EP0178502B1 - Procédé pour la fabrication d'alliages - Google Patents

Procédé pour la fabrication d'alliages Download PDF

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Publication number
EP0178502B1
EP0178502B1 EP85112130A EP85112130A EP0178502B1 EP 0178502 B1 EP0178502 B1 EP 0178502B1 EP 85112130 A EP85112130 A EP 85112130A EP 85112130 A EP85112130 A EP 85112130A EP 0178502 B1 EP0178502 B1 EP 0178502B1
Authority
EP
European Patent Office
Prior art keywords
media
molten
process according
chamber
molten media
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP85112130A
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German (de)
English (en)
Other versions
EP0178502A1 (fr
Inventor
Charles E. Eckert
Ronald E. Miller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Howmet Aerospace Inc
Original Assignee
Aluminum Company of America
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aluminum Company of America filed Critical Aluminum Company of America
Priority to AT85112130T priority Critical patent/ATE46367T1/de
Publication of EP0178502A1 publication Critical patent/EP0178502A1/fr
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Publication of EP0178502B1 publication Critical patent/EP0178502B1/fr
Expired legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/026—Alloys based on aluminium

Definitions

  • the invention relates generally to a method for adding alloying elements to molten metals. More particularly, however, it relates to the addition of elements which normally dissolve slowly and with difficulty in molten metals, particularly aluminum.
  • U.S. Patent 3,729,309 to Kawawa also discloses a method for adding alloying elements in the form of a wire rod to molten metals.
  • the rod has a controlled size and is added to a molten metal bath by inserting it at a controlled speed, so as to produce a refined and purified metal alloy.
  • U.S. Patent 3,947,265 to Guzowski et al proposes a solution to the problem of adding such "hard-to- alloy" materials to molten metal.
  • the process employs a high current arc which is formed between the molten base metal and the alloying addition.
  • the alloying addition is passed through the arc where it is melted and converted into a spray of finely divided superheated molten particles. In such a condition, the particles are able to rapidly dissolve in the molten metal upon contact therewith. While the Guzowski concept of alloying is certainly an interesting one, a need still exists for a process capable of providing improved results.
  • the chamber means is elongate and has an upper inlet, at least a portion of which is located above the upper surface of the molten media, the material being fed into the chamber through said inlet, and the interior surface of the body of molten media being maintained at a depth below said exterior surface such that at least 50% of material being added to the molten media is recovered in the molten media.
  • a method for adding alloying material to a molten metal media, such as molten aluminum.
  • the method includes the step of converting the alloying material into a spray of superheated alloy material and directing the spray into the molten metal media at a predetermined depth below the media's surface, the depth having been determined beforehand to enhance dissolution and dispersion of the alloying material into the molten media.
  • the alloying material is converted into the spray of superheated alloy material in a spark cup means which is at least partially immersed in the molten media body.
  • the spark cup has a lower open end which is exposed to the molten media and an upper inlet, at least a portion of which is located above the exposed or exterior surface of the molten media. The lower open end of the spark cup is maintained or immersed a predetermined depth below the surface of the molten media.
  • the alloying material preferably in the form of an elongated element having a free end, is continually fed into the spark cup through its upper inlet, and an electrical arc discharge between the submerged molten metal surface and the alloying element in the spark cup is maintained with a current that exceeds the globular/spray transition current density of the alloying material.
  • Arc shielding gas is continually supplied to the spark cup through its upper inlet also. In addition to shielding the arc discharge, the gas slightly pressurizes the spark cup and thereby prevents molten media from entering its open end.
  • a submerged interior surface of molten metal media is created in the spark cup's open end at the aforementioned predetermined depth.
  • the shielding gas also carries or projects the superheated spray of alloy material into the molten media through the submerged molten metal surface so as to permit dissolution and dispersion of the alloy material in the media.
  • the predetermined depth of immersion has been found to significantly enhance dispersion and dissolution of the alloying material into the media.
  • the present invention also provides a lead alloyed, aluminum based article having high machinability.
  • the article is produced by converting lead alloy material into a spray of superheated alloy material which is injected into a bath of molten aluminum at a predetermined depth below the molten bath's surface.
  • the spray is formed by establishing an electrical arc discharge between a submerged surface of the molten media and the alloying material. The discharge is maintained with a current that exceeds the globular/spray transition current density of the alloying material.
