EP0262291A1 - Device for refuse pyrolysis - Google Patents
Device for refuse pyrolysis Download PDFInfo
- Publication number
- EP0262291A1 EP0262291A1 EP87106352A EP87106352A EP0262291A1 EP 0262291 A1 EP0262291 A1 EP 0262291A1 EP 87106352 A EP87106352 A EP 87106352A EP 87106352 A EP87106352 A EP 87106352A EP 0262291 A1 EP0262291 A1 EP 0262291A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pyrolysis
- flue gas
- waste incineration
- combustion chamber
- gases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000197 pyrolysis Methods 0.000 title claims abstract description 44
- 239000007789 gas Substances 0.000 claims abstract description 27
- 239000003546 flue gas Substances 0.000 claims abstract description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000002485 combustion reaction Methods 0.000 claims abstract description 13
- 238000004056 waste incineration Methods 0.000 claims abstract description 12
- 239000002699 waste material Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 abstract description 6
- 239000000463 material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 150000004074 biphenyls Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011273 tar residue Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
- F23G5/0273—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using indirect heating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/44—Details; Accessories
- F23G5/46—Recuperation of heat
Definitions
- the invention relates to a device for pyrolysis of waste materials, in particular contaminated sites, with an indirectly heated pyrolysis reactor, from which a pyrolysis gas line is led to a combustion chamber.
- a device of the type specified at the outset is described, for example, in AT-PS 3 46 997. From this document, however, it does not appear that the use of the pyrolysis gases in a conventional gas burner or in an internal combustion engine because of the composition of the pyrolysis gases and various admixtures contained in them are problematic in practice.
- a self-sufficient pyrolysis system ie a system that is equipped with the necessary units for cleaning and using the pyrolysis gases, therefore requires a high investment.
- Such an effort is not always economically justifiable, especially if the amount of the materials to be disposed of - as is often the case with contaminated sites - is limited so that the system can only be used for a limited period of time.
- the invention has for its object to reduce the investment in a device of the type mentioned in the beginning and in particular to save the effort for cleaning the pyrolysis gases.
- the solution according to claim 1 is particularly simple and cheap.
- the solution according to claim 2 is intended for special cases in which the pyrolysis gas has more thermally stable substances, e.g. Dioxin, can contain, especially for the pyrolysis of PCB-containing residues from transformer oils.
- Dioxin e.g. Dioxin
- the feature of claim 3 also allows the use of the residual heat contained in the exhaust gases from the heating of the pyrolysis reactor.
- the feature of claim 4 enables economically viable pyrolysis treatment of special wastes even if they can only be eliminated in a limited amount.
- the feature of claim 5 enables the saving of additional fuel for the pyrolysis treatment. This is particularly important if the material to be pyrolytically treated has only a low energy potential.
- FIGS. 1 and 2 each show a process diagram to illustrate the invention.
- FIG. 1 - separated by a dashed line 1 - a conventional waste incineration system is shown, consisting essentially of a furnace 2, a steam boiler 3, a flue gas cleaning system 4, a suction 5 and a chimney 6.
- the arrows drawn between the individual units represent symbolic represents the flue gas duct.
- the invention is not tied to a specific system. It can be designed, for example, as roller grate or moving grate firing for the combustion of domestic and commercial waste or as a rotary kiln with or without an afterburner chamber for the combustion of industrial or special waste.
- a pyrolysis reactor 7 is set up, preferably an indirectly heated rotary kiln, with feed lines 8 for fuel and combustion air.
- the rotary kiln 7 is fed with waste material via a feed device 9, e.g. with oil-soaked soil. Solid residues are discharged via a discharge device 10.
- the pyrolysis gas is passed through a pipeline 11, which is well insulated to avoid condensation and is as short as possible, into the furnace 2 and burned there in a burner, not shown, which serves as a support burner for waste incineration.
- the flue gas from the burner mixes with the flue gas from the refuse furnace and contributes to heating the steam boiler 3.
- the exhaust gas from the heating of the pyrolysis reactor 7 is introduced into the steam boiler 3 via an exhaust gas line 12 in the corresponding temperature zone, where it largely emits its heat content and mixes with the rest of the exhaust gas stream.
