Classifications

• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
  • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
  • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
  • G03C7/388—Processes for the incorporation in the emulsion of substances liberating photographically active agents or colour-coupling substances; Solvents therefor
  • G03C7/3885—Processes for the incorporation in the emulsion of substances liberating photographically active agents or colour-coupling substances; Solvents therefor characterised by the use of a specific solvent

Definitions

• This invention relates to dispersions of couplers useful in the manufacture of sensitive silver halide colour photographic materials.
• coupler comprises providing the coupler with a water-insoluble 'ballast' group and, before mixing it with the relevant coating composition, dispersing it as a uniform mixture with a water-insoluble high-boiling organic solvent, termed a coupler solvent or an 'oil-former', in an aqueous gelatin solution.
• a surface-active agent is used to facilitate the dispersion process and to help stabilise the dispersion obtained.
• Many photographic coupler dispersions contain compounds with phenolic or naphtholic groups of which the acidity is enhanced by the presence of electron-withdrawing substituents in the ortho and/or para positions relative to the hydroxyl group.
• Well-known compounds of this kind are certain phenolic and naphtholic cyan dye-forming couplers, but couplers for producing dyes of other colours are known which contain such acidic groups. It has been found that the dark stability of dyes formed by colour development of photographic materials containing dispersions of phenolic or naphtholic compounds with enhanced acidity is not as good as is desirable.
• the present invention is based upon the discovery that the adverse effect on dye stability of the phenolic or naphtholic compound can be mitigated to a useful extent by the use of certain lipophilic anionic surfactants in preparing the relevant dispersions. Additional anionic surfactants of more conventional type may be used to aid the dispersion process but non-ionic surfactants have been found to reduce the beneficial effect of the lipophilic surfactant and so are excluded.
• a method of making a photographic coupler dispersion by dispersing a mixture containing the coupler and an oil-former in an aqueous hydrophilic colloid solution in the presence of an anionic surfactant, the coupler and/or the oil-former comprising a phenolic or naphtholic moiety of which the acidity is enhanced by the presence of at least one electron-withdrawing group at a position ortho or para to the phenolic hydroxyl group, wherein there is added at any stage a anionic surfactant which comprises a sulphate or sulphonate group as the sole hydrophilic group and either a single aliphatic hydrocarbon group having at least 15 carbon atoms or two or more aliphatic hydrocarbon groups which together contain at least 17 carbon atoms, but wherein no non-ionic surfactant is used.
• anionic surfactant defined above is referred to below simply as the lipophilic anionic surfactant.
• the present invention concerns coupler dispersions which contain in the oily, dispersed, phase, at least one compound comprising a phenolic or naphtholic moiety, each such compound having at least one electron-withdrawing substituent in a position ortho or para to the phenolic hydroxyl group which enhances the acidity of that group.
• many substituents have an electron-withdrawing effect and the following are listed as examples: wherein R is an alkyl or aryl group, each of R 1 and R is hydrogen or an alkyl or aryl group, R is an aryl or heterocyclic group and M is a cation, any group R, R 1 , R 2 and R 3 possibly being itself substituted with such substituents as alkyl. alkoxy.
• a suitable substituent for the phenolic or naphtholic moiety has a Hammett p-Substituent Constant greater than zero: See, for instance, the article by Exner in the book 'Advances in Linear Free Energy Relationships', edited by Chapman and Shorter, Plenum Press (London) 1972.
• the compound comprising the acidic phenolic, or naphtholic, moiety may be the coupler itself, in which case it may be a suitably substituted member of one of the various classes of cyan dye-forming coupler.
• couplers are described in, for example:
• the compound comprising the acidic phenolic or naphtholic moiety may be a coupler giving, on colour development, a magenta or yellow dye, coupling taking place preferentially at a pyrazolone or active methylene coupling position rather than at a position para to the hydroxyl group of the phenolic or naphtholic moiety. Couplers of this kind are described in, for instance:
• Coupler solvents having acidic phenolic or naphtholic moieties are described in, for instance:
• Coupler solvents Any of the usual coupler solvents may be employed as the oil-former in a dispersion of the invention. Suitable solvents are inert high-boiling liquids or low-melting solids, well-known examples being dibutyl phthalate and tricresyl phosphate. Numerous other coupler solvents are described in UK Patent Speciication 541.589.