  • the spray of superheated alloying material is directed onto the submerged interior surface of the media where dissolution and dispersion of the alloy material into the media take place.
  • the submerged surface is maintained at the predetermined depth below the bath's surface having been found to enhance said dissolution and dispersion of the lead into molten aluminum bath.
  • the article so produced has acicular shaped particles of lead which are smaller and more uniformly sized and dispersed than those which are made by adding lead at the surface of the molten aluminum or at a depth above the aforesaid predetermined depth.
  • Figure 1 illustrates the addition of a wire 10 of alloying material into a bath or melt 12 of molten media in a flow-through furnace 14.
  • the surface of melt 12 is referred to herein as exposed or exterior surface 16.
  • Wire 10 is being fed by a feeder 18 which passes it through a triplex feed cable 20 into a spark cup 22, the spark cup being partially immersed in melt 12.
  • alloy wire 10 is converted into a spray 24 of superheated alloy material by passing it through a plasma arc discharge (not numbered).
  • the plasma arc discharge is established between a submerged surface 26 of the molten metal which is maintained within an open end 28 of spark cup 22 and a free end 30 of alloy wire 10.
  • the arc discharge is shielded with a shielding gas 32, preferably argon, which is provided via feed cable 20 by an arc shielding gas source 34.
  • a shielding gas 32 preferably argon
  • the shielding gas source 34 pressurizes the spark cup at a pressure which is sufficient to prevent molten metal from entering open end 28 of the spark cup. Such pressurization also facilitates maintenance of the aforementioned submerged surface at a certain predetermined depth below exposed surface 16 (more on this, infra).
  • the arc discharge is powered by a constant current power supply source 36 (more on this, infra).
  • Melt 12 serves as an anode with wire 10 serving as a consumable electrode.
  • the electrical circuit leading back to current source 36 is completed by a return wire 38 which is attached to a rod 40 immersed in melt 12.
  • the superheated spray produced by the arc discharge is directed or projected by the supply of shielding gas onto submerged surface 26 where the alloy material rapidly dissolves and disperses in melt 12.
  • the gas is preferably supplied at a flow rate that maximizes the projection of the spray into the melt.
  • An impeller 42 or agitating means is also provided to further enhance dispersion of the alloy material throughout the melt.
  • Spray 24 can be maintaiined as long as is desired by continually advancing or feeding the alloying wire into the spark cup.
  • Feeder 18 can also be controlled to maintain or vary the rate at which wire 10 is fed into the spark cup.
  • the alloying material can be provided in wire form, as described above, or in the form of rod, tube, strip or in powdered form wherein the powders are encased in a hollow tube made from a suitable metal which has been swaged or otherwise worked to reduce its diameter and compact the powdered material in the tube.
  • the only real limitation on the form of the alloying is that it should have a form which permits it to be fed into the feed cable in a seal-tight fashion, thereby enabling the pressurized atmosphere in the spark cup to be maintained. If the pressurized atmosphere in the spark cup is not maintained, molten metal will, quite obviously, enter the spark cup through its open end 28, thereby raising submerged surface 26 to a depth above its predetermined depth.
  • feeder 18 is preferably a consistent feed rate tractor drive.
  • Constant current source 36 is preferably of the type which maintains a relatively constant current regardless of voltage fluctuations.
  • the arc produced thereby has self-stabilizing characteristics and is relatively insensitive to changes in arc length which might be caused by fluctuations in the submerged molten metal depth. It may also be desirable in certain situations to further enhance arc stability by seeding the plasma discharge with certain additives, such as alkali metals which are known to promote arc stability. Arc stability can also be enhanced by using various fluxes known to those skilled in the relevant art.
  • the globular/spray transition current density defines the boundary line separating the two different types of metal transfer that are capable of occurring in the plasma arc discharge. (As pointed out by Guzowski in U.S. Patent 3,947,265, this transition point can vary with such factors as alloy type, wire size and wire speed.)
  • this transition point can vary with such factors as alloy type, wire size and wire speed.
  • alloy material being transferred through the arc detached into large drops which dissolve and disperse slowly in the molten metal media.
  • the transfer mechanism changes causing the alloy material to convert a fine spray of superheated alloy material. In this condition, the alloy material rapidly dissolves and disperses in the molten media upon contact with submerged surface 26.
  • Shielding gas 32 carrying or projecting spray 24 into the melt also typically enters the melt. This, however, should not introduce or cause any melt contamination since such gas simply escapes from the melt by bubbling through the melt to exterior surface 16.
