EP0235126A1 - Process for producing a high surface area alumina - Google Patents
Process for producing a high surface area aluminaInfo
- Publication number
- EP0235126A1 EP0235126A1 EP85904387A EP85904387A EP0235126A1 EP 0235126 A1 EP0235126 A1 EP 0235126A1 EP 85904387 A EP85904387 A EP 85904387A EP 85904387 A EP85904387 A EP 85904387A EP 0235126 A1 EP0235126 A1 EP 0235126A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alumina
- aluminum
- surface area
- ammonium
- cause
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/30—Preparation of aluminium oxide or hydroxide by thermal decomposition or by hydrolysis or oxidation of aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/78—Compounds containing aluminium and two or more other elements, with the exception of oxygen and hydrogen
- C01F7/782—Compounds containing aluminium and two or more other elements, with the exception of oxygen and hydrogen containing carbonate ions, e.g. dawsonite
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
Definitions
- This invention relates to a process for produc ⁇ ing a high surface area alumina that is useful in alumina- base catalysts.
- Catalysts are employed in many chemical indus ⁇ tries to facilitate chemical reactions which would other ⁇ wise require unduly stringent reaction conditions.
- Many catalysts are based on alumina, used either alone (such as
- Typical hydrorefining catalysts comprise a Group VIII metal (typically nickel or cobalt) and a Group VIB metal (typically molybdenum or tungsten) sup ⁇ ported on an alumina base. The preparation of such a
- catalyst may be exemplified by U.S. Patent No. 4,113,661 to Tamm, the disclosure of which is incorporated herein by reference.
- the alumina present in such catalysts is typically ⁇ -alumina, though some catalysts prepared by higher-temperature calcination contain ⁇ - or ⁇ -alumina.
- the catalysts are typically particulate, with sizes rang ⁇ ing from 0.8 mm diameter cylinders to 5-10 mm diameter cylinders, and more complex shapes such as ovals, tri- lobes, rings, etc. being common.
- 35 lyst is dependent in part on the surface area of that catalyst, it would be desirable to have an alumina that has a high surface area so that it could be used in such a catalyst.
- This invention provides a process for the pro- duction of such a high surface area alumina.
- this invention provides a process which comprises:
- alumina-base catalyst means a catalyst the base (i.e., the non-catalytic support, unless the support itself is catalytic) of which comprises alumina.
- the term refers to a catalyst base comprising at least 50%, usually at least 80%, and preferably at least 90% by weiqht of alumina.
- the non-alumina components may be, for example, silica or other refractory oxides, aluminosili- cates such as clays or zeolites, etc.
- aluminum salt particles are treated with an aqueous solu- tion of ammonium hydroxide and ammonium carbonate to cause a reaction converting at least a substantial proportion of the aluminum salt to an ammonium aluminum hydroxycarbo ⁇ nate, which is then heated slowly to between 150° and 400, ⁇ > C for a period of at least 2 hours to cause its decom- position to said alumina.
- the alumina should have a BET surface area of at least 300 m /g, preferably at least 450 m * Vg, more prefer- ably at least 800 m /g. It is often desirable to have a catalyst of very high surface area with corresponding small pores—less than 50 Angstroms. Such catalysts would be used in processes not limited by diffusion control or size exclusion of the reacting molecule. In these cases, reaction rates would be directly proportional to surface area.
- aluminum salt particles are treated with an aqueous solution of ammonium hydroxide and ammonium carbonate to cause a reaction converting at least a substantial proportion of the aluminum salt to an ammo ⁇ nium aluminum hydroxycarbonate.
- the aluminum salt is preferably either aluminum sulfate, aluminum chloride, or aluminum nitrate. More preferably, the aluminum salt is aluminum sulfate, because of its low cost. However when aluminum sulfate is used, the resulting alumina should be washed with water at a temperature of at least 50°C to remove a substantial part of the sulfur, ammonia, and other residuals from the alu ⁇ mina.
- the reaction pH of the first step is between 9 and 12, preferably between* 10 and 11.
- a typical solution contains ammonium hydroxide and ammonium carbonate.
- a typical reaction in this case may be:
- the ammonium aluminum hydroxycarbonate is heated slowly to between 150° and 400°C for a period of at least two hours to cause its decomposition to said alumina.
- the heating temperature is about 200°C, for at that temperature, decomposition will occur slowly which is important in obtaining the highest surface area.
