EP0359071A1 - Fire-resistant hydraulic fluid and process of manufacture - Google Patents
Fire-resistant hydraulic fluid and process of manufacture Download PDFInfo
- Publication number
- EP0359071A1 EP0359071A1 EP89116232A EP89116232A EP0359071A1 EP 0359071 A1 EP0359071 A1 EP 0359071A1 EP 89116232 A EP89116232 A EP 89116232A EP 89116232 A EP89116232 A EP 89116232A EP 0359071 A1 EP0359071 A1 EP 0359071A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fire
- hydraulic fluid
- acid
- resistant hydraulic
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/32—Esters
- C10M105/38—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
- C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
- C10M107/34—Polyoxyalkylenes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/10—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/68—Esters
- C10M129/76—Esters containing free hydroxy or carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/12—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
- C10M137/10—Thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/027—Neutral salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/22—Acids obtained from polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/288—Partial esters containing free carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
- C10M2209/1045—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
- C10M2209/1055—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/106—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
- C10M2209/1065—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
- C10M2209/1075—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106 used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
- C10M2209/1085—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
- C10M2209/1095—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
- C10M2215/065—Phenyl-Naphthyl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/066—Arylene diamines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/067—Polyaryl amine alkanes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/068—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings having amino groups bound to polycyclic aromatic ring systems, i.e. systems with three or more condensed rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
Definitions
- the instant invention concerns a fire-resistant hydraulic fluid.
- the present invention concerns a hyardulic fluid having an improved response to heat and flame under controlled conditions,i.e. having a useful degree of fire resistance in industrial applications,as well as a process for making said hydraulic fluid.
- fire-resistant hydraulic fluids are employed in all the drive and power hydraulic transmission systems operating at pressures up to 700 bar in the vicinity of or under the danger of open flames or of incandescent bodies, and ambient temperatures ranging from -15°C to +150°C.
- the present safety hydraulic fluids suitable for elevated circuit temperatures are based either on phosphoric esters (such as e.g. tricresylphosphate or trixylenylphosphate) or on organic esters, or on 9:1 mixtures of organic esters with phosphoric esters.
- phosphoric esters such as e.g. tricresylphosphate or trixylenylphosphate
- organic esters or on 9:1 mixtures of organic esters with phosphoric esters.
- fire-resistant hydraulic fluids must meet at least the following three fundamental requisites, i.e. they must have:
- the hydraulic fluids on the basis of phosphoric esters are the most reliable,whereas those on the basis of organic esters are the least reliable.
- the second and third requisites are satisfied to a substantially equal degree by good quality phosphoric esters and organic esters treated with suitable additives.
- Another object of this invention is that of providing a hydraulic safety fluid which does not decompose or which decomposes far less than prior art fluids, during operation.
- test method for rating the flammability of fire-resistant hydraulic fluids in Europe, is that provided by the Sixth Luxembourg Report of the Commission of European Communities Parts III 3.1 to 3.2.2.7 inclusive entitled "Tests for Resistance to Flame".
- Another test method has been developed by the Factory Mutual Research Corporation: ASTM-Committee D-2 Technical Division N-Hydraulic Fluids, Section VI on Fire Resistivity.
- ASTM-Committee D-2 Technical Division N-Hydraulic Fluids, Section VI on Fire Resistivity ASTM-Committee D-2 Technical Division N-Hydraulic Fluids, Section VI on Fire Resistivity.
- ASTM-Committee D-2 Technical Division N-Hydraulic Fluids, Section VI on Fire Resistivity ASTM-Committee D-2 Technical Division N-Hydraulic Fluids, Section VI on Fire Resistivity.
- the fluid to be tested is heated in a steel cylinder pressurized and discharged through a nozzle.
- a hydraulic fluid should at least pass a test temperature of 75°C rather than of 60°C (which is the standard test temperature) in order to be considered sufficiently safe. This is particularly true when it comes to using such liquids in the hydraulic systems of coke furnaces since their hydraulic system is not provided with heat exchangers.
- the main object of the present invention to provide a less fire hazardous and less degradable hydraulic fluid. More specifically, the main object of the present invention is that of providing a hydraulic fluid with a better response to heat and flame under controlled conditions, said fluid being characterized by its capability of passing the above referred F.M. test method for spray flammability of hydraulic fluids at a test temperature higher than 60°C, preferably at a test temperature higher than 75°C.
- a typical hydraulic fluid is made of at least a polyalkylene glycol (PAG), a no-phosphorus organic ester and an antioxidant.
- no-phosphorus organic ester refers to organic esters which do not contain phosphorus in their molecule.
- said hydraulic fluid may further contain other additives such as e.g. anti-rust agents, anti-wear agents and viscosity index improvers.
- PAGs are made by polymerizing or copolymerizing ethylene oxide, propylene oxide or/and isobutylene oxide.
- the copolymers can be random or block copolymers.
- ethylene oxide (EO ) polymers are water soluble, whereas propylene oxide ( PO ) polymers are not water soluble.
- Copolymers on the other hand will be more or less water soluble according to the amount of E0 present in the copolymer molecule, whereas the oil solubility of the copolymer increases as the amount of PO . increases.
- the fire-resistant hydraulic fluid of the instant invention is preferably made using mixtures of PEGs and PPGs having a degree of polymerization of from 4 to 24.
- PG polymers and/or mixtures thereof wherein n, in the above referred formula (I) is ⁇ 10, in which the ester component is soluble (with or without additives),are preferably used. It is preferred that the ester component yields perfectly homogeneous solutions at any ratio.
- Suitable PAGs are e.g. Breox B-65-X as well as lower and higher homologues thereof.
- the brand name Breox designates polyalkylene glycol fluids and lubricants manufactured by BP Chemicals, a branch of the British Petroleum Company Limited.
- Breox fluids and lubricants are designated by a three-part alpha-numeric symbol identifying the polymer type,viscosity and additive type.
- the B-series are water insoluble lubricants for metal-to-metal lubrication.
- the number following the polymer designation represents the viscosity of the product in cS at 40°C.
- the letter following the viscosity designation shows the presence of an additive which can be a special antioxidant, a rust inhibitor, an E.P. agent, or some other special purpose additive.
- Suitable monocarboxylic non-hindered fatty acids for preparing the ester component of the fire-resistant hydraulic fluids of this invention are represented by any natural or synthetic saturated or unsaturated fatty acid or mixtures thereof having from 10 to 24 carbon atoms, inclusive, such as e.g. capric acid, lauric acid, ⁇ 9,10-dodecenoic acid, myristic acid, ⁇ 9,10-tetradecenoic acid, pentadecanoic acid, palmitic acid, ⁇ 9,10-hexadecenoic acid, margaric acid, stearic acid, oleic acid, linoleic acid, and mixtures thereof.
- capric acid lauric acid
- ⁇ 9,10-dodecenoic acid myristic acid
- ⁇ 9,10-tetradecenoic acid pentadecanoic acid, palmitic acid, ⁇ 9,10-hexadecenoic acid, margaric acid, ste
- dicarboxylic fatty acids can usefully be employed.
- examples of such acids are represented e.g. by the following acids : succinic, adipic, sebacic, azelaic acid or mixtures thereof, as well as phthalic, isophthalic acid, malic acid, fumaric acid and tetrahydrophthalic acid or mixtures thereof.
- hindered fatty acids Hindered acids, also called neo-acids, are those acids having no hydrogen atoms bonded to the carbon atoms at the beta-position.
