EP0199403A3 - Stable liquid detergent compositions - Google Patents

Stable liquid detergent compositions Download PDF

Info

Publication number
EP0199403A3
EP0199403A3 EP86200584A EP86200584A EP0199403A3 EP 0199403 A3 EP0199403 A3 EP 0199403A3 EP 86200584 A EP86200584 A EP 86200584A EP 86200584 A EP86200584 A EP 86200584A EP 0199403 A3 EP0199403 A3 EP 0199403A3
Authority
EP
European Patent Office
Prior art keywords
liquid detergent
detergent compositions
surfactant
stable liquid
amine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86200584A
Other versions
EP0199403B1 (en
EP0199403A2 (en
Inventor
Eugene Paul Gosselink
Larry James Hughes
Antoinette Louise Larrabee
Robert Mermelstein
Nodie Monroe Washington
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to AT86200584T priority Critical patent/ATE98674T1/en
Publication of EP0199403A2 publication Critical patent/EP0199403A2/en
Publication of EP0199403A3 publication Critical patent/EP0199403A3/en
Application granted granted Critical
Publication of EP0199403B1 publication Critical patent/EP0199403B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/521—Carboxylic amides (R1-CO-NR2R3), where R1, R2 and R3 are alkyl or alkenyl groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Heavy-duty liquid detergents containing an essential block polyester soil release agent; anionic surfactant; ethoxylated non-ionic surfactant; optional quaternary ammonium, amine, amide, or amine oxide surfactant; preferably fatty acid and/or poly-carboxylate builders; a neutralization system preferably comprising sodium, potassium and/or low levels of alkanolamines; and a solvent system comprising ethanol, polyol and/or water. The compositions are isotropic liquids providing a high level of detergency performance.
EP86200584A 1985-04-15 1986-04-07 Stable liquid detergent compositions Expired - Lifetime EP0199403B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86200584T ATE98674T1 (en) 1985-04-15 1986-04-07 STABLE LIQUID DETERGENT.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US72312085A 1985-04-15 1985-04-15
US723120 1985-04-15

Publications (3)

Publication Number Publication Date
EP0199403A2 EP0199403A2 (en) 1986-10-29
EP0199403A3 true EP0199403A3 (en) 1989-07-05
EP0199403B1 EP0199403B1 (en) 1993-12-15

Family

ID=24904937

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86200584A Expired - Lifetime EP0199403B1 (en) 1985-04-15 1986-04-07 Stable liquid detergent compositions

Country Status (4)

