Classifications

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  • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
  • C10L1/00—Liquid carbonaceous fuels
  • C10L1/10—Liquid carbonaceous fuels containing additives
  • C10L1/14—Organic compounds
  • C10L1/22—Organic compounds containing nitrogen
  • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
  • C10L1/224—Amides; Imides carboxylic acid amides, imides
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  • C10L1/00—Liquid carbonaceous fuels
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  • C10L1/234—Macromolecular compounds
  • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
  • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
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  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
  • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
  • C10M133/16—Amides; Imides
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  • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
  • C10M133/56—Amides; Imides
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
  • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/086—Imides
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/22—Heterocyclic nitrogen compounds
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  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/22—Heterocyclic nitrogen compounds
  • C10M2215/221—Six-membered rings containing nitrogen and carbon only
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/22—Heterocyclic nitrogen compounds
  • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/22—Heterocyclic nitrogen compounds
  • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
  • C10M2215/226—Morpholines
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  • C10M2215/26—Amines
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  • C10M2215/28—Amides; Imides
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  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/30—Heterocyclic compounds
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  • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
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  • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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  • C10N2040/00—Specified use or application for which the lubricating composition is intended
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  • C10N2040/00—Specified use or application for which the lubricating composition is intended
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  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/25—Internal-combustion engines
  • C10N2040/255—Gasoline engines
  • C10N2040/28—Rotary engines

Definitions

• This invention relates to additives which are useful as dispersant and/or detergents in lubricating oils and in hydrocarbon fuels.
• Alkenyl or alkyl succinimides have previously been modified with alkylene oxides to produce poly(oxyalkylene)hydroxy derivatives thereof. These alkylene oxide treated succinimides are taught as additives for lubricating oils (see U.S. 3,373,111 and 3,367,943).
• U.S. Patent No. 2,991,162 discloses carburetor detergent additives for gasoline obtained by reacting an N-alkyl propylene diamine with ethylene carbonate to produce a two-component detergent additive consisting of a carbamate and a urea compound.
• U.S. Patent No. 3,652,240 discloses carburetor detergent additives for hydrocarbonaceous fuel which are carbamates formed by the reaction of an amino-amide with ethylene carbonate.
• U.S. Patent Nos. 4,501,597 and 4,460,381 disclose that the reaction product of oxalic acid with a mono- or bis-succinimide is useful as a fuel stabilizer and as a carburetor detergent.
• U.S. Patent No. 4,482,464 discloses succinimides which have been modified by treatment with a hydroxyalkylene carboxylic acid selected from glycolic acid, lactic acid, 2-hydroxymethyl propionic acid and 2,2'-bis-hydroxy- methylpropionic acid. These modified succinimides of U.S. 4,482,464 are disclosed as lubricating oil additives.
• 4,490,154 discloses fuels containing an alkenylsuccinyl polyglycolcarbonate ester as a deposit control additive.
• U.S. Patent No. 3,216,936 discloses a product prepared from an aliphatic amine, a polymer substituted succinic acid and an aliphatic monocarboxylic acid.
• U.S. Patent No. 4,191,537 discloses hydrocarbyl capped poly(oxyalkylene) polyamino carbamates useful as dispersants and detergents or fuels and lubricating oils.
• polyamino alkenyl or alkyl succinimides may be modified to yield a polyamino alkenyl or alkyl succinimide wherein one or more of the basic nitrogens of the polyamino moiety is substituted by a substituent represented by the general formula: wherein R 4 is hydrocarbyl of from 1 to 30 carbon atoms; R 5 is hydrocarbyl of from 2 to 30 carbon atoms or -R 6 ( ⁇ OR 6 ) ⁇ p wherein R 6 is alkylene of from 2 to 5 carbon atoms and p is an integer from 1 to 100; and m is 0 or 1.
• a lubricating oil composition comprising an oil of lubricating viscosity and a modified polyamino alkenyl or alkyl succinimide in an amount sufficient to provide dispersancy and/or detergency.
• a fuel composition comprising a hydrocarbon boiling in a gasoline or diesel range and a modified polyamino alkenyl or alkyl succinimide in an amount sufficient to provide dispersancy and/or detergency.
• R 4 is hydrocarbyl of from 2 to 20 carbon atoms while R 5 is preferably a straight- or branched-chain alkylene group of from 2 to 30 carbon atoms optionally substituted by aryl of from 6 to 10 carbon atoms or alkaryl of from 7 to 12 carbon atoms. Most preferably, R 5 is an unsubstituted straight- or branched-chain alkylene group of from 2 to 30 carbon atoms.
• p is an integer from 1 to 50; more preferably p is an integer from 2 to 30 and most preferably p is an integer from 2 to 20 while R 6 is preferably a C 2 -C 4 alkylene group and most preferably C 3 or C 4 .
