EP0214540A2 - Liquid abrasive cleaner compositions - Google Patents
Liquid abrasive cleaner compositions Download PDFInfo
- Publication number
- EP0214540A2 EP0214540A2 EP86111706A EP86111706A EP0214540A2 EP 0214540 A2 EP0214540 A2 EP 0214540A2 EP 86111706 A EP86111706 A EP 86111706A EP 86111706 A EP86111706 A EP 86111706A EP 0214540 A2 EP0214540 A2 EP 0214540A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- abrasive
- weight
- composition according
- micrometres
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
Definitions
- the present invention relates to liquid abrasive cleaner compositions comprising particulate abrasive material stably suspended in an aqueous liquid medium.
- Liquid abrasive cleaners have been known in the art for many years. They are widely used in the ordinary household cleaning of hard surfaces as they provide a convenient means for the elimination of stubborn soils, greases, burnt-in materials and stains which are not or not completely removed by abrasive-free cleaning products.
- liquid abrasive cleaners have become increasingly more sophisticated, the in-use properties other than straightforward cleaning efficiency becoming relevant factors in the consumer appreciation. Accordingly, the art is aiming at liquid abrasive cleaner products which display a combination of properties such as cleaning efficiency, non-scratching behaviour, rich foaming, a non-gritty creamy appearance, good rinsability, etc.
- liquid abrasive cleaner compositions comprising calcium metasilicate as sole abrasive, or in conjunction with calcium carbonate, which are stated to yield abrasive cleaners of superior cleaning action and reduced abrasion.
- the abrasive material should have a mean particle size in the range of about 5.5 to 16 micrometres and substantially no particles above 40 micrometres.
- liquid abrasive cleaners comprising from 1 to 20% by weight of water-insoluble particulate abrasive of particle sizes in the range of 1 to 40 micrometres.
- Compositions are stated to have a creamy consistency and to exhibit effective removal of grease and other soils with effective polishing action and virtually no scratching.
- liquid scouring cleanser compositions comprising an abrasive powder of mean particle size between 4 and 17.5 micrometres with substantially no particles of size above 75 micrometres.
- An improved soft and smooth consistency is combined with acceptable cleaning performance.
- a drawback of liquid abrasive cleaner compositions formulated with relatively high amounts of fine mineral abrasives, in particular very fine calcite, is that on storage the fine mineral will grow to particles of much larger size which consequently adversely affect the consistency of the product and the non-scratching behaviour thereof on the softer substrates such as e.g. plastic surfaces.
- the present invention provides a liquid abrasive cleaner composition which is free from phosphates, comprising, stably suspended in a liquid medium, from 40 to 70% by weight of a mineral abrasive having particles in the size range of from 1 to 10 micrometres, and up to 20% by weight of one or more electrolytes selected from the group consisting of alkali metal and ammonium salts of citric, carbonic, sulphuric, hydrochloric, succinic, adipic and glutaric acids.
- Suitable for use as the abrasive material are both natural and synthetic mineral abrasives, for example dolomite, precipitated calcium carbonate (aragonite), feldspar, alumina, silica, abrasives, such as quartz and quartzite; and preferably an abrasive material is used with a hardness on Moh's scale of from 1 to 4.
- mineral abrasives for example dolomite, precipitated calcium carbonate (aragonite), feldspar, alumina, silica, abrasives, such as quartz and quartzite
- an abrasive material is used with a hardness on Moh's scale of from 1 to 4.
- Particularly suitable is calcite, for instance limestone, chalk or marble such as those forms of calcite referred to in the British Patent 1 345 119.
- the mineral abrasive is included in an amount of from 40 to 70% by weight of the composition, preferably of from 45 to 55% by weight.
- Suitable abrasive distributions in accordance with the present invention are highly classified distributions having particles within the range of from 1 to 10 micrometres.
- particle size distributions of 1 to 10 micrometres are understood to denote distributions comprising less than 10% by weight of particles having sizes above 10 micrometres and less than 30% by weight of particles having sizes below 1 micrometre.
- the classification at the upperside preferably results in distributions having less than 5 or even 3% by weight of particles having sizes above 10 micrometres.
- a very sharp classification at the lower side is less pertinent, but preferably results in distributions comprising less than 20% by weight of particles having sizes below 1 micrometre.
