EP0190087B1 - Nicht zu fälschendes Sicherheitspapier, Verfahren zur Fälschungssicherung eines Papiers und wässrige oder organische Zusammensetzung, die insbesondere zur Fälschungssicherung eines Papiers nützlich ist - Google Patents
Nicht zu fälschendes Sicherheitspapier, Verfahren zur Fälschungssicherung eines Papiers und wässrige oder organische Zusammensetzung, die insbesondere zur Fälschungssicherung eines Papiers nützlich ist Download PDFInfo
- Publication number
- EP0190087B1 EP0190087B1 EP86420015A EP86420015A EP0190087B1 EP 0190087 B1 EP0190087 B1 EP 0190087B1 EP 86420015 A EP86420015 A EP 86420015A EP 86420015 A EP86420015 A EP 86420015A EP 0190087 B1 EP0190087 B1 EP 0190087B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- paper
- compound
- formula
- forge
- proof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/46—Elements suited for chemical verification or impeding chemical tampering, e.g. by use of eradicators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/914—Transfer or decalcomania
- Y10S428/915—Fraud or tamper detecting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31993—Of paper
Definitions
- the invention relates to the field of stationery. It relates to a new tamper-proof security paper comprising an aromatic product, a process for rendering a paper to be tamper-proof and an aqueous or organic composition useful, in particular, for rendering a tamper-proof paper.
- French Patent No. 2,365,656 describes a security paper comprising a chemical sensitizing composition based on an indicator of acid-basicity, very sensitive to variations in pH.
- the indicator is chosen, in particular, from the group of phthalein or sulfophthalein.
- the pH rises due to the action of the eraser
- the paper develops a color.
- all of the products described are of delicate papermaking use, mainly because of their solubilization conditions, pH of use or reversibility or stability.
- French Patent No. 2,399,505 and its certificate of addition 2,402,739 describe a security paper comprising a chemical sensitizing composition based on a salt of oxypyrene tricarboxylic acid, called Pyranine.
- Pyranine a salt of oxypyrene tricarboxylic acid
- French patents no. 2 406 027, 2 427 426 and its certificate of addition 2 432 576 describe a security paper comprising dinitrophenols which, under the action of an erasing pencil, are colored in non-fluorescent yellow.
- French Patent No. 2,410,702 describes a security paper comprising a chemical sensitizing composition composed of Pyranin combined with an optical brightener and various other compounds. The action of an erasing felt on such a paper leads to a fluorescent yellow coloring.
- the object of the invention is to provide a compound which, associated with a paper, makes it unforgeable, even with erasers, by instantly developing a color clearly detectable with the naked eye.
- the paper according to the invention is characterized in that it comprises, on its surface and / or in its mass, at least one compound corresponding to the formula:
- the paper can have any fibrous constitution, purely cellulosic or partly synthetic, to which can be added the conventional stationery additives, namely mineral fillers, various resistance agents, binders, resins, shading dyes, neutral bonding products, acid or basic, alumina sulfate for acid bonding or pH adjustment.
- the conventional stationery additives namely mineral fillers, various resistance agents, binders, resins, shading dyes, neutral bonding products, acid or basic, alumina sulfate for acid bonding or pH adjustment.
- N0 2 can be in ortho, meta or para of CH 2 CN.
- the paper will comprise at least 0.0001 g / m 2 of the compound and, advantageously, between 0.01 and 0.15 g / m2.
- the paper can also include sensitizing reagents, similar to those already used currently in security papers, for example products ensuring a modification of the appearance of the paper by contact of the latter with acids, oxidizing reagents.
- sensitizing reagents similar to those already used currently in security papers, for example products ensuring a modification of the appearance of the paper by contact of the latter with acids, oxidizing reagents.
- these products are introduced, either in aqueous solution, in which case it is necessary to ensure their retention on the fibers by direct bonding or by means of fixing agents, or in the microdispersed or pigmented precipitated state. .