- the entire flue gas is freed from solid and gaseous admixtures in the flue gas cleaning system 4 and is released into the open via the suction 5 through the chimney 6.
- the plant illustrated in FIG. 2 is intended in particular for the disposal of waste materials which may contain harmful, thermally more stable substances, such as chlorinated biphenyls. It differs from the system according to FIG. 1 in that the pyrolysis gas is fed via a line 13 to a combustion chamber 14 which is separate from the furnace 2 and there at one temperature is burned separately above 1200 ° C. The high combustion temperature ensures that the harmful substances are safely decomposed. In the furnace 2, the usual flue gas temperature level of 800 to 900 ° C can be maintained. The flue gas produced in the combustion chamber 14 is introduced via a line 15 into the flue gas duct of the furnace 2 before entering the steam boiler 3.
- the pyrolysis gas is fed via a line 13 to a combustion chamber 14 which is separate from the furnace 2 and there at one temperature is burned separately above 1200 ° C.
- the high combustion temperature ensures that the harmful substances are safely decomposed.
- the usual flue gas temperature level of 800 to 900 ° C can be maintained.
- the pyrolysis reactor 7 is heated in the system according to FIG. 2 by means of a partial flow of hot flue gases, which branches off from the flue gas duct via a line 16 before entering the steam boiler 3 and is led to the pyrolysis reactor 7 via a hot gas filter 17.
- the system shown schematically in FIG. 2 corresponds to the system described first. It is of course also possible to heat the pyrolysis reactor with hot flue gas from the waste incineration plant if, as in the embodiment shown in FIG. 1, the pyrolysis gases are burned in the waste incineration plant.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Gasification And Melting Of Waste (AREA)
- Incineration Of Waste (AREA)
Abstract
Ein Pyrolysereaktor (7) ist mit einer Müllverbrennungsanlage (1) gekoppelt. Die Pyrolysegase gelangen bei einer Variante direkt in die Feuerung (2) der Müllverbrennungsanlage (1) Bei einer anderen Variante werden sie in einer separaten Verbrennungskammer (14) verbrannt, und die entstehenden Rauchgase werden in den Rauchgaskanal der Müllverbrennungsanlage (1) eingespeist. Dadurch werden die bei autarken Pyrolyseanlagen erforderlichen Aggregate für die Reinigung und Nutzung der Pyrolysegase und für die Rauchgasreinigung eingespartA pyrolysis reactor (7) is coupled to a waste incineration plant (1). In one variant, the pyrolysis gases go directly into the furnace (2) of the waste incineration plant (1). In another variant, they are burned in a separate combustion chamber (14), and the resulting flue gases are fed into the flue gas duct of the waste incineration plant (1). This saves the units required for self-sufficient pyrolysis plants for cleaning and using the pyrolysis gases and for flue gas cleaning
Description
Die Erfindung betrifft eine Vorrichtung zur Pyrolyse von Abfallstoffen, insbesondere von Altlasten mit einem indirekt beheizten Pyrolysereaktor, von dem eine Pyrolysegasleitung zu einer Verbrennungskammer geführt ist.The invention relates to a device for pyrolysis of waste materials, in particular contaminated sites, with an indirectly heated pyrolysis reactor, from which a pyrolysis gas line is led to a combustion chamber.
Mit Hilfe der Pyrolyse ist es möglich, in umweltfreundlicher Weise gewisse problematische Abfallstoffe zu beseitigen. Hierzu gehören insbesondere die sogenannten Altlasten, wie z.B. mit Ölen oder Lösungsmitteln verseuchtes Erdreich, Teerrückstände, Säureharze und dergleichen, aber auch andere spezielle Abfälle, wie Altreifen oder Reste von kunststoffisolierten Kabeln. Als Rückstand fällt ein festes Produkt an, das verwertbare und/oder deponiefähige Bestandteile enthält. Außerdem wird ein brennbares Pyrolysegas gewonnen.With the help of pyrolysis, it is possible to remove certain problematic waste materials in an environmentally friendly manner. This includes in particular the so-called contaminated sites, such as Soil contaminated with oils or solvents, tar residues, acid resins and the like, but also other special waste, such as used tires or the remains of plastic-insulated cables. A solid product is obtained as a residue, which contains usable and / or landfillable components. A flammable pyrolysis gas is also obtained.