  • the preferred shielding gas is argon; however, other shielding gases, such as helium, carbon monoxide and carbon dioxide, may also be used in appropriate situations.
  • the spark cup is preferably cylindrically shaped. Such a shape provides a relatively high spark cup surface area to volume ratio which facilitates conductive heat transfer from the spark cup to the melt. It is important to facilitate such heat transfer to prevent the spark cup from overheating. Moreover, those skilled in the relevant art will appreciate that such heat transfer to the melt is advantageous in that it provides a convenient way of adding heat to the melt, thereby reducing furnace fuel needs. Conventional alloy adding processes such as that disclosed in Guzowski et al U.S. Patent No. 3,947,265 do not add much, if any, heat to their respective melts. For example, most of the heat generated during melting of the alloy material in Guzowski et al is lost to the atmosphere since the superheated spray is formed entirely above the melt surface.
  • the spark cup's cylindrical shape also enhances projection of the shielding gas carrying the superheated spray into the melt. Such projection is important in that it enhances dissolution and dispersion of the alloying material into the melt. While a cylindrical shape is preferred, other shapes, such as an inverted frustoconical shape, which provide enhanced projection and heat transfer are considered to be within the purview of the present invention.
  • the spark cup's composition is another important aspect of the present invention.
  • it is made from material having the following characteristics:
  • FIG. 3 Another briefly alluded to but important aspect of the present invention is directed to immersing the spark cup and maintaining submerged surface 26 in the open end of the spark cup at its predetermined depth below exposed surface 16. Such depth will be referred to hereinafter as the predetermined immersion depth. It has been found that a difference of one or two inches in the immersion depth can have a significant impact upon the rate at which alloying material dissolves and disperses in the molten media.
  • Figures 3 and 4 set forth test data from experiments conducted to determine the effects of immersion depth upon dissolution and dispersion.
  • Figure 3 sets forth data respecting dissolution rate versus immersion depth
  • Figure 4 shows actual recovery in percentages versus immersion depth. The goal of the experiments was to add 0.5% lead to a substantially lead-free body of molten aluminum.
  • the experiments were conducted with a setup similar to that disclosed in Figure 1 except that a constant voltage supply source was used instead of the preferred constant current supply source.
  • the flow-through furnace used in the experiments contained approximately 454 Kgs (1000 pounds) of aluminum.
  • the bath of molten aluminum in the furnace had a depth of approximately 76 cm (30 inches) with a diameter of approximately 58 cm (23 inches).
  • Lead wire of 3.175 mm (8 inch) diameter was fed into a borosilicate spark cup at a feed rate of about 76 cm (30 inches) per minute via a triplex feed cable.
  • the spark cup was cylindrically shaped and had a lower opening similar to that described in Figure 1 with a diameter of approximately five centimeters.
  • the spark cup's length to diameter ratio was approximately 6 to 1.
  • Argon shielding gas was fed into the spark cup via the feed cable at a flow rate of about 0.28 standard m 3 /hr (10 standard ft 3 /hr).
  • a plasma arc discharge was established in the spark cup between the free end of the lead wire and the submerged molten metal surface at a voltage of about 35 volts and a current of about 125 amperes, which translates into a current density of about 1550 amps/cm 2 (10,000 amp/ in 2 ).
  • the free end of the wire melted and converted into an axial spray of superheated alloy material upon entering the arc discharge.
  • the spray was directed onto the submerged melt surface by the shielding gas.
  • the alloyed molten aluminum was continuously cast into several ingots having dimensions of 15 cm x 15 cm x 91 cm (6 in. x 6 in. x 36 in.).
  • immersion depth providing enhanced dissolution and dispersion in accordance with the present invention will vary with the material being added, bath size, bath flow rate, alloy feed rate and size, inter alia, and will have to be determined for each setup, those skilled in the relevant art will appreciate that the method and apparatus of the present invention can result in greatly increased dissolution rates, particularly for alloy material with limited solubility, such as lead, bismuth and tin and for high oxidizable materials such as magnesium and zinc.
  • Continuous casting processes are those that permit the continual flow of metal from a melting furnace into a casting mold. Since continuous casting usually proceeds at a uniform rate, it will be easy to calculate the desired alloy feed rate with the method of the present invention.
  • the invention is particularly amenable to continuous casting processes wherein the casting rate varies. Suitable instrumentation can be installed on the casting line to detect any changes in the casting rate which can then be used to make adjustments in the alloy feed rate.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Claims (13)

