EP0156833A1 - Deodorant - Google Patents

Deodorant

Info

Publication number
EP0156833A1
EP0156833A1 EP19840903348 EP84903348A EP0156833A1 EP 0156833 A1 EP0156833 A1 EP 0156833A1 EP 19840903348 EP19840903348 EP 19840903348 EP 84903348 A EP84903348 A EP 84903348A EP 0156833 A1 EP0156833 A1 EP 0156833A1
Authority
EP
European Patent Office
Prior art keywords
deodorant according
deodorant
amount
camphor
toilet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19840903348
Other languages
German (de)
French (fr)
Inventor
Horst Hautmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Globol Werk GmbH
Original Assignee
Globol Werk GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Globol Werk GmbH filed Critical Globol Werk GmbH
Publication of EP0156833A1 publication Critical patent/EP0156833A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0068Deodorant compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/015Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/05Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating specially adapted to be released by contact with a liquid, e.g. for toilets

Definitions

  • the present invention relates to a deodorant, preferably for use as an air purifier and in toilet facilities.
  • the object of the present invention is therefore to provide deodorants which are not only outstandingly suitable for air purification and odor removal, particularly in toilet facilities, but also all the necessary physical, chemical and organoleptic properties for the production and use of ent have speaking deodorants. Above all, the new deodorants should be as environmentally friendly and toxicologically safe as possible.
  • the present invention relates to a deodorant, preferably for use as an air purifier and in toilet facilities, which is characterized in that it comprises a camphor compound.
  • the deodorizing agents according to the invention are in the form of toilet sticks (toilet inserts), basin stones or solid bodies, for example for interior design in buildings.
  • the camphor compound used is borneol, isoborneoi, camphene or camphor itself.
  • the proportion of camphor compound as a WC stick or basin stone is advantageously about 1 to 50% by weight, in particular 2 to 10% by weight (this and the following details of the proportions relate to the entire deodorant).
  • the deodorants according to the invention may contain, as further components, those which have also been used in the known deodorants of the present type.
  • one or more detergents may be present, suitably non-ionic or anionic surfactants.
  • a range of 40 to 50% by weight of these substances is outstandingly suitable according to the invention.
  • detergents which can be used according to the invention include sodium alkylbenzenesulfonate, sodium fatty alcohol sulfate, coconut fatty acid monoethanolamide, ethoxylated oxo alcohols, ethoxylated fatty alcohols or alkyl phenol oxyalkylates, in particular alkylphenol oxyethylates
  • the deodorants according to the invention can also contain polywaxes or other binders, with amounts of up to 10% by weight being particularly expedient.
  • Fillers can preferably be present in the deodorants according to the invention in amounts of up to 30%.
  • An example of such a suitable filler is sodium sulfate.
  • the deodorants according to the invention may also contain perfuming agents / optionally other customary additives as further constituents. If perfuming agents are present, their amount is preferably between 0.5 to 10% by weight.
  • the deodorants according to the invention are intended as typical air cleaning agents, it is advantageous if they consist exclusively of volatile substances which do not result in a residue. In this case it is therefore expedient that they contain only the camphor compound and optionally a perfuming agent.
  • the deodorants according to the invention can be prepared in a manner known per se. For example, one of the following three methods is available:
  • All desired components of the deodorant can first be mixed and then expediently at elevated temperatures, such as e.g. 50 to 60 ° C are homogenized. Moldings are obtained from this mixture in corresponding commercial devices by extrusion.
  • Another possibility is to heat the components so high that there is a melt of at least the main components of the composition. If necessary, this is mixed thoroughly in order then to obtain the individual pieces of the deodorant by pouring them into a mold and cooling them. Finally, it is also possible to mix the components of the deodorizing agent and to process the mixture by compression molding into corresponding commercially available moldings.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Detergent Compositions (AREA)

Abstract

Nouveau désodorisant caractérisé par le fait qu'il comporte un composé de camphre. Le désodorisant est conçu en particulier pour être utilisé comme épurateur d'air et dans des installations de toilettes. Le désodorisant a de préférence une teneur en composé de camphre se situant entre 2 et 10% en poids.New air freshener characterized by the fact that it contains a camphor compound. The deodorant is designed in particular to be used as an air purifier and in toilet installations. The deodorant preferably has a content of camphor compound between 2 and 10% by weight.