Eine Vorrichtung der eingangs angegebenen Gattung ist z.B. in der AT-PS 3 46 997 beschrieben. Aus dieser Schrift geht aber nicht hervor, daß die Nutzung der Pyrolysegase in einem üblichen Gasbrenner oder auch in einer Brennkraftmaschine wegen der Zusammensetzung der Pyrolysegase und der in ihnen enthaltenen verschiedenen Beimengungen in der Praxis mit Problemen verbunden ist. Die DE-OS 27 32 418, die DE-OS 24 32 504 und die US-PS 42 06 186, die sich eingehend mit diesen Problemen befassen, lassen erkennen, daß zur Behandlung der Pyrolysegase ein erheblicher Aufwand an peripheren Aggregaten erforderlich ist. In der EP-A1 0 111 081 und der bereits erwähnten AT-PS 3 46 997 wird zwar vorgeschlagen, die Entstehung gewisser gasförmiger Verunreinigungen, wie Halogenwasserstoffe oder Schwefeldioxid, dadurch zu vermeiden, daß vor oder beim Schwelprozeß feinkörniges basisches Material zugesetzt wird. Hierdurch wird zwar der Aufwand für die nachträgliche Beseitigung dieser Schadgase eingespart; andererseits verursacht aber ein stark erhöhter Staubgehalt der Pyrolysegase einen erhöhten Aufwand für die Entstaubung.A device of the type specified at the outset is described, for example, in AT-
Ein Problem liegt auch darin, daß geeignete Abnehmer für das in schwankender Menge und schwankender Qualität anfallende Pyrolysegas nicht immer vorhanden sind. Die Nutzung in der Pyrolyseanlage selbst setzt entsprechende Einrichtungen voraus.Another problem lies in the fact that suitable customers for the pyrolysis gas produced in fluctuating quantities and quality are not always available. Appropriate facilities are required for use in the pyrolysis plant itself.
Eine autarke Pyrolyseanlage, d.h. eine Anlage, die mit den notwendigen Aggregaten für die Reinigung und Nutzung der Pyrolysegase ausgestattet ist, bedingt daher einen hohen Investitionsaufwand. Ein solcher Aufwand ist wirtschaftlich nicht immer vertretbar, vor allem wenn die Menge der zu beseitigenden Stoffe - wie z.B. vielfach bei Altlasten-begrenzt ist, so daß die Anlage nur für einen begrenzten Zeitraum nutzbar ist.A self-sufficient pyrolysis system, ie a system that is equipped with the necessary units for cleaning and using the pyrolysis gases, therefore requires a high investment. Such an effort is not always economically justifiable, especially if the amount of the materials to be disposed of - as is often the case with contaminated sites - is limited so that the system can only be used for a limited period of time.
Der Erfindung liegt die Aufgabe zugrunde, bei einer Vorrichtung der eingangs angegebenen Gattung den Investitionsaufwand zu verkleinern und insbesondere den Aufwand für die Reinigung der Pyrolysegase einzusparen.The invention has for its object to reduce the investment in a device of the type mentioned in the beginning and in particular to save the effort for cleaning the pyrolysis gases.
Diese Aufgabe wird durch die kennzeichnenden Merkmale des Anspruchs 1 oder alternativ durch die kennzeichnenden Merkmale des Anspruchs 2 gelöst.This object is achieved by the characterizing features of claim 1 or alternatively by the characterizing features of
Die Lösung gemäß Anspruch 1 ist besonders einfach und billig.The solution according to claim 1 is particularly simple and cheap.