- ferric chloride / manganese ferrocyanide couple provides a reaction to attempts at falsification by acids, oxidants and erasers with an acid reaction (of the "corector" type).
- These papers may also contain, in their mass, in the pigmented state, dispersed, one or more dyes insoluble in water but organo-soluble, so as to preserve the writings or statements made on these papers vis-à-vis attempts at falsification using organic solvents.
- these papers can be watermarked or contain various devices intended to ensure recognition, such as fibers, pellets, colored and / or fluorescent particles.
- a first method for making a falsifiable paper consists of incorporating the compound of formula (1) during the manufacture of the paper.
- a second method consists in depositing on one or both sides of a sheet of paper an aqueous composition comprising a compound of formula (1), as defined above, and a coating binder.
- coating binders mention may be made, by way of indication, of synthetic or natural polymers with compatible hydroxy terminations, such as starch, polyvinyl alcohol and cellulose derivatives.
- the category of surfactant selected will depend on the structure of the compound corresponding to formula (I) used. Thus, for the substructure compounds (1), a surfactant from category (B) will advantageously be chosen and, for the substructure compounds (2), a surfactant from group (C) and, among these, the quaternary ammonium compounds.
- chlorine activators such as bleach can be added to this composition.
- a third method consists in depositing on one or both sides of a sheet of paper a composition comprising a compound of formula (1), an organic solvent and a compatible coating binder.
- solvent there may be mentioned esters, ketones, alcohols, essences or aromatics.
- composition designates solutions, that is to say the compositions in which the constituents are in the form of solutes but, also, the dispersions partially or not dissolved.
- compositions can be deposited using a coating technique used in stationery (for example size press, roller systems, blade.
- a subject of the invention is also the compositions as such.
- the coloring obtained with ink erasers and bases is purple-magenta.
- the paper thus treated also reacts with bleach, giving a beige-brown color, with acids and acid-erasing products (of the "corector” type), producing blue, the solvents color differently the paper according to their nature.
- reaction with acids, bleach and acid reaction erasers can be obtained by addition of products usually known in the coating solution or in the bulk.
- the paper thus treated becomes purple-magenta in the presence of bases, reducers or erasable felts, and. as before, in blue with the acids and the acid-erasing products with acid reaction (of the "corector” type), in brown with the bleach and of a variable coloring according to the solvents (according to the dye used).
- a paper support During the manufacture of a paper support, are introduced into the mass, in addition to the reagents previously described as a ferric salt, a precipitate of manganese ferrocyanide and one or more dispersed organosoluble dyes, paranitrophenyl acetonitrile: finely divided, in combination with hexadecyl pyridinium chloride. After formation of the sheet, a reactivity identical to that described in Example 1 is obtained (magenta coloring with erasers, bases and reducers, blue with acids and erasers with acid reaction (of the "corector” type). ), brown with bleach, variable with solvents).
- the paper is white and not fluorescent after facing.
