanetriol, 1,2,5-hexanetriol, 2,3,4-hexanetriol, 1,2,3-butanetriol, 1,2,4-butanetriol, 2,2,6,6-tetrakis(hydroxymethyl)-­cyclohexanol, 1,10-decanediol, and the like.
  • polyhydric alcohols are the polyhydric alkanols containing three to 15, especially three to six carbon atoms and having at least three hydroxyl groups.
  • Such alcohols are exemplified in the above specifically identified alcohols and are represented by glycerol, erythritol, pentaerythritol, mannitol, sorbitol, 1,2,4-hexanetriol, and tetrahydroxy pentane and the like.
  • the poly-n-butene substituted dicarboxylic acid material which is used to make the multifunctional viscosity index improver of the instant invention includes the reaction product of poly-n-butene with (i) monounsaturated C4 to C10 dicarboxylic acid wherein (a) the carboxyl groups are vicinyl, i.e., located on adjacent carbon atoms, and (b) at least one, preferably both, of said adjacent carbon atoms are part of said mono unsaturation; or with (ii) derivatives of (i) such as anhydrides or C1 to C5 alcohol derived mono- or diesters of (i).
  • the monounsaturation of the dicarboxylic acid, anhydride, or ester becomes saturated.
  • maleic anhydride becomes a poly-n-butene substituted succinic anhydride.
  • 0.7 to about 4.0 e.g., 0.7 to 2.6
  • 1.0 to about 2.0 preferably from about 1.0 to about 2.0, and most preferably from about 1.1 to about 1.7 moles of said unsaturated C4 to C10 dicarboxylic acid, anhydride or ester are charged to the reactor per mole of polynormalbutene charged.
  • the poly-n-butene substituted dicarboxylic acid material will contain unreacted poly-n-butene.
  • the unreacted poly-n-butene is typically not removed from the reaction mixture (because such removal is difficult and would be commercially infeasible) and the product mixture, stripped of any unreacted monounsaturated C4 to C10 dicarboxylic acid, anhydride, or ester is employed for further reaction with the amine as described hereinafter.
  • Characterization of the average number of moles of dicarboxylic acid, anhydride, or ester, which have reacted per mole of poly-n-butene charged to the reaction (whether it has undergone reaction or not) is defined herein as functionality. Said functionality is based upon (i) determination of the saponification number of the resulting product mixture using potassium hydroxide; and (ii) the (ii) number average molecular weight of the poly-n-butene charged, using techniques well known in the art. Functionality is defined solely with reference to the resulting product mixture. Although the amount of said reacted poly-n-butene contained in the resulting product mixture can be subsequently modified, i.e. increased or decreased by techniques known in the art, such modifications do not alter functionality as defined above.
  • poly-n-butene substituted dicarboxylic acid material is intended to refer to the product mixture whether it has undergone such modification of not.
  • the functionality of the poly-n-butene substituted dicarboxylic acid material will be typically at least about 0.5, preferably at least about 0.8, and most preferably at least about 0.9, and will vary typically from about 0.5 to about 2.8 (e.g., 0.6 to 2), preferably from about 0.8 to about 1.4, and most preferably from about 0.9 to about 1.3.
  • the ethylenically unsaturated dicarboxylic acid material i.e., acid, anhydride or ester
  • a n-butene polymer will usually have number average molecular weights ( M n ) within the range of about 300 to about 3,000, preferably between about 400 and 2,000.
  • M n number average molecular weights
  • the n-butene polymers are derived from n-butene monomers. Generally, these n-butene polymers are derived from mixtures of n-butene-1 and n-butene-2 (both cis and trans) monomers.
  • such monomer mixtures contain from about 40-90 wt.% n-butene-1 and from about 10-50 wt.% n-butene-2 monomers, preferably from about 50-90 wt.% n-butene-1 and from about 10-50 wt.% n-butene-2 monomers. These monomer mixtures may also contain minor amounts, i.e., below about 5 wt% of isobutene monomers.
