EP0210435A2 - Procédé pour refroidir et purifier un gaz de générateur et un gaz de haut-fourneau et dispositif pour l'exécution de ce procédé - Google Patents

Procédé pour refroidir et purifier un gaz de générateur et un gaz de haut-fourneau et dispositif pour l'exécution de ce procédé Download PDF

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Publication number
EP0210435A2
EP0210435A2 EP86108610A EP86108610A EP0210435A2 EP 0210435 A2 EP0210435 A2 EP 0210435A2 EP 86108610 A EP86108610 A EP 86108610A EP 86108610 A EP86108610 A EP 86108610A EP 0210435 A2 EP0210435 A2 EP 0210435A2
Authority
EP
European Patent Office
Prior art keywords
gas
cooling
cleaning
cleaning unit
unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86108610A
Other languages
German (de)
English (en)
Other versions
EP0210435A3 (en
EP0210435B1 (fr
Inventor
Bogdan Vuletic
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Primetals Technologies Austria GmbH
Deutsche Voest Alpine Industrieanlagenbau GmbH
Original Assignee
Voestalpine AG
Voest Alpine Industrienlagenbau GmbH
Deutsche Voest Alpine Industrieanlagenbau GmbH
Korf Engineering GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Voestalpine AG, Voest Alpine Industrienlagenbau GmbH, Deutsche Voest Alpine Industrieanlagenbau GmbH, Korf Engineering GmbH filed Critical Voestalpine AG
Publication of EP0210435A2 publication Critical patent/EP0210435A2/fr
Publication of EP0210435A3 publication Critical patent/EP0210435A3/de
Application granted granted Critical
Publication of EP0210435B1 publication Critical patent/EP0210435B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/008Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/0073Selection or treatment of the reducing gases
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/40Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
    • C21B2100/44Removing particles, e.g. by scrubbing, dedusting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S75/00Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures
    • Y10S75/958Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures with concurrent production of iron and other desired nonmetallic product, e.g. energy, fertilizer