- the mean particle size of the distribution according to the present invention lies in general within the range of from 1 to 5 micrometres, optimal results being obtained with mean particle sizes within the preferred range of from 2 to 4 micrometres.
- the mineral abrasive is stably suspended in a liquid medium, which normally comprises an aqueous medium in which an anionic detergent material is present, preferably in combination with a nonionic or zwitterionic detergent material.
- Suitable anionic surfactants are alkali metal or alkanol amine salts of C12-C18 branched or straight chain alkylaryl sulphonates, of C10-C18 alkyl (EO)1 - 10 sulphates, of C10-C24 fatty acid soaps etc.
- the amount of anionic surfactant will vary between 0.5 and 15 percent, preferably between 1 and 5 percent by weight of the final composition.
- nonionic or zwitterionic detergent material i n the aqueous medium in an amount of from 0.3 to 7 percent, preferably from 0.5 to 5 percent by weight.
- Suitable examples of nonionic detergents are water-soluble condensation products of ethylene oxide and/or propylene oxide with linear primary or secondary C8-C18 alcohols, with C8-C18 fatty acid amides or fatty acid alkylolamides (both mono- and diamides), with C9-C18 alkyl phenols and so on.
- the alkoxylated C8-C18 fatty acid mono- and dialkylolamides should contain more than one alkylene oxide unit; for example, they should be condensed with e.g.
- alkylene oxide such as ethylene oxide.
- Fatty acid mono-or dialkylolamides in which the fatty acid radical contains 10-16 carbon atoms are also suitable nonionics, such as for instance coco fatty acid mono-or diethanolamide.
- Suitable zwitterionic detergents are trialkyl amine oxides having one long alkyl chain (C8-C18) and two short (C1-C4) alkyl chains; betaines and sulphobetaines.
- liquid medium should exhibit Bingham plastic characteristics, thus forming a stable suspending medium for the mineral abrasive.
- surfactants possibly in combination with other surfactants, are described in British patent specifications 1 167 597, 1 181 607, 1 262 280, 1 303 810, 1 308 190 and 1 418 671.
- one or more electrolytes are included, which must not be of the phosphate type.
- Suitable electrolytes are selected from the group consisting of alkali metal and ammonium salts of citric, carbonic, sulphuric, hydrochloric, succinic, adipic and glutaric acids.
- Preferred electrolytes are the alkali metal salts of citric and carbonic acid, such as sodium citrate, sodium carbonate and sodium bicarbonate.
- the level of electrolyte depends on the particular surfactant system of choice and in general ranges from 0.5 to 25% by weight, preferably from 1 to 7% by weight.
- compositions of the present invention optimally include a bleaching agent of the chlorine-releasing type, such as sodium hypochlorite and isocyanurate.
- adjuncts for liquid abrasive cleansers may be included, such as colouring agents, perfumes, fluorescers, hydrotropes, soil-suspending agents, enzymes, opacifiers, germicides, humectants, etc.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Colloid Chemistry (AREA)
Abstract
Description
- The present invention relates to liquid abrasive cleaner compositions comprising particulate abrasive material stably suspended in an aqueous liquid medium.
- Liquid abrasive cleaners have been known in the art for many years. They are widely used in the ordinary household cleaning of hard surfaces as they provide a convenient means for the elimination of stubborn soils, greases, burnt-in materials and stains which are not or not completely removed by abrasive-free cleaning products.
- Over the last two decades, a multitude of publications have dealt with the formulating of liquid abrasive cleaners. A majority of these publications focus on the stability and suspending properties of the aqueous liquid medium. Suspending media have e.g. been described in the British patent specifications Nos 1 167 597, 1 181 607, 1 262 280, 1 303 810, 1 308 190 and 1 418 671. Other disclosures are concerned with the stability of the suspending media under high shear rates during processing, such as the European patent specifications Nos. 0 050 887 and 0 080 221.
- Over recent years liquid abrasive cleaners have become increasingly more sophisticated, the in-use properties other than straightforward cleaning efficiency becoming relevant factors in the consumer appreciation. Accordingly, the art is aiming at liquid abrasive cleaner products which display a combination of properties such as cleaning efficiency, non-scratching behaviour, rich foaming, a non-gritty creamy appearance, good rinsability, etc.
- Unfortunately, various of these properties prove to be difficult to combine in one product. Good cleaning efficiency is difficult to achieve simultaneously with non-scratching behaviour and/or non-gritty appearance. The same applies e.g. to a combination of rich foaming and easy rinsability.