• a coupler dispersion of the invention contains an anionic surfactant which comprises, as the sole hydrophilic group, a group of formula -S0 3 M or -OS0 3 M (where M is any convenient cation) and either a single aliphatic hydrocarbon group having at least 15 carbon atoms or two or more aliphatic hydrocarbon groups which together contain at least 17 carbon atoms.
• the aliphatic hydrocarbon group or groups may contain unsaturation and the surfactant molecule may contain such non-hydrophilic features as ether, amide or sulphonamide linkages and ester groups.
• Classes of surfactant having at least some members in accordance with these requirements include:
• Preferred surfactants from these classes are alkane sulphonates (class i) of formula: R 1 SO 3 M and alkylphenol sulphonates (class ix) of formula:
• a mixture of two or more compounds may be used.
• two or more couplers, coupler solvents or lipophilic surfactants may be employed, it being necessary for only one of these compounds to comprise an acidic phenolic or naphtholic moiety.
• the dispersing agent used in a method of the invention may also include a second, and less lipophilic, anionic surfactant.
• a second anionic surfactant may contain a single group -SO 3 M or -OS0 3 M and either a single aliphatic hydrocarbon group having fewer than 15 carbon atoms or two or more aliphatic hydrocarbon groups which together contain fewer than 17 carbon atoms.
• a second anionic surfactant may be of some other class such as a sulphated monoglyceride, a sulphated fat or oil having a free carboxyl group, an a-sulphocarboxylic acid, an aklyl glyceryl ether sulphonate or an N-acylated-amino acid.
• the coupler-coupler solvent solution or mixture is dispersed, with the aid of a surfactant or surfactant mixture, in an aqueous hydrophilic colloid solution.
• the colloid is preferably gelatin or a simple derivative such as phthalated gelatin.
• the dispersion step in a method of the invention may be effected conventionally using any high-speed mixing device.
• a water-miscible or volatile water-immiscible_'auxiliary solvent' may be present, being removed by washing with water from the set dispersion or when volatile, by evaporation under reduced pressure.
• Auxiliary solvents and their use are described in, for example, U.S. Patent 2,801,171.
• the compound comprising a phenolic or naphtholic moiety of enhanced acidity, or mixture of such compounds preferably constitutes at least 5% by weight of the oil phase (i.e. the coupler, water-immiscible solvent and lipophilic anionic surfactant) and the lipophilic anionic surfactant preferably constitutes at least 1% by weight of the oil phase.
• the weight of lipophilic surfactant is usually present at a concentration of from 1 to 100% by weight, the preferred range being 3 to 20%.
• a coupler dispersion made by a method of the invention is employed conventionally in the manufacture of incorporated-coupler silver halidecolour photographic materials, both negative and positive.
• Numerous references to patent specifications and other publications relating to silver halide photographic materials, including colour materials and their processing, are given in Research Disclosure December 1978. Item 17643 (see especially sections VII. XI, XIV and XIX).
• the dispersion is mixed with the appropriate coating composition, usually a gelatino-silver halide photographic emulsion, prior to coating.
• Dispersions of coupler I having the structure were prepared by dissolving the coupler, 0.60g, in di-n-butyl phthalate, 0.60g, and mechanically dispersing the resulting oily solution in 9.4al of 6.6% w/v gelatin solution to which had been added surfactant as in Table 1. The result was an oil-in-water dispersion having an average droplet diameter of less than 1 ⁇ m.
• Photographic coatings were prepared by combining together, under safelight conditions, 1.5g of coupler dispersion, 1.5g of 12.1/2% w/v aqueous gelatin solution, 0.20ml of photographic paper type silver chlorobromide emulsion (approximately 1.0M in silver halide) and 5.5ml water. 5% w/v chromic sulphate solution, 0.30ml, was added immediately prior to coating on photographic film base at a wet thickness of approximately O.lmm.