• the alkenyl or alkyl group of the succinimide has from 10 to 300 carbon atoms. While the modified succinimides of this invention possess good detergency properties even for alkenyl or alkyl groups of less than 20 carbon atoms, dispersancy is enhanced when the alkenyl or alkyl group has at least 20 carbon atoms. Accordingly, in a preferred embodiment, the alkenyl or alkyl group of the succinimide has at least 20 carbon atoms (i.e. the alkenyl or alkyl group has from 20 to 300 carbon atoms), more preferably 20 to 100 carbon atoms.
• Hydrocarbyl denotes an organic radical composed of carbon and hydrogen which may be aliphatic, aromatic or combinations thereof, e.g. aralkyl, alkaryl.
• Suitable hydrocarbyls are alkyls such as ethyl, propyl, etc.; alkenyls such as propenyl, isobutenyl, etc.; aralkyl such as benzyl, etc.; alkaryl such as dodecylphenyl (C 12 H 25 -C 6 H 4 -), etc.; and aryls such as phenyl, napthyl, etc.
• a straight- or branched-chain alkylene group of from 2 to 30 carbon atoms refers to straight-chain alkylene groups such as 1,2-ethylene; 1,3-propylene, 1,5-pentylene, 1,20-eicosylene, l-30,tricontylene; etc., and branched-chain alkylene groups such as l,2-propylene; 1,3-butylene; 1,2-(2-methyl)pentylene; 1,2-(2-ethyl)hexylene; 1,10-eicosylene; etc.
• a straight- or branched-chain alkylene group of from 2 to 30 carbon atoms substituted with aryl of from 6 to 10 carbon atoms or alkaryl of from 7 to 12 carbon atoms refers to the above-described straight- or branched-chain alkylene groups substituted with an aryl or an alkaryl group.
• Suitable aryls include phenyl, napthyl, etc.
• Suitable alkaryls include benzyl, etc.
• the modified polyamino alkenyl or alkyl succinimides of this invention may be prepared from a polyamino alkenyl or alkyl succinimide.
• these materials Eybe prepared by reacting an alkenyl or alkyl succinic anhydride with a polyamine as shown below: wherein R is an alkenyl or alkyl group of from 10 to 300 carbon atoms; and R 1 is the remainder of the polyamino moiety.
• succinimide alkenyl or alkyl succinimides that can be used herein are disclosed in numerous references and are well known in the art. Certain fundamental types of succinimides and related materials encompassed by the term of art "succinimide” are taught in U.S. Patent Nos. 2,992,708; 3,018,291; 3,024,237; 3,100,673; 3,219,666; 3,172,892; and 3,272,746. "succinimide” is understood in the art to include many of the amide, imide and amidine species which are also formed by this reaction.
• succinimide The predominant product however is succinimide and this term has been generally accepted as meaning the product of a reaction of an alkenyl substituted succinic acid or anhydride with a polyamine as shown in reaction (1) above. As used herein, included within this term are the alkenyl or alkyl mono-, bis-succinimides and other higher analogs.
• the preparation of the alkenyl-substituted succinic anhydride by reaction with a polyolefin and maleic anhydride has been described, e.g., U.S. Patents Nos. 3,018,250 and 3,024,195.
• Such methods include the thermal reaction of the polyolefin with maleic anhydride and the reaction of a halogenated polyolefin, such as a chlorinated polyolefin, with maleic anhydride.
• Reduction of the alkenyl-substituted succinic anhydride yields the corresponding alkyl derivative.
• the alkenyl substituted succinic anhydride may be prepared as described in U.S. Patents Nos. 4,388,471 and 4,450,281.
• Polyolefin polymers for reaction with the maleic anhydride are polymers comprising a major amount of C 2 to C 5 mono-olefin, e.g., ethylene, propylene, butylene, isobutylene and pentene.
• the polymers can be homopolymers such as polyisobutylene as well as copolymers of 2 or more such olefins such as copolymers of: ethylene and propylene, butylene, and isobutylene, etc.
• copolymers include those in which a minor amount of the copolymer monomers, e.g., 1 to 20 mole percent is a C 4 to c 8 nonconjugated diolefin, e.g., a copolymer of isobutylene and butadiene or a copolymer of ethylene, propylene and 1,4-hexadiene, etc.
• a minor amount of the copolymer monomers e.g., 1 to 20 mole percent is a C 4 to c 8 nonconjugated diolefin, e.g., a copolymer of isobutylene and butadiene or a copolymer of ethylene, propylene and 1,4-hexadiene, etc.
• the polyolefin polymer represented in Figure 1 as R, usually contains from about 10 to 300 carbon atoms, although preferably 20 to 300 carbon atoms. Other preferred embodiments include 12 to 100 carbon atoms and more preferably 20 to 100 carbon atoms.
• a particularly preferred class of olefin polymers comprises the polybutenes, which are prepared by polymerization of one or more of 1-butene, 2-butene and isobutene. Especially desirable are polybutenes containing a substantial proportion of units derived from isobutene.
• the polybutene may contain minor amounts of butadiene which may or may not be incorporated in the polymer. Most often the isobutene units constitute 80%, preferably at least 90%, of the units in the polymer.