  • the isobutene monomers is, however, present merely as an impurity or byproduct resulting from the processes used to produce the n-butene-1 and n-butene-2 monomers. It is desirable to minimize the amount of isobutene monomer present in the monomer mixture.
  • poly-n-butene or n-butene polymer refers to a polymer derived from a mixture containing about 95-100 wt.% n-butene-1 and n-butene-2 monomers as described above, and from 0 to about 5 wt. % of isobutene monomer.
  • n-butene polymer Processes for reacting the n-butene polymer with the C4-C10 unsaturated dicarboxylic acid, anhydride or ester are known in the art.
  • the n-butene polymer and the dicarboxylic acid material may be simply heated together as disclosed in U.S. Pat. Nos. 3,361,673 and 3,401,118 to cause a thermal "ene" reaction to take place.
  • the n-butene polymer can be first halogenated, for example, chlorinated or brominated to about 1 to 8, preferably 3 to 7 wt.
  • % chlorine or bromine based on the weight of polymer, by passing the chlorine or bromine through the polynormalbutene at a temperature of 60 to 160°C, e.g., 110. to 130°C, for about 0.5 to 10, preferably 1 to 7 hours.
  • the halogenated polymer may then be reacted with sufficient unsaturated acid or anhydride at 100 to 250°C, usually about 180 to 235°C., for about 0.5 to 10 hours, e.g. 3 to 8 hours.
  • Processes of this general type are taught, inter alia, in U.S. Patents 3,087,436; 3,172,892; 3,272,746; and EP-A-0264247.
  • the poly-n-butene and the unsaturated acid material are mixed and heated while adding chlorine to the hot material.
  • Processes of this type are disclosed in U.S. Patents 3,215,707; 3,231,587; 3,912,764; 4,110,349; 4,234,435; and in U.K. 1,440,219, all of which are incorporated herein by reference.
  • halogen about 65 to 95 wt. % of the poly-n-butene, will normally react with the dicarboxylic acid material.
  • the preferred poly-n-butene substituted dicarboxylic acid material is poly-n-butene succinic anhydride or acid, preferably the anhydride.
  • the grafted ethylene copolymer preferably in solution generally equal to about 5 to 30 wt. %, preferably 10 to 20 wt. % polymer, can be readily reacted with a mixture of polyamine or polyol and poly-n-butene substituted dicarboxylic acid material by heating said mixture at a temperature of from about 100°C to 250°C, preferably from 150° to 200°C, for from 0.1 to 10 hours, usually about 0.5 to about 3 hours.
  • the heating is preferably carried out to favor, in the case of polyamines, formation of imides rather than amides and salts.
  • imide formation will give a lower viscosity of the reaction mixture than amide formation and particularly lower than salt formation.
  • the amount of polyamine used is an amount which is effective to provide from about 0.5 to about 1.5 equivalents, preferably from about 0.8 to about 1.2 equivalents, and more preferably from about 0.9 to about 1.0 equivalents of primary amine per equivalent of acid of the grafted dicarboxylic acid moiety e.g., succinic anhydride.
  • the amount of poly-n-butene substituted dicarboxylic acid material utilized is an amount which is effective to prevent cross-linking or excessive chain-extenion of the grafted ethylene copolymer during amination/imidation thereof. Generally, this amount is from about 1 to about 4, preferably about 1.5 to 3, most preferably about 2, mole equivalents of said poly-n-butene substituted dicarboxylic acid material per mole of said dicarboxylic acid moiety content in the grafted ethylene copolymer.
  • adduct if pre-reacted amine and poly-n-butene substituted dicarboxylic acid material adduct, as described hereinafter, is used, sufficient adduct is used to provide about 1 to 2 reactive, e.g., primary, amine groups per dicarboxylic acid moiety in the grafted ethylene copolymer, depending upon whether primarily imides or amides are formed. Usually, 1 to 2 moles of said adduct are used per molar amount of said dicarboxylic acid moieties in the grafted copolymer.
  • the polyamine and the poly-n-butene substituted dicarboxylic acid material may be pre-reacted to form an amine-acid adduct, and this adduct may then be reacted with the grafted ethylene copolymer.
