EP0321427A2 - Heat radiation tube - Google Patents

Heat radiation tube Download PDF

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Publication number
EP0321427A2
EP0321427A2 EP88850409A EP88850409A EP0321427A2 EP 0321427 A2 EP0321427 A2 EP 0321427A2 EP 88850409 A EP88850409 A EP 88850409A EP 88850409 A EP88850409 A EP 88850409A EP 0321427 A2 EP0321427 A2 EP 0321427A2
Authority
EP
European Patent Office
Prior art keywords
tube
tubes
radiation
extrusion
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88850409A
Other languages
German (de)
French (fr)
Other versions
EP0321427A3 (en
EP0321427B1 (en
Inventor
Jan-Olof Olsson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanthal AB
Original Assignee
Kanthal AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanthal AB filed Critical Kanthal AB
Publication of EP0321427A2 publication Critical patent/EP0321427A2/en
Publication of EP0321427A3 publication Critical patent/EP0321427A3/en
Application granted granted Critical
Publication of EP0321427B1 publication Critical patent/EP0321427B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B5/00—Muffle furnaces; Retort furnaces; Other furnaces in which the charge is held completely isolated
    • F27B5/06—Details, accessories, or equipment peculiar to furnaces of these types
    • F27B5/14—Arrangements of heating devices
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/62—Heating elements specially adapted for furnaces
    • H05B3/64—Heating elements specially adapted for furnaces using ribbon, rod, or wire heater
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/06—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity heated without contact between combustion gases and charge; electrically heated
    • F27B9/068—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity heated without contact between combustion gases and charge; electrically heated heated by radiant tubes, the tube being heated by a hot medium, e.g. hot gases