• These polybutenes are readily available commercial materials well known to those skilled in the art. Disclosures thereof will be found, for example, in U.S. Patents Nos. 3,215,707; 3,231,587; 3,515,669: and 3,579,450, as well as U.S. Patent No. 3,912,764.
• alkylating hydrocarbons may likewise be used with maleic anhydride to produce alkenyl succinic anhydride.
• suitable alkylating hydrocarbons include cyclic, linear, branched and internal or alpha olefins with molecular weights in the range 100-4,500 or more with molecular weights in the range of 200-2,000 being more preferred.
• alpha olefins obtained from the thermal cracking of paraffin wax. Generally, these olefins range from 5-20 carbon atoms in length.
• Another source of alpha olefins is the ethylene growth process which gives even number carbon olefins.
• Another source of olefins is by the dimerization of alpha olefins over an appropriate catalyst such as the well known Ziegler catalyst. Internal olefins are easily obtained by the isomerization of alpha olefins over a suitable catalyst such as silica.
• the polyamine employed to prepare the polyamino alkenyl or alkyl succinimides is preferably a polyamine having from 2 to 12 amine nitrogen atoms and from 2 to 40 carbon atoms.
• the polyamine is reacted with an alkenyl or alkyl succinic anhydride to produce the polyamino alkenyl or alkyl succinimide, employed in this invention.
• the polyamine is so selected so as to provide at least one basic amine per succinimide.
• the polyamine preferably has a carbon-to-nitrogen ratio of from 1:1 to 10:1.
• At least one of the basic amine nitrogens of the polyamine moiety must be either a primary or secondary amine.
• the polyamino portion of the polyamino alkenyl or alkyl succinimide may be substituted with substituents selected from (A) hydrogen, (B) hydrocarbyl groups of from 1 to about 10 carbon atoms, (C) acyl groups of from 2 to about 10 carbon atoms, and (D) monoketo, monohydroxy, mononitro, monocyano, lower alkyl and lower alkoxy-derivatives of (B) and (C).
• “Lower”, as used in terms like lower alkyl or lower alkoxy, means a group containing from 1 to about 6 carbon atoms.
• Hydrocarbyl denotes an organic radical composed of carbon and hydrogen which may be aliphatic, alicyclic, aromatic or combinations thereof, e.g., aralkyl.
• the hydrocarbyl group will be relatively free of aliphatic unsaturation, i.e., ethylenic and acetylenic, particularly acetylenic unsaturation.
• the substituted polyamines of the present invention are generally, but not necessarily, N-substituted polyamines.
• hydrocarbyl groups and substituted hydrocarbyl groups include alkyls such as methyl, ethyl, propyl, butyl, isobutyl, pentyl, hexyl, octyl, etc., alkenyls such as propenyl, isobutenyl, hexenyl, octenyl, etc., keto- alkyls, such as 2-ketopropyl, 6-ketooctyl, etc., alkoxy and lower alkenoxy alkyls, such as ethoxyethyl, ethoxypropyl, propoxyethyl, propoxypropyl, 2-(2- ethoxyethoxy)ethyl, 2-[2-(2-ethoxyethoxy)ethoxy]ethyl, 3,6,9,12-tetraoxatetradecyl, 2-(2-ethoxyethoxy)hexyl, etc.
• alkyls such as methyl
• the acyl groups of the aforementioned (C) substituents are such as propionyl, acetyl, etc.
• the more preferred substituents are hydrogen, C 1 -C 6 alkyls, and C 1 -C 6 hydroxyalkyl.
• substituted polyamine the substituents are found at any atom capable of receiving them.
• the substituted atoms e.g., substituted nitrogen atoms, are generally geometrically inequivalent, and consequently the substituted amines finding use in the present invention can be mixtures of mono- and polysubstituted polyamines with substituent groups situated at equivalent and/or inequivalent atoms.
• the more preferred polyamine finding use within the scope of the present invention is a polyalkylene polyamine, including alkylene diamine, and including substituted polyamines, e.g., alkyl substituted polyalkylene polyamine.
• the alkylene group contains from 2 to 6 carbon atoms, there being preferably from 2 to 3 carbon atoms between the nitrogen atoms.
• Such groups are exemplified by ethylene, 1,2-propylene, 2,2-dimethylpropylene, trimethylene, etc.
• polyamines examples include ethylene diamine, diethylene triamine, di(trimethylene)triamine, dipropylene triamine, triethylene tetramine, tripropylene tetramine, tetraethylene pentamine, and pentaethylene hexamine.
• amines encompass isomers such as branched-chain polyamines and the previously mentioned substituted polyamines, including hydrocarbyl-substitutedtpolyamines.
• polyalkylene polyamines those containing 2-12 amine nitrogen atoms and 2-24 carbon atoms are especially preferred, and the C 2 -c 5 alkylene polyamines are most preferred, in particular, the lower polyalkylene polyamines, e.g., ethylene diamine, dipropylene triamine, etc.