  • the acid moiety of the poly-n-butene substituted dicarboxylic acid material is generally attached to the polyamine moiety through salt, imide, amide, amidine, or other linkages formed with one reactive, e.g., primary, amine group of said polyamine so that another reactive, e.g., primary, amine group of the polyamine is still available for reaction with the acid moieties of the grafted ethylene copolymer.
  • these adducts are made by condensing the poly-n-butene substituted dicarboxylic material, preferably a succinic acid or anhydride with a polyamine such as those described above under "The Amines".
  • dicarboxylic acid polyamine adduct by reaction of polyamine with poly-n-butene succinic anhydride prepared from the reaction of a poly-n-butene or chlorinated polynormalbutene and maleic anhydride, etc. is known in the art, as seen in U.S. Pat. No. 3,272,746.
  • Reaction in the case of a polyamine, preferably amination and/or imidation of the poly-n-butene substituted dicarboxylic acid material can be done as a solution reaction with said dicarboxylic acid material, preferably poly-n-butene succinic anhydride, dissolved in a solvent such as mineral oil, to which the other reactant is added.
  • the formation of the adducts in high yield can be effected by adding from about 0.5 to 3.3 preferably about 0.7 to 1.3, most preferably about 1 molar proportion of the alkylene polyamine per molar proportion of poly-n-butene succinic anhydride to said solution and heating the mixture at 140°C to 175°C or higher until the appropriate amount of water of reaction is evolved.
  • the mineral oil solvent is adjusted so that it constitutes 50% by weight of the final acyl nitrogen compound solution.
  • Another, and generally preferred, method of making the multi-functional viscosity index improvers of the instant invention is a sequential reaction process comprising (i) forming the grafted ethylene copolymer, (ii) adding to said grafted ethylene copolymer the poly-n-butene substituted dicarboxylic acid material so as to form a mixture of said grafted ethylene copolymer and said poly-n-butene substituted dicarboxylic acid material, and (iii) reacting this mixture with the polyamine or polyol.
  • a minor amount, e.g. 0.001 up to 50 wt. %, preferably 0.005 to 25 wt. %, based on the weight of the total composition, of the oil-soluble functionalized graft ethylene copolymers produced in accordance with this invention can be incorporated into a major amount of an oleaginous material, such as lubricating oil or hydrocarbon fuel, depending upon whether one is forming finished products or additives concentrates.
  • an oleaginous material such as lubricating oil or hydrocarbon fuel
  • the nitrogen-containing or ester-containing grafted polymer concentrations are usually within the range of about 0.01 to 10 wt. %, e.g. 0.1 to 6.0 wt.
  • the lubricating oils to which the products of this invention can be added include not only hydrocarbon oil derived from petroleum, but also include synthetic lubricating oils such as esters of dibasic acids; complex esters made by esterification of monobasic acids, polyglycols, dibasic acids and alcohols; polyolefin oils, etc.
  • the multi-functional viscosity index improvers of the instant invention may be utilized in a concentrate form, e.g., from about 5 wt. % up to about 50 wt. %, preferably 7 to 25 wt. %, in oil, e.g., mineral lubricating oil, for ease of handling, and may be prepared in this form by carrying out the reaction of the invention in oil as previously discussed.
  • oil e.g., mineral lubricating oil
  • compositions produced in accordance with the present invention have been found to be particularly useful as fuel and lubricating oil additives.
  • compositions of this invention are used in normally liquid petroleum fuels, such as middle distillates boiling from about 65° to 430°F. including kerosene, diesel fuels, home heating fuel oil, jet fuels, etc.
  • a concentration of the additive in the fuel in the range of typically from 0.001 wt. % to 0.5 wt. %, preferably 0.005 wt. % to 0.2 wt. %, based on the total weight of the composition, will usually be employed.
  • These additives can contribute fuel stability as well as dispersant activity and/or varnish control behavior to the fuel.
  • the compounds of this invention find their primary utility, however, in lubricating oil compositions, which employ a base oil in which the additives are dissolved or dispersed.