Definitions

  • the present invention is for a heat radiation tube for furnaces and the like heating purposes.
  • the source of heat can be electrical resistance elements or a burner using for example gas.
  • Furnaces primarily means furnaces for heat treatment in industrial processes.
  • Heat radiation tubes are mainly used in furnaces where the furnace atmosphere does not allow direct heat. This can be due to that the atmosphere is harmful to the elements which are being used for electrical heating or a wish to con­trol the atmosphere in the furnace whereby combustion gases are not allowed therein.
  • Other reasons for the use of radiation tubes instead of direct heating might be for example that one wants to repair or exchange the heat source while the furnace is being used. It will then be easier to do this in a separate space, e.g. inside the radiation tube, than in the furnace chamber itself.
  • a heat radiation tube may comprise a cylindrical tube.
  • a bottom is mounted in one end of the tube.
  • In the other end of the tube there is as a rule a flange for mounting in the furnace wall.
  • the tube can also have other arrangements, protrusions, etc. for mounting in the furnace as well as distance pieces and the like. Mainly when heating is obtained by combustion there may in the tube be inserts for­ming flow channels for the combustion gases.
  • Radiation tubes have hitherto mainly been used by furnace temperatures up to about 1100°C.
  • the tubes are often made from an alloy mainly comprising nickel, chromium and iron.
  • the alloy composition is for example 40-60 weight % nickel, 15-20 % chrom and 25-45 % iron.
  • These radiation tubes how­ever, have certain drawbacks which are of great importance in most application.
  • On the surfaces of the tubes the outside as well as the inside oxide layers are formed which are spalled off when they have reached a certain thickness, which varies due to conditions in each application.
  • the oxide layers do not give protection against continuing attacks on the tubes. Downfalling oxide flakes may cause problems if they get into contact with the products which are present inside the furnaces.
  • the oxide flakes inside the tubes may cause short-circuiting between separate elements and between separate parts of one element which brings with it an imme­diate interruption of the function of the element or a con­siderably decreased life of the element.
  • an element is exchanged, which means that element and element support is pulled out from the radiation tube and after repair or ex­change again is pushed into it,the supports may func­tion as scrapes and bring about heaps of oxides in most cases in the far end of the tube which may cause difficulties by the repair work and function deficiencies.
  • Hitherto used radiation tubes do not have satisfactory mechanical properties by high temperatures of use. Due to their own weight and the internal load the tubes tend to sag. In order to compensate for this the tubes have to be turn­ed 180° at regular intervals. This can in most cases be made in connection with normal maintenance or repair but it is still an important drawback and a factor which limits the possibilities of use.
  • the object of the present invention is to avoid the above-mentioned drawbacks of hitherto known radiation tubes and to make possible a higher temperature of use than has hitherto been possible.
  • the invention also makes it possible to have longer intervals between stops for main­tenance works.
  • the much reduced or totally eliminated sagging of the tubes means much for reliable function of the radiation tubes as well as easier maintenance.
  • Radiation tubes according to the invention are intended for use in furnaces and the like heating purposes and are characterized therein that the tube is made from an alloy of FeCrAl-type whereby a cylindrical part is a seamless tube. These radiation tubes have important advantages compared to conventional tubes made by casting or welding of plates from nickel chromium or iron-nickel-chromium-alloys. Radia­tion tubes according to the invention can be used at tempe­ratures up to 1250-1300°C.
  • FeCrAl-alloys at oxidizing con­ditions form a stable and adhering layer of aluminium oxide on the surface of the material.