• Portions of dried coating were exposed to room light for 5s and then developed for 210 s in a p-phenylenediamine developer (KODAK 'Ektaprint 2', trade mark) at 31°C, bleach-fixed for 120s in a bleach-fix solution (KODAK 'Ektaprint'), washed for 30 minutes in running water, and dried.
• a p-phenylenediamine developer (KODAK 'Ektaprint 2', trade mark) at 31°C
• bleach-fixed for 120s in a bleach-fix solution (KODAK 'Ektaprint')
• the resulting cyan density of each sample was measured with a transmission densitometer through a red filter.
• the samples were then incubated in an oven at 60°C and 70% relative humidity and the dye density measured from time to time.
• the initial optical density (D i ) and the percentage density loss at the various times are recorded in Table 1.
• This example illustrates the use of a combination of hydrophilic and hydrophobic surfactants according to the invention.
• a coupler dispersion was prepared by dissolving coupler I. 5.0g, in di-n-butyl phthalate, 2.8g together with 2 - (2 - butoxyethoxy) ethyl acetate, 0.4g, and mechanically dispersing the resulting oily solution in 11.5% w/v gelatin solution, 42g, containing sodium tri-isopropylnaphthalene sulphonate. 0.18g. Portions of log were withdrawn, and 10% w/v solutions of sodium bis (tridecyl) sulphosuccinate in 1:2 methanol:water were added as in Table 2 and mechanically dispersed into the dispersion.
• Photographic coatings were prepared by combining together, under safelight conditions, 1.0g of coupler dispersion, 1.5g of 12.1/2% w/v aqueous gelatin solution, 0.20al of photographic paper type silver chlorobromide emulsion (approximately 1.0M in silver halide), and 6.0ml water. 5% w/v chromic sulphate solution, 0.30ml, was added immediately prior to coating on photographic film base at a wet thickness of approximately O.lmm.
• Example 2 Portions of dried coating were exposed, processed and tested as in Example 1: the results are given in Table 2.
• a low humidity accelerated keeping test was also carried out by placing processed strips in an oven at 77 0 C with no added humidity, and measuring the dye density at intervals as before. These results are given in Table 3.
• This example illustrates another combination of hydrophilic and hydrophobic surfactants according to the invention.
• Coupler dispersions were prepared by dissolving together l.Og of coupler I. 0.6g of tricresyl phosphate, and 0.10g of sodium bis (tridecyl) sulphosuccinate, and mechanically dispersing the resulting oily solution into 5.0g of a 12.1/2% w/v aqueous gelatin solution mixed with 3.0ml water and 10% w/v aqueous sodium dioctyl sulphosuccinate (a non-lipophilic anionic surfactant) as stated in Table 4.
• the dispersion prepared for Example 2 was used for the control.
• Coatings were prepared as in Example 2. except that 0.9ml of dispersion and 6.1ml of water were added. Testing was as in Example 2, and results are given in Tables 4 and 5.
• a dispersion of coupler II having the formula was prepared by dissolving 3.5g of coupler into a mixture of 2.0g of di-n-butyl phthalate and 8.0g of 2-(2-butoxyethoxy) ethyl acetate, and mechanically dispersing the resulting oily solution into 40g of 9.0% w/v gelatin solution to which had been added 0.5g of sodium tri-isopropylnaphthalene sulphonate. The dispersion was then cooled, and when set was cut into small cubes of approximately 0.5 cm edge. The chopped dispersion was washed for 5 hours in chilled ( 5 0 C ) demineralised water which was maintained at approximately pH5.5 by addition of a small quantity of propionic acid.
• the washed dispersion was melted at 40°C and to a 5.0g portion was added 0.2g of a 70% w/w solution of sodium bis (tridecyl) sulphosuccinate ('Aerosol TR 70' - trade mark - supplied by Cyanamid of Great Britian Limited). This solution was mechanically dispersed into the dispersion sample.
• Coatings were prepared as in Example 2. except that 1.3g of dispersion and 4.9 ml of water were used for each coating. Testing was carried out as in Example 2 and the results are shown in Table 6.