1. Procédé d'addition d'un matériau dans un milieu métallique en fusion, dans lequel:
(a) on prépare une masse de milieu en fusion;
(b) on met en place une chambre comportant une extrémité d'évacuation ouverte, disposée dans cette masse de milieu;
(c) on introduit, dans la chambre, un gaz comprenant un gaz ionisable, sous une pression suffisante pour maintenir une surface intérieure du milieu en fusion, à peu près au niveau de la partie d'extrémité d'évacuation de la chambre;
(d) on introduit le matériau dans la chambre, au niveau d'une zone située au-dessus de la surface intérieure du milieu en fusion;
(e) on établit un arc électrique entre le matériau au niveau de ladite zone et de la surface intérieure du milieu en fusion, et on maintient un plasma s'étendant à peu près à partir de ladite zone dans la chambre jusqu'à la surface intérieure du milieu en fusion; et
(f) on maintient le plasma à une énergie suffisante pour convertir le matériau en un jet pulvérisé surchauffé, s'étendant à peu près dans le plasma en direction de la surface intérieure du milieu en fusion;
(g) l'introduction du gaz dans la chambre, étant effectuée à une vitesse suffisante pour projeter le matériau dans le milieu en fusion de façon à favoriser la pénétration du matériau dans ce milieu.
2. Procédé selon la revendication 1, dans lequel la chambre est allongée et comporte un orifice d'entrée supérieur, au moins une partie de celle-ci étant située au-dessus de la surface supérieure du milieu en fusion, le matériau étant introduit dans la chambre, à travers l'orifice d'entrée, et la surface intérieure de la masse de milieu en fusion étant maintenue à une profondeur située en-dessous de la surface extérieure, de telle façon qu'au moins 50% du matériau additionné dans le milieu en fusion, soient récupérés dans le milieu en fusion.
3. Procédé selon la revendication 1 ou 2, dans lequel la surface intérieure du milieu en fusion, est maintenue à une profondeur prédéterminée sous la surface supérieure du milieu en fusion, cette profondeur étant suffisante pour favoriser la dissolution et la dispersion du matériau dans ce milieu.
4. Procédé selon l'une quelconque des revendications précédentes, dans lequel une quantité importante de chaleur est transmise au milieu en fusion, à travers la partie de la chambre, immergée dans le milieu.
5. Procédé selon l'une quelconque des revendications précédentes, dans lequel le milieu en fusion, comprend de l'aluminium.
6. Procédé selon l'une quelconque des revendications précédentes, dans lequel le matériau additionné, est introduit dans la chambre sous la forme d'un fil ou d'une tige plein.
7. Procédé selon l'une quelconque des revendications précédentes, dans lequel le gaz comprend un gaz non réactif.
8. Procédé selon la revendication 7, dans lequel on disperse dans le gaz au moins un additif destiné à favoriser la stabilité de l'arc ou l'absorption de l'oxygène.
9. Procédé selon l'une quelconque des revendications précédentes, dans lequel l'arc électrique est formé à partir d'un courant continu.
10. Procédé selon l'une quelconque des revendications précédentes, dans lequel la longueur de la chambre, le long de la direction de projection dans le milieu en fusion, est supérieure à la dimension transversale de l'orifice de sortie de la chambre.
11. Procédé selon l'une quelconque des revendications précédentes, dans lequel le matériau additionné, comprend un ou plusieurs éléments choisis parmi le plomb, le bismuth, l'antimoine, le magnésium, le zinc et le cuivre.
12. Procédé selon l'une quelconque des revendications précédentes, dans lequel la chambre est réalisée en alumine, en borosilicate, en mullite ou en silice.
13. Procédé selon l'une quelconque des revendications précédentes, dans lequel le milieu en fusion est agité pour favoriser encore la dispersion du matériau dans le milieu.
EP85112130A 1984-09-27 1985-09-24 Procédé pour la fabrication d'alliages Expired EP0178502B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT85112130T ATE46367T1 (de) 1984-09-27 1985-09-24 Verfahren zur herstellung von legierungen.

