EP0232680A1

EP0232680A1 - Shield against radiations

Info

Publication number: EP0232680A1
Application number: EP86830023A
Authority: EP
Inventors: Sergio Grifoni
Original assignee: Individual
Current assignee: Individual
Priority date: 1986-01-30
Filing date: 1986-01-30
Publication date: 1987-08-19
Also published as: JPS62180294A

Abstract

A shield against ionizing radiations comprises at least one layer including one or more boron minerals and/or one or more lead minerals and/or directly derived products, which preferably constitute the inert or slightly active aggregate fraction of cement-based conglomerates (such as concrete or mortar). Galena and/or other lead minerals can be used for the shielding from y rays, and colemanite and/or other boron minerals can be used for neutron shielding. Particular purpose additives will also be used. The family of compositions according to the invention will contain by weight 65-75% of floated galena, 5-10% of colemanite and 20-25% of binding agents and additives.

Description

The present invention relates to a shield against ionizing radiations, comprising at least one layer consisting of a cement based conglomerate which contains, as a substitute of the inert aggregate fraction, one or more lead minerals and/or one or more boron minerals and/or their directly derived products.
The advantage of using the above mentioned minerals or their directly derived products resides in the fact that same are more easily available than industrial chemical products, and with physical properties (grain size and distribution, surface roughness, etc.) close or more similar to the ones of the inert aggregates used in cement-based concretes and mortars.
The reason for using lead minerals in the shield, than baryta or iron minerals, or manganese minerals is that, for equal weights, lead is much more efficient in the shielding against X-rays and a-rays than any other readily available element. The higher cost of lead as a commercial metal (in comparison with 4 iron or manganese) is abundantly compensated by the higher efficiency of the shield thus obtained.
According to a preferred embodiment of the invention, a particular family of shielding compositions has been found to be well suited to constitute the biological shield of a nuclear reactor (particularly a Boiling Water Reactor).
According to the invention, one layer of cement-based conglomerate or mortar contains a composition belonging to the following family:
The mixture obtained with the above listed materials is then mixed with water for immediate use.
The additives in the above composition have a very important role, in consideration of the fact that the shielding material must satisfy a number of additional needs, i.e.:

- to remain fluid for a sufficient time after preparation;
- to be poured or pumped into the compartments of the shielding structure;
- to expand inside the compartments to fill small voids;
- not to shrink during the hardening process;
- not to corrode the walls of the shielding structure.

Basic additives are: sulphonates, chelate forming agents, aerating agents, expanding agents.
Moreover, in order to avoid problems at the construction site, the wet mixture must not have a specific weight much higher than the weight of ordinary concrete. The specific weight of the mortar must be therefore comprised between 2.5 and 3.5 g/cm³.
In order to obtain the above mentioned results, floated galena (i.e. galena obtained with flotation methods) can be used, which presents a grain distribution comprised, by way of example, between 5 and 80 µ. To the floated galena a small quantity of silver can be added.
The shielding layers thus obtained are very effective against γ, β and α rays, as well as against fast and slow neutrons. The efficiency against neutrons will be the best if all the water is kept in the shield. The efficiency is still very good however if the shield is allowed to dry (in this case just the reaction, hydratation and adsorbed water is kept).
The final shield will contain:

- lead, at least 38 % of weight;
- boron, at least 0.6 % of weight;
- hydrogen, at least 1.5 % of weight (wet shield), or
- hydrogen, at least 0.7 % of weight (dry shield).

The shield will be preferably maintained in wet conditions.
Of course the invention is not limited to the above described preferred embodiment, but it can be broadly varied and modified, particularly as for what concerns the equivalents of the various components. Thus, for example, the lead minerals may comprise, besides galena, also cerussite or anglesite, while the boron mineral may comprise, besides colemanite, also borax or ulexite.

Claims

1) A shield against ionizing radiations, characterized by the fact that it comprise at least one layer constituted by a cement-based conglomerate or a cement-based mortar containing, in substitution of the inert or slightly active aggregate fraction, a mixture of one or more boron and/or lead minerals.

2) A shield according to claim 1 characterized by the fact of further comprising a mixture of additives such as sulphonates, chelate forming agents, aerating agents and expanding agents.

3) A shield according to claim 1, characterized by the fact that the lead minerals comprise galena and/or cerussite and/or anglesite.

4) A shield according to claim 1, characterized by the fact that the boron minerals comprise colemanite and/or borax and/or ulexite.

5) A shield according to claim 3, characterized by the fact that the lead mineral consists of floated galena containing optionally a small quantity of silver.

6) A shield according to claim 2, characterized by that fact of comprising, by weight:

7) A shield according to claim 1, characterized by the fact that after the addition of water it will present a density comprised between 2.5 and 3.5 g/cm³.

8) A shield according to claim 1, characterized by the fact that the cement-based mortar prepared with addition of water will retain all or almost all of the added water.