EP0199399A3 - Improved hydroconversion catalyst and process - Google Patents

Improved hydroconversion catalyst and process Download PDF

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Publication number
EP0199399A3
EP0199399A3 EP86200542A EP86200542A EP0199399A3 EP 0199399 A3 EP0199399 A3 EP 0199399A3 EP 86200542 A EP86200542 A EP 86200542A EP 86200542 A EP86200542 A EP 86200542A EP 0199399 A3 EP0199399 A3 EP 0199399A3
Authority
EP
European Patent Office
Prior art keywords
hydroconversion catalyst
improved hydroconversion
improved
catalyst
hydroconversion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86200542A
Other versions
EP0199399A2 (en
EP0199399B1 (en
Inventor
David Hamilton, Jr.
Charles Terrell Adams
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of EP0199399A2 publication Critical patent/EP0199399A2/en
Publication of EP0199399A3 publication Critical patent/EP0199399A3/en
Application granted granted Critical
Publication of EP0199399B1 publication Critical patent/EP0199399B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
EP86200542A 1985-04-24 1986-04-01 Improved hydroconversion catalyst and process Expired - Lifetime EP0199399B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US72685285A 1985-04-24 1985-04-24
US726852 1985-04-24

Publications (3)

Publication Number Publication Date
EP0199399A2 EP0199399A2 (en) 1986-10-29
EP0199399A3 true EP0199399A3 (en) 1988-08-24
EP0199399B1 EP0199399B1 (en) 1990-08-22

Family

ID=24920278

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86200542A Expired - Lifetime EP0199399B1 (en) 1985-04-24 1986-04-01 Improved hydroconversion catalyst and process

Country Status (4)

Country Link
EP (1) EP0199399B1 (en)
JP (1) JPS61254253A (en)
CA (1) CA1261814A (en)
DE (1) DE3673548D1 (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9010075D0 (en) * 1990-05-04 1990-06-27 Shell Int Research Process for the preparation of alumina based extrudates
JPH0860165A (en) 1994-08-24 1996-03-05 Idemitsu Kosan Co Ltd Fuel oil composition and production thereof
EP0790073A4 (en) * 1994-11-04 1999-05-12 Deqing Chemical Industry And T TITANIA (TiO 2) SUPPORT AND PROCESS FOR ITS PREPARATION AND USE THE SAME
CN1043359C (en) * 1994-11-25 1999-05-12 中国石化齐鲁石油化工公司 Hydrocarbon hydrodesulfurization catalyst and preparation method thereof
MXPA98005494A (en) * 1998-07-07 2002-07-30 Mexicano Inst Petrol Process for a catalyst preparation for hydrodenitrogenation, hydrodesulphurization and hidrodemetallized of intermediate and heavy fractions of petroleum and resulting product.
CN1094072C (en) * 1999-04-30 2002-11-13 北京海顺德钛催化剂有限公司 Hydrodesulphurization method of gas containing hydrocarbon, and catalyst and its application
DK1145763T3 (en) * 1999-10-27 2012-10-08 Idemitsu Kosan Co Hydrogenation catalyst for hydrocarbon oil, carrier thereof and process for hydrogenation of hydrocarbon oil
US10941353B2 (en) 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
JP5318410B2 (en) 2004-04-28 2013-10-16 ヘッドウォーターズ ヘビー オイル リミテッド ライアビリティ カンパニー Boiling bed hydroprocessing method and system and method for upgrading an existing boiling bed system
US7670984B2 (en) 2006-01-06 2010-03-02 Headwaters Technology Innovation, Llc Hydrocarbon-soluble molybdenum catalyst precursors and methods for making same
US8034232B2 (en) 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US8142645B2 (en) 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US7951745B2 (en) 2008-01-03 2011-05-31 Wilmington Trust Fsb Catalyst for hydrocracking hydrocarbons containing polynuclear aromatic compounds
US8097149B2 (en) 2008-06-17 2012-01-17 Headwaters Technology Innovation, Llc Catalyst and method for hydrodesulfurization of hydrocarbons
JP5599212B2 (en) * 2010-03-30 2014-10-01 千代田化工建設株式会社 Hydrocarbon oil hydrotreating catalyst, method for producing the same, and hydrotreating method for hydrocarbon oil using the same
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
CN103055946B (en) * 2011-10-21 2015-04-15 中国石油化工股份有限公司 Synthesis method of mesoporous TiO2-Al2O3 composite carrier
US9403153B2 (en) 2012-03-26 2016-08-02 Headwaters Heavy Oil, Llc Highly stable hydrocarbon-soluble molybdenum catalyst precursors and methods for making same
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
CN104971706B (en) * 2014-04-09 2017-09-29 中国石油化工股份有限公司 A kind of method and its application for preparing titanium oxide alumina compound
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
US11118119B2 (en) 2017-03-02 2021-09-14 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with less fouling sediment
CA3069261C (en) * 2017-07-21 2022-12-06 Albemarle Europe Srl Hydrotreating catalyst with a titanium containing carrier and sulfur containing organic additive
SG11202000461XA (en) * 2017-07-21 2020-02-27 Albemarle Europe Srl Hydrotreating catalyst with a titanium containing carrier and organic additive
CA3057131C (en) 2018-10-17 2024-04-23 Hydrocarbon Technology And Innovation, Llc Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms
CZ308889B6 (en) * 2020-08-27 2021-08-04 ORLEN UniCRE a.s. Process for producing a sulphur-free catalyst for hydrorefining petroleum fractions and their mixtures with vegetable oils