Die Lösung gemäß Anspruch 2 ist für spezielle Fälle vorgesehen, bei denen das Pyrolysegas thermisch stabilere Substanzen, wie z.B. Dioxin, enthalten kann, insbesondere für die Pyrolyse von PCB-haltigen Rückständen aus Transformatorenölen.The solution according to
Beide Lösungen beruhen auf dem gemeinsamen Konzept, das Pyrolysegas ungereinigt zu verbrennen und für die Reinigung des Rauchgases die bei einer Müllverbrennungsanlage ohnehin vorhandenen Aggregate zu nutzen. Dies ist in den meisten praktisch vorkommenden Fällen problemlos möglich, da die Menge der organischen Anteile der durch Pyrolyse zu beseitigenden Sonderabfälle relativ gering ist im Vergleich zur Menge des kommunalen und gewerblichen Mülls, der in einer Müllverbrennungsanlage durchgesetzt wird.Both solutions are based on the common concept of incinerating the pyrolysis gas unpurified and using the units that are already present in a waste incineration plant to purify the flue gas. This is easily possible in most practical cases, since the amount of organic parts of the special waste to be removed by pyrolysis is relatively small compared to the amount of municipal and commercial waste that is put through in a waste incineration plant.
Das Merkmal des Anspruchs 3 erlaubt auch die Nutzung der in den Abgasen d er Heizung des Pyrolysereaktors enthaltenen Restwärme.The feature of
Durch das Merkmal des Anspruchs 4 wird eine wirtschaftlich tragbare Pyrolysebehandlung von Sonderabfällen auch dann ermöglicht, wenn diese nur in begrenzter Menge zu beseitigen sind.The feature of
Das Merkmal des Anspruchs 5 ermöglicht die Einsparung von Zusatzbrennstoff für die Pyrolysebehandlung. Dies ist insbesondere von Bedeutung, wenn das pyrolytisch zu behandelnde Material nur ein geringes Energiepotential hat.The feature of
Die Figuren 1 und 2 zeigen zur Veranschaulichung der Erfindung je ein Verfahrensschema.FIGS. 1 and 2 each show a process diagram to illustrate the invention.
In Figur 1 ist - durch eine gestrichelte Linie 1 abgetrennt - eine herkömmliche Müllverbrennungsanlage dargestellt, bestehend im wesentlichen aus einer Feuerung 2, einem Dampfkessel 3, einer Rauchgasreinigungsanlage 4, einem Saugzug 5 und einem Schornstein 6. Die zwischen den einzelnen Aggregaten gezeichneten Pfeile stellen symbolisch den Rauchgaskanal dar.In Figure 1 - separated by a dashed line 1 - a conventional waste incineration system is shown, consisting essentially of a
Bezüglich der Feuerung ist die Erfindung nicht an ein bestimmtes System gebunden. Sie kann z.B. als Walzenrost- oder Vorschubrostfeuerung zur Verbrennung von Hausmüll und Gewerbemüll oder als Drehrohrofen mit oder ohne Nachbrennkammer zur Verbrennung von Industrie- oder Sondermüll ausgebildet sein.With regard to the firing, the invention is not tied to a specific system. It can be designed, for example, as roller grate or moving grate firing for the combustion of domestic and commercial waste or as a rotary kiln with or without an afterburner chamber for the combustion of industrial or special waste.