  • This oxide is also more heat resistant and resistant against chemical attacks than the layers which are formed on nickel-chromium-alloys. This is particularly obvious in sulphur containing environments, where rapid and severe attacks are obtained on nickel-chro­mium materials. If the oxide layer is undamaged the FeCrAl-­alloys are better also in carburating atmosphere. In many app­lications it is therefore important to pre-oxidize the radiation tubes according to the invention. This shall be done also if the intended temperature of use is below 1100°C.
  • Suitable pre-oxidation is for example heat treatment in air at 1100°C for at least 8 hours.
  • the FeCrAl-alloy may also contain minor amounts of other alloying components such as yttrium, titanium and zirkonium in amounts up to 0.2 weight % of each. These additives influence the oxide layers as well as the structure and properties of the material.
  • the cylindrical tube which is a main part of the radia­tion tube is seam-less and preferably made by extrusion.
  • the slab which is used for the extrusion is made in a well-­known way be casting or by power metallurgy.
  • the shearing speed and other conditions by extrusion are choosen to give the tubes a striped surface which means that all of the outer surface of the tubes is rough with axially extending irregular grooves and ridges, the size of which is chosen to optimize the properties of the oxide layer, mainly its strength and elasticity, in order to avoid oxide spalling by high temperatures and changing temperature.
  • Fig. 1 shows several radiation tubes (1, 2A, 2B) which have been mounted into a furnace, whereof a brick wall (3) is shown.
  • the radiation tubes have a sheath which is a cylindrical tube (9) made from FeCrAl material.
  • FeCrAl material means iron-chromium-aluminium-alloys as described above.
  • a wall (not shown) from the same material.
  • Into the wall (3) of the furnace is opened a hole which corresponds to the tube and wherein the end of the tube is supported.
  • a corresponding support for example a shelf or an opening in the furnace wall.
  • the distance between the walls of the furnace can be up to 2 meters and the radi­ation tube is hanging unsupported therein between.
  • an electrical resistance element (4) which in the example shown is made from MoSi2 of the kind which is marketed under the trademark KANTHAL SUPER.
  • the element is resting on a ceramic support (5).
  • the terminal parts (7) of the element pass through two plugs (6, 8), which separate the hot atmosphere of the radiation tube from the surroundings and support the terminal parts.
  • the radiation tube shown in Fig. 2 is intended to be heated by an indicated gas burner (14).
  • the combustion gases from the burner flow firstly through the insert (12), make a turn at the wall (10) and flow back along the radiation tube (9).
  • the latter has a flange (11) for mounting to the furnace wall in a conventional way.
  • Supports (13) are welded to the insert.
  • the radiation tubes shown in figures 1 and 2 have dimen­sions chosen with respect to the furnace wherein they are to be used.
  • the length of the tube may be 1800 mm, its external diameter 200 mm and wall thickness 8 mm.
  • Figures 3 and 4 show the appearance of a radiation tube according to the invention.
  • Figure 3 is a photograph of the surface of the tube and figure 4 shows a cross section of the same surface of the tube at about 50 times magnifica­tion. The striped appearance of the surface is shown in the pictures. These crystal stripes are obtained by the use of a sufficient high shearing speed at the extrusion process and can be essential for the properties of the oxide layer.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Resistance Heating (AREA)
  • Combustion Of Fluid Fuel (AREA)
  • Furnace Details (AREA)
  • Gas Burners (AREA)
  • Heat Treatment Of Articles (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Extrusion Of Metal (AREA)

Abstract

The invention is for heat radiation tubes for furnaces and the like heating devices, mainly for industrial processes.
Heating can be obtained by electrical heating elements or by combustion for example of gas. The radiation tube is a circular tube having end walls, flanges etc. as required.
Thereby that a radation tube according to the invention is a seam-less tube made from iron-chromium-aluminium essential advantages are obtained in respect of oxide spalling which is greatly reduced and shape strength at high tempera­tures of use. Preferably the tubes are made by extrusion whereby conditions are chosen to give a rough surface with grooves and ridges which further improves the adhesion of the oxide layer.