- Useful neo-alkyl acids have from 7 to 9 carbon atoms, such as e.g.
- neo-acids and neo-alcanoic acids having from 5 to 20 carbon atoms preferably those having from 5 to 10 carbon atoms
- R1, R2 and R3 can be the same or different, each representing a (C1-C6)-alkyl group
- R2, R3 are preferably (C1-C4 )-alkyl groups, more preferably a methyl group.
- neo-alkyl acids examples include 2,2-dimethyl propanoic, 2,2-dimethyl-butanoic, 2,2-dimethyl pentanoic, 2,2-dimethylhexanoic, and 2,2-dimethyl octanoic acid.
- the esters suitivelyable for admixing with the above defined PAGs may be made by reacting the carboxylic moiety of any of the above referred carboxylic acids or mixtures thereof with at least 2-3 or preferably all the hydroxyl groups of a hindered or non-hindered diol or mixtures thereof. Concerning the carboxylic moiety, a neo-alkanoic structure is preferred.
- the polyols suitable for preparing the ester component of the fire-resistant hydraulic fluid are hindered polyols having from 2 to 12 hydroxyl groups in their molecule.
- Preferred examples are represented e.g. by the following polyols: pentaerythritol,tetramethylol methane and/or polymers thereof (such as e.g. dipentaerythritol), trimethylolpropane , triethylolpropane , tributylolpropane .
- hindered diols such as e.g. neo-pentylglycol can be advantageously used.
- non-hindered diols which can be suitably used for making the inventive fire-resistant hydraulic fluids, those having from 2 to 40 carbon atoms are preferred.
- the inventive fire-resistant hydraulic fluids consist of at least 3 components, viz. a PAG (as hereinabove defined) an ester (also as defined above) and an anti-oxidant.
- Useful anti-oxidants for making the inventive fluids are selected among the phenol derivatives, the aromatic amines as well as combinations of the two.
- Suitable examples are represented e.g. by bisphenol-A, alpha-naphthylamine, diphenyl-alpha-naphthylamine and/or p,p′-di-octylphenylamine.
- Known anti-oxidants of this class are marketed under the trademark PARABAR.
- PARABAR p-cresol-di-tertiary butylates and/or hydroxytoluene butylates are used.
- an additive such as the one marketed under the trademark COBRATEC can be used but any other so-called metal deactivator can be added provided its solubility in the inventive fluid, within the required temperature range, is good.
- Anti-wear agent compounds which do not contain active phosphorus are much preferred. Thus additives on the basis of zinc di-alkyl dithiophosphate (ZDDP) are excluded.
- ZDDP zinc di-alkyl dithiophosphate
- TPPT The product known as TPPT having the formula contains only inactive phosphorus and can, therefore, be used, preferably in combination with the additive IRGALUBE 349 (IRGALUBE is a trademark owned by Ciba-Geigy,Switzerland).
- an anti-rust agent may be required or useful.
- Compounds like e.g. glycolmonooleate,sobitan, monooleate, dimers or trimers of oleic acid can be used.
- the above referred IRGALUBE 349 besides inactivating the phosphorus contained in TPPT acts as anti-rust agent.
- Another anti-rust agent which can be usefully employed is sold under the trademark LUBRIZOL 859.
- the viscosity is obviously chosen to meet the machinery requirement.
- Preferred viscosity ranges of the inventive fire-resistant hydraulic fluid are typically from 10 to 1000 cS,more preferably of from 10 to 150 cSt.
- viscosity index improving agents may be useful.
- these agents belong to either one of the following classes: 1)polymers on the basis of isobutylene and 2) acrylic copolymers.
- the polymers of the first class are relatively more oxidizable but have a higher shear resistance, whereas the agents of the second class are relatively less oxidizable but have a lower shear resistance.
- the polymers on the basis of isobutylene are preferred.
- hydraulic fluids must be stable under operating conditions.
- the performance may be assessed by the method indicated in parenthesis : a) Hydrolytic stability (ASTM D 2619) b) Air-separation capacity (ASTM D 892 or CEE LUX 5 Part III, 3-6) c) Water separation (ASTM D 1401) d) Foaming characteristics of lubricating oils (ASTM D 892) e) Volume change of elastomeric materials in hydraulic fluids under static conditions (ASTM D 3604) f) Compatibility with varnishes (end-user agreed method) g) Corrosion resistance (CETOP/RP 48H CEE LUX 5 Part III, 3-8) h) Oxidability test (ASTM D 3893)
- the lubricity of the inventive fire-resistant hydraulic fluids is rated by assessing the following parameters: i) Vickers test (DIN E 51389) ii) 4-ball wear (DIN 51350 or ASTM D 2266) iii) 4-ball EP (ASTM D 2783) iv) 4-ball wear (six hours) v) FZG (DIN 51354)
- inventive fire-resistant hydraulic fluids while being safer than the prior art fluids, in fact they all pass the spray flammability test at a temperature of from 75° to 85°C, they are also superior with respect to the above listed parameters.
- the lubricity test of the inventive fluids gives outstanding results.
- a good fire resistant hydraulic fluid i.e. one capable of meeting end-user requirements, should pass Stage 9 in DIN 51354, the inventive hydraulic fluids are capable of passing at least Stage 10.
- the weight losses are significantly lower, viz. of from 12 to 9 mg on the ring and of from 8 to 6 mg on the vanes; typically weight losses of 9.5 mg and 6.4 mg, respectively, are obtained.
- the organic ester is an ester mixture obtained by esterifying neopolyol mixtures (of the type described hereinabove) with fatty acids and neoacids (of the type described hereinabove).
- esters suitable for making the inventive fire-resistant hydraulic fluid are prepared by the esterification of a neo-alkyl polyol having from 10 to 12 carbon atoms and from 2 to 6 hydroxyl groups and,preferively, not more than 7 carbon atoms and from 2 to 4 hydroxyl groups, such as, e.g.
- pentaerythrol, dipentaerythrol or 1,1,1-trimethylolalkanes from 5 to 7 carbon atoms, with straight chain carboxylic acids having from 4 to 12 carbon atoms or branched chain carboxylic acids having from 4 to 10 carbon atoms and a hindered neoalkaneoic acid having from 5 to 20 carbon atoms, preferably from 5 to 10 carbon atoms.
- the esterification of the neo-alkylpolyol with the straight or branched chain neo-alkyl acid is carried out using a mole ratio of the neo-alkyl polyol over the straight or branched acid and the neo-alkyl acid of 1 :(1.5 to 2) : (3 to 8) and it is allowed to proceed at 80 ⁇ 90% depending upon the quantity of water formed during the reaction.
- the esterification is preferably carried out in the presence of an inert gas, such as nitrogen, at a temperature of from 15O° to 220°C and in the presence of a solvent to facilitate the mixing in the first esterification step and to facilitate the removal of the water by azeotrope formation.
- an inert gas such as nitrogen
- Xylene is employed as the solvent; also other aliphatic solvents of equal distillation properties may be used.
- the final product is to be purified, it is subjected to distillation at reduced pressure by removing the excess acidity. Subsequently, it is neutralized by means of an aqueous Na2CO3 solution and wash water.
- Example 1 Neoheptanoate/pentaerythritol-n-caproate.
- ester mixture is distilled under reduced pressure for removing the residual acid and then washed with a 5% Na2CO3 aqueous solution.
