EP0366410A2 - Ceramic-metal composite body with friction welding joint and ceramic insert cast piston - Google Patents

Ceramic-metal composite body with friction welding joint and ceramic insert cast piston Download PDF

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Publication number
EP0366410A2
EP0366410A2 EP89310943A EP89310943A EP0366410A2 EP 0366410 A2 EP0366410 A2 EP 0366410A2 EP 89310943 A EP89310943 A EP 89310943A EP 89310943 A EP89310943 A EP 89310943A EP 0366410 A2 EP0366410 A2 EP 0366410A2
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EP
European Patent Office
Prior art keywords
ceramic
metal
crown
piston
friction welding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP89310943A
Other languages
German (de)
French (fr)
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EP0366410B1 (en
EP0366410A3 (en
Inventor
Tomio Suzuki
Hiroyuki Ohi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NGK Insulators Ltd
Original Assignee
NGK Insulators Ltd
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Filing date
Publication date
Priority claimed from JP63268818A external-priority patent/JPH063171B2/en
Priority claimed from JP26881988A external-priority patent/JPH02115556A/en
Application filed by NGK Insulators Ltd filed Critical NGK Insulators Ltd
Publication of EP0366410A2 publication Critical patent/EP0366410A2/en
Publication of EP0366410A3 publication Critical patent/EP0366410A3/en
Application granted granted Critical
Publication of EP0366410B1 publication Critical patent/EP0366410B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02FCYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F3/00Pistons 
    • F02F3/0015Multi-part pistons
    • F02F3/003Multi-part pistons the parts being connected by casting, brazing, welding or clamping
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02FCYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F3/00Pistons 
    • F02F3/10Pistons  having surface coverings
    • F02F3/12Pistons  having surface coverings on piston heads
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    • C04B37/00Joining burned ceramic articles with other burned ceramic articles or other articles by heating
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02FCYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
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    • F02F3/0015Multi-part pistons
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    • F02F2003/0061Multi-part pistons the parts being connected by casting, brazing, welding or clamping by welding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2201/00Metals
    • F05C2201/02Light metals
    • F05C2201/021Aluminium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2201/00Metals
    • F05C2201/04Heavy metals
    • F05C2201/0433Iron group; Ferrous alloys, e.g. steel
    • F05C2201/0448Steel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2251/00Material properties
    • F05C2251/04Thermal properties
    • F05C2251/042Expansivity