• Dispersions of coupler were prepared by dissolving coupler. 1.5g, in di-n-butyl phthalate. 0.9g, and ethyl acetate, 0.9g, and mechanically dispersing the resultant solution in 15g of 9.2% w/w gelatin to which had been added 10% sodium tri-isopropyl naphthalene sulphonate, 0.6 ml.
• Photographic coatings were prepared by combining together, under safelight conditions, the treated portion of coupler dispersion, 1.5g of 12 1/2 w/v aqueous gelatin solution, 0.25 ml of photographic paper type silver chlorobromide emulsion (approximately 1.0M in silver halide) and 5.7 ml water.
• Couplers III to V had the structures:
• Coupler IV 1.0g: n-dodecyl-p-hydroxybenzoate, 0.33g; n-octyl-p-hydroxy-benzoate, 0.33g: and N,N-diethyl lauramide, 0.33g, were melted together to form an oily solution. This solution was mechanically dispersed into 7.6g of 10.5% w/w gelatin solution, to which had been added 0.8g of 10% w/w sodium dioctyl sulphosuccinate aqueous solution and other surfactants as stated in Table 9.
• Photographic coatings were prepared by combining tgether under safelight conditions, 0.8g of coupler dispersion, 0.25g of silver chlorobromide photographic paper emulsion (approximately 1.0M in silver halide), l.Og of 12% w/w gelatin aqueous solution, and 6.6 ml of water. 5% w/v chromic sulphate solution, 0.30 ml, was added immediately prior to coating on photographic film base at a wet thickness of approximately 0.10 mm.
• the coupler used in this Example had an acidic phenol leaving group.
• the results show how the dark stability of the image dye was most diminished in areas of low image density, where most acidic phenol remained.
• the stabilising effect of the surfactants of the Invention is illustrated: the effects varied with the humidity at which the accelerated dark fading was carried out.
• a coupler dispersion and coatings were prepared as in Example 5, except that coupler VI was used.
• the coatings were exposed to a photographic step wedge and processed as in Example 5.
• the image densities of the various steps of the image were measured (blue filter).
• the strips were incubated either for 60 days at 60 C, 70% RH or for 28 days at 77°C. low RH. Results are given in Table 10: coating A had 0.3 ml water added, B had 0.3 ml 7% Aerosol TR70, as in Example 5.
• Multilayer coatings were made on a paper support according to the following summary.
• the numbers in parenthesis are coverages expressed as mg/m 2 .
• the coverages relate to the silver present.
• the couplers were incorporated in the layers as dispersions, being mixed with di-n-butyl phthalate (one half the coupler weight in the case of the cyan and magenta couplers and one quarter the coupler weight in the case of the yellow coupler) and dispersed in aqueous gelatin solutions with the aid of sodium tri-isopropyl naphthalene sulphonate.
• the UV absorber in layer 4 comprised a mixture of 84.1% (by weight) of 2-(2-hydroxy-3,5-di-tert-pentyl-phenyl) benzotriazole, 15% 2-(2-hydroxy-3-tert-butyl-5-methylphenyl) benzotriazole and 0.9% dioctylhydroquinone dispersed in 2-(2-butoxyethoxy) ethyl acetate.
• the gelatin hardener in layer 1 was bis(vinylsulphonylmethyl) ether and was added in an amount equal to 1.75% of the total weight of the gelatin in the multilayer coating.
• Samples of the four coatings were exposed, processed as described in Example 1 and then used for determining the stability of the cyan dye image under incubation test conditions. In all the tests the loss in red-light reflection density of an image having an initial value of 1.7 was measured as a function of the incubation time. Two different test conditions were used. 77 0 C and 15% relative humidity for the two week tests and 60°C and 70% relative humidity for 16 week tests.

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• 1984
  • 1984-11-23 GB GB848429677A patent/GB8429677D0/en active Pending
• 1985
  • 1985-11-07 CA CA000494801A patent/CA1261190A/fr not_active Expired
  • 1985-11-20 DE DE8585308436T patent/DE3577358D1/de not_active Expired - Fee Related
  • 1985-11-20 EP EP19850308436 patent/EP0182658B1/fr not_active Expired
  • 1985-11-25 JP JP26470085A patent/JPS61184542A/ja active Pending

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