- Although it has long been recognised that the size of the abrasive is of the greatest importance for an effective cleaner, only in the recent art has it been indicated that the specific particle size distribution of the abrasive material may play an important rôle in the formulation of liquid abrasive cleaner products which, to an acceptable extent, satisfy a number of the desired properties simultaneously.
- In the British patent specification N° 1 581 433 it has been disclosed that rinsing properties are considerably improved if the amount of finest particles in the abrasive powder used in making the cleaner is reduced. In preferred particle distributions less than 20% by weight of the particles are of size below 10 micrometres and substantially no particles are of size above 125 micrometres.
- In the United States patent N° 4 181 633 there are disclosed liquid abrasive cleaner compositions comprising calcium metasilicate as sole abrasive, or in conjunction with calcium carbonate, which are stated to yield abrasive cleaners of superior cleaning action and reduced abrasion. The abrasive material should have a mean particle size in the range of about 5.5 to 16 micrometres and substantially no particles above 40 micrometres.
- In the United States patent N° 4 302 347 all-purpose liquid abrasive cleaners are disclosed comprising from 1 to 20% by weight of water-insoluble particulate abrasive of particle sizes in the range of 1 to 40 micrometres. Compositions are stated to have a creamy consistency and to exhibit effective removal of grease and other soils with effective polishing action and virtually no scratching.
- In the British patent specification N° 2 125 428 liquid scouring cleanser compositions are described comprising an abrasive powder of mean particle size between 4 and 17.5 micrometres with substantially no particles of size above 75 micrometres. An improved soft and smooth consistency is combined with acceptable cleaning performance.
- Compared to the conventional household liquid abrasive cleaners comprising abrasive powders with particle sizes ranging from 1 to about 150 micrometres and mean particle size of between 10 and 50 micrometres, recent prior art suggests a considerable shift to lower particle size ranges and sharper distributions, thereby improving consistency and rinsing properties without unacceptable loss of cleaning performance.
- A drawback of liquid abrasive cleaner compositions formulated with relatively high amounts of fine mineral abrasives, in particular very fine calcite, is that on storage the fine mineral will grow to particles of much larger size which consequently adversely affect the consistency of the product and the non-scratching behaviour thereof on the softer substrates such as e.g. plastic surfaces.
- It has now been found that in compositions which are free from phosphates, a specific selection of electrolyte type effectively reduces this tendency to particle growth.
- In accordance with these findings, the present invention provides a liquid abrasive cleaner composition which is free from phosphates, comprising, stably suspended in a liquid medium, from 40 to 70% by weight of a mineral abrasive having particles in the size range of from 1 to 10 micrometres, and up to 20% by weight of one or more electrolytes selected from the group consisting of alkali metal and ammonium salts of citric, carbonic, sulphuric, hydrochloric, succinic, adipic and glutaric acids.
- Suitable for use as the abrasive material are both natural and synthetic mineral abrasives, for example dolomite, precipitated calcium carbonate (aragonite), feldspar, alumina, silica, abrasives, such as quartz and quartzite; and preferably an abrasive material is used with a hardness on Moh's scale of from 1 to 4. Particularly suitable is calcite, for instance limestone, chalk or marble such as those forms of calcite referred to in the British Patent 1 345 119.
- The mineral abrasive is included in an amount of from 40 to 70% by weight of the composition, preferably of from 45 to 55% by weight.
- Suitable abrasive distributions in accordance with the present invention are highly classified distributions having particles within the range of from 1 to 10 micrometres. For the purpose of this invention particle size distributions of 1 to 10 micrometres are understood to denote distributions comprising less than 10% by weight of particles having sizes above 10 micrometres and less than 30% by weight of particles having sizes below 1 micrometre.
- The classification at the upperside preferably results in distributions having less than 5 or even 3% by weight of particles having sizes above 10 micrometres. A very sharp classification at the lower side is less pertinent, but preferably results in distributions comprising less than 20% by weight of particles having sizes below 1 micrometre.
- The mean particle size of the distribution according to the present invention lies in general within the range of from 1 to 5 micrometres, optimal results being obtained with mean particle sizes within the preferred range of from 2 to 4 micrometres.