- the ester mixture is then added with 6 g sodium borohydride (NaBH4) and 100 ml 0.1N NaOH and stirred for 20 hours at 50°-60°C under nitrogen atmosphere.
- NaBH4 sodium borohydride
- reaction mixture After separation of the washing water, the reaction mixture is heated to 130°C and subjected to reduced pressure (1 mm Hg) and thereafter filtered with diatomaceous earth.
- the washed ester is then dessicated at 165°C. By applying a reduced pressure of 1 mm Hg, 144 g of a viscous ester is obtained.
- Physico-chemical characteristics kinematic viscosity at 210°F (98.88°C) approx. 14 cSt kinematic viscosity at 100°F (37.78°C) approx.277 cSt pour point - 10°F (appr. - 2 saponification number (mg KOH/g) 355
- the end product is of a brownish colour, of clear appearance at ⁇ 25°C Physico-mechanical characteristics: kinematic viscosity at 104°F (40°C) 40 ⁇ 45 cSt acidity number (mg KOH/g) 1 sapnification number (mg KOH/g) ⁇ 180
- the end product is of a dark straw colour, of clear appearance at ⁇ 8°C.
- Physico-chemical characteristics kinematic viscosity at 104°F (40°C) 30 ⁇ 38 cSt acidity number (mg KOH/g) 1 saponification number (mg KOH/g) ⁇ 180
- the end product is of a brownish colour and consists essentially of pentaerythritol-tetraoleate.
- Physico-chemical characteristics kinematic viscosity at 104°F (40°C) 110 ⁇ 150 cSt acidity number (mg KOH/g) 1 sapnification number (mg KOH/g) ⁇ 200
- Example 7 Breox B65X 88 Pentraerythritol-tetraoleate(Ex.6) 10 Hydroxytoluene butylate 0.2 Cobratec 0.04 Irgalube TPPT 1 Irgalube 349 1
- the inventive fire-resistant hydraulic fluid shows two absorption bands in the infrared, viz. 1710 ⁇ 1720 cm ⁇ 1 (not very pronounced peak) 1080 ⁇ 1100 cm ⁇ 1 (very pronounced peak)
- Example 8 Breox B65X 88 Neoheptanoate/pentaerythritol-n-caprate (Ex.1) 10 Hydroxytoluene butylate 0.2 Cobratec 0.04 Irgalube TPPT 1 Irgalube 349 1
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
Abstract
A fire-resistant hydraulic fluid is disclosed which has an improved response to heat and flame under controlled conditions and a high degree of flame propagation resistance. The safety hydraulic fluids of the instant invention are made of at least a polyalkylene glycol, an ester and an antioxidant. Depending on the specific use, the inventive hydraulic fluid may further contain other additives such as e.g. anti-rust agents, anti-wear agents and viscosity index improvers.
A process for making the novel safety hydraulic fluid is also disclosed.
A process for making the novel safety hydraulic fluid is also disclosed.
Description
- The instant invention concerns a fire-resistant hydraulic fluid.
- More particularly, the present invention concerns a hyardulic fluid having an improved response to heat and flame under controlled conditions,i.e. having a useful degree of fire resistance in industrial applications,as well as a process for making said hydraulic fluid.
- The field of use of fire-resistant hydraulic fluids is e.g. in the hydraulic systems of the continuous casting plants for making steel billets, in the opening or closing systems of furnaces, in the loading devices of coke furnaces or lime furnaces, etc. Generally speaking, fire-resistant hydraulic fluids are employed in all the drive and power hydraulic transmission systems operating at pressures up to 700 bar in the vicinity of or under the danger of open flames or of incandescent bodies, and ambient temperatures ranging from -15°C to +150°C.
- The present safety hydraulic fluids suitable for elevated circuit temperatures are based either on phosphoric esters (such as e.g. tricresylphosphate or trixylenylphosphate) or on organic esters, or on 9:1 mixtures of organic esters with phosphoric esters.
- As it is known to those skilled in the art, fire-resistant hydraulic fluids must meet at least the following three fundamental requisites, i.e. they must have:
- (i) a high degree of flame propagation resistance;
- (ii) a lubricity adequate to the operating conditions existing in the hydraulic system;
- (iii) a high operational stability.
- As to the first requisite, it is known that the hydraulic fluids on the basis of phosphoric esters are the most reliable,whereas those on the basis of organic esters are the least reliable. The second and third requisites are satisfied to a substantially equal degree by good quality phosphoric esters and organic esters treated with suitable additives.
- The use of phosphoric esters for making fire-resistant hydraulic fluids is being phased out because of their toxicity, replacing them in most cases with organic esters.
- On the other hand it is generally admitted that the greatest drawback of organic esters is their insufficient capability to limit flame propagation, when they catch fire. It is also known that the prior art hydraulic fluids, due to their chemical nature, are subject to decomposing during operation, thus negatively affecting their response to heat and flame, with consequent greater fire hazard.
- Moreover, the prior art hydraulic fluids all tend - to a greater or lesser degree - to form, during operation, insoluble sludge, varnish and other deposits that clog the filters and oxidize the seat of the needle valves which are thus subject to corrosion and imperfect sealing.
- In the light of the above referred drawbacks of the prior art materials it is generally recognized that a need existed for less hazardous and more stable hydraulic fluids.
- It is therefore the main object of the present invention to provide a hydraulic safety fluid having an improved flame propagation resistance and a higher autoignition temperature than the prior art fluids.
- Another object of this invention is that of providing a hydraulic safety fluid which does not decompose or which decomposes far less than prior art fluids, during operation.
- The test method for rating the flammability of fire-resistant hydraulic fluids, in Europe, is that provided by the Sixth Luxembourg Report of the Commission of European Communities Parts III 3.1 to 3.2.2.7 inclusive entitled "Tests for Resistance to Flame". Another test method has been developed by the Factory Mutual Research Corporation: ASTM-Committee D-2 Technical Division N-Hydraulic Fluids, Section VI on Fire Resistivity. According to this method, the fluid to be tested is heated in a steel cylinder pressurized and discharged through a nozzle. The flame from a propane-air torch is introduced at points 152 mm (6 in.) and 457 mm (18 in.) from the nozzle. When the torch flame is removed from spray pattern, the duration of the burning in the spray pattern is recorded. A duration of 10 seconds or more is a failure. The most critical parameter of this test method is the bulk temperature of the fluid being tested. The above referred specifications provide a temperature of 60°C.
- Now, it is known that the presently employed safety hydraulic fluids based on organic esters fail the test at temperatures between 65°C and 80°C.
- Since the high-pressure hydraulic circuits of the continuous casting plants for making steel billets are provided with heat-exchange systems which, under improper working conditions, do not allow thermostating the hydraulic fluid within a suitable temperature range above or below the pre-set temperature of 50°C, thus a hydraulic fluid should at least pass a test temperature of 75°C rather than of 60°C (which is the standard test temperature) in order to be considered sufficiently safe. This is particularly true when it comes to using such liquids in the hydraulic systems of coke furnaces since their hydraulic system is not provided with heat exchangers.
- In the light of the above outlined situation it is apparent that a need existed for an improved fire-resistant hydraulic fluid.
- It is therefore the main object of the present invention to provide a less fire hazardous and less degradable hydraulic fluid. More specifically, the main object of the present invention is that of providing a hydraulic fluid with a better response to heat and flame under controlled conditions, said fluid being characterized by its capability of passing the above referred F.M. test method for spray flammability of hydraulic fluids at a test temperature higher than 60°C, preferably at a test temperature higher than 75°C.