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4018714A (en) * 1975-12-03 1977-04-19 Filtrol Corporation Hydrodesulfurization catalyst and process for producing the same
US4382854A (en) * 1978-02-03 1983-05-10 Kaiser Aluminum & Chemical Corporation Ni/Co Mo P on titania-alumina hydrodesulfurizing catalyst and process of hydrodesulfurizing using the same
US4440631A (en) * 1982-06-15 1984-04-03 Chiyoda Chemical Engineering & Construction Co., Ltd. Process for hydrocracking heavy hydrocarbon oils and catalyst therefor
US4465790A (en) * 1983-03-17 1984-08-14 American Cyanamid Company Hydrotreating catalyst

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4932436A (en) * 1972-07-21 1974-03-25
JPS5921657B2 (en) * 1977-07-15 1984-05-21 フイルトロ−ル・コ−ポレイシヨン Hydrogen desulfurization catalyst containing anatase and its manufacturing method
JPS5927615B2 (en) * 1977-12-13 1984-07-06 千代田化工建設株式会社 Hydrorefining catalyst
JPS54104495A (en) * 1978-02-03 1979-08-16 Filtrol Corp Hydrogenating desulfurization catalyst containing anatase
JPS54104494A (en) * 1978-02-03 1979-08-16 Filtrol Corp Manufacture of alumina pellet
JPS5821532B2 (en) * 1979-06-07 1983-04-30 フイルトロ−ル・コ−ポレイシヨン Hydrodesulfurization catalyst and its manufacturing method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4018714A (en) * 1975-12-03 1977-04-19 Filtrol Corporation Hydrodesulfurization catalyst and process for producing the same
US4382854A (en) * 1978-02-03 1983-05-10 Kaiser Aluminum & Chemical Corporation Ni/Co Mo P on titania-alumina hydrodesulfurizing catalyst and process of hydrodesulfurizing using the same
US4440631A (en) * 1982-06-15 1984-04-03 Chiyoda Chemical Engineering & Construction Co., Ltd. Process for hydrocracking heavy hydrocarbon oils and catalyst therefor
US4465790A (en) * 1983-03-17 1984-08-14 American Cyanamid Company Hydrotreating catalyst

Also Published As

Publication number Publication date
EP0199399A2 (en) 1986-10-29
JPS61254253A (en) 1986-11-12
DE3673548D1 (en) 1990-09-27
EP0199399B1 (en) 1990-08-22
CA1261814A (en) 1989-09-26

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