• the polyamine component also may contain heterocyclic polyamines, heterocyclic substituted amines and substituted heterocyclic compounds, wherein the heterocycle comprises one or more 5-6 membered rings containing oxygen and/or nitrogen.
• heterocycles may be saturated or unsaturated and substituted with groups selected from the aforementioned (A), (B), (C) and (D).
• the heterocycles are exemplified by piperazines, such as 2-methylpiperazine, 1,2-bis-(N-piperazinyl)ethane, and N,N'-bis(N-piperazinyl)piperazine, 2-methylimidazoline, 3-aminopiperidine, 2-aminopyridine, 2-(3-aminoethyl)-3-pyrroline, 3-aminopyrrolidine, N-(3-aminopropyl)-morpholine, etc.
• the piperazines are preferred.
• Typical polyamines that can be used to form the compounds of this invention include the following: ethylene diamine, 1,2-propylene diamine, 1,3-propylene diamine, diethylene triamine, triethylene tetramine, hexamethylene diamine, tetraethylene pentamine, methylamino- propylene diamine, N-(betaaminoethyl)piperazine, N,N'- di(betaaminoethyl)piperazine, N,N'-di(beta-aminoethyl)-imidazolidone-2, N-(beta-cyanoethyl)ethane-l,2-diamine, 1,3,6,9-tetraaminooctadecane, 1,3,6-triamino-9-oxadecane, N-methyl-l,2-propanediamine, 2-(2-aminoethylamino)-ethanol.
• propyleneamines bisaminopropylethylenediamines
• Propyleneamines are prepared by the reaction of acrylonitrile with an ethyleneamine, for example, an ethyleneamine having the formula H 2 N(CH 2 CH 2 NH) Z H wherein Z is an integer from 1 to 5, followed by hydrogenation of the resultant intermediate.
• the product prepared from ethylene diamine and acrylonitrile would be H 2 N(CH 2 ) 3 NH(C H 2 ) 2 NH ( CH 2 ) 3 NH 2 .
• the polyamine used as a reactant in the production of succinimides of the present invention is not a single compound but a mixture in which one or several compounds predominate with the average composition indicated.
• tetraethylene pentamine prepared by the polymerization of aziridine or the reaction of dichloroethylene and ammonia will have both lower and higher amine members, e.g., triethylene tetramine, substituted piperazines and pentaethylene hexamine, but the composition will be largely tetraethylene pentamine and the empirical formula of the total amine composition will closely approximate that of tetraethylene pentamine.
• polyamino alkenyl or alkyl succinimide refers to both polyamino alkenyl or alkyl mono- and bis-succinimides and to the higher analogs of polyamino alkenyl or alkyl poly succinimides.
• Preparation of the bis- and higher analogs may be accomplished by controlling the molar ratio of the reagents.
• a product comprising predominantly mono- or bis-succinimide can be prepared by controlling the molar ratios of the polyamine and succinic anhydride.
• a particularly preferred class of polyamino alkenyl or alkyl succinimides employed in the instant invention may be represented by Formula II: wherein R is alkenyl or alkyl of from 10 to 300 carbon atoms; R 2 is alkylene of 2 to 10 carbon atoms; R 3 is hydrogen, lower alkyl or lower hydroxy alkyl; a is an integer from 0 to 10; and W is - N H 2 or represents a group of Formula III: wherein R is alkenyl or alkyl of from 10 to 300 carbon atoms; with the proviso that when W is the group of Formula III above, then a is not zero and at least one of R 3 is hydrogen.
• the polyamine employed in preparing the succinimide is often a mixture of different compounds having an average composition indicated as the Formula II. Accordingly, in Formula II each value of R 2 and R 3 may be the same as or different from other R 2 and R 3 .
• R is alkenyl or alkyl of from 20 to 300 carbon atoms. In another preferred embodiment, R is preferably 12 to 100 carbon atoms and more preferably 20 to 100 carbon atoms.
• R 2 is alkylene of 2 to 6 carbon atoms and most preferably is either ethylene or propylene.
• R 3 is hydrogen or lower alkyl.
• a is an integer from 1 to 6.
• polyamino alkenyl or alkyl succinimides may be conveniently viewed as being composed of three moieties that is the alkenyl or alkyl moiety R, the succinimide moiety represented by the formula: and the polyamino moiety represented by the group
• the preferred alkylene polyamines employed in this reaction are generally represented by the formula: wherein R 2 is an alkylene moiety of 2 to 10 carbon atoms and a is an integer from about 0 to 10.
• R 2 is an alkylene moiety of 2 to 10 carbon atoms and a is an integer from about 0 to 10.
• the preparation of these alkylene polyamines do not produce a single compound and cyclic heterocycles, such as piperazine, may be included to some extent in the alkylene diamines.