Definitions

  • This invention relates to a ceramic-metal friction welded composite body and a ceramic insert cast piston (cast-in bonded piston).
  • the articles of the invention are useful for heat-resistant and wear-resistant parts in engines and other industrial machines.
  • Ceramic joined pistons made of integrally joined ceramic and metal members by cast-in bonding have been known disclosed in, for example, Japanese Patent Laid-­open No. 59-101,566 and Japanese Utility Model Laid-open No. 62-200,147.
  • the ceramic joined piston disclosed in the Japanese Patent Laid-open No. 59-101,566 is made of a ceramic member and a metal member being integrally joined by cast-in bonding through a metallized layer coated on a surface of the ceramic member and a cushioning material joined to the metallized layer.
  • the ceramic joined piston disclosed in the Japanese Utility Model Laid-open No. 62-200,147 includes a ceramic member provided in a piston cavity and having an outer circumference which is formed with a groove or tapered diverging from an upper end to a bottom end of a piston, thereby preventing any dislodgment of the ceramic member.
  • this publication discloses a feature of metallizing the outer circumference of the ceramic member.
  • the joining force between the piston main body and the ceramic member is enhanced by a bond force of the metallized layer. Therefore, the metallized layers are formed in wide areas in order to endure stresses due to inertia forces, thermal deformations and the like of the piston. However, it is technically difficult to form the metallized layers uniformly in the wide areas, and which tend to increase the manufacturing cost. Moreover, as the inertia forces and the thermal deformations are supported only by the metallized layers, the reliability in strength is insufficient.
  • the ceramic joined piston disclosed in the Japanese Utility Model Laid-open No. 62-200,147 includes the ceramic member having the outer circumference formed with the groove or tapered to prevent the dislodgment of the ceramic member. Any sealing for preventing burnt gases from entering the joining surfaces is not considered. This is clear from the fact that in the embodiment of Fig. 5 in the Japanese Utility Model Laid-open No. 62-200,147, surfaces of the piston to be joined to the ceramic member are not subjected to any treatment.
  • a ceramic-­metal friction welded member including a ceramic member and a metal member according to the invention comprises an annular notch on an outer circumference of a surface of the ceramic member to be joined to the metal member, on which annular notch is joined the metal member by friction welding.
  • a first ceramic cast-in bonded piston including a crown made of a ceramic material and a piston main body made of an aluminum alloy surrounding the crown by cast-in bonding
  • the crown comprises an annular notch formed in an outer circumference of its surface to be in contact with the piston main body, on which annular notch is joined a metal annular member by friction welding.
  • a second ceramic cast-in bonded piston including a crown made of a ceramic material and a piston main body made of an aluminum alloy surrounding the crown by cast-in bonding
  • the crown comprises an annular member made of a metal different from aluminum member joined by friction welding to an outer circumference of a surface of the crown to be in contact with the piston main body.
  • the ceramic-metal friction welded member according to the invention is particularly preferable for producing a product including a metal member which is difficult to be directly joined to the ceramic member by friction welding.
  • the ceramic-metal friction welded member according to the invention is applicable to a ceramic cast-in bonded piston as above described and is applicable to an engine valve made of a metal member 20 and ceramic member 21 (Figs. 14a and 14b). Moreover, the ceramic-metal friction welded member according to the invention is also applicable to members having ceramic members 21 joined by friction welding to a rocker arm 24 for transmitting power for operating engine valves, push rods 25 and sliding portions of a tappet 26 (Fig. 14c), and to corrosion-resistant and heat-resistant equipment of industrial machines, for example, ceramic spindles, ceramic rotors and the like of oxide-resistant pumps.
  • the ceramic cast-in bonded piston is classified into two kinds as above described.
  • the first ceramic cast-in bonded piston has an annular notch in its outer circumference, to which notch is joined an annular member.
  • an annular member of a metal different from aluminum is joined to an outer circumference of a crown by friction welding.
  • the ceramic crown and the aluminum alloy piston main body are indirectly joined through the annular member, and joining surfaces between the ceramic crown and the piston main body respectively and the annular member are sealed so that sealing is very effective.
  • the ceramic crown is strongly joined to the aluminum alloy with a protrusion of the lower portion of the crown by shrinkage force caused in solidification in cooling process in aluminum alloy cast-in bonding.
  • the "friction welding” used herein is a joining method wherein after members to be joined are brought into contact with each other, one is moved relative to the other at contacting surfaces under a constant pressure to produce frictional heat by which the contacting surfaces are heated to a high temperature and metal material is caused to flow plastically by friction force and applied pressure, while both the materials are diffused each other to join the members.
  • this method has a limitation concerning configurations and sizes of the members to be joined, it has merits which other methods do not have.
  • the friction welding is very effective for joining members of different materials.
  • Ceramic materials superior in heat-resistance, thermal shock-resistance, adiabatic property and light weight is preferably used for the invention.
  • the ceramic member used in the invention is preferably one selected from a group consisting of silicon nitride, silicon carbide, sialon, zirconia, mullite and alumina.
  • Roughnesses of the ceramic members to be welded by the friction welding are preferably 0.05-1.0 ⁇ mRa. In the case that a flatness of the surface is controlled, a fired surface may be acceptable.
  • a metal hitherto impossible to be directly joined to a ceramic material by friction welding is effective, for example, Ag, Cu, Ti, Nb, Mo, W, Ni, Fe, Inconel, Incolloy and the like.
  • Other metals such as aluminum previously possible to be directly joined to ceramics by friction welding may of course be used. In this case, a friction-welded body more reliable in bond strength can be obtained.
  • the radial depth of the annular notch is preferably not more than 20% of a diameter of the ceramic member, more preferably not more than 10%. Moreover, the radial depth of the annular notch is preferably somewhat less than the inner diameter of the metal annular member. In other words, a clearance A (Fig. 2) at the annular notch between the ceramic member and a metal annular member is more than 1% of the inner diameter of the metal annular member.
  • a height t of the protrusion 4 formed by the annular notch (Fig. 2) should be determined in consideration of stresses required to the joined surfaces. The value t is preferably 3-10 mm for parts such as pistons subjected to the influence of heating.