  • base oils may be natural or synthetic.
  • base oils suitable for use in preparing the lubricating compositions of the present invention include those conventionally employed as crankcase lubricating oils for spark-ignited and compression-ignited internal combustion engines, such as automobile and truck engines, marine and railroad diesel engines, and the like.
  • Advantageous results are also achieved by employing the additives of the present invention in base oils conventionally employed in and/or adapted for use as power transmitting fluids such as automatic transmission fluids, tractor fluids, universal tractor fluids and hydraulic fluids, heavy duty hydraulic fluids, power steering fluids and the like.
  • Gear lubricants, industrial oils, pump oils and other lubricating oil compositions can also benefit from the incorporation therein of the additives of the present invention.
  • the additives of the present invention may be suitably incorporated into synthetic base oils such as alkyl esters of dicarboxylic acids, polyglycols and alcohols; polyalpha-olefins, polybutenes, alkyl benzenes, organic esters of phosphoric acids, polysilicone oils, etc. selected type of lubricating oil composition can be included as desired.
  • the additives of this invention are oil-soluble, dissolvable in oil with the aid of a suitable solvent, or are stably dispersible materials.
  • Oil-soluble, dissolvable, or stably dispersible does not necessarily indicate that the materials are soluble, dissolvable, miscible, or capable of being suspended in oil in all proportions. It does mean, however, that the additives, for instance, are soluble or stably dispersible in oil to an extent sufficient to exert their intended effect in the environment in which the oil is employed.
  • the additional incorporation of other additives may also permit incorporation of higher levels of a particular polymer adduct hereof, if desired.
  • any effective amount of these additives can be incorporated into the fully formulated lubricating oil composition, it is contemplated that such effective amount be sufficient to provide said lube oil composition with an amount of the additive of typically from 0.01 to about 10, e.g., 0.1 to 6.0, and preferably from 0.25 to 3.0 wt. %, based on the weight of said composition.
  • the additives of the present invention can be incorporated into the lubricating oil in any convenient way.
  • they can be added directly to the oil by dispersing, or dissolving the same in the oil at the desired level of concentration, typically with the aid of a suitable solvent such as toluene, cyclohexane, or tetrahydrofuran.
  • a suitable solvent such as toluene, cyclohexane, or tetrahydrofuran.
  • Such blending can occur at room temperature or elevated.
  • Natural base oils include mineral lubricating oils which may vary widely as to their crude source, e.g., whether paraffinic, naphthenic, mixed, paraffinic-­naphthenic, and the like; as well as to their formation, e.g., distillation range, straight run or cracked, hydrofined, solvent extracted and the like.
  • the natural lubricating oil base stocks which can be used in the compositions of this invention may be straight mineral lubricating oil or distillates derived from paraffinic, naphthenic, asphaltic, or mixed base crudes, or, if desired, various blends oils may be employed as well as residuals, particularly those from which asphaltic constituents have been removed.
  • the oils may be refined by conventional methods using acid, alkali, and/or clay or other agents such as aluminum chloride, or they may be extracted oils produced, for example, by solvent extraction with solvents of the type of phenol, sulfur dioxide, furfural, dichlorodiethyl ether, nitrobenzene, crotonaldehyde, etc.
  • the lubricating oil base stock conveniently has a viscosity of typically about 2.5 to about 12, and preferably about 2.5 to about 9 cSt. at 100°C.
  • the additives of the present invention can be employed in a lubricating oil composition which comprises lubricating oil, typically in a major amount, and the additive, typically in a minor amount, which is effective to impart enhanced dispersancy relative to the absence of the additive.
  • Additional conventional additives selected to meet the particular requirements of a temperatures. In this form the additive per se is thus being utilized as a 100% active ingredient form which can l added to the oil or fuel formulation by the purchaser.
  • these additives may be blended with suitable oil-soluble solvent and base oil to form concentrate, which may then be blended with a lubricating oil base stock to obtain the final formulation. Concentrates will typically contain from about 2 to 80 wt. %, by weight of the additive, and preferably from about 5 to 40% by weight of the additive.