• the polyamino alkenyl or alkyl succinimides wherein one or more of the nitrogens of the polyamino moiety is substituted with wherein R 4 , R 5 and m are as defined above may be prepared by reacting a polyamino alkenyl or alkyl succinimide, IV, with a chloroformate, V, as shown in reaction (1) below: wherein R 8 and R 7 form the remainder of a polyamino alkenyl or alkyl succinimide and R 4 , R 5 and m are as defined above.
• Reaction (1) is conducted by contacting the chloroformate, V, with the polyamino alkenyl or alkyl succinimide, IV.
• the reaction may be conducted neat or in a suitable inert diluent. Suitable diluents include ethyl acetate, toluene, xylene, oil and the like.
• An organic base such as pyridine, triethylamine and the like may be added to the reaction to scavenge the acid generated.
• the generated acid may also be removed by an alkaline water wash (pH of from 8-9 or higher) or an alkaline brine wash (pH of from 8-9 or higher) of the reaction solution after reaction completion without the need of added base.
• the reaction is generally conducted at from 0"C to 50°C and is generally complete from within 0.5 to 24 hours. Afterwards, the product may be further isolated by conventional techniques such as chromatography, filtration and the like. If the succinimide contains hydroxyalkyl, use of lower temperature (-78°C to 0°C) helps prevent carbonate formation. Carbonates may be removed via reaction with an amine of the succinimide or an alcohol (i.e., ethanol) under transesterification conditions.
• maximum conversion of the reactive amines of the polyamino alkenyl or alkyl succinimide can be obtained by employing a molar charge of chloroformate to the theoretical basic nitrogen of the alkenyl or alkyl succinimide of from 0.7:1 to 1:1. In some cases, a slight excess of chloroformate may be employed to enhance reaction rate.
• the products of this invention are also prepared by reacting a polyaminoalkenyl or alkyl succinimide, IV, with an aryl carbonate as shown in reaction l(a) below: wherein R 4 , R 5 , R 7 , R 8 and m are as defined above and aryl is preferably phenyl or substituted phenyl such as p-nitrophenyl, p-chlorophenyl, etc.
• Reaction (la) is conducted by contacting the aryl carbonate with the polyamino alkenyl or alkyl succinimide, IV.
• the reaction may be conducted neat or in a suitable inert diluent. Suitable diluents include toluene, xylene, thinners, oil, and the like.
• the reaction is generally conducted at from 50°C to 150°C and is generally complete from within 1 to 4 hours. Afterwards, the product may be further isolated by conventional techniques such as stripping, chromatography, filtration, and the like.
• the aryl carbonate is prepared via conventional processes from the aryl alcohol and the chloroformate, V, under conditions known per se.
• the reaction is conducted by adding the alcohol, VII, to a suitable diluent such as toluene, benzene, methylene chloride, and the like. Phosgene or oxalyl chloride is then added to the system over a period of time. Alternatively, the phosgene or oxalyl chloride may be added to the diluent prior to addition of the alcohol. In general, approximately 1.1-2.5 equivalents of phosgene or oxalyl chloride is added per equivalent of alcohol, VII.
• the reaction is conducted at from -78° to 50°C, preferably -10 0 to 10°C, and is generally complete from within 1/2 to 12 hours.
• the chloroformate, V may be isolated by conventional techniques such as distillation but preferably the system is stripped of a portion of the inert diluent which also removes hydrogen chloride gas generated and excess reagent, VIII.
• the product, V, contained in the remaining diluent is then used as is reaction (1) above.
• the term "molar charge of chloroformate to the basic nitrogen of a polyamino alkenyl or alkylsuccinimide” means that the molar charge of chloroformate employed in the reaction is based upon the theoretical number of basic nitrogens contained in the succinimide.
• TETA triethylene tetraamine
• the resulting monosuccinimide will theoretically contain 3 basic nitrogens. Accordingly, a molar charge of 1 would require that a mole of chloroformate be added for each basic nitrogen or in this case 3 moles of chloroformate for each mole of monosuccinimide prepared from TETA.
• the alcohols, VII are either commercially available or may be readily prepared by known processes.
• hydrocarbyl-terminated poly(oxyalkylene) polymers which are utilized in preparing the chloroformates used in the present invention are monohydroxy compounds, i.e., alcohols, often termed monohydroxy polyethers, or polyalkylene glycol monohydrocarbylethers, or "capped" poly(oxyalkylene) glycols and are to be distinguished from the poly(oxyalkylene) glycols (diols), or polyols, which are not hydrocarbyl-terminated, i.e., not capped.
• the hydrocarbyl-terminated poly(oxyalkylene) alcohols are produced by the addition of lower alkylene oxides, such as oxirane, ethylene oxide, propylene oxide, the butylene oxides, or the pentylene oxides to the hydroxy compound R 6 0H under polymerization conditions, wherein R 6 is the hydrocarbyl group which caps the poly(oxyalkylene) chain.