  • the thickness (one half of difference of inner and outer diameters) in the circumferential directions is not particularly limited. However, it is preferably not more than 20% of the diameter of the ceramic member, more preferably not more than 10% for the reason that temperature distribution becomes uniform to produce less thermal stresses.
  • the ceramic crown is formed with an annular notch in an outer circumference of its surface to be in contact with the piston main body, to which annular notch is joined a metal annular member by friction welding and thereafter the crown is surrounded by the aluminum alloy by cast-in bonding.
  • the ceramic crown is provided with an annular member made of a metal different from aluminum welded thereto by friction welding and then the crown is surrounded by cast-in bonding to seal between the piston main body and the crown.
  • any one metal can be used such as titanium, cast iron, carbon steel, copper, stainless steels, aluminum alloys and nickel alloys. In view of heat-resistance and corrosion-resistance, titanium is preferable.
  • the annular member of titanium is joined to the aluminum by friction welding and then the aluminum of the joined member is joined to the ceramic member by friction welding.
  • the material of the annular member is preferably an aluminum alloy other than aluminum alloy die cast. In case of requiring stable bond strength, a high purity aluminum alloy is preferably used.
  • the width and thickness are not limited, the width X shown in Fig. 9 is preferably 0.2-2 mm, and the thickness Y is preferably not more than 10 mm. For example, if the thickness is 0.4 mm, a tensile strength not less than 13 kg/mm2 is preferably obtained at room temperature.
  • the burnt gas is sealed by a top ring so that the annular member is not needed to be joined to an aluminum alloy. Therefore, the processes for joining are advantageously eliminated to lower the manufacturing cost. Moreover, as the annular member and the aluminum alloy piston main body are not joined, the thermal expansion of the aluminum alloy does not adversely affect the joining surfaces between the ceramic material and the annular member so that the reliability of the joining surfaces is improved.
  • the annular member is made of Niresist iron, it is also possible to form a top ring groove in the Niresist iron.
  • surfaces of the friction welded annular member may be surface-treated so as to make possible to be joined with a molten aluminum alloy or if the annular member and the aluminum alloy are possible to be welded, after cast-in bonding without any surface treatment, the annular member and the aluminum alloy may be welded.
  • the electron beam welding is preferably used because of its less thermal influence onto the surroundings.
  • Fig. 2 schematically illustrates one embodiment of a ceramic-metal friction welded member according to the invention.
  • the friction welded member consists of a ceramic member 1 silicon nitride and a metal annular member 3 of titanium.
  • the ceramic member 1 is formed with an annular notch 2 on its outer circumference to be in opposition to the metal annular member 3.
  • the metal annular member 3 is joined to the annular notch of the ceramic member 1 by means of friction welding.
  • clearances A therebetween so that softened part of the metal annular member 3 plastically flows into the clearances A to restrain or clamp a protrusion 4 of the ceramic member 1 by means of thermal shrinkage fit or press-fitting action.
  • the value of the clearances A is preferably determined by assuming that one third of the softened volume of the metal annular member 3 flows into the clearance A in friction welding.
  • particularly good result can be obtained when the total of the clearances A is 0.2 mm to 1 mm.
  • Fig. 3 is a schematic sectional view illustrativelying another embodiment of the ceramic-metal friction welded member according to the invention.
  • a tensile test was effected at room temperature for testing tensile strength of the ceramic and metal friction welded members.
  • the friction welded member is subjected to annealing treatment within a temperature range to be used.
  • the friction welding is effected in an inert gas or vacuum because it can be effectively prevent any oxidation to mitigate any destruction of the ceramics due to its brittleness.
  • a ceramic crown 7 forming a top end of the piston in its entirety is cast-in bonded by an aluminum alloy member forming a piston main body.
  • the piston main body 5 and the ceramic crown 7 are joined by a force acting upon the protrusion 4 formed at a lower portion of the crown 7 owing to shrinkage of the aluminum alloy in cast-in bonding.
  • an annular member 13 is provided in the proximity of a top land 14 at outer circumference between the ceramic crown 7 and the piston main body 5. The annular member 13 serves to prevent burnt gases from entering a boundary of the ceramic crown 7 and the piston main body 5.
  • an aluminum ring 12 and a titanium ring 9 are joined by friction welding to form an annular member 13 integrally formed of aluminum and titanium.
  • This composite member 13 is then attached by friction welding to a surface of the crown member 7 at its outer circumference to be in opposition to the piston main body. Thereafter, the composite member 13 is joined to the aluminum alloy.
  • Crowns 7 made of silicon nitride having an outer diameter of 90 mm were prepared, which was formed with an annular notch 6 having a width of 3 mm and a depth of 3 mm in an outer circumference on a surface to be in opposition to a piston main body 5 as shown in Figs. 4a and 4b.
  • a titanium hollow cylinder 8 was then made, which had an inner diameter of 80 mm, an outer diameter of 90 mm and an axial length of 50 mm as shown in Fig. 4b. Then the crown 7 was fixed and the titanium hollow cylinder 8 was arranged in alignment with the crown 7 and rotated at a rotating speed of 800 rpm relative to the crown 7. The cylinder 8 was urged against the crown 7 with progressively increasing pressure to a maximum 3 kg/mm2 so that they were friction welded to obtain a ceramic and metal bonded member.
  • the titanium hollow cylinder 8 of the bonded member was worked on its outer circumference to obtain a titanium ring 9 having an axial length l of 4 mm as shown in Fig. 4c.
  • a surface of the ring 9 was then treated by alfin treatment (or alumelt treatment).
  • the thus obtained silicon nitride crown 7 having the ring 9 was arranged in a sand mold into which molten aluminum alloy was poured at about 700°C to obtain a ceramic cast-in bonded body.
  • the body was annealed at a temperature near to that at which the piston is used.
  • the body was machined to finish outer circumferences, annular grooves, piston pin holes and the like to complete a ceramic cast-in piston sealed by the titanium ring (Fig. 4d).
  • the metal member used for friction welding with the silicon nitride has been explained, it may be inexpensive cast iron for obtaining the similar performance and effect.
  • a silicon nitride crown 7 had a notch 6 having an angle of 70° as shown in Fig. 5a.
  • Other construc­tions and producing processes were similar to those in Example 1.
  • a thus obtained ceramic cast-in piston sealed by a titanium ring 9 was shown in Fig. 5b. Then joining surfaces 10 between the titanium ring 9 and piston main body 5 were welded by laser beams or electron beams.
  • the notch 6 of the silicon nitride crown 7 had an inclined surface merging with a round bottom of the annular notch.
  • Softened titanium in friction welding flowed into the bottom of the annular notch to enhance the prevention of dislodgment of the members.