  • the lubricating oil base stock for the additive of the present invention typically is adapted to perform selected function by the incorporation of additives therein to form lubricating oil compositions (i.e., formulations).
  • Representative additives typically present in such formulations include other viscosity modifiers, corrosion inhibitors, oxidation inhibitors, friction modifiers, other dispersants, anti-foaming agents, anti-wear agents, pour point depressants, detergents, rust inhibitors and the like.
  • Viscosity modifiers impart high and low temperature operability to the lubricating oil and permit it to remain shear stable at elevated temperatures and also exhibit acceptable viscosity or fluidity at low temper­atures.
  • These viscosity modifiers are generally high molecular weight hydrocarbon polymers including polyesters.
  • the viscosity modifiers may also be derivatized to include other properties or functions, such as the addition of dispersancy properties.
  • oil soluble viscosity modifying polymers will generally have weight average molecular weights of from about 10,000 to 1,000,000, preferably 20,000 to 500,000, as determined by gel permeation chromatography or light scattering methods.
  • suitable viscosity modifiers are any of the types known to the art including polyisobutylene, copolymers of ethylene and propylene, polymethacrylates, methacrylate copolymers, copolymers of an unsaturated dicarboxylic acid and vinyl compound, interpolymers of styrene and acrylic esters, and partially hydrogenated copolymers of styrene/isoprene, styrene/butadiene, and isoprene/butadiene, as well as the partially hydrogenated homopolymers of butadiene and isoprene.
  • Corrosion inhibitors also known as anti-corrosive agents, reduce the degradation of the metallic parts contacted by the lubricating oil composition.
  • Illustrative of corrosion inhibitors are phosphosulfurized hydrocarbons and the products obtained by reaction of a phosphosul­ furized hydrocarbon with an alkaline earth metal oxide or hydroxide, preferably in the presence of an alkylated phenol or of an alkylphenol thioester, and also preferably in the presence of an alkylated phenol or of an alkylphenol thioester, and also preferably in the presence of carbon dioxide.
  • Phosphosulfurized hydrocarbons are prepared by reacting a suitable hydrocarbon such as a terpene, a heavy petroleum fraction of a C2 to C6 olefin polymer such as polyisobutylene, with from 5 to 30 wt. % of a sulfide of phosphorus for 1/2 to 15 hours, at temperature in the range of about 66 to about 316°C.
  • a suitable hydrocarbon such as a terpene, a heavy petroleum fraction of a C2 to C6 olefin polymer such as polyisobutylene
  • Neutralization of the phosphosulfurized hydrocarbon may be effected in the manner taught in U.S. Patent No. 1,969,324.
  • Oxidation inhibitors reduce the tendency of mineral oils to deteriorate in service which deterioration can be evidenced by the products of oxidation such as sludge and varnish-like deposits on the metal surfaces, and by viscosity growth.
  • oxidation inhibitors include alkaline earth metal salts of alkylphenolthioesters having preferably C5 to C12 alkyl side chains, e.g., calcium nonylphenol sulfide, barium toctylphenyl sulfide, dioctylphenylamine, phenylalphanaphthylamine, phospho-sulfurized or sulfurized hydrocarbons, etc.
  • oxidation inhibitors or antioxidants useful in this invention comprise oil-soluble copper compounds.
  • the copper may be blended into the oil as any suitable oil soluble copper compound.
  • oil soluble it is meant that the compound is oil soluble under normal blending conditions in the oil or additive package.
  • the copper compound may be in the cuprous or cupric form.
  • the copper may be in the form of the copper dihydrocarbyl thio- or dithio-phosphates.
  • the copper may be added as the copper salt of a synthetic or natural carboxylic acid.
  • Examples of same thus include C10 to C18 fatty acids, such as stearic or palmitic acid, but unsaturated acids such as oleic or branched carboxylic acids such as napthenic acids of molecular weights of from about 200 to 500, or synthetic carboxylic acids, are preferred, because of the improved handling and solubility properties of the resulting copper carboxylates.
