EP0210435A2 - Procédé pour refroidir et purifier un gaz de générateur et un gaz de haut-fourneau et dispositif pour l'exécution de ce procédé - Google Patents
Procédé pour refroidir et purifier un gaz de générateur et un gaz de haut-fourneau et dispositif pour l'exécution de ce procédé Download PDFInfo
- Publication number
- EP0210435A2 EP0210435A2 EP86108610A EP86108610A EP0210435A2 EP 0210435 A2 EP0210435 A2 EP 0210435A2 EP 86108610 A EP86108610 A EP 86108610A EP 86108610 A EP86108610 A EP 86108610A EP 0210435 A2 EP0210435 A2 EP 0210435A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- gas
- cooling
- cleaning
- cleaning unit
- unit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/008—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0073—Selection or treatment of the reducing gases
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
- C21B2100/44—Removing particles, e.g. by scrubbing, dedusting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S75/00—Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures
- Y10S75/958—Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures with concurrent production of iron and other desired nonmetallic product, e.g. energy, fertilizer
Definitions
- the invention relates to a method according to the preamble of claim 1 and an apparatus for carrying it out.
- control range of the scrubbers used extends over a ratio of up to about 1: 4 Device and the permissible clean gas dust contents can no longer be maintained.
- a regulation for changes in quantity up to about 1:20 could possibly be achieved if each cleaning unit was included two adjustable venturi washers and the associated droplet separators.
- the invention is characterized in that for the generation of the cooling and excess gas separate cooling and cleaning units are used and that at least through the final stage of the cooling and cleaning unit for the cooling gas an essentially constant gas quantity is passed, such that the part of the generator gas to be cooled and cleaned exceeds this quantity of gas in the cooling and cleaning unit for the excess gas is passed.
- the cleaning in each of the cooling and cleaning units takes place in two stages, and the part of the generator gas used to generate the excess gas is passed through the first cleaning stage of the cooling and cleaning unit for the cooling gas and then through the second cleaning stage of the cooling and Cleaning unit led for the excess gas. It is preferably in the arrangement of melt-down gasifier and the reduction unit are no longer required part of the quantity of gas in total produced in the melter gasifier discharged exclusively through the cooling and Cleaner with q saggregat for Ubcrschußgas and further by the cooling and cleaning unit for the cooling gas only in the arrangement of melt-down gasifier and the reduction unit as the cooling and conveying gas.
- the part of the gas led out of the cooling and cleaning unit for the cooling gas which is not required as the cooling and conveying gas in the arrangement of the melter gasifier and the reduction unit, can be returned to the input of this unit, so that the gas passes through this unit guided amount of gas is essentially constant regardless of the cooling gas requirement.
- each cooling and cleaning unit has a pack washer and an adjustable venturi washer connected downstream of it.
- a connecting line is preferably provided from the outlet of the packing washer of the cooling and cleaning unit for the cooling gas to the input of the venturi washer of the cooling and cleaning unit for the excess gas.
- This shows a schematic representation of the cooling and cleaning units for the generator gas and the top gas of an arrangement consisting of a direct reduction unit and a melter gasifier.
- the blast furnace gas of a direct reduction shaft furnace is fed via a line 1 and the part of the generator gas generated in a melter gasifier, which is not blown directly into the reduction zone of the direct reduction shaft furnace, is fed via line 2.
- the top gas under pressure passes from line 1 into a pack washer 3, in which it is cooled to the desired temperature and prewashed.
- the blast furnace gas thus prepared is then passed via line 4 into an adjustable venturi scrubber 5.
- the part of the generator gas flowing through line 2 reaches a pack washer 6, in which this gas is also cooled to the desired temperature and prewashed. Part of this gas pretreated in this way is fed via line 7 to an adjustable venturi scrubber 8, in which it is washed again, so that the required clean gas dust content is achieved.
- This gas is then dewatered in a downstream droplet separator 9. It then passes through a line 10 to a blower 11, by means of which it is brought to the required pressure in order to be available as cooling gas in a line 12 mainly for setting the generator gas temperature.
- the blower 11 is a volume conveyor which always delivers the same amount of gas at a constant system pressure, so that a constant gas flow flows through the venturi scrubber 8. Since the amount of gas supplied via line 2 does not correspond to the amount of gas conveyed by the blower 11, the outlet line of the pack washer 6 is branched into line 7 and a further line 13, which conducts the gas quantity not taken up by line 7 to the inlet of venturi scrubber 5.
- the blast furnace gas processed in the pack scrubber 3 is thus fed via line 4 and part of the generator gas processed in the pack scrubber 6 is fed via line 13.
- the sum of these two quantities of gas is essentially constant even in exceptional operating conditions.
- the venturi scrubber 5 is a mist eliminator 14 for draining the overall reini g th gas downstream.
- the cleaned and cooled excess gas of the plant is passed to suitable consumers via a line 15.
- the cooling gas located in line 12 insofar as it is not required in the arrangement comprising the melter gasifier and direct reduction shaft furnace, is fed back to the inlet of the pack scrubber 6 via a branched line 16. This ensures that an approximately constant amount of gas always flows through the venturi scrubber 8 regardless of the cooling gas requirement of the reduction system.
