EP0272508A3 - Herbicides of the sulfonimide type with an aminomethyl phosphonic group - Google Patents

Herbicides of the sulfonimide type with an aminomethyl phosphonic group Download PDF

Info

Publication number
EP0272508A3
EP0272508A3 EP87117778A EP87117778A EP0272508A3 EP 0272508 A3 EP0272508 A3 EP 0272508A3 EP 87117778 A EP87117778 A EP 87117778A EP 87117778 A EP87117778 A EP 87117778A EP 0272508 A3 EP0272508 A3 EP 0272508A3
Authority
EP
European Patent Office
Prior art keywords
herbicides
carbon atoms
phosphonic group
alkyl
aminomethyl phosphonic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP87117778A
Other languages
German (de)
French (fr)
Other versions
EP0272508A2 (en
Inventor
Guy Borrod
Guy Lacroix
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience SA
Original Assignee
Rhone Poulenc Agrochimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR8312620A external-priority patent/FR2549839B1/en
Priority claimed from FR8402988A external-priority patent/FR2560198B1/en
Application filed by Rhone Poulenc Agrochimie SA filed Critical Rhone Poulenc Agrochimie SA
Publication of EP0272508A2 publication Critical patent/EP0272508A2/en
Publication of EP0272508A3 publication Critical patent/EP0272508A3/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/44—Amides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Procédé de préparation de composés de formule : dans laquelle
R₇, R₂₁, R₃₁ représentent un radical alkyle de 1 à 12 atomes de carbone, de préférence 1 à 8 atomes de carbone, un radical aryle de 6 à 12 atomes de carbone, les dits radicaux étant éventuellement substitués par les atomes d'halogéne, les groupes phényle, cyano, alkyle, alkoxyle, carboxylate d'alkyle dans lesquels les groupes alkyle ont 1 à 4 atomes de carbone. Process for the preparation of compounds of formula: in which
R₇, R₂₁, R₃₁ represent an alkyl radical of 1 to 12 carbon atoms, preferably 1 to 8 carbon atoms, an aryl radical of 6 to 12 carbon atoms, the said radicals being optionally substituted by the halogen atoms, phenyl, cyano, alkyl, alkoxyl, alkyl carboxylate groups in which the alkyl groups have 1 to 4 carbon atoms.

EP87117778A 1983-07-27 1984-07-25 Herbicides of the sulfonimide type with an aminomethyl phosphonic group Withdrawn EP0272508A3 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR8312620A FR2549839B1 (en) 1983-07-27 1983-07-27 NOVEL SULFONAMIDE GROUP HERBICIDES DERIVED FROM N-PHOSPHONOMETHYL GLYCINE
FR8312620 1983-07-27
FR8402988 1984-02-23
FR8402988A FR2560198B1 (en) 1984-02-23 1984-02-23 ESTERS OF THE N-PHOSPHONOMETHYLGLYCIN FAMILY AND THEIR USE FOR THE PREPARATION OF KNOWN HERBICIDES

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP84420127.7 Division 1984-07-25
EP84420127A Division EP0135454B1 (en) 1983-07-27 1984-07-25 Herbicides of the sulfon imide-type with an aminomethylphosphonic group

Publications (2)

Publication Number Publication Date
EP0272508A2 EP0272508A2 (en) 1988-06-29
EP0272508A3 true EP0272508A3 (en) 1988-10-05

Family

ID=26223542

Family Applications (2)

Application Number Title Priority Date Filing Date
EP87117778A Withdrawn EP0272508A3 (en) 1983-07-27 1984-07-25 Herbicides of the sulfonimide type with an aminomethyl phosphonic group
EP84420127A Expired EP0135454B1 (en) 1983-07-27 1984-07-25 Herbicides of the sulfon imide-type with an aminomethylphosphonic group

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP84420127A Expired EP0135454B1 (en) 1983-07-27 1984-07-25 Herbicides of the sulfon imide-type with an aminomethylphosphonic group

Country Status (25)