• lower alkylene oxides such as oxirane, ethylene oxide, propylene oxide, the butylene oxides, or the pentylene oxides
• alkylene oxide e.g., propylene oxide
• the product is a homopolymer, e.g., a poly-(oxypropylene) propanol.
• copolymers are equally satisfactory and random copolymers are readily prepared by contacting the hydroxyl-containing compound with a mixture of alkylene oxides, such as a mixture of propylene and butylene oxides.
• Block copolymers of oxyalkylene units also provide satisfactory poly(oxyalkylene) polymers for the practice of the present invention. Random polymers are more easily prepared when the reactivities of the oxides are relatively equal.
• Block copolymers are prepared by contacting the hydroxyl-containing compound with first one alkylene oxide, then the others in any order, or repetitively, under polymerization conditions.
• a particular block copolymer is represented by a polymer prepared by polymerizing propylene oxide on a suitable monohydroxy compound to form a poly(oxypropylene) alcohol and then polymerizing butylene oxide on the poly(oxypropylene) alcohol.
• poly(oxyalkylene) polymers are mixtures of compounds that differ in polymer chain length. However, their properties closely approximate those of the polymer represented by the average composition and molecular weight.
• the hydrocarbylpoly(oxyalkylene) moiety of the chloroformate is composed of oxyalkylene units containing from 2 to about 5 carbon atoms.
• the hydrocarbyl group contains from 1 to about 30 carbon atoms, preferably from 2 to about 20 carbon atoms.
• the oxyalkylene units contain from 3 to 4 carbon atoms and the molecular weight of the hydrocarbyl poly(oxyalkylene) moiety is from about 44 to about 10,000, more preferably from about 100 to about 5,000.
• Each poly(oxyalkylene) polymer contains from 1 to 100 oxyalkylene units, preferably 2 to about 50 oxyalkylene units, more preferably about 2 to 30 units and most preferably 2 to about 20 such units.
• the oxyalkylene units may be branched or unbranched.
• the structures of the C 3 -C S oxyalkylene units are any of the isomeric structures well known to the organic chemist, e.g., n-propylene, -CH 2 CH 2 CH 2 -; isopropylene, -C(CH 3 )CH 2 -; n-butylene, -CH 2 CH 2 CH 2 CH 2 -; sec.-butylene, -CH(CH 2 CH 3 )CH 2 - ⁇ tert.-butylene, -C(CH 3 ) 2 CH 2 -; disec.-butylene, -CH(CH 3 )CH(CH 3 )-; isobutylene, -CH 2 CH(CH 3 )CH 2 -; etc.
• the preferred poly(oxyalkylene) compounds are composed of from 1 to about 50 oxyalkylene units, more preferably about 2 to 30 oxyalkylene units and most preferably 2 to about
• the hydrocarbyl moiety (R-) which terminates the poly(oxyalkylene) chain contains from 1 to about 30 carbon atoms, preferably from 2 to about 20 carbon atoms, and is generally derived from the monohydroxy compound (ROH) which is the initial site of the alkylene oxide addition in the polymerization reaction.
• Such monohydroxy compounds are preferably aliphatic or aromatic alcohols of from 1 to about 30 carbon atoms, more preferably an alkanol or an alkylphenol, and most preferably an alkylphenol wherein the alkyl is a straight or branched chain of from 1 to about 24 carbon atoms.
• One such preferred alkyl group is obtained by polymerizing propylene to an average of 4 units and has the common name of propylene tetramer.
• the preferred material may be termed either an alkylphenylpoly(oxyalkylene) alcohol or a polyalkoxylated alkylphenol.
• hydrocarbyloxyhydrocarbyl alcohols may be prepared from the corresponding glycol by art recognized techniques as shown in reactions (3) - (6) below: wherein R 4 and R s are as defined above and base is an inorganic base such as potassium bicarbonate, sodium carbonate, sodium hydroxide and the like.
• base is an inorganic base such as potassium bicarbonate, sodium carbonate, sodium hydroxide and the like.
• Reaction (3) is a conventional esterification reaction and is conducted by combining the diol, I X , with the acid, X, to yield the monoester XI.
• acetic acid is employed in reaction (3)
• any suitable carboxylic acid such as trichloroacetic acid, propionic acid, benzoic acid, and the like, may be utilized to form the monoester, XI.
• an acid catalyst such as sulfuric, hydrochloric and the like may be employed to enhance the reaction rate.
• an excess of diol, IX is employed. In general, from 1.1 to 4 equivalents of diol, IX, and preferably 2 equivalents per equivalent of acid, X, are employed in reaction (3).
• the reaction may be conducted neat or in a suitable diluent such as toluene, benzene and the like.
• a suitable diluent such as toluene, benzene and the like.
• the water generated during the reaction may be readily removed via a Dean-Stark trap.
• the product ester, XI may be isolated by conventional techniques such as chromatography, filtration and the like or used in reaction (4) without purification.
• Reaction (4) is a conventional reaction of an alcohol with metallic sodium or potassium to form a sodium or potassium salt.
• potassium t-butoxide may be employed in place of metallic sodium or potassium.