- The mineral abrasive is stably suspended in a liquid medium, which normally comprises an aqueous medium in which an anionic detergent material is present, preferably in combination with a nonionic or zwitterionic detergent material. Suitable anionic surfactants are alkali metal or alkanol amine salts of C₁₂-C₁₈ branched or straight chain alkylaryl sulphonates, of C₁₀-C₁₈ alkyl (EO)₁ -₁₀ sulphates, of C₁₀-C₂₄ fatty acid soaps etc. In general the amount of anionic surfactant will vary between 0.5 and 15 percent, preferably between 1 and 5 percent by weight of the final composition.
- It is often desirable to include also a nonionic or zwitterionic detergent material i n the aqueous medium in an amount of from 0.3 to 7 percent, preferably from 0.5 to 5 percent by weight. Suitable examples of nonionic detergents are water-soluble condensation products of ethylene oxide and/or propylene oxide with linear primary or secondary C₈-C₁₈ alcohols, with C₈-C₁₈ fatty acid amides or fatty acid alkylolamides (both mono- and diamides), with C₉-C₁₈ alkyl phenols and so on. The alkoxylated C₈-C₁₈ fatty acid mono- and dialkylolamides should contain more than one alkylene oxide unit; for example, they should be condensed with e.g. 2-5 moles of alkylene oxide such as ethylene oxide. Fatty acid mono-or dialkylolamides in which the fatty acid radical contains 10-16 carbon atoms are also suitable nonionics, such as for instance coco fatty acid mono-or diethanolamide.
- Suitable zwitterionic detergents are trialkyl amine oxides having one long alkyl chain (C₈-C₁₈) and two short (C₁-C₄) alkyl chains; betaines and sulphobetaines.
- It is highly desirable that the liquid medium should exhibit Bingham plastic characteristics, thus forming a stable suspending medium for the mineral abrasive. Such media using the above-mentioned surfactants, possibly in combination with other surfactants, are described in British patent specifications 1 167 597, 1 181 607, 1 262 280, 1 303 810, 1 308 190 and 1 418 671.
- As a further essential component of the suspending medium, one or more electrolytes are included, which must not be of the phosphate type.
- Suitable electrolytes are selected from the group consisting of alkali metal and ammonium salts of citric, carbonic, sulphuric, hydrochloric, succinic, adipic and glutaric acids.
- Preferred electrolytes are the alkali metal salts of citric and carbonic acid, such as sodium citrate, sodium carbonate and sodium bicarbonate. The level of electrolyte depends on the particular surfactant system of choice and in general ranges from 0.5 to 25% by weight, preferably from 1 to 7% by weight.
- The compositions of the present invention optimally include a bleaching agent of the chlorine-releasing type, such as sodium hypochlorite and isocyanurate.
- Other adjuncts for liquid abrasive cleansers may be included, such as colouring agents, perfumes, fluorescers, hydrotropes, soil-suspending agents, enzymes, opacifiers, germicides, humectants, etc.
-
Claims (9)
from 0.3 to 7% by weight of a nonionic surfactant, and
from 0.5 to 25% by weight of the electrolyte.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB858522526A GB8522526D0 (en) | 1985-09-11 | 1985-09-11 | Liquid abrasive cleaner compositions |
GB8522526 | 1985-09-11 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0214540A2 true EP0214540A2 (en) | 1987-03-18 |
EP0214540A3 EP0214540A3 (en) | 1988-05-25 |
EP0214540B1 EP0214540B1 (en) | 1990-10-31 |
Family
ID=10585026
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19860111706 Expired EP0214540B1 (en) | 1985-09-11 | 1986-08-23 | Liquid abrasive cleaner compositions |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0214540B1 (en) |
JP (1) | JPS6270497A (en) |
DE (1) | DE3675301D1 (en) |
GB (1) | GB8522526D0 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0258707A2 (en) * | 1986-09-03 | 1988-03-09 | Kao Corporation | Liquid cleanser composition |