  • the joining surfaces 10 were welded by the laser beams or electron beams, firm joining between the titanium ring 9 and the piston main body 5 was obtained to produce a high performance ceramic cast-in piston.
  • Joining surfaces of the titanium ring 9 facing to the aluminum alloy may be subjected to alfin or alumelt treatment to join with the aluminum alloy.
  • a silicon nitride crown 7 having an annular notch as shown in Fig. 6a was produced substantially in the same manner as in Example 1 with exception of sintered surfaces of the crown 7.
  • the piston main body was formed in its center with a deep hole 11 as shown in Fig. 6b.
  • a depth of the deep hole 11 was 7-10 mm deeper than a height G of a protrusion of the silicon nitride crown 7 in order to avoid an abutment of a bottom surface C of the protrusion against the bottom of the deep hole 11.
  • the piston main body 5 was then welded to a titanium ring 9 by means of friction welding. Thereafter, the titanium ring 9 on the piston main body 5 was worked so that its extending length became equal to a depth F of the annular notch on the outer circumference of the silicon nitride crown 7. A contacting surface of the aluminum alloy piston main body 5 to be in contact with a side surface of the silicon nitride crown 7 was worked to form clearances E of 0.2-1 mm. Thereafter, the crown 7 and the piston main body 5 integral with the titanium ring 9 were welded by friction welding as shown in Fig. 6c. In this case, the C portion of the crown 7 was fixed to the piston main body 5 by means of thermal shrinkage effect thereof.
  • the silicon nitride and aluminum alloy were friction-welded and the titanium ring 9 was softened by frictional heat with the crown 7 and bitten into the notch 6 of the crown 7 to improve the sealing effect at the portion D in conjunction with the thermal shrinkage fitting.
  • a ceramic cast-in bonded piston as shown in Fig. 7 was produced which was similar to that of Example 1 with exception that instead of the titanium ring 9, an annular member 13 consisting of an aluminum ring 12 and a titanium annular member 9 was used and the aluminum ring 12 was positioned on the side of the crown 7.
  • This piston included the aluminum ring 12 between the ceramic crown 7 and titanium ring 9.
  • the ceramic piston having higher bond strength could be obtained.
  • the aluminum ring 12 to use an aluminum higher impurity.
  • a 1050 (JIS) whose aluminum purity was 99.5% was used.
  • the ring 9 has been explained made of titanium in the Example, it may be cast iron, particularly preferably Niresist cast iron generally used as piston ring carriers.
  • a ceramic piston was produced, which was similar to that of Example 4 with exception that an annular member 13 consisting of a titanium ring 9 and an aluminum ring 12 positioned on an inner circumference of the titanium ring 9 as shown in Fig. 8. Different from the piston of Example 4, this piston included the aluminum member which did not expose to burnt gases because it was covered by titanium, thereby improving corrosion-resistance. Moreover, as aluminum was interposed between titanium and ceramic, it provided a high performance ceramic piston having high bond strength.
  • An aluminum ring 15 having an inner diameter of 84 mm, and outer diameter of 90 mm and a length of 10 mm and a titanium ring 16 having an inner diameter of 84 mm, an outer diameter of 90 mm and a length of 60 mm were produced as shown in Fig. 10.
  • the titanium ring 1 was fixed, on the other hand the aluminum ring 15 was rotated at a speed of 800 rpm relative to and urged against the titanium ring 16 with progressively increasing pressure to the maximum 6 kgf/mm2 to obtain an aluminum-titanium joined ring (Al-Ti ring) 17.
  • Al-Ti ring aluminum-titanium joined ring
  • the titanium ring 16 may be fixed and the aluminum ring 15 may be rotated for friction welding.
  • both the rings may be rotated relatively to each other in reverse directions.
  • an aluminum A 1050 (JIS) and a titanium second class 35 (JIS) were used for the materials for the annular members.
  • a silicon nitride crown 17 having an outer diameter 90 mm was fixed, while the Al-Ti ring 17 having an aluminum length of 10 mm was rotated at a speed of 800 rpm and urged against the crown 17 with increasing pressure to the maximum 3 kgf/mm2 to friction-weld the crown 17 and Al-Ti ring 17 having the aluminum ring 15 of a thickness of 0.2-2 mm.
  • the crown 7 may be rotated, while the Al-Ti ring 17 may be fixed, or both the rings may be rotated relative to each other in reverse directions.
  • the A1-Ti ring 17 was worked so that its length in an axial direction of the piston to obtain an annular member 13.
  • An axial length of the annular member 13 was specified by top ring grooves to be formed in the aluminum ring 15.
  • the annular member 13 had an axial length of 4 mm.
  • a surface treatment was then applied to a surface of the annular member 13 to be in contact with the aluminum ring so that the surface reacted with the aluminum alloy when friction welding.
  • the alfin treatment may be used. So long as the annular member 13 can be joined to an aluminum alloy and difference in thermal expansion therebetween is so small as not to cause peeling therebetween, other surface treatments may be used.
  • the silicon nitride crown 7 provided with the annular member 13 was arranged in a sand mold 18 as shown in Fig. 13.
  • aluminum alloy molten metal AC8B heated at 700°C was poured into the sand mold 18.
  • the sand mold 18 was broken to take out a ceramic cast-in bonded body from the mold.
  • the mold 18 was a mold generally used as a sand mold.
  • the cast­ ing was effected by gravity casting to obtain a cast-in bonded product.
  • Reference numeral 19 denotes a core for the mold.
  • the ceramic member in joining a ceramic member and a metal member, is formed in its outer circumference with a notch to which the metal member is joined by means of the friction welding to have a thermal shrinkage fit and a press-fitting performance.
  • the restraining force will be determined by thermal expansion coefficient of the metal when it is softened by frictional heat. Therefore, the restraining force becomes high to obtain high bond strength.
  • this piston according to the invention is suitable for mass-production.
  • a metal member difficult in direct bonding with a ceramic material can be joined to the ceramic material as a friction welded body having a high bond strength.
  • a fric­tion welded body can be provided, which is joined with a higher bond strength.
  • the ceramic crown is provided with an annular member different from aluminum and bonded by friction welding on an outer circumference of the crown to be in contact with a piston main body according to the invention, any burnt gases are prevented from entering between the piston main body and the crown, and the boundary therebetween do not peel even in continuous operation.
  • the annular member by using the aluminum ring having an axial thickness X less than 2 mm, it is possible to mitigate the plastic deformation effect caused by slip in aluminum crystal when any tensile forces act thereon to ensure a higher tensile forces at the joined surfaces.
  • Figs. 14a and 14b show parts of engine valve members in which ceramic valve heads 20 are joined by friction welding to metal stems 20 at annular surfaces surrounding projections on the ceramic members 20, in accordance with the invention.
  • Fig. 14c shows ceramic tip parts 21 secured on a metal cam follower rod 25 and a metal rocker arm 24 which moves a valve 23, by the method of the invention.
  • the tip part 21 engaging the rotating cam has secured to it by the method of the invention an annular sleeve 26.