- According to the instant invention this object is achieved by providing a hydraulic fluid as defined in the claims.
- According to the instant invention, a typical hydraulic fluid is made of at least a polyalkylene glycol (PAG), a no-phosphorus organic ester and an antioxidant.***
- ***Within the context of this invention, the expression "no-phosphorus organic ester" refers to organic esters which do not contain phosphorus in their molecule.
- Depending on the specific use, said hydraulic fluid may further contain other additives such as e.g. anti-rust agents, anti-wear agents and viscosity index improvers.
- All the above referred compounds are per se known in the art.
- As it is known to the skilled artisan, PAGs are made by polymerizing or copolymerizing ethylene oxide, propylene oxide or/and isobutylene oxide. The copolymers can be random or block copolymers.
- It is further known in the art that ethylene oxide ( EO ) polymers are water soluble, whereas propylene oxide ( PO ) polymers are not water soluble. Copolymers on the other hand will be more or less water soluble according to the amount of E0 present in the copolymer molecule, whereas the oil solubility of the copolymer increases as the amount of PO . increases.
- The above referred E0 and PO polymers and copolymers can be defined by the following formula:
R₁ is usually H,-CH₃ or-C₂H₅
R₂ is usually H, so that :
- when R, R₁ and R₂ = H,the compound defined by the formula is polyethylene glycol (PEG); whereas
- when R = H and R₁ = -CH₃, the compound defined by the formula is a polypropylene glycol (PPG);and
- when R₁ = H or -CH₃ and R = R₂ = H, the compound defined by the formula is a copolymer. - The fire-resistant hydraulic fluid of the instant invention is preferably made using mixtures of PEGs and PPGs having a degree of polymerization of from 4 to 24.
- According to the instant invention, PG polymers and/or mixtures thereof, wherein n, in the above referred formula (I) is ≧ 10, in which the ester component is soluble (with or without additives),are preferably used. It is preferred that the ester component yields perfectly homogeneous solutions at any ratio.
- Suitable PAGs are e.g. Breox B-65-X as well as lower and higher homologues thereof. As it is known to those skilled in the art, the brand name Breox designates polyalkylene glycol fluids and lubricants manufactured by BP Chemicals, a branch of the British Petroleum Company Limited. Breox fluids and lubricants are designated by a three-part alpha-numeric symbol identifying the polymer type,viscosity and additive type. In particular the B-series are water insoluble lubricants for metal-to-metal lubrication. The number following the polymer designation represents the viscosity of the product in cS at 40°C. The letter following the viscosity designation shows the presence of an additive which can be a special antioxidant, a rust inhibitor, an E.P. agent, or some other special purpose additive.(*)
- (*)In particular the letter "X" denotes the presence of an antioxidant.
- Examples of suitable monocarboxylic non-hindered fatty acids for preparing the ester component of the fire-resistant hydraulic fluids of this invention are represented by any natural or synthetic saturated or unsaturated fatty acid or mixtures thereof having from 10 to 24 carbon atoms, inclusive, such as e.g. capric acid, lauric acid, Δ9,10-dodecenoic acid, myristic acid, Δ9,10-tetradecenoic acid, pentadecanoic acid, palmitic acid, Δ9,10-hexadecenoic acid, margaric acid, stearic acid, oleic acid, linoleic acid, and mixtures thereof. It is to be understood that also dicarboxylic fatty acids can usefully be employed. Examples of such acids are represented e.g. by the following acids : succinic, adipic, sebacic, azelaic acid or mixtures thereof, as well as phthalic, isophthalic acid, malic acid, fumaric acid and tetrahydrophthalic acid or mixtures thereof. According to the present invention it is also possible to use so-called hindered fatty acids. Hindered acids, also called neo-acids, are those acids having no hydrogen atoms bonded to the carbon atoms at the beta-position. Useful neo-alkyl acids have from 7 to 9 carbon atoms, such as e.g. 3,3-dimethylpentanoic acid, 3,3,6-trimethylpentanoic acid, 4,4-dimethylhexanoic acid, 4,4,5-trimethylhexanoic acid, and 5,5-dimethylhexanoic acid.
- Also neo-acids and neo-alcanoic acids having from 5 to 20 carbon atoms, preferably those having from 5 to 10 carbon atoms, can be used, corresponding to the following formula
R₁, R₂ and R₃ can be the same or different, each representing a (C₁-C₆)-alkyl group, and R₂, R₃ are preferably (C₁-C₄ )-alkyl groups, more preferably a methyl group. - Examples of preferred neo-alkyl acids are: 2,2-dimethyl propanoic, 2,2-dimethyl-butanoic, 2,2-dimethyl pentanoic, 2,2-dimethylhexanoic, and 2,2-dimethyl octanoic acid.
- According to the instant invention, the esters suitable for admixing with the above defined PAGs may be made by reacting the carboxylic moiety of any of the above referred carboxylic acids or mixtures thereof with at least 2-3 or preferably all the hydroxyl groups of a hindered or non-hindered diol or mixtures thereof. Concerning the carboxylic moiety, a neo-alkanoic structure is preferred.
- According to the instant invention, the polyols suitable for preparing the ester component of the fire-resistant hydraulic fluid are hindered polyols having from 2 to 12 hydroxyl groups in their molecule. Preferred examples are represented e.g. by the following polyols: pentaerythritol,tetramethylol methane and/or polymers thereof (such as e.g. dipentaerythritol), trimethylolpropane, triethylolpropane, tributylolpropane. Also hindered diols such as e.g. neo-pentylglycol can be advantageously used.
- Among the non-hindered diols which can be suitably used for making the inventive fire-resistant hydraulic fluids, those having from 2 to 40 carbon atoms are preferred.
- As said above, the inventive fire-resistant hydraulic fluids consist of at least 3 components, viz. a PAG (as hereinabove defined) an ester (also as defined above) and an anti-oxidant.
- Useful anti-oxidants for making the inventive fluids are selected among the phenol derivatives, the aromatic amines as well as combinations of the two.
- It is also important that products are chosen which do not darken severly. Suitable examples are represented e.g. by bisphenol-A, alpha-naphthylamine, diphenyl-alpha-naphthylamine and/or p,p′-di-octylphenylamine. Known anti-oxidants of this class are marketed under the trademark PARABAR. Preferably, p-cresol-di-tertiary butylates and/or hydroxytoluene butylates are used.
- In order to prevent corrosion of the heat exchangers, which are made of copper and/or brass, an additive such as the one marketed under the trademark COBRATEC can be used but any other so-called metal deactivator can be added provided its solubility in the inventive fluid, within the required temperature range, is good.
- Anti-wear agent compounds which do not contain active phosphorus are much preferred. Thus additives on the basis of zinc di-alkyl dithiophosphate (ZDDP) are excluded.
-
- The presence of an anti-rust agent may be required or useful. Compounds like e.g. glycolmonooleate,sobitan, monooleate, dimers or trimers of oleic acid can be used. The above referred IRGALUBE 349 besides inactivating the phosphorus contained in TPPT acts as anti-rust agent.
- Another anti-rust agent which can be usefully employed is sold under the trademark LUBRIZOL 859.
- Besides the above referred parameter relating to the spray flammability, there are other physico-chemical parameters which characterize a hydraulic fluid and which are useful information for the end-user.
