EP0215251A3 - Use in detergents of neutralised and/or amidised polymers containing carboxyl groups - Google Patents

Use in detergents of neutralised and/or amidised polymers containing carboxyl groups Download PDF

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Publication number
EP0215251A3
EP0215251A3 EP86110543A EP86110543A EP0215251A3 EP 0215251 A3 EP0215251 A3 EP 0215251A3 EP 86110543 A EP86110543 A EP 86110543A EP 86110543 A EP86110543 A EP 86110543A EP 0215251 A3 EP0215251 A3 EP 0215251A3
Authority
EP
European Patent Office
Prior art keywords
copolymers
carboxyl groups
alkyl
acrylic acid
methacrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86110543A
Other languages
German (de)
Other versions
EP0215251B1 (en
EP0215251A2 (en
Inventor
Walter Denzinger
Heinrich Dr. Hartmann
Wolfgang Dr. Trieselt
Erhard Dr. Klahr
Albert Dr. Hettche
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to AT86110543T priority Critical patent/ATE46716T1/en
Publication of EP0215251A2 publication Critical patent/EP0215251A2/en
Publication of EP0215251A3 publication Critical patent/EP0215251A3/en
Application granted granted Critical
Publication of EP0215251B1 publication Critical patent/EP0215251B1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines

Abstract

Washing agents contain, as additives for inhibiting redeposition and promoting the primary washing action, homopolymers of acrylic acid and of methacrylic acid, copolymers of acrylic acid and methacrylic acid and copolymers which contain, as essential components, (a) an ethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms and (b) acrylic acid, methacrylic acid and/or hydroxy-C2-C6-alkyl esters of ethylenically unsaturated C3-C6-carboxylic acids as copolymerized units, where the homo- and copolymers in the form of the free acids have a weight average molecular weight of from 5000 to 500,000 in the neutralized or amidated form, the carboxyl groups of the homo- and copolymers in each case being partially or completely neutralized with amines of the formula <IMAGE> where R is C8-C18-alkyl or R1-O-CH2-(CH2)n-, n is from 1 to 3, R1 is C1-C18-alkyl, R2 and R3 are each H or C1-C18-alkyl and/or from 5 to 50% of the said carboxyl groups being in the form of amides derived from primary and secondary amines of the formula I.
EP86110543A 1985-08-08 1986-07-30 Use in detergents of neutralised and/or amidised polymers containing carboxyl groups Expired EP0215251B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86110543T ATE46716T1 (en) 1985-08-08 1986-07-30 USE OF POLYMERISATS CONTAINING NEUTRALIZED AND/OR AMIDATED CARBOXYL GROUPS IN DETERGENTS.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3528460 1985-08-08
DE19853528460 DE3528460A1 (en) 1985-08-08 1985-08-08 USE OF NEUTRALIZED AND AMIDATED CARBOXYL GROUPS OF POLYMERISATES AS ADDITION TO DETERGENTS AND CLEANING AGENTS

Publications (3)

Publication Number Publication Date
EP0215251A2 EP0215251A2 (en) 1987-03-25
EP0215251A3 true EP0215251A3 (en) 1987-12-23
EP0215251B1 EP0215251B1 (en) 1989-09-27

Family

ID=6278021

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86110543A Expired EP0215251B1 (en) 1985-08-08 1986-07-30 Use in detergents of neutralised and/or amidised polymers containing carboxyl groups

Country Status (7)