Abstract

A ceramic-metal friction welded composite body includes a ceramic member (7) formed with an annular recess (6) in an outer circumference of its surface and a metal member (9) joined onto the annular recess (6) of the ceramic member by friction welding. The body may be a ceramic insert case piston in which the crown (7) made of a ceramic material has the annular recess (6). The piston main body (5) made of an aluminium alloy is fixed to the crown by insert casting.

Description

  • This invention relates to a ceramic-metal friction welded composite body and a ceramic insert cast piston (cast-in bonded piston). The articles of the invention are useful for heat-resistant and wear-resistant parts in engines and other industrial machines.
  • Recently, for example, with a piston for an internal combustion engine, in order to improve heat-­resistance and wear-resistance as well as light weight of the engine itself, a piston made of a ceramic material and a metal integrally joined by cast-in bonding has been proposed and actually being used.
  • Ceramic joined pistons made of integrally joined ceramic and metal members by cast-in bonding have been known disclosed in, for example, Japanese Patent Laid-­open No. 59-101,566 and Japanese Utility Model Laid-open No. 62-200,147.
  • The ceramic joined piston disclosed in the Japanese Patent Laid-open No. 59-101,566 is made of a ceramic member and a metal member being integrally joined by cast-in bonding through a metallized layer coated on a surface of the ceramic member and a cushioning material joined to the metallized layer.
  • Moreover, the ceramic joined piston disclosed in the Japanese Utility Model Laid-open No. 62-200,147 includes a ceramic member provided in a piston cavity and having an outer circumference which is formed with a groove or tapered diverging from an upper end to a bottom end of a piston, thereby preventing any dislodgment of the ceramic member. In order to improve the bonding to an aluminum alloy, moreover, this publication discloses a feature of metallizing the outer circumference of the ceramic member.
  • With the ceramic joined piston disclosed in the Japanese Patent Laid-open No. 59-101,566, however, the joining force between the piston main body and the ceramic member is enhanced by a bond force of the metallized layer. Therefore, the metallized layers are formed in wide areas in order to endure stresses due to inertia forces, thermal deformations and the like of the piston. However, it is technically difficult to form the metallized layers uniformly in the wide areas, and which tend to increase the manufacturing cost. Moreover, as the inertia forces and the thermal deformations are supported only by the metallized layers, the reliability in strength is insufficient. In fact, joined surfaces often peel in operation of the piston so that burnt gases enter the peeled portions, with the result that the combustion efficiency of the engine will be lowered and fuel consumption will be increased. Moreover, such an entrance of the burnt gases would cause damage of the piston material and accumulation of carbon particles therein.
  • On the other hand, the ceramic joined piston disclosed in the Japanese Utility Model Laid-open No. 62-200,147 includes the ceramic member having the outer circumference formed with the groove or tapered to prevent the dislodgment of the ceramic member. Any sealing for preventing burnt gases from entering the joining surfaces is not considered. This is clear from the fact that in the embodiment of Fig. 5 in the Japanese Utility Model Laid-open No. 62-200,147, surfaces of the piston to be joined to the ceramic member are not subjected to any treatment.
  • It is an object of the invention to provide an improved ceramic-metal friction welded member and a ceramic cast-in bonded piston made thereof which reduce or eliminate the disadvantages of the prior art.
  • A ceramic-­metal friction welded member including a ceramic member and a metal member according to the invention comprises an annular notch on an outer circumference of a surface of the ceramic member to be joined to the metal member, on which annular notch is joined the metal member by friction welding.
  • In a first ceramic cast-in bonded piston including a crown made of a ceramic material and a piston main body made of an aluminum alloy surrounding the crown by cast-in bonding, according to the invention the crown comprises an annular notch formed in an outer circumference of its surface to be in contact with the piston main body, on which annular notch is joined a metal annular member by friction welding.
  • In a second ceramic cast-in bonded piston including a crown made of a ceramic material and a piston main body made of an aluminum alloy surrounding the crown by cast-in bonding, according to the invention the crown comprises an annular member made of a metal different from aluminum member joined by friction welding to an outer circumference of a surface of the crown to be in contact with the piston main body.
  • The ceramic-metal friction welded member according to the invention is particularly preferable for producing a product including a metal member which is difficult to be directly joined to the ceramic member by friction welding.
  • Moreover, by interposing an aluminum member between a ceramic member and a metal member which is difficult to be directly joined to the ceramic member, a ceramic-metal friction welded member having a high bond strength can be obtained.
  • The ceramic-metal friction welded member according to the invention is applicable to a ceramic cast-in bonded piston as above described and is applicable to an engine valve made of a metal member 20 and ceramic member 21 (Figs. 14a and 14b). Moreover, the ceramic-metal friction welded member according to the invention is also applicable to members having ceramic members 21 joined by friction welding to a rocker arm 24 for transmitting power for operating engine valves, push rods 25 and sliding portions of a tappet 26 (Fig. 14c), and to corrosion-resistant and heat-resistant equipment of industrial machines, for example, ceramic spindles, ceramic rotors and the like of oxide-resistant pumps.
  • Moreover, the ceramic cast-in bonded piston is classified into two kinds as above described. The first ceramic cast-in bonded piston has an annular notch in its outer circumference, to which notch is joined an annular member. In the second ceramic cast-in bonded piston, an annular member of a metal different from aluminum is joined to an outer circumference of a crown by friction welding.
  • In the second ceramic cast-in bonded piston, the ceramic crown and the aluminum alloy piston main body are indirectly joined through the annular member, and joining surfaces between the ceramic crown and the piston main body respectively and the annular member are sealed so that sealing is very effective. Moreover, in addition to the sealing the joining surfaces between the ceramic crown and the piston main body by means of the annular member, the ceramic crown is strongly joined to the aluminum alloy with a protrusion of the lower portion of the crown by shrinkage force caused in solidification in cooling process in aluminum alloy cast-in bonding.
  • The "friction welding" used herein is a joining method wherein after members to be joined are brought into contact with each other, one is moved relative to the other at contacting surfaces under a constant pressure to produce frictional heat by which the contacting surfaces are heated to a high temperature and metal material is caused to flow plastically by friction force and applied pressure, while both the materials are diffused each other to join the members. Although this method has a limitation concerning configurations and sizes of the members to be joined, it has merits which other methods do not have. Particularly, the friction welding is very effective for joining members of different materials.
  • Ceramic materials superior in heat-resistance, thermal shock-resistance, adiabatic property and light weight is preferably used for the invention. The ceramic member used in the invention is preferably one selected from a group consisting of silicon nitride, silicon carbide, sialon, zirconia, mullite and alumina.
  • Roughnesses of the ceramic members to be welded by the friction welding are preferably 0.05-1.0 µmRa. In the case that a flatness of the surface is controlled, a fired surface may be acceptable.
  • In the first ceramic cast-in piston according to the invention, as a metal member to be used for friction welding with the ceramic member, a metal hitherto impossible to be directly joined to a ceramic material by friction welding is effective, for example, Ag, Cu, Ti, Nb, Mo, W, Ni, Fe, Inconel, Incolloy and the like. Other metals such as aluminum previously possible to be directly joined to ceramics by friction welding may of course be used. In this case, a friction-welded body more reliable in bond strength can be obtained.
  • With respect to the shape of the annular notch formed in the outer circumference of the ceramic member, the radial depth of the annular notch is preferably not more than 20% of a diameter of the ceramic member, more preferably not more than 10%. Moreover, the radial depth of the annular notch is preferably somewhat less than the inner diameter of the metal annular member. In other words, a clearance A (Fig. 2) at the annular notch between the ceramic member and a metal annular member is more than 1% of the inner diameter of the metal annular member. A height t of the protrusion 4 formed by the annular notch (Fig. 2) should be determined in consideration of stresses required to the joined surfaces. The value t is preferably 3-10 mm for parts such as pistons subjected to the influence of heating.
  • With the annular member used in the ceramic cast-in member according to the invention, the thickness (one half of difference of inner and outer diameters) in the circumferential directions is not particularly limited. However, it is preferably not more than 20% of the diameter of the ceramic member, more preferably not more than 10% for the reason that temperature distribution becomes uniform to produce less thermal stresses.