• the reaction is generally conducted by adding an equimolar amount of the metallic sodium or potassium to the alcohol which is generally contained in an anhydrous inert diluent such as tetrahydrofuran, dioxane, toluene and the like.
• the reaction is generally conducted at from 0° to 60°C and is generally complete from within 1 to 24 hours.
• the resulting salt, XII is generally employed in reaction (5) without isolation and/or purification.
• Reaction (5) is a metathesis reaction to form the ethers, XIV.
• the reaction is generally conducted by adding an equimolar amounts of the hydrocarbyl chloride, XIII to the sodium (or potassium) salt, XII.
• the reaction is generally conducted in an inert diluent such as toluene, dioxane and the like.
• the reaction is generally conducted at from 0° to 110°C and is generally complete from with 1 to 24 hours.
• the resulting ether-ester, XIV may be isolated by conventional techniques such as chromatography, filtration and the like or used in reaction (6) without purification.
• Reaction (6) is a conventional hydrolysis reaction to form the alcohol-ether, VII.
• the reaction is conducted by adding the ether-ester, XIV, to an aqueous alcohol solvent such as water/methanol, water/ethanol and the like.
• An inorganic base such as sodium carbonate, sodium hydroxide, potassium bicarbonate and the like, is added to the reaction.
• the reaction is generally conducted at from room temperature to about 80°C and is generally complete from within 1 to 24 hours.
• the resulting alcohol-ether, VII may then be isolated by conventional techniques such as chromatography, filtration, distillation and the like.
• the hydrocarbyl chloride, XIII may be prepared from the corresponding alcohol via a chlorinating agent such as thionyl chloride. This reaction is well known and is described by Buehler and Pearson, Survey of Organic Synthesis, Vol. I, pp. 330-332, Wiley & Sons, N.Y. (1978).
• R is alkenyl or alkyl of from 10 to 300 carbon atoms
• R2 is alkylene of from 2 to 10 carbon atoms
• a is an integer from 0 to 10
• R 8 is hydrogen, lower alkyl of from 1 to 6 carbon atoms, lower hydroxyalkyl of from 1 to 6 carbon atoms, or -C(C) m
• OR 4 wherein m is ⁇ 0 or 1, R4 is hydrocarbyl of from 1 to 30 carbon atoms, and R 5 is a straight- or branched-chain alkylene group of from 2 to 30 carbon atoms optionally substituted by aryl of from 6 to 10 carbon atoms or alkaryl of from 7 to 12 carbon atoms, or -R 6 (OR 6 )p-wherein R 6 is alkylene of from 2 to 300 carbon atoms
• R2 is alkylene of from 2 to 10 carbon atoms
• a is an integer from 0 to 10
• R 8 is hydrogen, lower alkyl of from
• R is alkenyl or alkyl of from 20 to 100 carbon atoms.
• R 2 is alkylene of from 2 to 6 carbon atoms; a is an integer from 1 to 6.
• R 4 is hydrocarbyl of from 2 to 20 carbon atoms.
• R 5 is -R 6 (OR 6 ) p -; wherein R 6 is alkylene of 3 or 4 carbon atoms, and p is an integer from 2 to 30.
• the modified succinimides of this invention can be reacted at a temperature sufficient to cause reaction with boric acid or a similar boron compound to form borated dispersants having utility within the scope of this invention.
• boric acid boron acid
• suitable boron compounds include boron oxides, boron halides and esters of boric acid. Generally from about 0.1 equivalents to 10 equivalents of boron compound to the modified succinimide may be employed.
• the modified polyamino alkenyl or alkyl succinimides of this invention are useful as detergent and dispersant additives when employed in lubricating oils.
• the modified polyamino alkenyl or alkyl succinimide additive is usually present in from 0.2 to 10 percent by weight to the total composition and preferably at about 0.5 to 5 percent by weight.
• the lubricating oil used with the additive compositions of this invention may be mineral oil or synthetic oils of lubricating viscosity and preferably suitable for use in the crankcase of an internal combustion engine. Crankcase lubricating oils ordinarily have a viscosity of about 1300 CSt 0°F (-18°C) to 22.7 CSt at 210°F (99°C).
• the lubricating oils may be derived from synthetic or natural sources.
• Mineral oil for use as the base oil in this invention includes paraffinic, naphthenic and other oils that are ordinarily used in lubricating oil compositions.
• Synthetic oils include both hydrocarbon synthetic oils and synthetic esters.
• Useful synthetic hydrocarbon oils include liquid polymers of alpha olefins having the proper viscosity. Especially useful are the hydrogenated liquid oligomers of C 6 to C 12 alpha olefins such as 1-decene trimer.
• alkyl benzenes of proper viscosity such as didodecyl benzene
• useful synthetic esters include the esters of both monocarboxylic acid and polycarboxylic acids as well as monohydroxy alkanols and polyols. Typical examples are didodecyl adipate, pentaerythritol tetracaproate, di-2-ethylhexyl adipate, dilaurylsebacate and the like.
