Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
  • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
  • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
• • A—HUMAN NECESSITIES
  • A62—LIFE-SAVING; FIRE-FIGHTING
  • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
  • A62D5/00—Composition of materials for coverings or clothing affording protection against harmful chemical agents
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
  • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material

Definitions

• This invention relates to an inexpensive foam-coated non-woven fabric useful as a barrier fabric for protective clothing worn by workers exposed to dust and dirt.
• Foam-coated and foam-backed textile materials are described in the patent literature, primarily relating to domestic textiles and upholstery fabric.
• U.S. Patent 3,625,970 describing a glass fabric having a foam polymer backing for a drapery
• U.S. Patent 3,748,217 in which a foam organic polymer bonds a textile fabric to a spunlaced nonwoven fabric, again for drapery face fabrics
• U.S. Patent 3 862,921 also U.S. Patent 4,362,774 relating to foam-backed drapery fabrics.
• Various techniques of applying foam to textile substrates are also described in the patent literature, as evidenced by U.S. Patents 3,862,291; 4,362,774; and 4,387,118.
• Other foam polymer applications and procedures are described in U.S. Patents 3,527,565 and 3,642,563.
• U.S. Patent No. 4,499,139 describes forming a strata or layer within the single ply fibrous web, as depicted in figures 1 and 2 of this patent in which the froth is worked into the fabric to form interconnecting links to hold the surface fibers in place.
• the face of the fabric is scraped free of froth so that the outermost fibers on both the top and bottom surfaces are substantially froth-free.
• the fabric of the present invention has an entirely different structure with a quantity of foam on at least one surface of the fabric as well as the foam penetrating most, if not all, of the nonwoven fabric web.
• This invention provides a barrier-type fabric for the protective apparel market at a competitive cost and with comfort advantages.
• the nonwoven coated fabric offers a favorable balance of protection as compared with product cost.
• Foam coating provides a uniform, consistent product, required for an apparel fabric, that may be produced in high volume to further lower the expense of production.
• the fabric's performance may be adjusted to accommodate various requirements and properties by changing the nature of the foam and/or the manner and density to which it is applied.
• the fabric provides ample barrier properties to particulates (dirt, dust, short fibers, lint) and fluids, together with antistatic properties. Product opacity and uniform appearance make the fabric suitable for use in apparel.
• the product consists of a nonwoven substrate, such as a lightweight spunbonded fabric, coated with an open celled polymeric foam preferably including additives to render the coated fabric hydrophobic and antistatic.
• the substrate is a lightweight spunbonded nonwoven or a spunbonded and pointbonded synthetic fabric made of polyester, nylon or, preferably an olefin such as polypropylene may be used. Specific examples include: Other nonwoven substrates could be used depending upon their properties and costs.
• the preferred substrate is spunbonded polypropylene; the most preferred substrate is spunbonded/pointbonded polypropylene.
• Basis weight of the uncoated substrate is in the range of 0.75 to about 2.0 oz/sg. yd. Fiber denier falls in the range of from 1.0 to 5.0.
• the polymeric foam is prepared from an aqueous polymeric solution containing a surfactant (for foaming), fillers and opacifying agents, dyes, curing agents to cure the polymer and property modifiers such as water repellents, antistats, detacifiers, surface lubricants, fungicides or antibacterial agents.
• a surfactant for foaming
• fillers and opacifying agents such as water repellents, antistats, detacifiers, surface lubricants, fungicides or antibacterial agents.
• property modifiers such as water repellents, antistats, detacifiers, surface lubricants, fungicides or antibacterial agents.
• a suitable, open-celled, hydrophobic polymeric foam is created by the mechanical induction of air into a suitable aqueous coating compound or formulation.
• a typical composition for a material of this type is as follows:
• the aqueous polymer dispersion may be acrylic, vinylacetate, vinyl chloride, vinyl alcohol, urethane, styrene butadiene, acrylonitrile, ethylene vinyl acetate, and ethylene vinyl chloride, vinylidene chloride, and is preferably an acrylic latex such as TR77, HAS. HA16, TR934, TR407 (Rohm and Haas) or 21638 (Hycar), HYCAR 561X87 or HYCAR 26804 (B.F. Goodrich).
• the fillers include inorganic mineral fillers such as clay, talc, and silica and opacifiers such as titanium dioxide.
• These solid, substantially insoluble particles are dispersed in the aqueous solution with the use of a dispersing aid or surfactant.
• a dispersing aid or surfactant include kaolin clay, talc, feldspar, mica, silica, pyrophyllite, hydrated alumina and calcium carbonate.
• An appropriate pigment may be included, as desired.
• Titanium dioxide is optional; when present it serves as an opacifier and imparts a more attractive look to a semi-transparent substrate.
• An appropriate colored pigment may be included, as desired. Filler loading is from 0% up to 150% of polymer solids.
• the foam coating is prepared first by mixing the solid fillers and colors to form a dispersion. Solids range from 30% to 65% of the dispersion. Suitable fillers are inorganic mineral fillers such as clays, talcs and carbonates, all as listed above. An opacifier or white pigment such as titanium dioxide may be included, if desired, to lend the correct degree of opacity, or it may be omitted entirely, as explained above. These solid, substantially insoluble particles are dispersed in water with the use of a dispersing aid or surfactant.
• the coating composition is based upon a resin or combination of resins plus filler(s) and indeed the filler(s) may represent more than half of the total weight of the two components.