  • oil-soluble copper dithiocarbamates of the general formula (R20R21,NCSS) z Cu (where z is 1 or 2, and R20 and R21, are the same or different hydrocarbyl radicals containing from 1 to 18, and preferably 2 to 12, carbon atoms, and including radicals such as alkyl, alkenyl, aryl, aralkyl, alkaryl and cycloaliphatic radicals.
  • R20 and R21 groups are alkyl groups of from 2 to 8 carbon atoms.
  • the radicals may, for example, be ethyl, n-propyl, i-propyl, n-butyl, i-butyl, sec-butyl, amyl, n-hexyl, i-hexyl, n-heptyl, n-octyl, decyl, dodecyl, octadecyl, 2-ethylhexyl, phenyl, butylphenyl, cyclohexyl, methylcyclopentyl, propenyl, butenyl, etc.
  • the total number of carbon atoms i.e., R20 and R21, will generally be about 5 or greater. Copper sulphonates, phenates, and acetylacetonates may also be used.
  • Exemplary of useful copper compounds are copper Cu I and/or Cu II salts of alkenyl succinic acids or anhydrides.
  • the salts themselves may be basic, neutral or acidic. They may be formed by reacting (a) polyalkylene succinimides (having polymer groups of M n of 700 to 5,000) derived from polyalkylene-polyamines, which have at least one free carboxylic acid group, with (b) a reactive metal compound.
  • Suitable reactive metal compounds include those such as cupric or cuprous hydroxides, oxides, acetates, borates, and carbonates or basic copper carbonate.
  • these metal salts are Cu salts of polyisobutenyl succinic anhydride, and Cu salts of polyisobutenyl succinic acid.
  • the selected metal employed is its divalent form, e.g., Cu+2.
  • the preferred substrates are polyalkenyl succinic acids in which the alkenyl group has a molecular weight greater than about 700.
  • the alkenyl group desirably has a M n from about 900 to 1,400, and up to 2,500, with a M n of about 950 being most preferred.
  • polyisobutylene succinic anhydride or acid is especially preferred.
  • These materials may desirably be dissolved in a solvent, such as a mineral oil, and heated in the presence of a water solution (or slurry) of the metal bearing material. Heating may take place between 70°C and about 200°C. Temperatures of 100°C to 140°C are entirely adequate. It may be necessary, depending upon the salt produced, not to allow the reaction to remain at a temperature above about 140°C for an extended period of time, e.g., longer than 5 hours, or decomposition of the salt may occur.
  • a solvent such as a mineral oil
  • the copper antioxidants e.g., Cu-polyisobutenyl succinic anhydride, Cu-oleate, or mixtures thereof
  • Cu-polyisobutenyl succinic anhydride e.g., Cu-polyisobutenyl succinic anhydride, Cu-oleate, or mixtures thereof
  • Friction modifiers serve to impart the proper friction characteristics to lubricating oil compositions such as automatic transmission fluids.
  • Dispersants maintain oil insolubles, resulting from oxidation during use, in suspension in the fluid thus preventing sludge flocculation and precipitation or deposition on metal parts.
  • Suitable dispersants include high molecular weight alkyl succinimides, the reaction product of oil-soluble polyisobutylene succinic anhydride with ethylene amines such as tetraethylene pentamine and borated salts thereof.
  • Pour point depressants otherwise known as lube oil flow improvers, lower the temperature at which the fluid will flow or can be poured.
  • Such additives are well known.
  • those additives which usefully optimize the low temperature fluidity of the fluid are C8-C18 dialkylfumarate vinyl acetate copolymers, polymethacrylates, and wax naphthalene.
  • Foam control can be provided by an antifoamant of the polysiloxane type, e.g., silicone oil and polydimethyl siloxane.
  • Anti-wear agents reduce wear of metal parts.
  • Representatives of conventional antiwear agents are zinc dialkyldithiophosphate and zinc diaryldithiosphate.
  • Detergents and metal rust inhibitors include the metal salts of sulphonic acids, alkyl phenols, sulfurized alkyl phenols, alkyl salicylates, naphthenates and other oil soluble mono- and dicarboxylic acids.