  • In the first ceramic cast-in bonded piston according to the invention, the ceramic crown is formed with an annular notch in an outer circumference of its surface to be in contact with the piston main body, to which annular notch is joined a metal annular member by friction welding and thereafter the crown is surrounded by the aluminum alloy by cast-in bonding.
  • In the second ceramic cast-in bonded piston according to the invention, the ceramic crown is provided with an annular member made of a metal different from aluminum welded thereto by friction welding and then the crown is surrounded by cast-in bonding to seal between the piston main body and the crown.
  • As the metal different from aluminum, any one metal can be used such as titanium, cast iron, carbon steel, copper, stainless steels, aluminum alloys and nickel alloys. In view of heat-resistance and corrosion-resistance, titanium is preferable.
  • In case of using the titanium, the annular member of titanium is joined to the aluminum by friction welding and then the aluminum of the joined member is joined to the ceramic member by friction welding.
  • By using the friction welding in this manner without requiring complicated operations such as metallizing, the manufacturing cost is lowered and products are advantageously produced in mass-production.
  • The material of the annular member is preferably an aluminum alloy other than aluminum alloy die cast. In case of requiring stable bond strength, a high purity aluminum alloy is preferably used. Although the width and thickness are not limited, the width X shown in Fig. 9 is preferably 0.2-2 mm, and the thickness Y is preferably not more than 10 mm. For example, if the thickness is 0.4 mm, a tensile strength not less than 13 kg/mm² is preferably obtained at room temperature.
  • With the second ceramic cast-in bonded piston, in case that an annular member long in an axial direction and formed with a top ring groove in an outer circumference is used, the burnt gas is sealed by a top ring so that the annular member is not needed to be joined to an aluminum alloy. Therefore, the processes for joining are advantageously eliminated to lower the manufacturing cost. Moreover, as the annular member and the aluminum alloy piston main body are not joined, the thermal expansion of the aluminum alloy does not adversely affect the joining surfaces between the ceramic material and the annular member so that the reliability of the joining surfaces is improved.
  • In the event that the annular member is made of Niresist iron, it is also possible to form a top ring groove in the Niresist iron.
  • In the second ceramic cast-in bonded piston, before cast-in bonding, surfaces of the friction welded annular member may be surface-treated so as to make possible to be joined with a molten aluminum alloy or if the annular member and the aluminum alloy are possible to be welded, after cast-in bonding without any surface treatment, the annular member and the aluminum alloy may be welded. In this case, the electron beam welding is preferably used because of its less thermal influence onto the surroundings.
  • In order that the invention may be more clearly understood, preferred embodiments will be described, by way of example, with reference to the accompanying drawings.
    • Fig. 1 is an explanatory view of a friction welded construction of the prior art;
    • Figs. 2 and 3 are schematic sectional views illustrating embodiments of ceramic-metal friction welded members according to the invention, respectively;
    • Figs. 4a, 4b, 4c and 4d and 5a and 5b are schematic sectional views illustrating embodiments of applications of the friction welded members to ceramic pistons according to the invention;
    • Figs. 6a, 6b and 6c and 7 and 8 are schematic sectional views illustrating other embodiments of applications of the invention to ceramic pistons;
    • Fig. 9 is a schematic sectional view illustrating one embodiment of a ceramic cast-in piston according to the invention;
    • Figs. 10, 11, 12 and 13 are explanatory views illustrating one example of methods of producing the piston according to the invention;
    • Figs. 14a and 14b are schematic views illustrating an engine valve as an application of the invention; and
    • Fig. 14c is a schematic view illustrating a rocker arm as an application of the invention.
  • Fig. 2 schematically illustrates one embodiment of a ceramic-metal friction welded member according to the invention.
  • The friction welded member consists of a ceramic member 1 silicon nitride and a metal annular member 3 of titanium. The ceramic member 1 is formed with an annular notch 2 on its outer circumference to be in opposition to the metal annular member 3. The metal annular member 3 is joined to the annular notch of the ceramic member 1 by means of friction welding. In the joining the ceramic member 1 and the metal annular member 3, there are previously provided clearances A therebetween so that softened part of the metal annular member 3 plastically flows into the clearances A to restrain or clamp a protrusion 4 of the ceramic member 1 by means of thermal shrinkage fit or press-fitting action. In this case the value of the clearances A is preferably determined by assuming that one third of the softened volume of the metal annular member 3 flows into the clearance A in friction welding. For example, particularly good result can be obtained when the total of the clearances A is 0.2 mm to 1 mm.
  • Fig. 3 is a schematic sectional view illustrat­ing another embodiment of the ceramic-metal friction welded member according to the invention. Different from the column-shaped protrusion 4 of the ceramic member 1 in the embodiment shown in Fig. 2, a protrusion 4 of a ceramic member 1 has at its bottom a reduced diameter portion concaved with a curvature of R=1.5 mm. With this arrangement, the softened metal in friction welding plastically flows into the concaved portion to ensure the prevention of the dislodgement of the metal annular member 3 from the ceramic member 1 in a more reliable manner.
  • A tensile test was effected at room temperature for testing tensile strength of the ceramic and metal friction welded members. In the test, ceramic and metal friction welded members were prepared which had dimen­sions of r₁=20 mm, r₂=14 mm and t=5 mm (Fig. 2). With the welded members as shown in Fig. 2, dislodgments occurred at a load of 1,700 kg, while with the members as shown in Fig. 3, dislodgments occurred at a load of 2,800 kg.
  • As can be seen from the above explanation, although with the hitherto used ceramic and metal joined constructions having no notch in ceramic members it is impossible to join a ceramic member to metal members other than aluminum, it becomes possible to join a ceramic member to metal members other than aluminum with the aid of the annular notch formed in the ceramic member according to the invention.
  • Moreover, it is preferable that the friction welded member is subjected to annealing treatment within a temperature range to be used.
  • It is furthermore preferable that the friction welding is effected in an inert gas or vacuum because it can be effectively prevent any oxidation to mitigate any destruction of the ceramics due to its brittleness.
  • A second embodiment of the ceramic cast-in bonded piston will be explained hereinafter by referring to Fig. 9.
  • A ceramic crown 7 forming a top end of the piston in its entirety is cast-in bonded by an aluminum alloy member forming a piston main body. The piston main body 5 and the ceramic crown 7 are joined by a force acting upon the protrusion 4 formed at a lower portion of the crown 7 owing to shrinkage of the aluminum alloy in cast-in bonding. Moreover, an annular member 13 is provided in the proximity of a top land 14 at outer circumference between the ceramic crown 7 and the piston main body 5. The annular member 13 serves to prevent burnt gases from entering a boundary of the ceramic crown 7 and the piston main body 5.
  • Before cast-in bonding, an aluminum ring 12 and a titanium ring 9 are joined by friction welding to form an annular member 13 integrally formed of aluminum and titanium. This composite member 13 is then attached by friction welding to a surface of the crown member 7 at its outer circumference to be in opposition to the piston main body. Thereafter, the composite member 13 is joined to the aluminum alloy.
  • Concrete examples of the first and second embodiment of the ceramic cast-in bonded piston according to the invention will be explained hereinafter.
  • Example 1
  • Crowns 7 made of silicon nitride having an outer diameter of 90 mm were prepared, which was formed with an annular notch 6 having a width of 3 mm and a depth of 3 mm in an outer circumference on a surface to be in opposition to a piston main body 5 as shown in Figs. 4a and 4b.
  • A titanium hollow cylinder 8 was then made, which had an inner diameter of 80 mm, an outer diameter of 90 mm and an axial length of 50 mm as shown in Fig. 4b. Then the crown 7 was fixed and the titanium hollow cylinder 8 was arranged in alignment with the crown 7 and rotated at a rotating speed of 800 rpm relative to the crown 7. The cylinder 8 was urged against the crown 7 with progressively increasing pressure to a maximum 3 kg/mm² so that they were friction welded to obtain a ceramic and metal bonded member.
  • Thereafter, the titanium hollow cylinder 8 of the bonded member was worked on its outer circumference to obtain a titanium ring 9 having an axial length ℓ of 4 mm as shown in Fig. 4c. A surface of the ring 9 was then treated by alfin treatment (or alumelt treatment). The thus obtained silicon nitride crown 7 having the ring 9 was arranged in a sand mold into which molten aluminum alloy was poured at about 700°C to obtain a ceramic cast-in bonded body. The body was annealed at a temperature near to that at which the piston is used. The body was machined to finish outer circumferences, annular grooves, piston pin holes and the like to complete a ceramic cast-in piston sealed by the titanium ring (Fig. 4d).
  • Although the metal member used for friction welding with the silicon nitride has been explained, it may be inexpensive cast iron for obtaining the similar performance and effect.
  • Example 2