Description

  • The present invention is for a heat radiation tube for furnaces and the like heating purposes. The source of heat can be electrical resistance elements or a burner using for example gas. Furnaces primarily means furnaces for heat treatment in industrial processes.
  • Heat radiation tubes are mainly used in furnaces where the furnace atmosphere does not allow direct heat. This can be due to that the atmosphere is harmful to the elements which are being used for electrical heating or a wish to con­trol the atmosphere in the furnace whereby combustion gases are not allowed therein. Other reasons for the use of radiation tubes instead of direct heating where such should be possible might be for example that one wants to repair or exchange the heat source while the furnace is being used. It will then be easier to do this in a separate space, e.g. inside the radiation tube, than in the furnace chamber itself.
  • A heat radiation tube may comprise a cylindrical tube. A bottom is mounted in one end of the tube. In the other end of the tube there is as a rule a flange for mounting in the furnace wall. The tube can also have other arrangements, protrusions, etc. for mounting in the furnace as well as distance pieces and the like. Mainly when heating is obtained by combustion there may in the tube be inserts for­ming flow channels for the combustion gases. There are also U-shaped radiation tubes.
  • Radiation tubes have hitherto mainly been used by furnace temperatures up to about 1100°C. The tubes are often made from an alloy mainly comprising nickel, chromium and iron. The alloy composition is for example 40-60 weight % nickel, 15-20 % chrom and 25-45 % iron. These radiation tubes, how­ever, have certain drawbacks which are of great importance in most application. On the surfaces of the tubes the outside as well as the inside oxide layers are formed which are spalled off when they have reached a certain thickness, which varies due to conditions in each application. Hereby the oxide layers do not give protection against continuing attacks on the tubes. Downfalling oxide flakes may cause problems if they get into contact with the products which are present inside the furnaces. However, the greatest problems are cau­sed by the oxide flakes inside the tubes. If these are holding electrical elements for the heating the flakes may cause short-circuiting between separate elements and between separate parts of one element which brings with it an imme­diate interruption of the function of the element or a con­siderably decreased life of the element. When an element is exchanged, which means that element and element support is pulled out from the radiation tube and after repair or ex­change again is pushed into it,the supports may func­tion as scrapes and bring about heaps of oxides in most cases in the far end of the tube which may cause difficulties by the repair work and function deficiencies.
  • Hitherto used radiation tubes do not have satisfactory mechanical properties by high temperatures of use. Due to their own weight and the internal load the tubes tend to sag. In order to compensate for this the tubes have to be turn­ed 180° at regular intervals. This can in most cases be made in connection with normal maintenance or repair but it is still an important drawback and a factor which limits the possibilities of use.
  • The object of the present invention is to avoid the above-mentioned drawbacks of hitherto known radiation tubes and to make possible a higher temperature of use than has hitherto been possible. This mainly refers to a higher con­stant temperature by continuous use. The invention also makes it possible to have longer intervals between stops for main­tenance works. The much reduced or totally eliminated sagging of the tubes means much for reliable function of the radiation tubes as well as easier maintenance.
  • Radiation tubes according to the invention are intended for use in furnaces and the like heating purposes and are characterized therein that the tube is made from an alloy of FeCrAl-type whereby a cylindrical part is a seamless tube. These radiation tubes have important advantages compared to conventional tubes made by casting or welding of plates from nickel chromium or iron-nickel-chromium-alloys. Radia­tion tubes according to the invention can be used at tempe­ratures up to 1250-1300°C.
  • At high temperatures FeCrAl-alloys at oxidizing con­ditions form a stable and adhering layer of aluminium oxide on the surface of the material. This oxide is also more heat resistant and resistant against chemical attacks than the layers which are formed on nickel-chromium-alloys. This is particularly obvious in sulphur containing environments, where rapid and severe attacks are obtained on nickel-chro­mium materials. If the oxide layer is undamaged the FeCrAl-­alloys are better also in carburating atmosphere. In many app­lications it is therefore important to pre-oxidize the radiation tubes according to the invention. This shall be done also if the intended temperature of use is below 1100°C. Suitable pre-oxidation is for example heat treatment in air at 1100°C for at least 8 hours. The FeCrAl-alloy may also contain minor amounts of other alloying components such as yttrium, titanium and zirkonium in amounts up to 0.2 weight % of each. These additives influence the oxide layers as well as the structure and properties of the material.
  • The cylindrical tube which is a main part of the radia­tion tube is seam-less and preferably made by extrusion. The slab which is used for the extrusion is made in a well-­known way be casting or by power metallurgy. The shearing speed and other conditions by extrusion are choosen to give the tubes a striped surface which means that all of the outer surface of the tubes is rough with axially extending irregular grooves and ridges, the size of which is chosen to optimize the properties of the oxide layer, mainly its strength and elasticity, in order to avoid oxide spalling by high temperatures and changing temperature.
  • Below the invention will be further described with re­ference to the accompanying figures.
    • Fig. 1 shows electrically heated radiation tubes inside a furnace. One of the radiation tubes is shown with part of the tube cut away in order to show the element.
    • Fig. 2 shows a cross section through a radiation tube which is heated by combustion of gas.
    • Fig. 3 shows the surface of the cylindrical tube of a radiation tube.
    • Fig. 4 shows a cross section of the cylindrical tube.
  • Fig. 1 shows several radiation tubes (1, 2A, 2B) which have been mounted into a furnace, whereof a brick wall (3) is shown. The radiation tubes have a sheath which is a cylindrical tube (9) made from FeCrAl material. FeCrAl material means iron-chromium-aluminium-alloys as described above. At the outer end of the tube is a wall (not shown) from the same material. Into the wall (3) of the furnace is opened a hole which corresponds to the tube and wherein the end of the tube is supported. For the not shown end of the tube there is a corresponding support, for example a shelf or an opening in the furnace wall. The distance between the walls of the furnace can be up to 2 meters and the radi­ation tube is hanging unsupported therein between. Inside the tube there is an electrical resistance element (4) which in the example shown is made from MoSi₂ of the kind which is marketed under the trademark KANTHAL SUPER. The element is resting on a ceramic support (5). The terminal parts (7) of the element pass through two plugs (6, 8), which separate the hot atmosphere of the radiation tube from the surroundings and support the terminal parts.
  • The radiation tube shown in Fig. 2 is intended to be heated by an indicated gas burner (14). The combustion gases from the burner flow firstly through the insert (12), make a turn at the wall (10) and flow back along the radiation tube (9). The latter has a flange (11) for mounting to the furnace wall in a conventional way. Supports (13) are welded to the insert.
  • The radiation tubes shown in figures 1 and 2 have dimen­sions chosen with respect to the furnace wherein they are to be used. For example, the length of the tube may be 1800 mm, its external diameter 200 mm and wall thickness 8 mm.
  • Figures 3 and 4 show the appearance of a radiation tube according to the invention. Figure 3 is a photograph of the surface of the tube and figure 4 shows a cross section of the same surface of the tube at about 50 times magnifica­tion. The striped appearance of the surface is shown in the pictures. These crystal stripes are obtained by the use of a sufficient high shearing speed at the extrusion process and can be essential for the properties of the oxide layer.