Country Link
US (2) US4738708A (en)
EP (2) EP0272508A3 (en)
KR (1) KR850001224A (en)
AR (1) AR240945A1 (en)
AT (1) ATE43603T1 (en)
AU (1) AU582120B2 (en)
BG (1) BG41475A3 (en)
BR (1) BR8403732A (en)
CA (2) CA1256446A (en)
DD (1) DD218544A5 (en)
DE (1) DE3478441D1 (en)
DK (1) DK364984A (en)
EG (1) EG17125A (en)
ES (8) ES534413A0 (en)
FI (1) FI78704C (en)
GB (2) GB2144425B (en)
GR (1) GR82228B (en)
IL (1) IL72488A (en)
NZ (1) NZ209010A (en)
OA (1) OA07757A (en)
PH (2) PH21384A (en)
PL (1) PL141870B1 (en)
PT (1) PT78984B (en)
RO (1) RO89639A (en)
TR (1) TR22114A (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES534413A0 (en) * 1983-07-27 1986-01-01 Rhone Poulenc Agrochimie SULFONAMIDES PREPARATION PROCEDURE WITH ANSYNOMETHYLPHOSPHONIC GROUP
FR2576024B1 (en) * 1985-01-14 1988-01-08 Rhone Poulenc Agrochimie TYPE N HERBICIDES - (PHOSPHONOMETHYLGLYCYL) SULFONYLAMINES
FR2576181B1 (en) * 1985-01-23 1987-04-03 Rhone Poulenc Agrochimie HERBICIDE MIXTURES BASED ON N- TYPE COMPOUND (PHOSPHONOMETHYLGLYCYL)
FR2579210B1 (en) * 1985-03-21 1987-09-11 Rhone Poulenc Agrochimie PREPARATION OF PHOSPHONATE GROUP HERBICIDES AND INTERMEDIATES FROM BENZOXAZINES
FR2590901B1 (en) * 1985-12-04 1988-07-29 Rhone Poulenc Agrochimie PROCESS FOR THE PREPARATION OF N-SULFONYL N- (PHOSPHONOMETHYL-GLYCYL) AMINES FOR USE AS HERBICIDES
FR2611204B1 (en) * 1987-02-19 1989-05-05 Rhone Poulenc Agrochimie INTERMEDIATE COMPOUNDS USEFUL FOR THE PREPARATION OF HERBICIDES
CA2097913C (en) * 1991-01-08 2002-08-20 Kristin Anne Arnold Improved herbicidal formulation
DE4326887A1 (en) * 1993-08-11 1995-02-16 Hoechst Ag Process for the preparation of N-substituted aminoalkylenephosphonic esters
US6505420B1 (en) 1996-02-09 2003-01-14 Reebok International Ltd. Cushioning member for an article of footwear
US7361767B2 (en) * 2003-11-14 2008-04-22 3M Innovative Properties Company N-sulfonyldicarboximide containing tethering compounds
WO2005049590A2 (en) * 2003-11-14 2005-06-02 3M Innovative Properties Company N-sulfonylaminocarbonyl containing compounds
US7169933B2 (en) * 2003-11-14 2007-01-30 3M Innovative Properties Company N-sulfonylaminocarbonyl containing compounds
US7943388B2 (en) * 2003-11-14 2011-05-17 3M Innovative Properties Company Acoustic sensors and methods
US7423155B2 (en) * 2003-11-14 2008-09-09 3M Innovative Properties Company N-sulfonyldicarboximide containing tethering compounds
ATE542425T1 (en) * 2004-09-17 2012-02-15 Monsanto Technology Llc GLYPHOSATE FORMULATIONS WITH EARLY BURNS SYMPTOMS
US7544756B2 (en) * 2005-09-30 2009-06-09 3M Innovative Properties Company Crosslinked polymers with amine binding groups
US7544754B2 (en) 2005-09-30 2009-06-09 3M Innovative Properties Company Crosslinked polymers with amine binding groups

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0055695A1 (en) * 1980-12-30 1982-07-07 Ciba-Geigy Ag Process for preparing N-phosphonomethyl glycine