  • A silicon nitride crown 7 had a notch 6 having an angle of 70° as shown in Fig. 5a. Other construc­tions and producing processes were similar to those in Example 1. A thus obtained ceramic cast-in piston sealed by a titanium ring 9 was shown in Fig. 5b. Then joining surfaces 10 between the titanium ring 9 and piston main body 5 were welded by laser beams or electron beams.
  • In this Example, the notch 6 of the silicon nitride crown 7 had an inclined surface merging with a round bottom of the annular notch. Softened titanium in friction welding flowed into the bottom of the annular notch to enhance the prevention of dislodgment of the members. Moreover, as the joining surfaces 10 were welded by the laser beams or electron beams, firm joining between the titanium ring 9 and the piston main body 5 was obtained to produce a high performance ceramic cast-in piston. Joining surfaces of the titanium ring 9 facing to the aluminum alloy may be subjected to alfin or alumelt treatment to join with the aluminum alloy.
  • Example 3
  • A silicon nitride crown 7 having an annular notch as shown in Fig. 6a was produced substantially in the same manner as in Example 1 with exception of sintered surfaces of the crown 7.
  • In order to mitigate stresses caused by joining the aluminum alloy piston main body 5 and the silicon nitride crown 7, the piston main body was formed in its center with a deep hole 11 as shown in Fig. 6b. A depth of the deep hole 11 was 7-10 mm deeper than a height G of a protrusion of the silicon nitride crown 7 in order to avoid an abutment of a bottom surface C of the protrusion against the bottom of the deep hole 11.
  • The piston main body 5 was then welded to a titanium ring 9 by means of friction welding. Thereafter, the titanium ring 9 on the piston main body 5 was worked so that its extending length became equal to a depth F of the annular notch on the outer circumference of the silicon nitride crown 7. A contacting surface of the aluminum alloy piston main body 5 to be in contact with a side surface of the silicon nitride crown 7 was worked to form clearances E of 0.2-1 mm. Thereafter, the crown 7 and the piston main body 5 integral with the titanium ring 9 were welded by friction welding as shown in Fig. 6c. In this case, the C portion of the crown 7 was fixed to the piston main body 5 by means of thermal shrinkage effect thereof. Moreover, the silicon nitride and aluminum alloy were friction-welded and the titanium ring 9 was softened by frictional heat with the crown 7 and bitten into the notch 6 of the crown 7 to improve the sealing effect at the portion D in conjunction with the thermal shrinkage fitting.
  • Thereafter, the thus joined body was machined to obtain a ceramic piston sealed by the titanium ring 9 as shown in Fig. 6c.
  • Example 4
  • A ceramic cast-in bonded piston as shown in Fig. 7 was produced which was similar to that of Example 1 with exception that instead of the titanium ring 9, an annular member 13 consisting of an aluminum ring 12 and a titanium annular member 9 was used and the aluminum ring 12 was positioned on the side of the crown 7. This piston included the aluminum ring 12 between the ceramic crown 7 and titanium ring 9. However, as the ceramic and the aluminum were highly bonded, the ceramic piston having higher bond strength could be obtained. It was better for the aluminum ring 12 to use an aluminum higher impurity. In this Example, A 1050 (JIS) whose aluminum purity was 99.5% was used. Although the ring 9 has been explained made of titanium in the Example, it may be cast iron, particularly preferably Niresist cast iron generally used as piston ring carriers.
  • Example 5
  • A ceramic piston was produced, which was similar to that of Example 4 with exception that an annular member 13 consisting of a titanium ring 9 and an aluminum ring 12 positioned on an inner circumference of the titanium ring 9 as shown in Fig. 8. Different from the piston of Example 4, this piston included the aluminum member which did not expose to burnt gases because it was covered by titanium, thereby improving corrosion-resistance. Moreover, as aluminum was interposed between titanium and ceramic, it provided a high performance ceramic piston having high bond strength.
  • Example 6
  • An aluminum ring 15 having an inner diameter of 84 mm, and outer diameter of 90 mm and a length of 10 mm and a titanium ring 16 having an inner diameter of 84 mm, an outer diameter of 90 mm and a length of 60 mm were produced as shown in Fig. 10. The titanium ring 1 was fixed, on the other hand the aluminum ring 15 was rotated at a speed of 800 rpm relative to and urged against the titanium ring 16 with progressively increasing pressure to the maximum 6 kgf/mm² to obtain an aluminum-titanium joined ring (Al-Ti ring) 17. In this case, the titanium ring 16 may be fixed and the aluminum ring 15 may be rotated for friction welding. As an alternative, both the rings may be rotated relatively to each other in reverse directions. In this Example, an aluminum A 1050 (JIS) and a titanium second class 35 (JIS) were used for the materials for the annular members.
  • Thereafter, as shown in Fig. 11, a silicon nitride crown 17 having an outer diameter 90 mm was fixed, while the Al-Ti ring 17 having an aluminum length of 10 mm was rotated at a speed of 800 rpm and urged against the crown 17 with increasing pressure to the maximum 3 kgf/mm² to friction-weld the crown 17 and Al-Ti ring 17 having the aluminum ring 15 of a thickness of 0.2-2 mm. In this case, the crown 7 may be rotated, while the Al-Ti ring 17 may be fixed, or both the rings may be rotated relative to each other in reverse directions. However, in fact it is better to fix the crown 7 and rotate the Al-Ti ring 17.
  • After friction welding, the A1-Ti ring 17 was worked so that its length in an axial direction of the piston to obtain an annular member 13. An axial length of the annular member 13 was specified by top ring grooves to be formed in the aluminum ring 15. In the example shown in Fig. 12, the annular member 13 had an axial length of 4 mm.
  • A surface treatment was then applied to a surface of the annular member 13 to be in contact with the aluminum ring so that the surface reacted with the aluminum alloy when friction welding.
  • Although the surfaces of the annular member 13 were subjected to the alumelt treatment, the alfin treatment may be used. So long as the annular member 13 can be joined to an aluminum alloy and difference in thermal expansion therebetween is so small as not to cause peeling therebetween, other surface treatments may be used.
  • Thereafter, the silicon nitride crown 7 provided with the annular member 13 was arranged in a sand mold 18 as shown in Fig. 13. After pre-heating the sand mold 18 at 200°C, aluminum alloy molten metal AC8B heated at 700°C was poured into the sand mold 18. After about 30 minutes, the sand mold 18 was broken to take out a ceramic cast-in bonded body from the mold. The mold 18 was a mold generally used as a sand mold. The cast­ ing was effected by gravity casting to obtain a cast-in bonded product. Reference numeral 19 denotes a core for the mold.
  • After cast-in bonding, outer circumferences, grooves for piston rings, holes for piston pins and the like were worked in finishing working to produce a ceramic cast-in bonded piston.
  • In order to ascertain the friction cast-in bond strength at the friction welded portion of the piston, a tensile test was carried out in an atmosphere at 400°C. As a result, the tensile strength was more than 8 kg/mm² and the bonded performance between the piston main body 5 and the ceramic crown 7 was good so that no peeling at the bonded portion occurred.
  • As can be seen from the above description, the following effects can be accomplished according to the invention.
  • In one form of the invention, in joining a ceramic member and a metal member, the ceramic member is formed in its outer circumference with a notch to which the metal member is joined by means of the friction welding to have a thermal shrinkage fit and a press-fitting performance. The restraining force will be determined by thermal expansion coefficient of the metal when it is softened by frictional heat. Therefore, the restraining force becomes high to obtain high bond strength. In comparison with the hitherto used thermal shrinkage fitting and press-fitting, no complicated operations are needed so that cost for producing can be lowered. Therefore, this piston according to the invention is suitable for mass-production.
  • According to the invention, even a metal member difficult in direct bonding with a ceramic material can be joined to the ceramic material as a friction welded body having a high bond strength. Moreover, by interposing an aluminum member between a ceramic member and a metal member, a fric­tion welded body can be provided, which is joined with a higher bond strength. By providing the annular notch in the crown according to the invention reliable joining can be obtained with the aid of thermal shrinkage fitting and press-fitting action. In the invention high machining accuracy for parts to be joined is not needed and complicated operations such as metallizing are not needed so that cost for producing can be lowered and mass-production can be effectively employed.
  • As the ceramic crown is provided with an annular member different from aluminum and bonded by friction welding on an outer circumference of the crown to be in contact with a piston main body according to the invention, any burnt gases are prevented from entering between the piston main body and the crown, and the boundary therebetween do not peel even in continuous operation. Moreover, with the arrangement of the annular member, by using the aluminum ring having an axial thickness X less than 2 mm, it is possible to mitigate the plastic deformation effect caused by slip in aluminum crystal when any tensile forces act thereon to ensure a higher tensile forces at the joined surfaces.
  • Figs. 14a and 14b show parts of engine valve members in which ceramic valve heads 20 are joined by friction welding to metal stems 20 at annular surfaces surrounding projections on the ceramic members 20, in accordance with the invention. Fig. 14c shows ceramic tip parts 21 secured on a metal cam follower rod 25 and a metal rocker arm 24 which moves a valve 23, by the method of the invention. The tip part 21 engaging the rotating cam has secured to it by the method of the invention an annular sleeve 26.