- an alumina having a BET surface area of at least 800 irr/g is produced by treating aluminum sulfate particles with an aqueous solution of ammonium hydroxide and ammonium carbonate at a pH of 10 to 11 to cause a reaction converting at least a substantial proportion of the aluminum sulfate to NH 4 Al(OH) 2 C0 3 * H 2 0, heating said NH 4 A1(0H) 2 C0 3 * H 2 0 to about 200°C for a period of at least 2 hours to cause its decomposition to alumina; and washing the alumina with water at a temperature of at least 50°C to remove a substantial part of the sulfur, ammonia, and other residuals from the alumina.
- Example 1 An ammonium aluminum hydroxycarbonate was prepared by adding 318 grams of Al 2 (S0 4 ) 3 *16H 2 0 to 1 liter of solution containing 3M NH3 and 1.5 M (NH3) 2 C0 . The mixture was reacted for one hour at 70°C and filtered, then the precipitate was dried in a vacuum oven overnight at 150°C. A similar preparation was made by adding dissolved aluminum sulfate to the same ammonical solution.
- Example 2 A large preparation was made by adding solid aluminum sulfate as in the previous example. In this case, 704 grams of hydroxycarbonate were decomposed at 250°C for eight hours. As in the previous example, the large mass of material resulted in a relatively slow heating rate. The BET surface area was 700 /g.
- Example 3 This example shows the adverse effect that rapid : heat-up has on surface area. A hydroxycarbonate prepared as in previous examples was decomposed at various tempera ⁇ tures for three hours. The important variable in this example was the rapid heating rate. Rapid heating resulted from placing only about 8 grams of hydroxycarbon- ' ate into a preheated oven. Table I shows that rapid decomposition even at low temperatures reduced the surface area significantly from the very high values seen previously.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Catalysts (AREA)
Abstract
Une alumine ayant une très grande surface spécifique est produite en traitant des particules de sel d'aluminium avec une solution aqueuse d'hydroxyde d'ammonium et de carbonate d'ammonium à un pH de 9 à 12, afin de convertir le sel d'aluminium en un hydroxycarbonate d'aluminium d'ammonium, et en chauffant ensuite l'hydroxycarbonate d'aluminium d'ammonium à une température située entre 150o et 400oC pendant une période d'au moins deux heures, afin de le décomposer en alumine.An alumina having a very large specific surface is produced by treating particles of aluminum salt with an aqueous solution of ammonium hydroxide and ammonium carbonate at a pH of 9 to 12, in order to convert the salt of aluminum into an aluminum ammonium hydroxycarbonate, and then heating the aluminum ammonium hydroxycarbonate to a temperature between 150o and 400oC for a period of at least two hours, in order to decompose it into alumina.
Description
Claims
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1985/001649 WO1987001365A1 (en) | 1985-08-27 | 1985-08-27 | Process for producing a high surface area alumina |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0235126A1 true EP0235126A1 (en) | 1987-09-09 |
EP0235126A4 EP0235126A4 (en) | 1988-05-10 |
Family
ID=22188818
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19850904387 Withdrawn EP0235126A4 (en) | 1985-08-27 | 1985-08-27 | Process for producing a high surface area alumina. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0235126A4 (en) |
JP (1) | JPS63500794A (en) |
DE (1) | DE3590012T1 (en) |
NL (1) | NL8520271A (en) |
WO (1) | WO1987001365A1 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1048471C (en) * | 1994-12-29 | 2000-01-19 | 重庆大学 | Process for preparing aluminium hydroxide from coal gangue |
US8007760B2 (en) * | 2008-12-11 | 2011-08-30 | Uop Llc | Process for producing enhanced alumina |
US7947250B2 (en) * | 2008-12-11 | 2011-05-24 | Uop Llc | Process for conversion of aluminum oxide hydroxide |
CN103332717A (en) * | 2013-07-18 | 2013-10-02 | 北京世纪地和控股有限公司 | Production method of high-activity aluminium oxide |
RU2632437C1 (en) * | 2016-10-21 | 2017-10-04 | Федеральное государственное бюджетное учреждение науки Институт химии и технологии редких элементов и минерального сырья им. И.В. Тананаева Кольского научного центра Российской академии наук (ИХТРЭМС КНЦ РАН) | Method of producng aluminium oxide |
CN108970628B (en) * | 2018-08-08 | 2023-08-29 | 北京众智创新科技开发有限公司 | Preparation method of ebullated bed hydrotreating catalyst |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3557025A (en) * | 1968-05-13 | 1971-01-19 | Kaiser Aluminium Chem Corp | Method of producing alkalized alumina and products produced thereby |