  • Highly basic (viz. overbased) metal sales such as highly basic alkaline earth metal sulfonates (especially Ca and Mg salts) are frequently used as detergents. Representative examples of such materials, and their methods of preparation, are found in EP-A-0208560.
  • compositions when containing these conventional additives are typically blended into the base oil in amounts which are effective to provide their normal attendant function.
  • Representative effective amounts of such additives are illustrated as follows:
  • additive concentrates comprising concentrated solutions or dispersions of the V.I.-dispersant (in concentrate amounts hereinabove described), together with one or more of said other additives (said concentrate when constituting an additive mixture being referred to herein as an additive package) whereby several additives can be added simultaneously to the base oil to form the lubricating oil composition. Dissolution of the additive concentrate into the lubricating oil may be facilitated by solvents and by mixing accompanied with mild heating, but this is not essential.
  • the concentrate or additive-package will typically be formulated to contain the V.I.-dispersant or multi-functional viscosity index improver additive and optional additional additives in proper amounts to provide the desired concentration in the final formulation when the additive-package is combined with a predetermined amount of base lubricant.
  • the products of the present invention can be added to small amounts of base oil or other compatible solvents along with other desirable additives to form additive-packages containing active ingredients in collective amounts of typically from about 2.5 to about 90%, and preferably from about 5 to about 75%, and most preferably from about 8 to about 50% by weight additives in the appropriate proportions with the remainder being base oil.
  • the final formulations may employ typically about 10 wt. % of the additive-package with the remainder being base oil.
  • weight percents expressed herein are based on active ingredient (a.i.) content of the additive, and/or upon the total weight of any additive-package, or formulation which will be the sum of the a.i. weight of each additive plus the weight of total oil or diluent.
  • PIBSA polyisobutenyl succinic anhydride
  • DETA diethylenetriamine
  • the Shear Stability Index (SSI) and thickening efficiency (T.E.) of the EPSA-PIBSA-DETA polymer are determined and the results are set forth in Table I.
  • the Shear Stability Index is determined in accordance with ASTM D3945.
  • the Shear Stability Index is an indication or measurement of the propensity of a polymer to degrade or breakdown to a lower molecular weight polymer upon exposure to shearing forces. The higher the SSI the more shear stable the polymer.
  • the thickening efficiency (T.E.) is defined as 2 divided by the number of grams of a polymer dissolved in a 100 gram blend of said polymer in a test oil, which is a solvent extracted neutral mineral lubricating oil having a viscosity of 6.04 CST at 100°C, a viscosity index of 105 and an ASTM pour point of -25°F, which will give a viscosity of 12.08 CST at 100°C.
  • the thickening efficiency is related to the number average molecular weight and is a more convenient, practical measurement.
  • a lubricating oil composition formulated to 10W40 specifications with a standard detergent inhibitor package and containing 12.52 weight % of the reaction product of Comparative Example 1 is prepared by adding said reaction product to said oil.
  • the CCS at -20°C in centipoise and the Kinematic Viscosity at 100°C in centistokes of this fully formulated lubricating oil composition is determined, and the results are set forth in Table I.
  • PNBSA poly-n-butene succinic anhydride
  • S100NLP base oil containing 50 weight % poly-n-butene succinic anhydride (PNBSA) (having poly-n-butene M n of about 905, a SAP number of 90.9, and about 22.7% unreacted poly-n-butene, with said poly-n-butene being derived from a monomer mixture containing 65 wt% n-butene-1, 32 wt.% n-butene-2, and 3 wt.% isobutene) in S100NLP base oil.
  • the resultant reaction mixture is mixed with nitrogen stripping for 15 minutes and 3.62 grams of diethylenetriamine (DETA) are added to this reaction mixture over a period of 6 minutes.