Country Link
EP (1) EP0199403B1 (en)
AT (1) ATE98674T1 (en)
AU (1) AU601679B2 (en)
DE (1) DE3689385T2 (en)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IN166313B (en) * 1985-08-05 1990-04-07 Colgate Palmolive Co
US4711730A (en) * 1986-04-15 1987-12-08 The Procter & Gamble Company Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents
GB8609806D0 (en) * 1986-04-22 1986-05-29 Unilever Plc Cleaning composition
GB8617255D0 (en) * 1986-07-15 1986-08-20 Procter & Gamble Ltd Laundry compositions
GB8629936D0 (en) * 1986-12-15 1987-01-28 Procter & Gamble Laundry compositions
US4721580A (en) * 1987-01-07 1988-01-26 The Procter & Gamble Company Anionic end-capped oligomeric esters as soil release agents in detergent compositions
GB8722540D0 (en) * 1987-09-24 1987-10-28 Unilever Plc Composition for softening fabrics
US4877896A (en) * 1987-10-05 1989-10-31 The Procter & Gamble Company Sulfoaroyl end-capped ester of oligomers suitable as soil-release agents in detergent compositions and fabric-conditioner articles
US4976879A (en) * 1987-10-05 1990-12-11 The Procter & Gamble Company Sulfoaroyl end-capped ester oligomers suitable as soil-release agents in detergent compositions and fabric-conditioner articles
FR2636961B1 (en) * 1988-09-29 1994-09-09 Vitalis Bernard COMPOSITION FOR CLEANING THE AERAULIC NETWORK, CONTROLLED MECHANICAL VENTILATION INSTALLATIONS AND SIMILAR INSTALLATIONS
US5082585A (en) * 1989-02-02 1992-01-21 Lever Brothers Company, Division Of Conopco, Inc. Enzymatic liquid detergent compositions containing nonionic copolymeric stabilizing agents for included lipolytic enzymes
US4908150A (en) * 1989-02-02 1990-03-13 Lever Brothers Company Stabilized lipolytic enzyme-containing liquid detergent composition
US5196133A (en) * 1989-10-31 1993-03-23 The Procter & Gamble Company Granular detergent compositions containing peroxyacid bleach and sulfobenzoyl end-capped ester oligomers useful as soil-release agents
US5256168A (en) * 1989-10-31 1993-10-26 The Procter & Gamble Company Sulfobenzoyl end-capped ester oligomers useful as soil release agents in granular detergent compositions
US5182043A (en) * 1989-10-31 1993-01-26 The Procter & Gamble Company Sulfobenzoyl end-capped ester oligomers useful as soil release agents in granular detergent compositions
ES2111628T3 (en) * 1992-06-29 1998-03-16 Procter & Gamble CONCENTRATED AQUEOUS LIQUID DETERGENT COMPOSITIONS INCLUDING POLYVINYLPYROLIDONE AND A TEREFTALATE BASED DIRT RELEASE POLYMER.
US5597795A (en) * 1992-10-27 1997-01-28 The Procter & Gamble Company Detergent compositions inhibiting dye transfer
DK0594893T3 (en) * 1992-10-27 1998-03-02 Procter & Gamble Color transfer inhibiting detergent compositions
PT629690E (en) * 1993-06-09 2000-04-28 Procter & Gamble AQUEOUS EMULSES STABLE OF NON-IONIC TENSIOACTIVE AGENTS
DE4402852C1 (en) * 1994-01-31 1995-02-16 Henkel Kgaa Detergent mixtures and the use thereof
US5500153A (en) * 1994-07-05 1996-03-19 The Procter & Gamble Company Handwash laundry detergent composition having improved mildness and cleaning performance
DE4440956A1 (en) * 1994-11-17 1996-05-23 Henkel Kgaa Dirt-repellent detergent with a specific combination of surfactants
GB9524488D0 (en) * 1995-11-30 1996-01-31 Unilever Plc Detergent compositions containing soil release polymers
EP0776965A3 (en) 1995-11-30 1999-02-03 Unilever N.V. Polymer compositions
ZA974226B (en) * 1996-05-17 1998-12-28 Procter & Gamble Detergent composition
MA25183A1 (en) * 1996-05-17 2001-07-02 Arthur Jacques Kami Christiaan DETERGENT COMPOSITIONS
ES2176708T3 (en) * 1996-10-18 2002-12-01 Procter & Gamble DETERGENT COMPOSITIONS.
AR010265A1 (en) * 1996-11-01 2000-06-07 Procter & Gamble DETERGENT COMPOSITIONS FOR HAND WASHING INCLUDING A COMBINATION OF SURFACTANTS AND DIRT RELEASE POLYMER
US6462014B1 (en) 2001-04-09 2002-10-08 Akzo Nobel N.V. Low foaming/defoaming compositions containing alkoxylated quaternary ammonium compounds
US20030228991A1 (en) * 2002-05-31 2003-12-11 Johnson Andress Kirsty Premix compositions suitable for the preparation of aqueous or semi-aqueous cleaning and degreasing formulations with low VOCs.
HUE025312T2 (en) 2010-04-01 2016-02-29 Unilever Nv Structuring detergent liquids with hydrogenated castor oil
WO2012104158A1 (en) 2011-01-31 2012-08-09 Unilever Plc Soil release polymers
EP2670787B1 (en) 2011-01-31 2015-08-05 Unilever PLC Soil release polymers
EP2495300A1 (en) 2011-03-04 2012-09-05 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Structuring detergent liquids with hydrogenated castor oil
ES2421162T3 (en) 2011-04-04 2013-08-29 Unilever Nv Fabric washing procedure
CN104011192B (en) * 2011-12-20 2017-08-25 荷兰联合利华有限公司 Isotropic liquid detergent comprising soil release polymer
WO2013139702A1 (en) 2012-03-21 2013-09-26 Unilever Plc Laundry detergent particles
ES2788101T3 (en) 2014-11-11 2020-10-20 Clariant Int Ltd Laundry detergents containing polymers that facilitate the loosening of dirt
WO2016075179A1 (en) 2014-11-11 2016-05-19 Clariant International Ltd Laundry detergents containing soil release polymers
WO2016155993A1 (en) 2015-04-02 2016-10-06 Unilever Plc Composition
WO2017133879A1 (en) 2016-02-04 2017-08-10 Unilever Plc Detergent liquid
US20190136162A1 (en) 2016-06-09 2019-05-09 Conopco, Inc., D/B/A Unilever Laundry products
BR112018075521B1 (en) 2016-06-09 2022-11-08 Unilever Ip Holdings B.V COMBINATION OF TANKS PROVIDING MULTID AND SEGREGATED STOCKS OF COMPONENTS FOR WASHING PRODUCTS
WO2018127390A1 (en) 2017-01-06 2018-07-12 Unilever N.V. Stain removing composition
CN110998014A (en) 2017-06-09 2020-04-10 荷兰联合利华有限公司 Laundry detergent dispensing system
WO2019038187A1 (en) 2017-08-24 2019-02-28 Unilever Plc Improvements relating to fabric cleaning
WO2019038186A1 (en) 2017-08-24 2019-02-28 Unilever Plc Improvements relating to fabric cleaning
US20200283699A1 (en) 2017-09-29 2020-09-10 Conopco, Inc., D/B/A Unilever Laundry products
TR202005218U5 (en) 2017-10-05 2020-08-21 Unilever Nv Laundry products.
EP3489340A1 (en) 2017-11-28 2019-05-29 Clariant International Ltd Renewably sourced soil release polyesters
EP3489338A1 (en) 2017-11-28 2019-05-29 Clariant International Ltd Detergent compositions containing renewably sourced soil release polyesters
WO2019224030A1 (en) 2018-05-24 2019-11-28 Clariant International Ltd Soil release polyesters for use in detergent compositions
EP4153710A1 (en) 2020-05-20 2023-03-29 Clariant International Ltd Soil release polyesters for use in detergent compositions
WO2024126303A1 (en) 2022-12-12 2024-06-20 Clariant International Ltd Polyesters