- the two pack washers 3 and 6 are relatively insensitive to large fluctuations in the gas quantities passed through. In them, the dust is largely removed from the gases, so that the amounts of dust washed out in the venturi scrubbers 5 and 8 are relatively small and there is no risk of blockage of these scrubbers. This also makes it possible to use gases with an extremely low clean gas dust content of 5 mg / Nm 3 at the outlet of the Venturi scrubber to obtain.
- venturi scrubbers The mode of operation of the venturi scrubbers depends on the amount of gas passed through them. However, the measures described, in particular the fan 11, which conveys a constant gas volume, and the line 13 between the outlet of the pack washer 6 and the inlet of the venturi washer 5 ensure that the venturi washers 5 and 8 are flowed through by essentially constant gas flows.
- venturi scrubber 5 it is therefore possible, on the one hand, for optimal degrees of separation for the venturi scrubber 5, in that the part of the total amount of gas generated in the melter gasifier, which is not required in the arrangement of the melter gasifier and direct reduction shaft furnace, is discharged as excess gas exclusively via this venturi scrubber and, on the other hand, for the venturi scrubber 8 in that only through this the amount of gas required in the arrangement of the melter gasifier and direct reduction shaft furnace as cooling and conveying gas is reached.
- the venturi scrubbers only carry out the final cleaning of the gases, there is also no need to fear that they will be blocked by too much dust.
- the device thus not only delivers excellent operating results, but also works largely trouble-free and easy to maintain.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3524011 | 1985-07-02 | ||
DE19853524011 DE3524011A1 (de) | 1985-07-02 | 1985-07-02 | Verfahren zur kuehlung und reinigung von generatorgas und gichtgas und vorrichtung zur durchfuehrung dieses verfahrens |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0210435A2 true EP0210435A2 (fr) | 1987-02-04 |
EP0210435A3 EP0210435A3 (en) | 1989-11-23 |
EP0210435B1 EP0210435B1 (fr) | 1991-08-28 |
Family
ID=6274999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86108610A Expired - Lifetime EP0210435B1 (fr) | 1985-07-02 | 1986-06-24 | Procédé pour refroidir et purifier un gaz de générateur et un gaz de haut-fourneau et dispositif pour l'exécution de ce procédé |
Country Status (14)
Country | Link |
---|---|
US (2) | US4793857A (fr) |
EP (1) | EP0210435B1 (fr) |
JP (1) | JPH0768526B2 (fr) |
KR (1) | KR940001529B1 (fr) |
CN (1) | CN1011418B (fr) |
AU (1) | AU595532B2 (fr) |
BR (1) | BR8603067A (fr) |
CA (1) | CA1283542C (fr) |
CS (1) | CS274656B2 (fr) |
DD (1) | DD247917A5 (fr) |
DE (2) | DE3524011A1 (fr) |
IN (1) | IN165848B (fr) |
SU (1) | SU1561828A3 (fr) |
ZA (1) | ZA864394B (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6511529B1 (en) | 1996-05-15 | 2003-01-28 | Voest-Alpine Industrieanlagenbau Gmbh | Method of reducing the number of pollutants in a gas flow and device for carrying out said method |
EP2746408A1 (fr) * | 2012-12-21 | 2014-06-25 | Siemens VAI Metals Technologies GmbH | Surchauffe de gaz d'exportation, utilisé dans un procédé de reduction, pour compenser des variations de flux et dispositif à cet effet |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5320676A (en) * | 1992-10-06 | 1994-06-14 | Bechtel Group, Inc. | Low slag iron making process with injecting coolant |
US5354356A (en) * | 1992-10-06 | 1994-10-11 | Bechtel Group Inc. | Method of providing fuel for an iron making process |
US5397376A (en) * | 1992-10-06 | 1995-03-14 | Bechtel Group, Inc. | Method of providing fuel for an iron making process |
US6197088B1 (en) | 1992-10-06 | 2001-03-06 | Bechtel Group, Inc. | Producing liquid iron having a low sulfur content |
US5958107A (en) * | 1993-12-15 | 1999-09-28 | Bechtel Croup, Inc. | Shift conversion for the preparation of reducing gas |
JPH1157402A (ja) * | 1997-08-13 | 1999-03-02 | Mitsubishi Heavy Ind Ltd | ガス精製方法及びガス精製設備 |
AT507003B1 (de) * | 2008-06-27 | 2010-03-15 | Siemens Vai Metals Tech Gmbh | Prozessgas-reinigungseinrichtung für eine schmelzreduktionsanlage zur gewinnung von roheisen |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1582232A (en) * | 1976-08-14 | 1981-01-07 | Lodge Cottrell Ltd | Gas cleaning |