- The viscosity is obviously chosen to meet the machinery requirement. Preferred viscosity ranges of the inventive fire-resistant hydraulic fluid are typically from 10 to 1000 cS,more preferably of from 10 to 150 cSt.
- In some cases the addition of viscosity index improving agents may be useful. As it is known in the art, these agents belong to either one of the following classes: 1)polymers on the basis of isobutylene and 2) acrylic copolymers. The polymers of the first class are relatively more oxidizable but have a higher shear resistance, whereas the agents of the second class are relatively less oxidizable but have a lower shear resistance.
- According to the instant invention the polymers on the basis of isobutylene are preferred.
- As referred above, hydraulic fluids must be stable under operating conditions. The performance may be assessed by the method indicated in parenthesis :
a) Hydrolytic stability (ASTM D 2619)
b) Air-separation capacity (ASTM D 892 or CEE LUX 5 Part III, 3-6)
c) Water separation (ASTM D 1401)
d) Foaming characteristics of lubricating oils (ASTM D 892)
e) Volume change of elastomeric materials in hydraulic fluids under static conditions (ASTM D 3604)
f) Compatibility with varnishes (end-user agreed method)
g) Corrosion resistance (CETOP/RP 48H CEE LUX 5 Part III, 3-8)
h) Oxidability test (ASTM D 3893) - The lubricity of the inventive fire-resistant hydraulic fluids is rated by assessing the following parameters:
i) Vickers test (DIN E 51389)
ii) 4-ball wear (DIN 51350 or ASTM D 2266)
iii) 4-ball EP (ASTM D 2783)
iv) 4-ball wear (six hours)
v) FZG (DIN 51354) - It should be noted that the inventive fire-resistant hydraulic fluids, while being safer than the prior art fluids, in fact they all pass the spray flammability test at a temperature of from 75° to 85°C, they are also superior with respect to the above listed parameters. For instance, the lubricity test of the inventive fluids gives outstanding results. In fact, whereas in continous casting steel plants a good fire resistant hydraulic fluid, i.e. one capable of meeting end-user requirements, should pass Stage 9 in DIN 51354, the inventive hydraulic fluids are capable of passing at least Stage 10.
Moreover, whereas the end-user specifications provide for a maximum weight loss of 60 mg on the ring and a maximum weight loss of 20 mg on the vanes (DIN E 51389 Vickers test), with the inventive hydraulic fluids the weight losses are significantly lower, viz. of from 12 to 9 mg on the ring and of from 8 to 6 mg on the vanes; typically weight losses of 9.5 mg and 6.4 mg, respectively, are obtained. - According to the instant invention, the organic ester is an ester mixture obtained by esterifying neopolyol mixtures (of the type described hereinabove) with fatty acids and neoacids (of the type described hereinabove).
- More particularly, the esters suitable for making the inventive fire-resistant hydraulic fluid are prepared by the esterification of a neo-alkyl polyol having from 10 to 12 carbon atoms and from 2 to 6 hydroxyl groups and,preferably, not more than 7 carbon atoms and from 2 to 4 hydroxyl groups, such as, e.g. pentaerythrol, dipentaerythrol or 1,1,1-trimethylolalkanes from 5 to 7 carbon atoms, with straight chain carboxylic acids having from 4 to 12 carbon atoms or branched chain carboxylic acids having from 4 to 10 carbon atoms and a hindered neoalkaneoic acid having from 5 to 20 carbon atoms, preferably from 5 to 10 carbon atoms.
- The esterification of the neo-alkylpolyol with the straight or branched chain neo-alkyl acid is carried out using a mole ratio of the neo-alkyl polyol over the straight or branched acid and the neo-alkyl acid of 1 :(1.5 to 2) : (3 to 8) and it is allowed to proceed at 80 ÷ 90% depending upon the quantity of water formed during the reaction.
- At this point the unreacted acids are distilled off, preferably at low pressure.
- After the removal of the unreacted acids, in order to complete the reaction there is added a sufficient quantity of straight chain carboxylic acids having from 4 to 12 carbon atoms. The esterification is preferably carried out in the presence of an inert gas, such as nitrogen, at a temperature of from 15O° to 220°C and in the presence of a solvent to facilitate the mixing in the first esterification step and to facilitate the removal of the water by azeotrope formation.
- Xylene is employed as the solvent; also other aliphatic solvents of equal distillation properties may be used.
- If the final product is to be purified, it is subjected to distillation at reduced pressure by removing the excess acidity. Subsequently, it is neutralized by means of an aqueous Na₂CO₃ solution and wash water.
- The solution is then dried at reduced pressure and filtered to yield a clear product.
- The present invention will now be further illustrated by way of the following examples which are not to be construed in a restrictive manner, as the skilled artisan may obviously modify and adapt these examples to render them more suitable for his specific needs, without any inventive effort on his part and without departing from the scope of the instant invention.
- In a round bottom, 4-necked 2 l glass vessel provided with mechanical stirrer, thermometer, reflux condenser (or vacuum pump connecting means) and water trap, 2 moles (272 g) of pentaery thritol are added with 4 moles (464 g) of n-caproic acid and 8 moles (1040 g) of neoheptanoic acid and 200 g xylene. Thereafter, the reaction mixture is refluxed at 160°-175°C until 122 ml (84.6%) reaction water is collected (about 43 hours).Then the reflux condenser is disconnected and the reaction vessel is connected to the vacuum pump for removing the unreacted organic acid. The reflux condenser is then reconnected. 115 g (approx.1 mole) n-caproic acid abd 100 g xylene are added. The esterification reaction is then continued by refluxng at 175°-177°C and until the formation of reaction water has come to an end.
- Subsequently, the ester mixture is distilled under reduced pressure for removing the residual acid and then washed with a 5% Na₂CO₃ aqueous solution. The ester mixture is then added with 6 g sodium borohydride (NaBH₄) and 100 ml 0.1N NaOH and stirred for 20 hours at 50°-60°C under nitrogen atmosphere.
- After cooling and separation of the water layer, the latter is discarded and the ester mixture is dissolved in xylene and washed 2 times with distilled water.
- The so purified ester solution is dessicated under reduced pressure (1 mm Hg) and the residue is treated with 50 g infusorial earth for 2 hours at 100°-110°C and finally filtered on diatomaceous earth. 940g of the title compound in the form of a pale yellow viscous liquid is obtained.
Physico-chemical characteristics: kinematic viscosity at 210°F (98.88°C) approx. 5 cSt kinematic viscosity at 100°F (37.78°C) approx.30 cSt pour point - 75°F (approx. -59° appearance, after 60 hours clear liquid - Into a 1 l 4-necked glass vessel provided with stirrer, thermometer, reflux condenser (or vacuum pump connecting means) and water trap, are poured 54 g (0.4 mole) trimethylolpropane, 180 g (1.25 moles) 2,2-dimethylhexanoic acid and 100 g xylene. The reaction mixture is then stirred and refluxed for 28 hours at 161°-168°C, whereupon 20 ml reaction water is collected. The reaction vessel is then connected to a vacuum pump (1 mm Hg) in order to remove the xylene (180°C, azeotrope) and the unreacted acid.
- The residue is then dissolved in hexane and washed 3 times with a 5% Na₂CO₃ aqueous solution and then once only with distilled water.
- After separation of the washing water, the reaction mixture is heated to 130°C and subjected to reduced pressure (1 mm Hg) and thereafter filtered with diatomaceous earth.
- 190 g of the title compound in the form of a pale yellow viscous liquid is obtained.