Country Link
US (1) US4702858A (en)
EP (1) EP0215251B1 (en)
JP (1) JPS6234996A (en)
AT (1) ATE46716T1 (en)
CA (1) CA1265019A (en)
DE (2) DE3528460A1 (en)
ES (1) ES2001072A6 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4746455A (en) * 1986-06-27 1988-05-24 Kao Corporation Liquid detergent composition for clothing articles
DE3708451A1 (en) * 1987-03-16 1988-10-06 Henkel Kgaa ZWITTERIONIC POLYMERS AND THEIR USE IN HAIR TREATMENT AGENTS
GB8708312D0 (en) * 1987-04-07 1987-05-13 Unilever Plc Detergent powder composition
DE3715051A1 (en) * 1987-05-06 1988-11-17 Degussa PHOSPHATE-FREE DETERGENT BUILDER
DE3716544A1 (en) * 1987-05-16 1988-11-24 Basf Ag USE OF WATER-SOLUBLE COPOLYMERS, WHICH CONTAIN MONOMERS WITH AT LEAST TWO ETHYLENICALLY UNSATURATED DOUBLE BINDINGS IN DETERGENT AND CLEANING AGENTS
DE3716543A1 (en) * 1987-05-16 1988-11-24 Basf Ag USE OF WATER-SOLUBLE COPOLYMERS, WHICH CONTAIN MONOMERS WITH AT LEAST TWO ETHYLENICALLY UNSATURATED DOUBLE BINDINGS IN DETERGENT AND CLEANING AGENTS
DE3838093A1 (en) * 1988-11-10 1990-05-17 Basf Ag USE OF COPOLYMERISES AS ADDITION TO LIQUID DETERGENTS
GB8918575D0 (en) * 1989-08-15 1989-09-27 Unilever Plc Liquid detergent composition
IE902759A1 (en) * 1990-02-16 1991-08-28 Rohm & Haas Liquid cleaning compositions containing water-soluble¹polymer
US5409629A (en) * 1991-07-19 1995-04-25 Rohm And Haas Company Use of acrylic acid/ethyl acrylate copolymers for enhanced clay soil removal in liquid laundry detergents
FR2693127B1 (en) * 1992-07-01 1994-08-26 Coatex Sas Stable aqueous suspensions of zeolites, processes for obtaining them and their uses.
CA2143328A1 (en) * 1992-09-01 1994-03-17 Kofi Ofosu-Asante Liquid or gel dishwashing detergent containing alkyl ethoxy carboxylate, divalent ions and alkylpolyethoxypolycarboxylate
DE4313908A1 (en) * 1993-04-28 1994-11-03 Huels Chemische Werke Ag Water-softening formulations
DE4326129A1 (en) * 1993-08-04 1995-02-09 Huels Chemische Werke Ag detergent formulations
DE19534847A1 (en) * 1995-09-20 1997-03-27 Basf Ag Use of polycarboxylic acid halamides as an additive to detergents and cleaning agents
US6126757A (en) * 1998-03-16 2000-10-03 Chemtek, Inc. Method of releasing asphalt from equipment using surfactant solutions
MX341950B (en) * 2009-12-02 2016-09-08 Huntsman Petrochemical Llc Preparation and use of poymeric dispersant compositions.
US9279097B1 (en) 2014-08-14 2016-03-08 Ecolab USA, Inc. Polymers for industrial laundry detergents
PL3196284T3 (en) * 2016-01-21 2018-11-30 Henkel Ag & Co. Kgaa Removal of anti-transpirant contamination

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3821147A (en) * 1972-03-24 1974-06-28 Colgate Palmolive Co Composition for imparting non-permanent soil-release characteristics comprising an aqueous solution of polycarboxylate copolymer and water-soluble amine
FR2294231A1 (en) * 1974-12-10 1976-07-09 Procter & Gamble Europ FLOOR MAINTENANCE AND CLEANING COMPOSITION
US4095035A (en) * 1974-04-15 1978-06-13 Lever Brothers Company Aligomeric polyacrylates
EP0106991A1 (en) * 1982-09-11 1984-05-02 BASF Aktiengesellschaft Process for preparing copolymers of monoethylenically unsaturated mono- and dicarboxylic acids (anhydride)
EP0137669A1 (en) * 1983-08-27 1985-04-17 The Procter & Gamble Company Detergent compositions

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1337972A (en) * 1970-01-08 1973-11-21 Unilever Ltd Detergent compositions
US3706672A (en) * 1970-12-08 1972-12-19 Celanese Corp Detergent polyelectrolyte builders
CH624165A5 (en) * 1976-11-01 1981-07-15 Ciba Geigy Ag
DE3305637A1 (en) * 1983-02-18 1984-08-23 Basf Ag, 6700 Ludwigshafen COPOLYMERISATE, THEIR PRODUCTION AND THEIR USE AS AUXILIARIES IN DETERGENT AND CLEANING AGENTS

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3821147A (en) * 1972-03-24 1974-06-28 Colgate Palmolive Co Composition for imparting non-permanent soil-release characteristics comprising an aqueous solution of polycarboxylate copolymer and water-soluble amine
US4095035A (en) * 1974-04-15 1978-06-13 Lever Brothers Company Aligomeric polyacrylates
FR2294231A1 (en) * 1974-12-10 1976-07-09 Procter & Gamble Europ FLOOR MAINTENANCE AND CLEANING COMPOSITION
EP0106991A1 (en) * 1982-09-11 1984-05-02 BASF Aktiengesellschaft Process for preparing copolymers of monoethylenically unsaturated mono- and dicarboxylic acids (anhydride)
EP0137669A1 (en) * 1983-08-27 1985-04-17 The Procter & Gamble Company Detergent compositions

Also Published As

Publication number Publication date
EP0215251B1 (en) 1989-09-27
US4702858A (en) 1987-10-27
EP0215251A2 (en) 1987-03-25
ATE46716T1 (en) 1989-10-15
JPS6234996A (en) 1987-02-14
ES2001072A6 (en) 1988-04-16
CA1265019A (en) 1990-01-30
DE3665883D1 (en) 1989-11-02
DE3528460A1 (en) 1987-02-19

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