FR2478126A1 (fr) * | 1980-03-17 | 1981-09-18 | Loftus Corp Peter F | Procede et installation pour le traitement des gaz de hauts fourneaux |
US4316739A (en) * | 1979-07-16 | 1982-02-23 | Midrex Corporation | Method for producing molten iron |
EP0048008B1 (fr) * | 1980-09-12 | 1984-08-01 | Deutsche Voest-Alpine Industrieanlagenbau Gmbh | Procédé et dispositif pour la production directe de fonte liquide à partir de minerai de fer en morceaux |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT247385B (de) * | 1961-05-16 | 1966-06-10 | Zd Y Na Vyrobu Vzduchotechnick | Trockenreinigungsverfahren für Hochofen-(Gicht-)gas |
SU1479006A3 (ru) * | 1984-11-26 | 1989-05-07 | Фоест-Альпине (Фирма) | Способ получени жидкого чугуна или продуктов стали и восстановительного газа в плавильном газификаторе |
-
1985
- 1985-07-02 DE DE19853524011 patent/DE3524011A1/de active Granted
-
1986
- 1986-06-11 AU AU58555/86A patent/AU595532B2/en not_active Ceased
- 1986-06-12 ZA ZA864394A patent/ZA864394B/xx unknown
- 1986-06-24 EP EP86108610A patent/EP0210435B1/fr not_active Expired - Lifetime
- 1986-06-24 DE DE8686108610T patent/DE3681090D1/de not_active Expired - Fee Related
- 1986-06-25 CS CS470586A patent/CS274656B2/cs not_active IP Right Cessation
- 1986-06-30 CA CA000512850A patent/CA1283542C/fr not_active Expired - Fee Related
- 1986-06-30 DD DD86291863A patent/DD247917A5/de not_active IP Right Cessation
- 1986-07-01 JP JP61152823A patent/JPH0768526B2/ja not_active Expired - Fee Related
- 1986-07-01 BR BR8603067A patent/BR8603067A/pt not_active IP Right Cessation
- 1986-07-01 SU SU4027780A patent/SU1561828A3/ru active
- 1986-07-01 IN IN491/CAL/86A patent/IN165848B/en unknown
- 1986-07-02 CN CN86104420A patent/CN1011418B/zh not_active Expired
- 1986-07-02 US US06/881,071 patent/US4793857A/en not_active Expired - Lifetime
- 1986-07-02 KR KR1019860005360A patent/KR940001529B1/ko not_active IP Right Cessation
-
1988
- 1988-09-30 US US07/252,184 patent/US4850574A/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1582232A (en) * | 1976-08-14 | 1981-01-07 | Lodge Cottrell Ltd | Gas cleaning |
US4316739A (en) * | 1979-07-16 | 1982-02-23 | Midrex Corporation | Method for producing molten iron |
FR2478126A1 (fr) * | 1980-03-17 | 1981-09-18 | Loftus Corp Peter F | Procede et installation pour le traitement des gaz de hauts fourneaux |
EP0048008B1 (fr) * | 1980-09-12 | 1984-08-01 | Deutsche Voest-Alpine Industrieanlagenbau Gmbh | Procédé et dispositif pour la production directe de fonte liquide à partir de minerai de fer en morceaux |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6511529B1 (en) | 1996-05-15 | 2003-01-28 | Voest-Alpine Industrieanlagenbau Gmbh | Method of reducing the number of pollutants in a gas flow and device for carrying out said method |
EP2746408A1 (fr) * | 2012-12-21 | 2014-06-25 | Siemens VAI Metals Technologies GmbH | Surchauffe de gaz d'exportation, utilisé dans un procédé de reduction, pour compenser des variations de flux et dispositif à cet effet |
WO2014095111A1 (fr) * | 2012-12-21 | 2014-06-26 | Siemens Vai Metals Technologies Gmbh | Surchauffage d'un gaz exporté utilisé dans un processus de réduction pour compenser des fluctuations de quantité et dispositif correspondant |
Also Published As
Publication number | Publication date |
---|---|
IN165848B (fr) | 1990-01-27 |
SU1561828A3 (ru) | 1990-04-30 |
EP0210435A3 (en) | 1989-11-23 |
CS274656B2 (en) | 1991-09-15 |
BR8603067A (pt) | 1987-03-17 |
CA1283542C (fr) | 1991-04-30 |
CN1011418B (zh) | 1991-01-30 |
CN86104420A (zh) | 1987-02-04 |
JPS6284184A (ja) | 1987-04-17 |
KR940001529B1 (ko) | 1994-02-23 |
AU595532B2 (en) | 1990-04-05 |
ZA864394B (en) | 1987-02-25 |
CS470586A2 (en) | 1990-10-12 |
US4793857A (en) | 1988-12-27 |
US4850574A (en) | 1989-07-25 |
KR870001293A (ko) | 1987-03-12 |
DE3524011C2 (fr) | 1989-01-05 |
DE3681090D1 (de) | 1991-10-02 |
JPH0768526B2 (ja) | 1995-07-26 |
AU5855586A (en) | 1987-01-22 |
DD247917A5 (de) | 1987-07-22 |
EP0210435B1 (fr) | 1991-08-28 |
DE3524011A1 (de) | 1987-01-15 |
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