EP0301885A1 (en) * | 1987-07-31 | 1989-02-01 | Unilever Plc | Liquid abrasive cleaning composition |
US5281412A (en) * | 1991-12-30 | 1994-01-25 | The Procter & Gamble Company | Oral compositions |
US5460742A (en) * | 1993-05-18 | 1995-10-24 | Reckitt & Colman Inc. | Aqueous acidic hard surface cleaner with abrasive |
FR2735788A1 (en) * | 1995-06-23 | 1996-12-27 | Francais Prod Ind Cfpi | Acid aq. detergent compsn. contg. poly-carboxylic acid and strong mineral acid, |
EP1460125A1 (en) * | 2003-03-18 | 2004-09-22 | Unilever Plc | Abrasive hard surface cleaning compositions |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2014220C (en) * | 1989-04-11 | 1995-11-07 | Peter Leonard Dawson | Cleaning composition |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1534680A (en) * | 1977-10-14 | 1978-12-06 | Colgate Palmolive Co | Cleaning compositions |
US4181633A (en) * | 1976-12-01 | 1980-01-01 | Colgate-Palmolive Company | Liquid scouring cream containing calcium metasilicate |
EP0009942A1 (en) * | 1978-10-02 | 1980-04-16 | Unilever Plc | Pourable scouring cleanser compositions |
GB2055118A (en) * | 1979-06-25 | 1981-02-25 | Polymer Technology Corp | Cleaning contact lenses |
US4396525A (en) * | 1981-09-14 | 1983-08-02 | Lever Brothers Company | Phosphate free liquid scouring composition |
EP0103325A1 (en) * | 1982-08-20 | 1984-03-21 | Unilever N.V. | Scouring cleanser compositions |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS609560B2 (en) * | 1978-06-29 | 1985-03-11 | ライオン株式会社 | Aqueous detergent slurry |
JPS6021718B2 (en) * | 1980-12-16 | 1985-05-29 | ライオン株式会社 | liquid cleanser composition |
-
1985
- 1985-09-11 GB GB858522526A patent/GB8522526D0/en active Pending
-
1986
- 1986-08-23 DE DE8686111706T patent/DE3675301D1/en not_active Expired - Fee Related
- 1986-08-23 EP EP19860111706 patent/EP0214540B1/en not_active Expired
- 1986-09-09 JP JP21250886A patent/JPS6270497A/en active Granted
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4181633A (en) * | 1976-12-01 | 1980-01-01 | Colgate-Palmolive Company | Liquid scouring cream containing calcium metasilicate |
GB1534680A (en) * | 1977-10-14 | 1978-12-06 | Colgate Palmolive Co | Cleaning compositions |
EP0009942A1 (en) * | 1978-10-02 | 1980-04-16 | Unilever Plc | Pourable scouring cleanser compositions |
GB2055118A (en) * | 1979-06-25 | 1981-02-25 | Polymer Technology Corp | Cleaning contact lenses |
US4396525A (en) * | 1981-09-14 | 1983-08-02 | Lever Brothers Company | Phosphate free liquid scouring composition |
EP0103325A1 (en) * | 1982-08-20 | 1984-03-21 | Unilever N.V. | Scouring cleanser compositions |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0258707A2 (en) * | 1986-09-03 | 1988-03-09 | Kao Corporation | Liquid cleanser composition |
EP0258707A3 (en) * | 1986-09-03 | 1989-09-27 | Kao Corporation | Liquid cleanser composition |
EP0301885A1 (en) * | 1987-07-31 | 1989-02-01 | Unilever Plc | Liquid abrasive cleaning composition |
US4911857A (en) * | 1987-07-31 | 1990-03-27 | Lever Brothers Company | Aqueous liquid abrasive cleaning composition: particulate abrasive suspended in aqueous medium |
US5281412A (en) * | 1991-12-30 | 1994-01-25 | The Procter & Gamble Company | Oral compositions |
US5460742A (en) * | 1993-05-18 | 1995-10-24 | Reckitt & Colman Inc. | Aqueous acidic hard surface cleaner with abrasive |
FR2735788A1 (en) * | 1995-06-23 | 1996-12-27 | Francais Prod Ind Cfpi | Acid aq. detergent compsn. contg. poly-carboxylic acid and strong mineral acid, |
EP1460125A1 (en) * | 2003-03-18 | 2004-09-22 | Unilever Plc | Abrasive hard surface cleaning compositions |
WO2004083353A1 (en) * | 2003-03-18 | 2004-09-30 | Unilever N.V. | Abrasive hard surface cleaning compositions |
Also Published As
Publication number | Publication date |
---|---|
EP0214540B1 (en) | 1990-10-31 |
GB8522526D0 (en) | 1985-10-16 |
JPS6270497A (en) | 1987-03-31 |
EP0214540A3 (en) | 1988-05-25 |
JPH0455637B2 (en) | 1992-09-03 |
DE3675301D1 (en) | 1990-12-06 |
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