In unmittelbarer Nähe der Müllverbrennungsanlage 1 ist ein Pyrolysereaktor 7 aufgestellt, vorzugsweise ein indirekt beheizter Drehrohrofen, mit Zuleitungen 8 für Brennstoff und Verbrennungsluft. Der Drehrohrofen 7 wird über eine Aufgabevorrichtung 9 mit Abfallstoff beschickt, z.B. mit öldurchtränktem Erdreich. Über eine Austragvorrichtung 10 werden feste Rückstände ausgetragen. Das Pyrolysegas wird über eine Rohrleitung 11, die zur Vermeidung von Kondensation gut wärmeisoliert und möglichst kurz ist, in die Feuerung 2 geleitet und dort in einem nicht dargestellten Brenner, der als Stützbrenner für die Müllverbrennung dient, verbrannt. Das Rauchgas des Brenners mischt sich mit dem Rauchgas der Müllfeuerung und trägt zur Beheizung des Dampfkessels 3 bei. Das Abgas der Heizung des Pyrolysereaktors 7 wird über eine Abgasleitung 12 in der entsprechenden Temperaturzone in den Dampfkessel 3 eingeleitet, wo es seinen Wärmeinhalt weitgehend abgibt und sich mit dem übrigen Abgasstrom mischt. Das gesamte Rauchgas wird in der Rauchgasreinigungsanlage 4 von festen und gasförmigen Beimischungen befreit und gelangt über den Saugzug 5 durch den Schornstein 6 ins Freie.In the immediate vicinity of the waste incineration plant 1, a
Die in Figur 2 veranschaulichte Anlage ist insbesondere für die Beseitigung von Abfallstoffen vorgesehen, die schädliche, thermisch stabilere Stoffe, wie z.B. chlorierte Biphenyle, enthalten können. Sie unterscheidet sich von der Anlage gemäß Figur 1 dadurch, daß über eine Leitung 13 das Pyrolysegas einer von der Feuerung 2 getrennten Verbrennungskammer 14 zugeführt wird und dort bei einer Temperatur über 1200 °C separat verbrannt wird. Durch die hohe Verbrennungstemperatur wird eine sichere Zersetzung der schädlichen Stoffe erreicht. In der Feuerung 2 kann das bei der Müllverbrennung übliche Rauchgasstemperaturniveau von 800 bis 900 °C beibehalten werden. Das in der Brennkammer 14 entstehende Rauchgas wird über eine Leitung 15 vor dem Eintritt in den Dampfkessel 3 in den Rauchgaskanal der Feuerung 2 eingeleitet.The plant illustrated in FIG. 2 is intended in particular for the disposal of waste materials which may contain harmful, thermally more stable substances, such as chlorinated biphenyls. It differs from the system according to FIG. 1 in that the pyrolysis gas is fed via a
Die Beheizung des Pyrolysereaktors 7 erfolgt bei der Anlage gemäß Fig. 2 mittels eines Teilstroms heißer Rauchgase, der vor dem Eintritt in den Dampfkessel 3 über eine Leitung 16 vom Rauchgaskanal abgezweigt und über ein Heißgasfilter 17 zum Pyrolysereaktor 7 geführt ist.The
Ansonsten stimmt die in Figur 2 schematisch dargestellte Anlage mit der zuerst beschriebenen Anlage überein. Die Beheizung des Pyrolysereaktors mit heißem Rauchgas der Müllverbrennungsanlage ist natürlich auch möglich, wenn-wie bei dem in Fig. 1 dargestellten Ausführungsbeispiel-die Pyrolysegase in der Müllfeuerung verbrannt werden. Otherwise, the system shown schematically in FIG. 2 corresponds to the system described first. It is of course also possible to heat the pyrolysis reactor with hot flue gas from the waste incineration plant if, as in the embodiment shown in FIG. 1, the pyrolysis gases are burned in the waste incineration plant.
Claims (5)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19863626106 DE3626106A1 (en) | 1986-08-01 | 1986-08-01 | DEVICE FOR PYROLYSIS OF WASTE |
DE3626106 | 1986-08-01 |
Publications (1)
Publication Number | Publication Date |
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EP0262291A1 true EP0262291A1 (en) | 1988-04-06 |
Family
ID=6306506
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87106352A Ceased EP0262291A1 (en) | 1986-08-01 | 1987-05-02 | Device for refuse pyrolysis |
Country Status (3)
Country | Link |
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US (1) | US4774895A (en) |
EP (1) | EP0262291A1 (en) |
DE (1) | DE3626106A1 (en) |
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DE19617034C1 (en) * | 1994-11-26 | 1997-11-13 | Hoelter Heinz | Combustion process for fossil fuel and refuse |
