EP0348411A1 - An improved peroxide bleaching method. - Google Patents
An improved peroxide bleaching method.Info
- Publication number
- EP0348411A1 EP0348411A1 EP88901957A EP88901957A EP0348411A1 EP 0348411 A1 EP0348411 A1 EP 0348411A1 EP 88901957 A EP88901957 A EP 88901957A EP 88901957 A EP88901957 A EP 88901957A EP 0348411 A1 EP0348411 A1 EP 0348411A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- pulp
- bleaching
- suspension
- peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/16—Bleaching ; Apparatus therefor with per compounds
- D21C9/163—Bleaching ; Apparatus therefor with per compounds with peroxides
Definitions
- Combinations of hydrogen peroxide with certain organic acids stand out as an especially efficient form of the peroxide bleaching technique.
- the treatment is carried out within the acid range of the pH-scale, facilitating the formation of peroxyacid ⁇ which are the active chemical species in the bleaching process.
- the common way, of bleaching with peroxides is carried out using slightly alkaline conditions enhancing the formation of peroxide anions HC which are the active ionic species. Higher alkalinities are to be avoided since hydrogen peroxide then decomposes to oxygen.
- the purpose of the present disclosure is to describe a simple method to enhance the bleaching efficiency of hydrogen peroxide by adding certain inexpensive organic acids to the bleaching solution.
- the acids in question are formic, acetic, lactic, maleic acid and phtalic acid; they can be used separately or in various combinations. Contrary to similar mixtures of hydrogen peroxide with such acids which have been proposed to increase the efficiency of the bleaching process, cf. for instance Austrian Patent 203.454, the mixtures of the present disclosure are being used within the alkaline range of the pH-scale and not on its acid side.
- This alkalinity of the treating solution is the main characteristic feature of the present invention relating to peroxide bleaching process in the presence of the organic acids enumerated above, i.e. formic, acetic, lactic, maleic acid and phtalic acid or mixtures thereof.
- the bleaching efficiency of peroxides can be improved if the bleaching process is carried out in the presence of low concentrations of one or more of the enumerated acids while maintaining the pH-value within the alkaline range 8-13, which pH-range is provided by the addition of an alkali metal hydroxide, such as sodium hydroxide or potassium hydroxide.
- an alkali metal hydroxide such as sodium hydroxide or potassium hydroxide.
- potassium hydroxide gives a significantly higher brightness of the bleached material than does sodium hydroxide. The difference amounted to 2-8 SCAN brightness units.
- Example 1 The invention is illustrated by means of the following examples.
- Example 1 The invention is illustrated by means of the following examples.
- a bleaching mixture containing 4% H ? 0 2 , 1% acetic acid, and 1% formic acid (based on the weight of the quantity of pulp present in the system) gave after bleaching carried out as described above a brightness of 78%, the brightness gain being 18 units.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88901957T ATE83016T1 (en) | 1987-02-12 | 1988-02-12 | PEROXIDE BLEACHING PROCESS. |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE8700569A SE8700569D0 (en) | 1987-02-12 | 1987-02-12 | AN IMPROVED PEROXIDE BLEACHING METHOD |
SE8700569 | 1987-02-12 | ||
CA000612006A CA1333650C (en) | 1987-02-12 | 1989-09-19 | Peroxide bleaching method |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0348411A1 true EP0348411A1 (en) | 1990-01-03 |
EP0348411B1 EP0348411B1 (en) | 1992-12-02 |
Family
ID=25673050
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88901957A Expired EP0348411B1 (en) | 1987-02-12 | 1988-02-12 | An improved peroxide bleaching method |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0348411B1 (en) |
AT (1) | ATE83016T1 (en) |
CA (1) | CA1333650C (en) |
DE (1) | DE3876429T2 (en) |
FI (1) | FI91545C (en) |
SE (1) | SE8700569D0 (en) |
WO (1) | WO1988006202A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE505980C2 (en) * | 1993-12-23 | 1997-10-27 | Bim Kemi Ab | Ways to prevent peroxide-degrading enzymes by bleaching with hydrogen peroxide |
DE19516151A1 (en) * | 1995-05-03 | 1996-11-07 | Sven Siegle | Process for the production of a pulp from cellulosic material, the pulp itself and its use |
FI115470B (en) * | 1996-02-19 | 2005-05-13 | Kemira Oyj | Process for the treatment of chemical cellulose material |
FI115641B (en) * | 1996-02-19 | 2005-06-15 | Kemira Oyj | Bleaching process for high yields |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE633420A (en) * | 1962-07-16 | |||
DE2219505C3 (en) * | 1972-04-21 | 1974-10-17 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Chlorine-free multi-stage bleaching of cellulose |
-
1987
- 1987-02-12 SE SE8700569A patent/SE8700569D0/en unknown
-
1988
- 1988-02-12 EP EP88901957A patent/EP0348411B1/en not_active Expired
- 1988-02-12 WO PCT/SE1988/000055 patent/WO1988006202A1/en active IP Right Grant
- 1988-02-12 DE DE8888901957T patent/DE3876429T2/en not_active Expired - Fee Related
- 1988-02-12 AT AT88901957T patent/ATE83016T1/en not_active IP Right Cessation
-
1989
- 1989-08-08 FI FI893742A patent/FI91545C/en not_active IP Right Cessation
- 1989-09-19 CA CA000612006A patent/CA1333650C/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO8806202A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE3876429D1 (en) | 1993-01-14 |
FI91545B (en) | 1994-03-31 |
EP0348411B1 (en) | 1992-12-02 |
SE8700569D0 (en) | 1987-02-12 |
ATE83016T1 (en) | 1992-12-15 |
FI893742A0 (en) | 1989-08-08 |
WO1988006202A1 (en) | 1988-08-25 |
DE3876429T2 (en) | 1993-07-01 |
CA1333650C (en) | 1994-12-27 |
FI91545C (en) | 1994-07-11 |
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