Definitions

  • the invention relates to a method according to the preamble of claim 1 and an apparatus for carrying it out.
  • control range of the scrubbers used extends over a ratio of up to about 1: 4 Device and the permissible clean gas dust contents can no longer be maintained.
  • a regulation for changes in quantity up to about 1:20 could possibly be achieved if each cleaning unit was included two adjustable venturi washers and the associated droplet separators.
  • the invention is characterized in that for the generation of the cooling and excess gas separate cooling and cleaning units are used and that at least through the final stage of the cooling and cleaning unit for the cooling gas an essentially constant gas quantity is passed, such that the part of the generator gas to be cooled and cleaned exceeds this quantity of gas in the cooling and cleaning unit for the excess gas is passed.
  • the cleaning in each of the cooling and cleaning units takes place in two stages, and the part of the generator gas used to generate the excess gas is passed through the first cleaning stage of the cooling and cleaning unit for the cooling gas and then through the second cleaning stage of the cooling and Cleaning unit led for the excess gas. It is preferably in the arrangement of melt-down gasifier and the reduction unit are no longer required part of the quantity of gas in total produced in the melter gasifier discharged exclusively through the cooling and Cleaner with q saggregat for Ubcrschußgas and further by the cooling and cleaning unit for the cooling gas only in the arrangement of melt-down gasifier and the reduction unit as the cooling and conveying gas.
  • the part of the gas led out of the cooling and cleaning unit for the cooling gas which is not required as the cooling and conveying gas in the arrangement of the melter gasifier and the reduction unit, can be returned to the input of this unit, so that the gas passes through this unit guided amount of gas is essentially constant regardless of the cooling gas requirement.
  • each cooling and cleaning unit has a pack washer and an adjustable venturi washer connected downstream of it.
  • a connecting line is preferably provided from the outlet of the packing washer of the cooling and cleaning unit for the cooling gas to the input of the venturi washer of the cooling and cleaning unit for the excess gas.
  • This shows a schematic representation of the cooling and cleaning units for the generator gas and the top gas of an arrangement consisting of a direct reduction unit and a melter gasifier.
  • the blast furnace gas of a direct reduction shaft furnace is fed via a line 1 and the part of the generator gas generated in a melter gasifier, which is not blown directly into the reduction zone of the direct reduction shaft furnace, is fed via line 2.
  • the top gas under pressure passes from line 1 into a pack washer 3, in which it is cooled to the desired temperature and prewashed.
  • the blast furnace gas thus prepared is then passed via line 4 into an adjustable venturi scrubber 5.
  • the part of the generator gas flowing through line 2 reaches a pack washer 6, in which this gas is also cooled to the desired temperature and prewashed. Part of this gas pretreated in this way is fed via line 7 to an adjustable venturi scrubber 8, in which it is washed again, so that the required clean gas dust content is achieved.
  • This gas is then dewatered in a downstream droplet separator 9. It then passes through a line 10 to a blower 11, by means of which it is brought to the required pressure in order to be available as cooling gas in a line 12 mainly for setting the generator gas temperature.
  • the blower 11 is a volume conveyor which always delivers the same amount of gas at a constant system pressure, so that a constant gas flow flows through the venturi scrubber 8. Since the amount of gas supplied via line 2 does not correspond to the amount of gas conveyed by the blower 11, the outlet line of the pack washer 6 is branched into line 7 and a further line 13, which conducts the gas quantity not taken up by line 7 to the inlet of venturi scrubber 5.
  • the blast furnace gas processed in the pack scrubber 3 is thus fed via line 4 and part of the generator gas processed in the pack scrubber 6 is fed via line 13.
  • the sum of these two quantities of gas is essentially constant even in exceptional operating conditions.
  • the venturi scrubber 5 is a mist eliminator 14 for draining the overall reini g th gas downstream.
  • the cleaned and cooled excess gas of the plant is passed to suitable consumers via a line 15.
  • the cooling gas located in line 12 insofar as it is not required in the arrangement comprising the melter gasifier and direct reduction shaft furnace, is fed back to the inlet of the pack scrubber 6 via a branched line 16. This ensures that an approximately constant amount of gas always flows through the venturi scrubber 8 regardless of the cooling gas requirement of the reduction system.
  • the two pack washers 3 and 6 are relatively insensitive to large fluctuations in the gas quantities passed through. In them, the dust is largely removed from the gases, so that the amounts of dust washed out in the venturi scrubbers 5 and 8 are relatively small and there is no risk of blockage of these scrubbers. This also makes it possible to use gases with an extremely low clean gas dust content of 5 mg / Nm 3 at the outlet of the Venturi scrubber to obtain.
  • venturi scrubbers The mode of operation of the venturi scrubbers depends on the amount of gas passed through them. However, the measures described, in particular the fan 11, which conveys a constant gas volume, and the line 13 between the outlet of the pack washer 6 and the inlet of the venturi washer 5 ensure that the venturi washers 5 and 8 are flowed through by essentially constant gas flows.
  • venturi scrubber 5 it is therefore possible, on the one hand, for optimal degrees of separation for the venturi scrubber 5, in that the part of the total amount of gas generated in the melter gasifier, which is not required in the arrangement of the melter gasifier and direct reduction shaft furnace, is discharged as excess gas exclusively via this venturi scrubber and, on the other hand, for the venturi scrubber 8 in that only through this the amount of gas required in the arrangement of the melter gasifier and direct reduction shaft furnace as cooling and conveying gas is reached.
  • the venturi scrubbers only carry out the final cleaning of the gases, there is also no need to fear that they will be blocked by too much dust.
  • the device thus not only delivers excellent operating results, but also works largely trouble-free and easy to maintain.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Industrial Gases (AREA)
EP86108610A 1985-07-02 1986-06-24 Procédé pour refroidir et purifier un gaz de générateur et un gaz de haut-fourneau et dispositif pour l'exécution de ce procédé Expired - Lifetime EP0210435B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3524011 1985-07-02
DE19853524011 DE3524011A1 (de) 1985-07-02 1985-07-02 Verfahren zur kuehlung und reinigung von generatorgas und gichtgas und vorrichtung zur durchfuehrung dieses verfahrens

Publications (3)

Publication Number Publication Date
EP0210435A2 true EP0210435A2 (fr) 1987-02-04
EP0210435A3 EP0210435A3 (en) 1989-11-23
EP0210435B1 EP0210435B1 (fr) 1991-08-28

Family

ID=6274999

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86108610A Expired - Lifetime EP0210435B1 (fr) 1985-07-02 1986-06-24 Procédé pour refroidir et purifier un gaz de générateur et un gaz de haut-fourneau et dispositif pour l'exécution de ce procédé

Country Status (14)

Country Link
US (2) US4793857A (fr)
EP (1) EP0210435B1 (fr)
JP (1) JPH0768526B2 (fr)
KR (1) KR940001529B1 (fr)
CN (1) CN1011418B (fr)
AU (1) AU595532B2 (fr)
BR (1) BR8603067A (fr)
CA (1) CA1283542C (fr)
CS (1) CS274656B2 (fr)
DD (1) DD247917A5 (fr)
DE (2) DE3524011A1 (fr)
IN (1) IN165848B (fr)
SU (1) SU1561828A3 (fr)
ZA (1) ZA864394B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6511529B1 (en) 1996-05-15 2003-01-28 Voest-Alpine Industrieanlagenbau Gmbh Method of reducing the number of pollutants in a gas flow and device for carrying out said method
EP2746408A1 (fr) * 2012-12-21 2014-06-25 Siemens VAI Metals Technologies GmbH Surchauffe de gaz d'exportation, utilisé dans un procédé de reduction, pour compenser des variations de flux et dispositif à cet effet