  • DETA diethylenetriamine
  • the reaction mixture is then stripped with nitrogen for 15 minutes. At the end of the strip, 2.05 grams of dodecylsuccinic anhydride are added to the system as capping
  • a lubricating oil composition formulated to 10W40 specifications with the standard detergent inhibitor package as used in Comparative Example 2 and containing 12.50 weight percent of the reaction product of Example 3 is prepared by adding said reaction product to said oil.
  • the CCS at -20°C in centipoise and the Kinematic Viscosity at 100°C in centistokes of this fully formulated lubricating oil composition are determined, and the results are set forth in Table I.
  • TABLE I COMPARATIVE EXAMPLE 2 EXAMPLE 4 T.E. 1.65 1.69 SSI 27.3% 28.5% K.V. in cSt at 100°C 15.07 14.71 CCS in centipoise at -20°C 3749 3255
  • Example 4 As illustrated by the data in Table 1 the oil formulation containing the multifunctional viscosity index improver of the instant invention (Example 4) exhibits a much lower CCS, and, therefore, better low temperature viscometric properties, than the oil formulation containing a multifunctional viscosity index improver falling outside the scope of the instant invention (Comparative Example 2).
EP89311572A 1988-11-14 1989-11-08 Additif à fonctions multiples d'amélioration de l'indice de viscosité Expired - Lifetime EP0369674B1 (fr)

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US8058355B2 (en) * 2004-10-06 2011-11-15 Eastman Chemical Company Modified chlorinated carboxylated polyolefins and their use as adhesion promoters
US8058354B2 (en) * 2001-02-09 2011-11-15 Eastman Chemical Company Modified carboxylated polyolefins and their use as adhesion promoters
CN110256632A (zh) * 2019-06-03 2019-09-20 中韩(武汉)石油化工有限公司 一种不含铬的高支化度聚烯烃树脂的制备方法

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EP0352070A1 (fr) * 1988-07-18 1990-01-24 Exxon Chemical Patents Inc. Agent multifonctionnel modifié modifiant l'indice de viscosité

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5567344A (en) * 1992-12-17 1996-10-22 Exxon Chemical Patents Inc. Gel-free dispersant additives useful in oleaginous compositions, derived from functionalized and grafted alpha-olefin polymers
US5578237A (en) * 1992-12-17 1996-11-26 Exxon Chemical Patents Inc. Gel-free α-olefin dispersant additives useful in oleaginous compositions
US5663129A (en) * 1992-12-17 1997-09-02 Exxon Chemical Patents Inc. Gel-free ethylene interpolymer dispersant additives useful in oleaginous compositions
US5747596A (en) * 1992-12-17 1998-05-05 Exxon Chemical Patents Inc. Gel-free alpha-olefin dispersant additives useful in oleaginous compositions
US5814715A (en) * 1992-12-17 1998-09-29 Exxon Chemical Patents Inc Amorphous olefin polymers, copolymers, methods of preparation and derivatives thereof
US6831115B2 (en) 2001-02-09 2004-12-14 Eastman Chemical Company UV-curable, non-chlorinated adhesion promoters
US7388039B2 (en) 2001-02-09 2008-06-17 Eastman Chemical Company UV-curable, non-chlorinated adhesion promoters
US8058354B2 (en) * 2001-02-09 2011-11-15 Eastman Chemical Company Modified carboxylated polyolefins and their use as adhesion promoters
US8058355B2 (en) * 2004-10-06 2011-11-15 Eastman Chemical Company Modified chlorinated carboxylated polyolefins and their use as adhesion promoters
CN110256632A (zh) * 2019-06-03 2019-09-20 中韩(武汉)石油化工有限公司 一种不含铬的高支化度聚烯烃树脂的制备方法

Also Published As

Publication number Publication date
SG50493G (en) 1993-06-25
JPH02238095A (ja) 1990-09-20
BR8905789A (pt) 1990-06-12
DE68902130D1 (de) 1992-08-20
EP0369674B1 (fr) 1992-07-15
AU629593B2 (en) 1992-10-08
CA2001656A1 (fr) 1990-05-14
ES2052026T3 (es) 1994-07-01
DE68902130T2 (de) 1993-02-11
AU4458189A (en) 1990-05-17

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