Claims (9)

1. A ceramic-metal composite body having a ceramic member (1,7,21) and a metal member (3,9,13,20,24,25) joined by friction welding, characterized in that the friction welded joint is at an annular surface of the ceramic member, and in that inside said annular surface as seen in plan view the ceramic member has a projection (4) extending upwardly from said annuiar surface.
2. A composite body according to claim 1 wherein said metal member (3,9,13,20,24,25) has been deformed during the friction welding so as to contact the side of said projection (4) tightly.
3. A composite body according to claim 2 wherein said metal member (3,9,13,20,24,25) grips said projection (4) due to shrinkage fitting following the deformation and heating caused by the friction welding.
4. A composite body according to any one of the preceding claims wherein said metal member (13) has two portions (9,12) joined by friction welding, one said portion (12) being of aluminium and being friction welded to the ceramic member (7).
5. A composite body according to any one of claims 1 to 3 wherein the metal joined by friction welding to the ceramic member (1,7,21) is selected from Ag, Cu, Ti, Nb, Mo, W, Ni, Fe and alloys thereof.
6. A composite body according to any one of claims 1 to 5 which is an engine piston (5,7), an engine valve member (20), an engine cam follower (25) or an engine rocker arm (24).
7. A composite body according to claim 6 which is an engine piston in which the ceramic member (7) is at least part of the piston crown and is joined to said metal member (9,13) at its periphery at its side remote from the crown face exposed to the combustion gases, said crown (7) being secured to a piston main body (5) by insert casting after being joined by friction welding to said metal member (9,13).
8. A ceramic-metal composite piston including a crown (7) made of a ceramic material and a piston main body (5) made of an aluminium alloy united with the crown (7) by insert-casting wherein said crown (7) is attached to an annular member (9,13) made of aluminium or a metal other than aluminium joined by friction welding to an outer peripheral portion of the surface of the crown which is in contact with the piston main body.
9. A method of forming a ceramic-metal composite body including joining by friction welding a metal member (3,9,13,20,24,25) and a ceramic member (1,7,21) characterized in that the friction welding is at an annular surface of the ceramic member which has a projection (4) extending upwardly from inside the annular surface as seen in plan view, and in that in the friction welding the metal member is deformed to engage the projection tightly.
EP89310943A 1988-10-25 1989-10-24 Ceramic-metal composite body with friction welding joint and ceramic insert cast piston Expired - Lifetime EP0366410B1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP268819/88 1988-10-25
JP63268818A JPH063171B2 (en) 1988-10-25 1988-10-25 Ceramic-Metal Friction Welding Body and Ceramic Casting Piston Composed of It
JP268818/88 1988-10-25
JP26881988A JPH02115556A (en) 1988-10-25 1988-10-25 Ceramics-inserted piston

Publications (3)

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EP0366410A2 true EP0366410A2 (en) 1990-05-02
EP0366410A3 EP0366410A3 (en) 1992-02-26
EP0366410B1 EP0366410B1 (en) 1994-04-13

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EP89310943A Expired - Lifetime EP0366410B1 (en) 1988-10-25 1989-10-24 Ceramic-metal composite body with friction welding joint and ceramic insert cast piston

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EP (1) EP0366410B1 (en)
KR (1) KR900006661A (en)
DE (1) DE68914584T2 (en)

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DE4336691A1 (en) * 1992-10-27 1994-04-28 Mitsubishi Electric Corp Industrial sewing machine - has electronic control to ensure penetration of leather goods in the correct position.
WO2000004286A1 (en) * 1998-07-16 2000-01-27 Federal-Mogul Corporation Piston having a tube to deliver oil for cooling a crown
WO2018136985A1 (en) * 2017-01-26 2018-08-02 Mahle König Kommanditgesellschaft Gmbh & Co Kg Piston for use in internal combustion engines

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US6212349B1 (en) 1999-07-30 2001-04-03 Xerox Corporation Ceramic donor roll with shaft
AU2002213255A1 (en) * 2000-10-18 2002-04-29 Federal Mogul Corporation Multi-axially forged piston
JP3935037B2 (en) * 2002-09-30 2007-06-20 Dowaホールディングス株式会社 Method for manufacturing aluminum-ceramic bonding substrate
DE102005030556B8 (en) * 2005-06-22 2010-02-11 Mozzi, Andreas, Dipl.-Ing. Multi-part piston and method for producing a multi-part piston
DE102005047035B3 (en) * 2005-09-30 2007-04-19 Federal-Mogul Nürnberg GmbH A method of manufacturing a piston for an internal combustion engine and piston produced thereafter
DE102005061060A1 (en) * 2005-12-21 2007-06-28 Mahle International Gmbh Piston for internal combustion engine has cavity wall consisting of reinforcement ring formed from oxidation-resistant material of low thermal conductivity
FR2896842B1 (en) * 2006-02-01 2010-04-09 Hutchinson HYDRAULIC ANTIVIBRATORY SUPPORT AND METHOD FOR MANUFACTURING THE SAME
JP2007231830A (en) * 2006-03-01 2007-09-13 Nissan Motor Co Ltd Piston for internal combustion engine
DE102008053633B4 (en) * 2008-10-29 2011-08-25 Kindler, Thomas, 10405 Method of making a permanent bond between metal and stone
US10052713B2 (en) * 2015-08-20 2018-08-21 Ultex Corporation Bonding method and bonded structure

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DE4336691A1 (en) * 1992-10-27 1994-04-28 Mitsubishi Electric Corp Industrial sewing machine - has electronic control to ensure penetration of leather goods in the correct position.
WO2000004286A1 (en) * 1998-07-16 2000-01-27 Federal-Mogul Corporation Piston having a tube to deliver oil for cooling a crown
WO2018136985A1 (en) * 2017-01-26 2018-08-02 Mahle König Kommanditgesellschaft Gmbh & Co Kg Piston for use in internal combustion engines

Also Published As

Publication number Publication date
DE68914584T2 (en) 1994-09-08
US5144885A (en) 1992-09-08
KR900006661A (en) 1990-05-08
EP0366410B1 (en) 1994-04-13
EP0366410A3 (en) 1992-02-26
DE68914584D1 (en) 1994-05-19

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