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US3160632A (en) * 1961-01-30 1964-12-08 Stauffer Chemical Co Aminomethylenephosphinic acids, salts thereof, and process for their production
NL285361A (en) * 1961-11-13 1900-01-01
US3455675A (en) * 1968-06-25 1969-07-15 Monsanto Co Aminophosphonate herbicides
US3799758A (en) * 1971-08-09 1974-03-26 Monsanto Co N-phosphonomethyl-glycine phytotoxicant compositions
PH16509A (en) * 1971-03-10 1983-11-08 Monsanto Co N-phosphonomethylglycine phytotoxicant composition
US4659860A (en) * 1971-08-09 1987-04-21 Monsanto Company Thioester of n-phosphonomethylglycine
US3977860A (en) * 1971-08-09 1976-08-31 Monsanto Company Herbicidal compositions and methods employing esters of N-phosphonomethylglycine
GB1436843A (en) * 1972-07-21 1976-05-26 Ici Ltd Preparation of n-phosphonomethyl-glycine
RO67869A (en) * 1972-12-11 1981-06-22 Mensanto Co,Us PROCESS FOR THE PREPARATION OF N-PHOSPHONOMETHYL GLUCIUM N-OXIDES DERIVATIVES
US3835000A (en) * 1972-12-21 1974-09-10 Monsanto Co Electrolytic process for producing n-phosphonomethyl glycine
US3868407A (en) * 1973-11-21 1975-02-25 Monsanto Co Carboxyalkyl esters of n-phosphonomethyl glycine
US3948975A (en) * 1974-08-05 1976-04-06 Monsanto Company Hydroxyalkyl esters of N-phosphonomethyl glycine
US3993467A (en) * 1974-08-05 1976-11-23 Monsanto Company Hydroxyalkyl esters of N-phosphonomethyl glycine and the herbicidal use thereof
US3972915A (en) * 1974-08-14 1976-08-03 Monsanto Company N-phosphonomethylglycine phenyl hydrazides
US3927080A (en) * 1974-09-03 1975-12-16 Monsanto Co Process for producing N-phosphonomethyl glycine
US4106923A (en) * 1975-11-10 1978-08-15 Monsanto Company Phosphonomethyl glycine ester anhydrides, herbicidal composition containing same and use thereof
US4405531A (en) * 1975-11-10 1983-09-20 Monsanto Company Salts of N-phosphonomethylglycine
DE2860342D1 (en) * 1977-08-11 1981-02-12 Ciba Geigy Ag Glycylmethyl-phosphinic acid derivatives, their preparation and their use
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US4395276A (en) * 1980-06-18 1983-07-26 Monsanto Company Thiosulfenamide derivatives of N-phosphonomethylglycinonitriles as herbicides
US4428755A (en) * 1980-07-09 1984-01-31 General Electric Company Process for the production of silicone carbide composite
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US4666500A (en) * 1981-01-02 1987-05-19 Monsanto Company Alkyl N-arylsulfenyl-N-diaryloxy-phosphinylmethylglycinates
US4395374A (en) * 1981-01-02 1983-07-26 Monsanto Company Alkyl N-arylsulfenyl-N-diaryloxy-phosphinylmethylglycinates
US4388103A (en) * 1981-06-19 1983-06-14 Monsanto Company Alkylphosphonate monoesters of N-phosphonomethylglycinate as herbicides
US4525202A (en) * 1981-08-24 1985-06-25 Stauffer Chemical Co. Phosphonium salts of N-phosphonomethylglycine and their use as herbicides and plant growth regulants
US4405356A (en) * 1981-08-31 1983-09-20 Monsanto Company Ester derivatives of N-arylsulfinyl-N-phosphonomethylglycinates as herbicides
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US4368162A (en) * 1981-11-02 1983-01-11 Ciba-Geigy Corporation Process for producing aminomethylphosphonic acid
US4486358A (en) * 1982-06-24 1984-12-04 Ciba-Geigy Corporation Process for producing N-phosphonomethylglycine
IL65187A (en) * 1982-03-08 1985-03-31 Geshuri Lab Ltd N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them
US4427599A (en) * 1982-06-22 1984-01-24 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
US4476063A (en) * 1982-06-22 1984-10-09 Stauffer Chemical Company N-Acylaminomethyl-N-cyanomethyl phosphonates
US4534902A (en) * 1982-06-22 1985-08-13 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
US4422982A (en) * 1982-06-30 1983-12-27 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
US4482504A (en) * 1982-08-30 1984-11-13 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
US4534904A (en) * 1982-11-19 1985-08-13 Ciba-Geigy Corporation Process for producing N-phosphonomethylglycine
US4439373A (en) * 1982-12-27 1984-03-27 Stauffer Chemical Company Process for preparing phosphonomethylated amino acids
US4491548A (en) * 1983-04-28 1985-01-01 Stauffer Chemical Company Process for preparing phosphonomethylated amino acids
ES534413A0 (en) * 1983-07-27 1986-01-01 Rhone Poulenc Agrochimie SULFONAMIDES PREPARATION PROCEDURE WITH ANSYNOMETHYLPHOSPHONIC GROUP
EP0141794A1 (en) * 1983-08-04 1985-05-15 Monsanto Company Aralower alkyl and substituted aralower alkyl esters of N-phosphonomethylglycines
FR2575161B1 (en) * 1984-12-26 1989-03-31 Rhone Poulenc Agrochimie PREPARATION OF PHOSPHORUS INTERMEDIATES FOR HERBICIDE USES