• Other necessary ingredients include a foaming aid or surfactant to assist in forming a stable foam plus any other reactants or auxiliaries required to cross-link the resin and form a foam that, upon drying, remains stable and continues to exhibit the desired performance characteristics over the life of the article.
• a typical polymer selection may be an acrylic, styrene-butadiene rubber (SBR), vinyl acetate, polyvinyl alcohol urethane, vinyl chloride, or vinylidene chloride or achylonitrile polymer, preferably in the form of a dispersion.
• Total solids of the coating composition range from 40 to 70% by weight.
• the pH of the composition may be adjusted by the addition of a suitable base, such as ammonia, to maintain a pH in the range of 7 to 10, preferably in the range of pH 8 to 9.
• the coating composition prior to foaming, should have a viscosity of from about 400 to 2,000 cps with a viscosity of about 600 to 900 cps preferred.
• a thickener may be included to achieve the best viscosity.
• the coating composition is usually maintained and applied at a temperature in the range of from 70' F to 110°F.
• the melamine resin such as Aerotex 3030, Aerotex M-3 or Permafresh MEL, secures the polymer plus filler to the synthetic fibers of the nonwoven substrate.
• a suitable catalyst such as a diammonium phosphate, magnesium chloride, ammonium chloride or ammonium sulfate, is included to cure the malamine resin. Catalyst concentration is in the range of 0.2 to 5.0% of the formulation. Diammonium phosphate provides an exceptionally hard cure which improves the fabric's water repellency to retain fabric filtration efficiency even when wet. Unexpectedly, diammonium phosphate improves the fabric's antistatic properties, thus is a preferred catalyst.
• the optional fluorocarbon repellent component is typically a dispersion of fluoropolymer in water. See generally Fluorine-Containing Polymers, Encyclopedia of Polymer Science & Technology, pp. 179-203, Interscience, 1967, the disclosure of which is hereby incorporated by reference.
• the fluoropolymer component may be selected from a host of commercially available products including DuPont's Zonyl NWG, Zonyl NWF, Zepel RS, Zepel RN and 3-M's FC-831, FC-834 and FC-461.
• Detacifiers when used, reduce the tendency of the fabric to stick to itself.
• Surface lubricants give the finished fabric a hand similar to a woven fabric.
• Ampitol PE30 of Dexter Chemical is a suitable lubricant.
• Fungicides and antibacterial agents such as Dow Corning DC 5700 may be included.
• the property modifiers are included in the formulation to impart the specific characteristic(s) desired while monitoring the cost of the overall product.
• the coating composition is mechanically foamed in a foam generator such as an Oakes foamer or a L.E.S.S. model 500 super foamer to achieve a ratio of from four to twenty parts air to one part coating composition, with a ratio of 4:1 - 7:1 being preferred.
• a foam generator such as an Oakes foamer or a L.E.S.S. model 500 super foamer to achieve a ratio of from four to twenty parts air to one part coating composition, with a ratio of 4:1 - 7:1 being preferred.
• the compound is then applied by any convenient means, such as a knife coater (knife over roll, knife over gap, knife over table, knife over blanket, floating knife or air knife) or a gapped pad, or by dipping the substrate through the aerated compound.
• the coater is adjusted to apply the coating to the fabric in a fashion so as to both impregnate and surface coat the material.
• a knife coater is preferred to apply the foam.
• the fabric is then run through the coater at a speed of from 50 to 80 yards per minute. The combination of pressure and scraping action forces the coating into the fabric while leaving a thin surface coat. This serves to fill or partially fill the void space between the fibers and provide the degree of filtration desired.
• the fabric is then dried at 150' - 300 F in a conventional hot air tenter frame or infrared, belt or drum dryer at a speed which allows for at least eighteen seconds of drying time.
• Curing temperatures range from 260 . to 350 ⁇ F, the upper limit dependent upon the type of fiber in the substrate.
• the coating may be crushed between a set of rollers which are typically rubber over steel, steel over steel, or steel over rubber.
• the fabric may be post cured for an additional thirty seconds to two minutes at 285' F. During the post cure, an additional finish may be applied to enhance the fabric properties, improve repellency, add softness and reduce blocking. The post cure may be omitted if all properties are achieved in the coating pass.
• the finished fabric is then trimmed and packaged.
• Talc filtration is measured on a 3x3 inch sample for initial aerosol efficiency test IBR TM E-308 using an HIAC 236 laser counter with talc as the contaminant at a flow rate of .945 SCFM (equivalent face velocity of 15 ft/min).
• the results obtained for a typical sample of a barrier fabric according to this invention are as follows:
• a 1.25 oz/sq. yd. spunbonded/pointbonded polypropylene fabric (Celestra II by James River Nonwovens Co.) is knife over foam coated with the following foamed composition:
• the acrylic latex used was Hipofoam TW-1, a compounded, aqueous acrylic latex from High Point Chemical Corp., High Point, North Carolina, which includes fillers, thickeners and foaming agents.
• the above formulation was aerated in a L.E.S.S. Model Digifoam D-501 foamer at a ratio of 7 parts of air to 1 part of formulation.
• the foam was applied to the substrate by knife coating over a foam rubber pad to a solids coating weight of from 0.35 to 0.75 oz/sq. yd.
• the coated fabric was dried and cured in a forced air tenter frame at a temperature of 275 F for 40 seconds.
• the coated fabric was then passed through steel over urethane rubber nip roll to crush the coating structure.
• the coated fabric was slit to the desired width and packaged.
• the fabric produced displayed the following properties:

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Citations (4)

• 1989
  • 1989-06-16 EP EP19890306152 patent/EP0357185A3/de not_active Withdrawn

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