Landscapes
- Paper (AREA)
- Color Printing (AREA)
Claims (15)
dadurch gekennzeichnet, daß es auf der Oberfläche und/oder in der Masse mindestens eine Verbindung der Formel (I) enthält:
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8500939 | 1985-01-21 | ||
FR8500939A FR2576332B1 (fr) | 1985-01-21 | 1985-01-21 | Papier de securite infalsifiable, procede pour rendre infalsifiable un papier et composition aqueuse ou organique utile, notamment, pour rendre un papier infalsifiable |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0190087A1 EP0190087A1 (de) | 1986-08-06 |
EP0190087B1 true EP0190087B1 (de) | 1988-04-06 |
Family
ID=9315534
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86420015A Expired EP0190087B1 (de) | 1985-01-21 | 1986-01-16 | Nicht zu fälschendes Sicherheitspapier, Verfahren zur Fälschungssicherung eines Papiers und wässrige oder organische Zusammensetzung, die insbesondere zur Fälschungssicherung eines Papiers nützlich ist |
Country Status (6)
Country | Link |
---|---|
US (1) | US4725497A (de) |
EP (1) | EP0190087B1 (de) |
CA (1) | CA1276414C (de) |
DE (1) | DE3660121D1 (de) |
FR (1) | FR2576332B1 (de) |
PT (1) | PT81877B (de) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2647820B1 (fr) * | 1989-06-01 | 1991-09-20 | Aussedat Rey | Papier de securite infalsifiable et composition aqueuse ou organique utile, notamment pour rendre un papier infalsifiable |
FR2654445B1 (fr) * | 1989-11-14 | 1995-04-28 | Arjomari Prioux | Papier de securite comportant un nouveau fil de securite reagissant a la falsification. |
US5209515A (en) * | 1991-02-08 | 1993-05-11 | The Standard Register Company | Solvent and/or pressure sensitive security document |
US5718456A (en) * | 1994-01-26 | 1998-02-17 | Michael F. Detwiler, Jr. | Method for verifying authenticity of sales record |
DE19510974A1 (de) * | 1995-03-24 | 1996-09-26 | Drescher Geschaeftsdrucke | Einlagiges Papiererzeugnis |
US6783991B1 (en) | 2002-02-06 | 2004-08-31 | The Standard Register Company | Reversible and reusable authentication system for secure documents |
DE102007006059A1 (de) * | 2007-02-02 | 2008-08-07 | Peter Dr. Schneider | Verfahren zum Schutz von Produkten und Dokumenten auf Thermopapierbasis gegen Manipulation |
FR2970716B1 (fr) | 2011-01-25 | 2013-09-06 | Honnorat Rech S & Services | Papier de securite infalsifiable aux solvants |
FR2978461A1 (fr) * | 2011-07-29 | 2013-02-01 | Arjowiggins Security | Substrat de securite et methode d'authentification et de mise en evidence des tentatives de falsification |
FR2981955B1 (fr) | 2011-10-26 | 2013-11-01 | Honnorat Rech S & Services | Papier de securite infalsifiable aux agents oxydo-reducteurs |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2333979A (en) * | 1941-08-15 | 1943-11-09 | Fox River Paper Corp | Safety paper |
US3162675A (en) * | 1961-09-19 | 1964-12-22 | Dow Chemical Co | Process for making nitroaromatic nitriles |
GB1435686A (en) * | 1972-04-26 | 1976-05-12 | Culter Guard Bridge Holdings L | Coated paper |
FR2406027A1 (fr) * | 1977-10-14 | 1979-05-11 | Voiron Papeteries | Papier reagissant a la falsification par agents chimiques et son procede de fabrication |
JPS54115907A (en) * | 1977-12-02 | 1979-09-08 | Barry Graham Charles | Thin sheet printed with transparent ink* and developer eraser for said ink |
JPH0212197B2 (de) * | 1980-05-30 | 1990-03-19 | Gee Aa Oo G Fuyuuru Automatsuioon Unto Oruganizatsuioon Mbh |
-
1985
- 1985-01-21 FR FR8500939A patent/FR2576332B1/fr not_active Expired
-
1986
- 1986-01-16 DE DE8686420015T patent/DE3660121D1/de not_active Expired
- 1986-01-16 EP EP86420015A patent/EP0190087B1/de not_active Expired
- 1986-01-17 US US06/820,436 patent/US4725497A/en not_active Expired - Lifetime
- 1986-01-20 CA CA000499881A patent/CA1276414C/en not_active Expired - Lifetime
- 1986-01-20 PT PT81877A patent/PT81877B/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE3660121D1 (en) | 1988-05-11 |
PT81877A (fr) | 1986-02-01 |
FR2576332A1 (fr) | 1986-07-25 |
CA1276414C (en) | 1990-11-20 |
FR2576332B1 (fr) | 1987-04-10 |
US4725497A (en) | 1988-02-16 |
EP0190087A1 (de) | 1986-08-06 |
PT81877B (pt) | 1987-11-30 |
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