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US65473584A 1984-09-27 1984-09-27
US65473684A 1984-09-27 1984-09-27
US654735 1984-09-27
US654736 1991-02-13

Publications (2)

Publication Number Publication Date
EP0178502A1 EP0178502A1 (fr) 1986-04-23
EP0178502B1 true EP0178502B1 (fr) 1989-09-13

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EP85112130A Expired EP0178502B1 (fr) 1984-09-27 1985-09-24 Procédé pour la fabrication d'alliages

Country Status (4)

Country Link
EP (1) EP0178502B1 (fr)
AU (1) AU578493B2 (fr)
DE (1) DE3573000D1 (fr)
NO (1) NO167759C (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01132726A (ja) * 1984-09-27 1989-05-25 Aluminum Co Of America <Alcoa> 金属間化合物を生成する方法
NO165766C (no) * 1988-06-30 1991-04-10 Norsk Hydro As Fremgangsmaate for kornforfining av metaller.
WO1995025822A1 (fr) * 1994-03-18 1995-09-28 Sahm P R Materiaux de moulage
DE19839670A1 (de) * 1998-09-01 2000-03-02 Induga Industrieoefen Und Gies Verfahren zur kontinuierlichen Herstellung von Metall-Legierungen
CN102353267A (zh) * 2011-10-31 2012-02-15 中国铁建电气化局集团有限公司 铜镁熔炼炉加镁装置

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2263268B2 (de) * 1972-12-23 1976-12-30 Glyco-Metall-Werke Daelen & Loos Gmbh, 6200 Wiesbaden-Schierstein Verfahren zur herstellung von aluminium-blei-legierungen
US3947265A (en) * 1973-10-23 1976-03-30 Swiss Aluminium Limited Process of adding alloy ingredients to molten metal

Also Published As

Publication number Publication date
AU578493B2 (en) 1988-10-27
EP0178502A1 (fr) 1986-04-23
NO853784L (no) 1986-04-01
NO167759B (no) 1991-08-26
AU4781385A (en) 1986-04-10
NO167759C (no) 1991-12-04
DE3573000D1 (en) 1989-10-26

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