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4125370A (en) * 1976-06-24 1978-11-14 The Procter & Gamble Company Laundry method imparting soil release properties to laundered fabrics
EP0001305A1 (en) * 1977-09-23 1979-04-04 THE PROCTER & GAMBLE COMPANY Anionic surfactant-containing detergent compositions having soil-release properties
EP0185427B1 (en) * 1984-12-21 1992-03-04 The Procter & Gamble Company Block polyesters and like compounds useful as soil release agents in detergent compositions

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4713194A (en) * 1986-04-15 1987-12-15 The Procter & Gamble Company Block polyester and like compounds having branched hydrophilic capping groups useful as soil release agents in detergent compositions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4125370A (en) * 1976-06-24 1978-11-14 The Procter & Gamble Company Laundry method imparting soil release properties to laundered fabrics
EP0001305A1 (en) * 1977-09-23 1979-04-04 THE PROCTER & GAMBLE COMPANY Anionic surfactant-containing detergent compositions having soil-release properties
EP0185427B1 (en) * 1984-12-21 1992-03-04 The Procter & Gamble Company Block polyesters and like compounds useful as soil release agents in detergent compositions

Also Published As

Publication number Publication date
DE3689385D1 (en) 1994-01-27
EP0199403B1 (en) 1993-12-15
AU5612086A (en) 1986-10-23
EP0199403A2 (en) 1986-10-29
DE3689385T2 (en) 1994-05-19
AU601679B2 (en) 1990-09-20
ATE98674T1 (en) 1994-01-15

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