Physico-chemical characteristics: kinematic viscosity at 210°F (98.88°C) 6.8 cSt kinematic viscosity at 100°F (37.78°C) 65.6 cSt pour point - 25°F(approx. - 31°C) saponification number (mg KOH/g) : 315 acidity number (mg/KOH/g) : 0.08 corrosion index : 22.4 - Into a 1 l 4-necked glass vessel provided with stirrer,thermometer, reflux condenser (or vacuum pum connecting means) and water trap are poured 38 g (0.28 mole) pentaerythritol, 160 g (1.21 moles) dimethylpentanoic acid and 60 g xylene.The reaction mixture is then stirred and refluxed at 168°-210°C for 32 hours to collect 21 ml of reaction water. The lateral tube is disconnected from the vessel which is connected to a vacuum pump (1 mm Hg) and heated to 173°C. The residue is dissolved in xylene and washed two times with a 5% Na₂CO₃ solution. It is then washed two times with distilled water. The washed ester is then dessicated at 165°C. By applying a reduced pressure of 1 mm Hg, 144 g of a viscous ester is obtained.
Physico-chemical characteristics: kinematic viscosity at 210°F (98.88°C) approx. 14 cSt kinematic viscosity at 100°F (37.78°C) approx.277 cSt pour point - 10°F (appr. - 2 saponification number (mg KOH/g) 355 - Into a 1 l 4-necked glass vessel provided with stirrer, thermometer, reflux condenser (or vacuum pump connecting means) and water trap are poured 100 g tallow fatty acids and 14 g (0.12 mole) trimethylolethane and stirred. Thereafter the reaction mixture is heated under nitrogen bubbling from the bottom of the reaction vessel in order to remove, from the reaction mass, the water vapour produced by the esterification. The reaction mixture is kept under constant stirring for 8 hours at a temperature of from 250° to 260°C. The reaction is completed when the acidity number eraches a value equal or lower than 1 or after approx. 6.5g water has been collected in the water trap.
- The end product is of a brownish colour, of clear appearance at ≧ 25°C
Physico-mechanical characteristics: kinematic viscosity at 104°F (40°C) 40 ÷ 45 cSt acidity number (mg KOH/g) 1 sapnification number (mg KOH/g) ≧ 180 - Proceeding in the same manner as described in Example 4 but using 0.35 mole oleic acid in lieu of the tallow fatty acids
- The end product is of a dark straw colour, of clear appearance at ≧ 8°C.
Physico-chemical characteristics: kinematic viscosity at 104°F (40°C) 30 ÷ 38 cSt acidity number (mg KOH/g) 1 saponification number (mg KOH/g) ≧ 180 - Into a 4-necked 1 l glass vessel provided with stirrer,thermometer, reflux condenser (or vacuuum pump connecting means) and water trap are poured 100 g (0.35 mole) oleic acid, 12 g (0.088 mole) pentaerythritol, 0.1 g BF₃(C₂H₅)₂O catalysts and 100 g xylene. The reaction mixture is then stirred and heated at the reflux temperature of the xylene for 8 hours so as to remove the reaction water by means of azeotrope formation.The reaction is completed when the acidity number reaches a value equal or lower than 1 or after 6.2 g water has been collected in the trap.
- The end product is of a brownish colour and consists essentially of pentaerythritol-tetraoleate.
Physico-chemical characteristics: kinematic viscosity at 104°F (40°C) 110 ÷ 150 cSt acidity number (mg KOH/g) 1 sapnification number (mg KOH/g) ≧ 200 - In the following examples the preparation of the inventive fire-resistant hydraulic fluid is illustrated. Except when expressly stated otherwise, the quantities of the reactants are indicated in parts per weight.
Example 7 Breox B65X 88 Pentraerythritol-tetraoleate(Ex.6) 10 Hydroxytoluene butylate 0.2 Cobratec 0.04 Irgalube TPPT 1 Irgalube 349 1 - The listed components are added into a reaction vessel in the above referred order and mixed thoroughly at a temperature of from 40°C to 50°C for ½ hour.
Physico-chemical characteristics (ranges) specific weight at 68°F (20°C) 0.950 ÷ 0.990 kinematic viscosity at 104°F (40°C) 60 ÷ 70 cSt acidity number (mg KOH/g) 3 ÷ 4 saponification number (mg KOH/g) 15 ÷ 20 Cleveland open cup flash point ≧ 300 Test results FZG test (DIN 51354) exceeding Stage 10 Vickers test (DIN 51389) : loss on the ring : 9.5 mg loss on the vanes: 6.4 mg - The inventive fire-resistant hydraulic fluid shows two absorption bands in the infrared, viz.
1710 ÷ 1720 cm⁻¹ (not very pronounced peak)
1080 ÷ 1100 cm⁻¹ (very pronounced peak)Example 8 Breox B65X 88 Neoheptanoate/pentaerythritol-n-caprate (Ex.1) 10 Hydroxytoluene butylate 0.2 Cobratec 0.04 Irgalube TPPT 1 Irgalube 349 1 - The listed components are added into a reaction vessel in the above referred order and mixed thoroughly at a temperature of from 40 to 50°C for ½ hour.
Physico-chemical characteristics(ranges): specific weight at 68°F (20°C) 0.950 ÷ 0.990 kinematic viscosity at 104°F (40°C) 60 ÷ 70 cSt acidity number (mg KOH/g) 3 ÷ 4 saponification number (mg KOH/g) 20 ÷ 35 Cleveland open cup flash point ≧ 300°C Example 9 Breox B-65X 59.5 Dow Pol P 1200 (propylene oxide polimer having a MW of appr.1200) 15 Dow Pol E 600 (ethylene oxide polymer having a MW of app.600) 3 Trimethylpropane-2,2-dimethylhexanoate (Ex.2) 18 Trimethylol-tallowate (Ex.4) 2 Hydroxytoluene butylate 0.2 Cobratec 0.04 Irgalube TPPT 1 Irgalube 349 1.5 - The listed components are added into a reaction vessel in the above referred order and mixed thoroughly at a temperature of 50° to 60°C for ½ hour.
Physico-chemical characteristics (ranges): specific weight at 68°F (20°C) 0.950 ÷ 0.990 kinematic viscosity at 104°F (40°C) 60 ÷ 70 cSt acidity number (mg KOH/g) 3 ÷ 4 saponification number (mg KOH/g) 20 ÷ 35 Cleveland open cup flash point ≧ 300°C Example 10 Dow Pol P 1200 77 Pentaerythritol-2,2-dimethylpentanoate (Ex.3) 20 Hydroxytoluene butylate 0.2 Cobratec 0.04 Irgalube TPPT 1 Lubrizol 859 2 - The listed components are added in a reaction vessel in the above referred order and mixed thoroughly at a temperature from 40 ° to 50 °C for ½ hour.
Physico-chemical characteristics (ranges): specific weight at 68°F (20°C) 0.950 ÷ 0.990 kinematic viscosity at 104°F (40°C) 60 ÷ 70 cSt acidity number (mg KOH/g) 3 ÷ 4 saponification number (mg KOH/g) 30 ÷ 40 Cleveland open cup flash point ≧ 300°C - A homogenous mixture of a slightly strawy colour is obtained.