• Complex esters prepared from mixtures of mono and dicarboxylic acid and mono and dihydroxy alkanols can also be used.
• Blends of hydrocarbon oils with synthetic oils are also useful. For example, blends of 10 to 25 weight percent hydrogenated I-decene trimer with 75 to 90 weight percent 150 SUS (100°F,38°C) mineral oil gives an excellent lubricating oil base.
• Additive concentrates are also included within the scope of this invention.
• the concentrates of this invention usually include from about 90 to 10 weight percent of an oil of lubricating viscosity and from about 10 to 90 weight percent of the complex additive of this invention.
• the concentrates typically contain sufficient diluent to make them easy to handle during shipping and storage.
• Suitable diluents for the concentrates include any inert diluent, preferably an oil of lubricating viscosity, so that the concentrate may be readily mixed with lubricating oils to prepare lubricating oil compositions.
• Suitable lubricating oils which can be used as diluents typically have viscosities in the range from about 35 to about 500 Saybolt Universal Seconds (SUS) at 100°F (38°C), although an oil of lubricating viscosity may be used.
• SUS Saybolt Universal Seconds
• additives which may be present in the formulation include rust inhibitors, foam inhibitors, corrosion inhibitors, metal deactivators, pour point depressants, antioxidants, and a variety of other well-known additives.
• modified succinimides of this invention may be employed as dispersants and detergents in hydraulic fluids, marine crankcase lubricants and the like.
• the modified succinimide is added at from about 0.1 to 10 percent by weight to the oil. Preferably, at from 0.5 to 5 weight percent.
• the proper concentration of the additive necessary in order to achieve the desired detergency is dependent upon a variety of factors including the type of fuel used, the presence of other detergents or dispersants or other additives, etc.
• the range of concentration of the additive in the base fuel is 10 to 10,000 weight parts per million, preferably from 30 to 2,000 weight parts per million, and most preferably from 30 to 700 parts per million of the modified succinimide per part of base fuel. If other detergents are present, a lesser amount of the modified succinimide may be used.
• the modified succinimide additives of this invention may be formulated as a fuel concentrate, using an inert stable oleophilic organic solvent boiling in the range of about 150° to 400° F (66 to 204°C).
• an aliphatic or an aromatic hydrocarbon solvent is used, such as benzene, toluene, xylene or higher-boiling aromatics or aromatic thinners.
• Aliphatic alcohols of about 3 to 8 carbon atoms, such as isopropanol, isobutylcarbinol, n-butanol and the like, in combination with hydrocarbon solvents are also suitable for use with the fuel additive.
• the amount of the additive will be ordinarily at least 10 percent by weight and generally not exceed 70 percent by weight and preferably from 10 to 25 weight percent.
• the methylene chloride solution containing the chlorodicarbonyloxy derivative was then added to a composition containing 200 ml methylene chloride, 30 ml triethylamine and 406 g of a succinimide dispersant composition [prepared by reacting 1 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0.87 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil].
• a succinimide dispersant composition prepared by reacting 1 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0.87 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil.
• the methylene chloride solution containing the chloroformate derivative was then added to a composition containing 200 ml methylene chloride, 30 ml triethylamine and 406 g of a succinimide dispersant composition [prepared by reacting 1 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0.87 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil].
• a succinimide dispersant composition prepared by reacting 1 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0.87 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil.
• the methylene chloride solution containing the chlorodicarbonyloxy derivative is then added to a composition containing 200 ml methylene chloride, 30 ml triethylamine and 406 g of a succinimide dispersant composition [prepared by reacting 1 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0.87 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil].
• a succinimide dispersant composition prepared by reacting 1 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0.87 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil.
• the toluene solution containing the chloroformate derivative was then added to a composition containing 300 ml methylene chloride, 90 ml triethylamine and 406 g of a succinimide dispersant composition [prepared by reacting 1 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0.87 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil].
• a succinimide dispersant composition prepared by reacting 1 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0.87 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil.
• the methylene chloride solution containing the chlorodicarbonyloxy derivative is then added to a composition containing 200 ml methylene chloride, 30 ml triethylamine and 406 g of a succinimide dispersant composition [prepared by reacting 1.0 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0. 1 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil].
• a succinimide dispersant composition prepared by reacting 1.0 mole of polyisobutenyl succinic anhydride, where the polyisobutenyl group has a number average molecular weight of about 950, with 0. 1 mole of tetraethylene pentaamine; then diluting to about 35% actives with diluent oil.
• the system was then heated to l65°C and stirred under a nitrogen atmosphere for 2 hours at which time the alkalinity value of the system was 14.5.
• the system was cooled to 80°C and an additional 0.0255 moles (about 7.2 g) of carbonate was added.
• the system was heated to 165°C and stirred under nitrogen for an additional 40 minutes to give a product having an alkalinity value of 13.6 and affording the carbamate of the bissuccinimide.

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