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DE19646099C1 (en) * | 1996-11-08 | 1997-12-11 | Steinmueller Gmbh L & C | Incineration of waste and fossil fuels |
WO2002068569A2 (en) * | 2001-02-28 | 2002-09-06 | The Penn State Research Foundation | Reducing nitrogen oxides and carbon loss from emissions |
US20030127310A1 (en) * | 2002-01-07 | 2003-07-10 | Lemmons Donald W. | Method and system for extracting hydrocarbon fuel products from waste material |
US20070289507A1 (en) * | 2006-06-16 | 2007-12-20 | Alternative Power Solutions Inc. | System, method and apparatus for pyrolizing waste material |
US20090007484A1 (en) * | 2007-02-23 | 2009-01-08 | Smith David G | Apparatus and process for converting biomass feed materials into reusable carbonaceous and hydrocarbon products |
US7893307B2 (en) * | 2007-02-23 | 2011-02-22 | Smith David G | Apparatus and process for converting feed material into reusable hydrocarbons |
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DE2242012C3 (en) * | 1972-08-23 | 1975-10-16 | Mannesmann Ag, 4000 Duesseldorf | Process for the joint disposal of industrial and household waste as well as sewage sludge |
US3818869A (en) * | 1973-01-02 | 1974-06-25 | Combustion Eng | Method of operating a combined gasification-steam generating plant |
FR2331752A1 (en) * | 1975-11-13 | 1977-06-10 | Picard Du Chambon Michel | Domestic waste treatment unit - has primary air heater with pre:drying and double walled heat converter interconnected by lift |
US4432290A (en) * | 1979-10-30 | 1984-02-21 | The Agency Of Industrial Science And Technology | Method of pyrolyzing organic material using a two-bed pyrolysis system |
DE3447079A1 (en) * | 1984-08-28 | 1986-03-06 | Carl Still Gmbh & Co Kg, 4350 Recklinghausen | Process for thermally treating contaminated soil |
-
1986
- 1986-08-01 DE DE19863626106 patent/DE3626106A1/en not_active Withdrawn
-
1987
- 1987-05-02 EP EP87106352A patent/EP0262291A1/en not_active Ceased
- 1987-06-15 US US07/062,878 patent/US4774895A/en not_active Expired - Fee Related
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DE2432504A1 (en) | 1974-07-04 | 1976-01-15 | Karl Dipl Ing Kiener | Gaseous fuel from waste - produced by low temp. carbonisation and gasification of the coke |
US4206186A (en) | 1975-02-06 | 1980-06-03 | Holter Gesellschaft Fur Patentverwertungsverfahren Mbh | Refuse pyrolysis |
AT346997B (en) | 1976-06-11 | 1978-12-11 | Potuzak Karl | PROCESS FOR PROCESSING OF ACID TEER |
DE2732418A1 (en) | 1977-07-18 | 1979-02-01 | Linde Ag | Thermal treatment of refuse - by low temp. carbonisation and passing gases through fixed ceramic bed |
EP0111081A1 (en) | 1979-06-25 | 1984-06-20 | BKMI Industrieanlagen GmbH | Process for the pyrolysis of waste materials |
US4485745A (en) * | 1981-01-22 | 1984-12-04 | Mannesmann Veba Umwelttechnik Gmbh | Method for thermal processing of solid waste and the apparatus for carrying out the method |
DE3310534A1 (en) * | 1983-03-23 | 1984-10-04 | C. Deilmann AG, 4444 Bad Bentheim | DEVICE FOR RECOVERING ENERGY FROM PYROLIZABLE, CARBONATED WASTE MATERIALS, ALTERNATING COMPOSITION |
DE3400976A1 (en) * | 1984-01-13 | 1985-08-01 | Saarberg-Hölter-Umwelttechnik GmbH, 6600 Saarbrücken | Energy system for environmentally friendly refuse degassing or coal-refuse degassing with following fluidised bed furnace and integrated low temperature carbonisation gas combustion chamber and heat exchanger |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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WO1990000700A1 (en) * | 1988-07-15 | 1990-01-25 | Asea Brown Boveri Aktiengesellschaft | Process for depolluting an appliance |
EP0401460A1 (en) * | 1989-06-05 | 1990-12-12 | Masamoto Kaneko | A method and apparatus for disposing waste |
US5707592A (en) * | 1991-07-18 | 1998-01-13 | Someus; Edward | Method and apparatus for treatment of waste materials including nuclear contaminated materials |
Also Published As
Publication number | Publication date |
---|---|
US4774895A (en) | 1988-10-04 |
DE3626106A1 (en) | 1988-02-11 |
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