Claims (13)
1. A fire-resistant hydraulic fluid having a high degree of flame propagation resistance, a lubricity adequate to the operating conditions existing in hydraulic systems, a high operational stability, and of low toxicity characterized by the fact that it contains
(i) at least a polyalkylene glycol of formula
wherein R is a hydrogen atom, an alkyl group or an aryl group,
R₁ is a hydrogen atom, -CH₃ or -C₂H₅,
R₂ is a hydrogen atom, and is an integer from 4 to 24,
R₁ is a hydrogen atom, -CH₃ or -C₂H₅,
R₂ is a hydrogen atom, and is an integer from 4 to 24,
(ii) a no-phosphorus organic ester, capable of yielding homogeneous solutions at any ratio, and
(iii) an antioxidant chosen among the phenyl derivatives, the aromatic amines or consisting of a mixture thereof, further characterized by the capability of passing the Factory Mutual Research Corporation Fire Resistivity Test for spray flammability at a test temperature equal to or higher than 75°C.
2. A fire-resistant hydraulic fluid according to claim 1, characterized in that it further contains
(i) a corrosion inhibiting agent or a metal deactivator,
(ii) an anti-wear agent free of active phosphorus and,
(iii) an anti-rust agent.
3. A fire-resistant hydraulic fluid according to claim 1, characterized in that the polyalkylene glycol component is a mixture of polyethylene glycols and polypropylene glycols having a degree of polymerization of from 4 to 24.
4. A fire-resistant hydraulic fluid according to claim 1, characterized in that the polyalkylene glycol component consists of propylene and ethylene oxide polymers of formula (I), wherein n is an integer equal to or greater than 10.
5. A fire-resistant hydraulic fluid according to claim 1, characterized in that the ester component therefor is the reaction product of
(i) at least a neo-alkyl polyol having from 10 to 12 carbon atoms and from 2 to 6 hydroxy groups in its molecule, with
(ii) at least a straight chain carboxylic acid having from 4 to 12 carbon atoms in its molecule, or a branched chain carboxylic acid having from 4 to 10 carbon atoms in its molecule and a hindered neo-alkaneoic acid having from 5 to 20 carbon atoms in its molecule.
6. A fire-resistant hydraulic fluid according to claim 4, characterized in that for making the ester component a 1,1,1-3-methylol-alkane having from 5 to 7 carbon atoms in its molecule is used.
7. A fire-resistant hydraulic fluid according to claim 1, characterized in that the ester component is the reaction product of
(i) at least 1 carboxylic non-hindered saturated or unsaturated fatty acid having from 10 to 24 carbon atoms in its molecule, with
(ii) at least 2-3, or preferably all the hydroxyl groups of an hindered or a non-hindered diol or mixtures thereof.
8. A fire-resistant hydraulic fluid according to claim 1, characterized in that the ester component therefor consists of the reaction product of
(i) at least 1 neo-acid or neo-alkanoic acid having from 5 to 20 carbon atoms in its molecule, corresponding to the formula
wherein R₁, R₂ and R₃, which can be the same or different, each representing a (C₁-C₆)-alkyl group, and with
(ii) at least a neo-alkyl polyol having from 10 to 12 carbon atoms and from 2 to 6 hydroxyl groups in its molecule.
9. A fire-resistant hydraulic fluid according to claim 8, characterized in that the substituents R₂ and R₃ in the formula (II) acid each represents a methyl group.
10. A fire-resistant hydraulic fluid according to any one of claims 7 to 9, characterized in that for making the ester component at least a polyol is used which has from 2 to 12 hydroxyl groups in its molecule.
11. A fire-resistant hydraulic fluid according to any one of claims 7 to 9, characterized in that for making the ester component at least a non-hindered diol is used which has from 2 to 40 carbon atoms in its molecule.
12. A process for making a fire-resistant hydraulic fluid according to any of claims 1 or 2, characterized in that the components therefor are thoroughly mixed at a temperature of from 40° to 50°C.
13. A process for making the no-phosphorus organic component for making a fire-resistant hydraulic fluid according to any of claims 1 or 2, characterized by the fact that a neo-alkyl polyol is reacted, in the presence of a chemically inert gas, at a temperature of from 150° to 220°C, and in the presence of a solvent, with a straight or branched chain neoalkyl acid, using a mole ratio of the neo-alkyl polyol over the straight or branched chain acid, and the neo-alkyl acid of from 1 : (1.5 to 2) : (3 to 8), and the reaction is allowed to proceed up to an 80-90% reaction rate, depending upon the quantity of water formed during said reaction, and the unreacted acids are distilled off,whereupon said reaction is completed by adding a sufficient amount of straight chain carboxylic acids having from 4 to 12 carbon atoms in their molecule.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT8821908A IT1227061B (en) | 1988-09-13 | 1988-09-13 | SAFETY HYDRODYNAMIC FLUIDS RESISTANT TO FLAME PROPAGATION AND WITH HIGH SELF-IGNITION TEMPERATURE AND PROCEDURE FOR THEIR PREPARATION. |
IT2190888 | 1988-09-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0359071A1 true EP0359071A1 (en) | 1990-03-21 |
Family
ID=11188596
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89116232A Withdrawn EP0359071A1 (en) | 1988-09-13 | 1989-09-02 | Fire-resistant hydraulic fluid and process of manufacture |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP0359071A1 (en) |
IT (1) | IT1227061B (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992001030A1 (en) * | 1990-07-12 | 1992-01-23 | Henkel Corporation | Lubricant for refrigerant heat transfer fluids |
US5141663A (en) * | 1990-08-31 | 1992-08-25 | Olin Corporation | Fire resistant hydraulic fluid composition |
US5833876A (en) * | 1992-06-03 | 1998-11-10 | Henkel Corporation | Polyol ester lubricants for refrigerating compressors operating at high temperatures |
US5853609A (en) * | 1993-03-10 | 1998-12-29 | Henkel Corporation | Polyol ester lubricants for hermetically sealed refrigerating compressors |
EP0899324A1 (en) * | 1997-08-26 | 1999-03-03 | Exxon Research And Engineering Company | Corrosion inhibiting additive combination for turbine oils |
US5976399A (en) | 1992-06-03 | 1999-11-02 | Henkel Corporation | Blended polyol ester lubricants for refrigerant heat transfer fluids |
US6043199A (en) * | 1997-08-26 | 2000-03-28 | Exxon Research And Engineering Co. | Corrosion inhibiting additive combination for turbine oils |
US6183662B1 (en) | 1992-06-03 | 2001-02-06 | Henkel Corporation | Polyol ester lubricants, especially those compatible with mineral oils, for refrigerating compressors operating at high temperatures |
WO2001090232A2 (en) * | 2000-05-25 | 2001-11-29 | Union Carbide Chemicals & Plastics Technology Corporation | A method for providing a fluid composition with improved fire resistance |
WO2007028945A1 (en) * | 2005-09-09 | 2007-03-15 | Castrol Limited | Method of monitoring fire resistance of hydraulic fluids |
WO2008143648A2 (en) | 2006-12-05 | 2008-11-27 | Basf Corporation | A fluid composition having excellent fire-resistance |