Claims (6)

1) Radiation for furnaces and the like heating purposes, characterized in that the tube is made from a FeCrAl alloy, whereby its cylindrical part is a seam-less tube.
2) Radiation tube according to claim 1, characte­rized in that the tube is extruded.
3) Radiation tube according to any of the preceding claims, characterized in that the surface of the tube is rough having along the tube extending irregular grooves and ridges.
4) Radiation tube according to any of the preceding claims, characterized in that its outer surface by pre-oxidation has been covered with an oxide layer comprising mainly aluminum oxide.
5) Method of the production of tubes of alloys of FeCrAl type, characterized in that the tubes are obtained by extrusion.
6) Method according to claim 5, characterized in that the extrusion is made at such a shearing speed that the surface of the tube is rough having along the tube extending grooves and ridges.
EP88850409A 1987-12-04 1988-12-05 Heat radiation tube Expired - Lifetime EP0321427B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE8704859A SE459524B (en) 1987-12-04 1987-12-04 VAERMESTRAALNINGSROER

Publications (3)

Publication Number Publication Date
EP0321427A2 true EP0321427A2 (en) 1989-06-21
EP0321427A3 EP0321427A3 (en) 1989-07-05
EP0321427B1 EP0321427B1 (en) 1996-08-28

Family

ID=20370503

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88850409A Expired - Lifetime EP0321427B1 (en) 1987-12-04 1988-12-05 Heat radiation tube

Country Status (5)

Country Link
EP (1) EP0321427B1 (en)
KR (1) KR0126475B1 (en)
DE (1) DE3855704T2 (en)
ES (1) ES2090017T3 (en)
SE (1) SE459524B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0564665A2 (en) * 1990-05-14 1993-10-13 Kanthal AB Cracking Furnace
US5409748A (en) * 1990-12-31 1995-04-25 Pohang Iron & Steel Co., Ltd. Heat radiating tube for annealing furnace, with ceramic coated on the inside thereof
EP1018563A1 (en) * 1997-08-20 2000-07-12 Jgc Corporation Heating furnace tube, method of using the same, and method of manufacturing the same
FR2800450A1 (en) * 1999-10-28 2001-05-04 Stein Heurtey Device for indirect heating tubes, bands, rods, etc. using fossil fuel has parallelepiped shaped radiant cassette with rectangular cross section of specified aspect ratio

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3137486A (en) * 1962-11-28 1964-06-16 Multifastener Company Burner construction
US3735008A (en) * 1970-03-20 1973-05-22 Kokusai Electric Co Ltd Electric furnace
US3984616A (en) * 1975-10-14 1976-10-05 Btu Engineering Corporation High temperature furnace heater
US4011395A (en) * 1975-09-15 1977-03-08 Btu Engineering Company Electric furnace heater
US4215233A (en) * 1978-12-29 1980-07-29 Alco Standard Corporation Heating assembly with vibration dampening shipping supports for graphite heating elements
US4355973A (en) * 1981-02-17 1982-10-26 Caterpillar Tractor Co. Radiant heating apparatus
US4589844A (en) * 1984-07-25 1986-05-20 Advanced Combustion Inc. Heat exchange apparatus for industrial furnaces

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3137486A (en) * 1962-11-28 1964-06-16 Multifastener Company Burner construction
US3735008A (en) * 1970-03-20 1973-05-22 Kokusai Electric Co Ltd Electric furnace
US4011395A (en) * 1975-09-15 1977-03-08 Btu Engineering Company Electric furnace heater
US3984616A (en) * 1975-10-14 1976-10-05 Btu Engineering Corporation High temperature furnace heater
US4215233A (en) * 1978-12-29 1980-07-29 Alco Standard Corporation Heating assembly with vibration dampening shipping supports for graphite heating elements
US4355973A (en) * 1981-02-17 1982-10-26 Caterpillar Tractor Co. Radiant heating apparatus
US4589844A (en) * 1984-07-25 1986-05-20 Advanced Combustion Inc. Heat exchange apparatus for industrial furnaces

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DIN 2462 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0564665A2 (en) * 1990-05-14 1993-10-13 Kanthal AB Cracking Furnace
EP0564665A3 (en) * 1990-05-14 1993-12-01 Kanthal Ab Cracking furnace
US5409748A (en) * 1990-12-31 1995-04-25 Pohang Iron & Steel Co., Ltd. Heat radiating tube for annealing furnace, with ceramic coated on the inside thereof
EP1018563A1 (en) * 1997-08-20 2000-07-12 Jgc Corporation Heating furnace tube, method of using the same, and method of manufacturing the same
EP1018563A4 (en) * 1997-08-20 2001-12-12 Jgc Corp Heating furnace tube, method of using the same, and method of manufacturing the same
FR2800450A1 (en) * 1999-10-28 2001-05-04 Stein Heurtey Device for indirect heating tubes, bands, rods, etc. using fossil fuel has parallelepiped shaped radiant cassette with rectangular cross section of specified aspect ratio
EP1203921A1 (en) * 1999-10-28 2002-05-08 Stein Heurtey Fossil fuel indirect heating device for moving materials , in particular strips

Also Published As

Publication number Publication date
SE459524B (en) 1989-07-10
DE3855704D1 (en) 1997-01-23
SE8704859L (en) 1989-06-05
KR0126475B1 (en) 1997-12-26
DE3855704T2 (en) 1997-04-17
SE8704859D0 (en) 1987-12-04
EP0321427A3 (en) 1989-07-05
KR900010344A (en) 1990-07-07
ES2090017T3 (en) 1996-10-16
EP0321427B1 (en) 1996-08-28

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