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0055695A1 (en) * 1980-12-30 1982-07-07 Ciba-Geigy Ag Process for preparing N-phosphonomethyl glycine

Also Published As

Publication number Publication date
GB2193497B (en) 1988-06-29
ES8603901A1 (en) 1986-01-01
US4894082A (en) 1990-01-16
ES547466A0 (en) 1986-03-16
GB2193497A (en) 1988-02-10
FI842960A0 (en) 1984-07-25
OA07757A (en) 1985-08-30
US4738708A (en) 1988-04-19
EG17125A (en) 1991-03-30
PT78984A (en) 1984-08-01
CA1256446A (en) 1989-06-27
DD218544A5 (en) 1985-02-13
GB8418961D0 (en) 1984-08-30
DE3478441D1 (en) 1989-07-06
AR240945A2 (en) 1991-03-27
AR240945A1 (en) 1991-03-27
EP0135454A1 (en) 1985-03-27
ES8605528A1 (en) 1986-03-16
ES547467A0 (en) 1986-05-16
FI842960A (en) 1985-01-28
PL248926A1 (en) 1985-08-27
FI78704C (en) 1989-09-11
CA1249598A (en) 1989-01-31
ES547470A0 (en) 1986-05-16
GB2144425B (en) 1988-06-29
TR22114A (en) 1986-04-25
DK364984D0 (en) 1984-07-26
BR8403732A (en) 1985-07-02
ES8607328A1 (en) 1986-05-16
ES547468A0 (en) 1986-05-16
GB8626464D0 (en) 1986-12-03
NZ209010A (en) 1990-12-21
ES8607327A1 (en) 1986-05-16
GR82228B (en) 1984-12-13
DK364984A (en) 1985-01-28
ES8607330A1 (en) 1986-05-16
ATE43603T1 (en) 1989-06-15
ES534413A0 (en) 1986-01-01
IL72488A0 (en) 1984-11-30
BG41475A3 (en) 1987-06-15
AU3113384A (en) 1985-01-31
EP0135454B1 (en) 1989-05-31
KR850001224A (en) 1985-03-16
AU582120B2 (en) 1989-03-16
ES547465A0 (en) 1986-03-16
GB2144425A (en) 1985-03-06
PT78984B (en) 1986-10-23
IL72488A (en) 1989-01-31
ES8605527A1 (en) 1986-03-16
FI78704B (en) 1989-05-31
PH21384A (en) 1987-10-15
EP0272508A2 (en) 1988-06-29
ES8607329A1 (en) 1986-05-16
PL141870B1 (en) 1987-09-30
PH21723A (en) 1988-02-05
ES547469A0 (en) 1986-05-16
ES8607326A1 (en) 1986-05-16
ES547471A0 (en) 1986-05-16
RO89639A (en) 1986-06-30

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