WO2021219456A1 (en) * | 2020-04-27 | 2021-11-04 | Klueber Lubrication Muenchen Se & Co. Kg | Lubricant composition and use thereof |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1025294A (en) * | 1963-03-07 | 1966-04-06 | Exxon Research Engineering Co | Lubricants and additives |
EP0011730A1 (en) * | 1978-11-25 | 1980-06-11 | BASF Aktiengesellschaft | Brake fluids having a conserving activity and an amount of oleic acid |
EP0017072A2 (en) * | 1979-04-02 | 1980-10-15 | The Dow Chemical Company | Water-resistant lubricant for compressors and marine engines |
US4234497A (en) * | 1979-04-30 | 1980-11-18 | Standard Lubricants, Inc. | Iso-palmitate polyol ester lubricants |
US4263159A (en) * | 1978-03-24 | 1981-04-21 | Stauffer Chemical Company | Automatic transmission fluid comprising esters derived from a particular monocarboxylic acid composition |
GB2063909A (en) * | 1979-11-29 | 1981-06-10 | Mobil Oil Corp | High flashpoint hydraulic fluid |
US4645615A (en) * | 1986-02-27 | 1987-02-24 | Fmc Corporation | Fire-resistant hydraulic fluid |
-
1988
- 1988-09-13 IT IT8821908A patent/IT1227061B/en active
-
1989
- 1989-09-02 EP EP89116232A patent/EP0359071A1/en not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1025294A (en) * | 1963-03-07 | 1966-04-06 | Exxon Research Engineering Co | Lubricants and additives |
US4263159A (en) * | 1978-03-24 | 1981-04-21 | Stauffer Chemical Company | Automatic transmission fluid comprising esters derived from a particular monocarboxylic acid composition |
EP0011730A1 (en) * | 1978-11-25 | 1980-06-11 | BASF Aktiengesellschaft | Brake fluids having a conserving activity and an amount of oleic acid |
EP0017072A2 (en) * | 1979-04-02 | 1980-10-15 | The Dow Chemical Company | Water-resistant lubricant for compressors and marine engines |
US4234497A (en) * | 1979-04-30 | 1980-11-18 | Standard Lubricants, Inc. | Iso-palmitate polyol ester lubricants |
GB2063909A (en) * | 1979-11-29 | 1981-06-10 | Mobil Oil Corp | High flashpoint hydraulic fluid |
US4645615A (en) * | 1986-02-27 | 1987-02-24 | Fmc Corporation | Fire-resistant hydraulic fluid |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992001030A1 (en) * | 1990-07-12 | 1992-01-23 | Henkel Corporation | Lubricant for refrigerant heat transfer fluids |
US5141663A (en) * | 1990-08-31 | 1992-08-25 | Olin Corporation | Fire resistant hydraulic fluid composition |
US6221272B1 (en) | 1992-06-03 | 2001-04-24 | Henkel Corporation | Polyol ester lubricants for hermetically sealed refrigerating compressors |
US5833876A (en) * | 1992-06-03 | 1998-11-10 | Henkel Corporation | Polyol ester lubricants for refrigerating compressors operating at high temperatures |
US5976399A (en) | 1992-06-03 | 1999-11-02 | Henkel Corporation | Blended polyol ester lubricants for refrigerant heat transfer fluids |
US6296782B1 (en) | 1992-06-03 | 2001-10-02 | Henkel Corporation | Polyol ester lubricants for refrigerator compressors operating at high temperatures |
US6183662B1 (en) | 1992-06-03 | 2001-02-06 | Henkel Corporation | Polyol ester lubricants, especially those compatible with mineral oils, for refrigerating compressors operating at high temperatures |
US5853609A (en) * | 1993-03-10 | 1998-12-29 | Henkel Corporation | Polyol ester lubricants for hermetically sealed refrigerating compressors |
EP0899324A1 (en) * | 1997-08-26 | 1999-03-03 | Exxon Research And Engineering Company | Corrosion inhibiting additive combination for turbine oils |
US6043199A (en) * | 1997-08-26 | 2000-03-28 | Exxon Research And Engineering Co. | Corrosion inhibiting additive combination for turbine oils |
WO2001090232A2 (en) * | 2000-05-25 | 2001-11-29 | Union Carbide Chemicals & Plastics Technology Corporation | A method for providing a fluid composition with improved fire resistance |
WO2001090232A3 (en) * | 2000-05-25 | 2002-03-28 | Union Carbide Chem Plastic | A method for providing a fluid composition with improved fire resistance |
WO2007028945A1 (en) * | 2005-09-09 | 2007-03-15 | Castrol Limited | Method of monitoring fire resistance of hydraulic fluids |
WO2008143648A2 (en) | 2006-12-05 | 2008-11-27 | Basf Corporation | A fluid composition having excellent fire-resistance |
WO2008143648A3 (en) * | 2006-12-05 | 2009-01-15 | Basf Corp | A fluid composition having excellent fire-resistance |
JP2010511774A (en) * | 2006-12-05 | 2010-04-15 | ビーエーエスエフ コーポレーション | Fluid composition having excellent flame retardancy |
WO2021219456A1 (en) * | 2020-04-27 | 2021-11-04 | Klueber Lubrication Muenchen Se & Co. Kg | Lubricant composition and use thereof |
Also Published As
Publication number | Publication date |
---|---|
IT1227061B (en) | 1991-03-14 |
IT8821908A0 (en) | 1988-09-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3224971A (en) | Borate esters and lubricant compositions containing said esters | |
AU632942B2 (en) | Polyalkylene glycol lubricant compositions | |
US3471404A (en) | Lubricating compositions containing polysulfurized olefin | |
US2836564A (en) | Corrosion inhibitors and compositions containing the same | |
US4010105A (en) | Oil-in-water emulsion hydraulic fluid | |
RU2395513C2 (en) | Fuel additive and lubricant materials containing alkylhydroxy carboxylic acid esters | |
US3361672A (en) | Stabilized organic compositions | |
EP0359071A1 (en) | Fire-resistant hydraulic fluid and process of manufacture | |
CA2034717A1 (en) | Derivatized ethylene alpha-olefin polymer useful as multifunctional viscosity index improver additive for oleaginous composition | |
EP0382242A1 (en) | The use of a composition in an hydraulic fluid for power steering | |
EP0551760B1 (en) | Polyether phosphate esters | |
EP0411862A2 (en) | Process of producing sulfur-bridged phenolic antioxidants | |
US3539515A (en) | Lubricating oil compositions containing peroxide-treated phenothiazine as an antioxidant | |
CN101331216A (en) | Additive package for high temperature synthetic lubricants | |
DE3209720C2 (en) | Compositions containing nitrogen and oxygen, processes for their preparation and their use as additives in lubricants and fuels | |
US4655949A (en) | Lubricating oil compositions containing organometallic additives | |
JP5651018B2 (en) | Method for producing lubricating composition | |
US4166796A (en) | Composition comprising a cosulfurized blend of lard oil and an olefin | |
EP2147967A1 (en) | Thermally stable zinc-free antiwear agent | |
US5138065A (en) | Polyether glycol derivatives of 2,5-dimercapto-1,3,4-thiadiazole | |
US20040092411A1 (en) | High temperature stability lubricant composition containing short chain acids and method for making the same | |
EP0420453B1 (en) | Sulphur coupled hydrocarbyl derived mercaptobenzothiazole adducts as multifunctional antiwear additives and compositions containing same | |
US5529706A (en) | Lubricant compositions comprising tolyltriazole-derived tri/tetra esters as additives for distillate fuels | |
US4321153A (en) | Process of sulfurizing triglyceride and an olefin | |
EP0125144B1 (en) | Functional fluids and lubricants having improved water tolerance |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE ES FR GB LI LU NL SE |
|
17P | Request for examination filed |
Effective date: 19900822 |
|
17Q | First examination report despatched |
Effective date: 19910508 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19920407 |