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5320676A (en) * 1992-10-06 1994-06-14 Bechtel Group, Inc. Low slag iron making process with injecting coolant
US5354356A (en) * 1992-10-06 1994-10-11 Bechtel Group Inc. Method of providing fuel for an iron making process
US5397376A (en) * 1992-10-06 1995-03-14 Bechtel Group, Inc. Method of providing fuel for an iron making process
US6197088B1 (en) 1992-10-06 2001-03-06 Bechtel Group, Inc. Producing liquid iron having a low sulfur content
US5958107A (en) * 1993-12-15 1999-09-28 Bechtel Croup, Inc. Shift conversion for the preparation of reducing gas
JPH1157402A (ja) * 1997-08-13 1999-03-02 Mitsubishi Heavy Ind Ltd ガス精製方法及びガス精製設備
AT507003B1 (de) * 2008-06-27 2010-03-15 Siemens Vai Metals Tech Gmbh Prozessgas-reinigungseinrichtung für eine schmelzreduktionsanlage zur gewinnung von roheisen

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1582232A (en) * 1976-08-14 1981-01-07 Lodge Cottrell Ltd Gas cleaning
FR2478126A1 (fr) * 1980-03-17 1981-09-18 Loftus Corp Peter F Procede et installation pour le traitement des gaz de hauts fourneaux
US4316739A (en) * 1979-07-16 1982-02-23 Midrex Corporation Method for producing molten iron
EP0048008B1 (fr) * 1980-09-12 1984-08-01 Deutsche Voest-Alpine Industrieanlagenbau Gmbh Procédé et dispositif pour la production directe de fonte liquide à partir de minerai de fer en morceaux

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT247385B (de) * 1961-05-16 1966-06-10 Zd Y Na Vyrobu Vzduchotechnick Trockenreinigungsverfahren für Hochofen-(Gicht-)gas
SU1479006A3 (ru) * 1984-11-26 1989-05-07 Фоест-Альпине (Фирма) Способ получени жидкого чугуна или продуктов стали и восстановительного газа в плавильном газификаторе

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1582232A (en) * 1976-08-14 1981-01-07 Lodge Cottrell Ltd Gas cleaning
US4316739A (en) * 1979-07-16 1982-02-23 Midrex Corporation Method for producing molten iron
FR2478126A1 (fr) * 1980-03-17 1981-09-18 Loftus Corp Peter F Procede et installation pour le traitement des gaz de hauts fourneaux
EP0048008B1 (fr) * 1980-09-12 1984-08-01 Deutsche Voest-Alpine Industrieanlagenbau Gmbh Procédé et dispositif pour la production directe de fonte liquide à partir de minerai de fer en morceaux

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6511529B1 (en) 1996-05-15 2003-01-28 Voest-Alpine Industrieanlagenbau Gmbh Method of reducing the number of pollutants in a gas flow and device for carrying out said method
EP2746408A1 (fr) * 2012-12-21 2014-06-25 Siemens VAI Metals Technologies GmbH Surchauffe de gaz d'exportation, utilisé dans un procédé de reduction, pour compenser des variations de flux et dispositif à cet effet
WO2014095111A1 (fr) * 2012-12-21 2014-06-26 Siemens Vai Metals Technologies Gmbh Surchauffage d'un gaz exporté utilisé dans un processus de réduction pour compenser des fluctuations de quantité et dispositif correspondant

Also Published As

Publication number Publication date
IN165848B (fr) 1990-01-27
SU1561828A3 (ru) 1990-04-30
EP0210435A3 (en) 1989-11-23
CS274656B2 (en) 1991-09-15
BR8603067A (pt) 1987-03-17
CA1283542C (fr) 1991-04-30
CN1011418B (zh) 1991-01-30
CN86104420A (zh) 1987-02-04
JPS6284184A (ja) 1987-04-17
KR940001529B1 (ko) 1994-02-23
AU595532B2 (en) 1990-04-05
ZA864394B (en) 1987-02-25
CS470586A2 (en) 1990-10-12
US4793857A (en) 1988-12-27
US4850574A (en) 1989-07-25
KR870001293A (ko) 1987-03-12
DE3524011C2 (fr) 1989-01-05
DE3681090D1 (de) 1991-10-02
JPH0768526B2 (ja) 1995-07-26
AU5855586A (en) 1987-01-22
DD247917A5 (de) 1987-07-22
EP0210435B1 (fr) 1991-08-28
DE3524011A1 (de) 1987-01-15

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