JPS51140900A (en) * | 1975-05-29 | 1976-12-04 | Agency Of Ind Science & Technol | Process for production of aluminum carbonate hydroxide:ammonium |
GB2072636B (en) * | 1980-03-28 | 1983-07-27 | Nicholas Pty Ltd | Preparation of dihydroxyaluminium sodium carbonate |
US4356157A (en) * | 1980-08-14 | 1982-10-26 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Synthesis of dawsonites |
US4495087A (en) * | 1982-12-27 | 1985-01-22 | Ng Tai Wing | Preparation of aluminum hydroxycarbonate gels by a continuous process |
-
1985
- 1985-08-27 NL NL8520271A patent/NL8520271A/en not_active Application Discontinuation
- 1985-08-27 JP JP60503915A patent/JPS63500794A/en active Pending
- 1985-08-27 DE DE19853590012 patent/DE3590012T1/de not_active Withdrawn
- 1985-08-27 WO PCT/US1985/001649 patent/WO1987001365A1/en not_active Application Discontinuation
- 1985-08-27 EP EP19850904387 patent/EP0235126A4/en not_active Withdrawn
Non-Patent Citations (2)
Title |
---|
No relevant documents have been disclosed. * |
See also references of WO8701365A1 * |
Also Published As
Publication number | Publication date |
---|---|
NL8520271A (en) | 1987-06-01 |
WO1987001365A1 (en) | 1987-03-12 |
EP0235126A4 (en) | 1988-05-10 |
JPS63500794A (en) | 1988-03-24 |
DE3590012T1 (en) | 1987-07-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100431919B1 (en) | Composition Based On Zirconium Oxide and Cerium Oxide, Preparation Method Therefor and Use Thereof | |
JP3623517B2 (en) | Composition based on cerium oxide and zirconium oxide and having high specific surface area and high oxygen storage capacity, and method for producing the same | |
JP2947449B2 (en) | Mixed oxides of cerium and zirconium, their production and use | |
CA2318734C (en) | Catalysts for the selective oxidation of hydrogen sulfide to sulfur | |
FI107799B (en) | An oxide mixture of cerium and zirconium based composition and its precursor, processes for their preparation and use of the composition | |
NZ210549A (en) | Modified copper- and zinc- containing catalyst and methanol production | |
US4043939A (en) | Reactivation of catalysts useful for nitrogen oxide removal | |
EP0235126A1 (en) | Process for producing a high surface area alumina | |
JP4191044B2 (en) | Process for preparing oxides based on zirconium and titanium, oxides obtained by this process and the use of these oxides as catalysts | |
EP1893333B1 (en) | Method of making mixed metal oxide containing sulfur | |
EP0222471A1 (en) | Heat resistant composition and method of producing the same | |
US3193349A (en) | Method of producing boehmite of 50 to 80 a. crystal size | |
US11478777B2 (en) | Catalyst compositions having enhanced acidity for dry reforming processes | |
KR970001520B1 (en) | Carrier material for a catalyst and a process for making such a carrier material | |
US2398610A (en) | Stabilized alumina and preparation thereof | |
US2903418A (en) | Preparation of eta alumina by acid hydrolysis | |
RU2234460C1 (en) | Method of production of aluminum hydroxide of pseudo-boehmite structure and gamma aluminum oxide on its base | |
US2677649A (en) | Process and catalysts for petroleum conversions | |
US3948760A (en) | Catalytic conversion of hydrocarbons by improved zeolite catalyst | |
US4537751A (en) | Treatment of alumina-base catalysts | |
JPH024453A (en) | Preparation of catalyst for nitrogen oxide contact reduction | |
US2958582A (en) | Production of alumina | |
SU459247A1 (en) | Method for preparing nickel-silica gel catalyst for hydrogenation of organic compounds and fine gas cleaning | |
US5662880A (en) | Method for producing catalyst-grade alumina from aluminum sulphate | |
WO2021154910A1 (en) | Catalyst compositions having enhanced acidity for autothermal reforming processes |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): FR |
|
17P | Request for examination filed |
Effective date: 19870725 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: MARCANTONIO, PAUL, J. |
|
A4 | Supplementary search report drawn up and despatched |
Effective date: 19880510 |
|
17Q | First examination report despatched |
Effective date: 19881011 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: CHEVRON RESEARCH AND TECHNOLOGY COMPANY |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19930302 |
|
APAF | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNE |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: MARCANTONIO, PAUL, J. |