Description

Die vorliegende Erfindung betrifft ein Desodorierungsmittel, vorzugsweise zur Verwendung als Luftreinigungsmittel und in Toiletteneinrichtungen. The present invention relates to a deodorant, preferably for use as an air purifier and in toilet facilities.
Es ist bekannt, zur Luftreinigung und Bekämpfung schlechte r Gerüche, insbesondere im Inneren von Gebäuden, Luftreinigungsmittel in Form von Festkörpern zu verwenden. Des weiteren sind seit langer Zeit WC-Einsatzstücke in Toilettenanlagen bekannt, mit welchen eine effektive Geruchsbekämpfung vorgenommen werden kann.It is known to use air purifying agents in the form of solids for air purification and combating bad odors, especially inside buildings. Furthermore, toilet inserts in toilet facilities have been known for a long time, with which effective odor control can be carried out.
Erfolgreiche, bekannte Desodorierungsmittel der genannten Art sind solche auf der Grundlage von p-Dichlorbenzol. Es hat sich jedoch herausgestellt, daß diese Substanz den heutigen Anforderungen an die Reinhaltung der Umwelt nicht mehr genügt. Bei der bestimmungsmäßigen Verwendung derartiger bekannter WC-Sticks oder Beckensteine konnte nicht vermieden werden, daß Anteile von dem p-Dichlorbenzol in das Abwasser gelangten, so daß die Gefahr bestand, daß aufgrund dieser Umweltverschmutzung eine schädigende Wirkung auf den Menschen oder zumindest auf dessen Umwelt (Pflanzen, Tiere, etc.) ausgeübt wird. Bekanntlich sind bestimmte chlorierte Kohlenwasserstoffe auf Menschen oder den menschlichen Lebensraum nachgewiesenerweise toxisch oder zumindest außer- ordentlich bedenklich.Successful, known deodorants of the type mentioned are those based on p-dichlorobenzene. However, it has been found that this substance no longer meets today's environmental requirements. When using such known toilet sticks or pool stones as intended, it could not be avoided that portions of the p-dichlorobenzene were released into the wastewater, so that there was a risk that this environmental pollution would have a harmful effect on humans or at least on their environment ( Plants, animals, etc.) is exercised. It is known that certain chlorinated hydrocarbons have been proven to be toxic or at least extremely harmful to humans or the human environment.
Erfindungsgemäß ist nun gefunden worden, daß derartige bedenkliche Bestandteile von bekannten Desodorierungsmittel durch bestimmte toxikologisch unbedenkliche Substanzen ersetzt werden können.According to the invention, it has now been found that such questionable constituents of known deodorants can be replaced by certain toxicologically harmless substances.
Aufgabe der vorliegenden Erfindung ist also die Schaffung von Desodorierungsmitteln, welche nicht nur zur Luftreinigung und Geruchsbeseitigung, insbesondere in Toiletteneinrichtungen, hervorragend geeignet sind, sondern auch sämtliche notwendigen physikalischen, chemischanund organoleptischen Eigenschaften zur Herstellung und Verwendung von ent sprechenden Desodorierungsmitteln aufweisen. Vor allem sollen die neuen Desodorierungsmittel möglichst umweltfreundlieh und toxikologisch völlig unbedenklich sein.The object of the present invention is therefore to provide deodorants which are not only outstandingly suitable for air purification and odor removal, particularly in toilet facilities, but also all the necessary physical, chemical and organoleptic properties for the production and use of ent have speaking deodorants. Above all, the new deodorants should be as environmentally friendly and toxicologically safe as possible.
Gegenstand der vorliegenden Erfindung ist ein Desodorierungs mittel, vorzugsweise zur Verwendung als Luftreinigungsmittel und in Toiletteneinrichtungen, das dadurch gekennzeichnet ist, daß es eine Campherverbindung umfaßt.The present invention relates to a deodorant, preferably for use as an air purifier and in toilet facilities, which is characterized in that it comprises a camphor compound.
Nach speziellen Ausführungsformen der vorliegenden Erfindung liegen die erfindungsgemäßen Desodorierungsmittel in Form von WC-Sticks (WC-Einsatzstücke), Beckensteinen oder Festkörpern z.B.zur Auslegung ininnenräumen von Gebäuden vor.According to special embodiments of the present invention, the deodorizing agents according to the invention are in the form of toilet sticks (toilet inserts), basin stones or solid bodies, for example for interior design in buildings.
Gleichgültig, in welcher speziellen Anwendungsform das erfindungsgemäße Desodorierungsmittel verwendet wird, wird als Campherverbindung Borneol, Isoborneoi, Camphen oder Campher selbst verwendet.Regardless of the specific application in which the deodorant according to the invention is used, the camphor compound used is borneol, isoborneoi, camphene or camphor itself.
Als WC-Stick oder Beckenstein beträgt der Anteil der Campherverbindung vorteilhaft etwa 1 bis 50, insbesondere 2 bis 10 Gew.-% (diese und die folgenden Angaben der Mengenanteile beziehen sich auf das gesamte Desodorierungsmittel).The proportion of camphor compound as a WC stick or basin stone is advantageously about 1 to 50% by weight, in particular 2 to 10% by weight (this and the following details of the proportions relate to the entire deodorant).
In den erfindungsgemäßen Desodorierungsmitteln können als weitere Komponenten diejenigen enthalten sein, welche auch in den bekannten Desodorierungsmitteln der vorliegenden Art verwendet worden sind. So könnei ein oder mehrere Detergenzien anwesend sein und zwar zweckmäßig nicht-ionische oder anionische oberflächenaktive Mittel. Ein Mengenbereich an diesen Stoffen von 40 bis 50 Gew.-% ist erfindungsgemäß hervorragend geeignet. Zu Beispielen von erfindungsgemäß verwendbaren Detergenzien zählen Natriumalkylbenzolsulfonat, Natriumfettalkoholsulfat, Cocosfettsäure - monoethanolamid, ethoxylierte Oxoalkohole, ethoxylierte Fettalkohole bzw. Alkylphe noloxalkylate, insbesondere Alkylphenoloxethylate Des weiteren können die erfindungsgemäßen Desodorierungsmittel auch Polywachse oder andere Bindemittel enthalten, wobei Mengen bis zu 10 Gew.-% besonders zweckmäßig sind.The deodorants according to the invention may contain, as further components, those which have also been used in the known deodorants of the present type. For example, one or more detergents may be present, suitably non-ionic or anionic surfactants. A range of 40 to 50% by weight of these substances is outstandingly suitable according to the invention. Examples of detergents which can be used according to the invention include sodium alkylbenzenesulfonate, sodium fatty alcohol sulfate, coconut fatty acid monoethanolamide, ethoxylated oxo alcohols, ethoxylated fatty alcohols or alkyl phenol oxyalkylates, in particular alkylphenol oxyethylates Furthermore, the deodorants according to the invention can also contain polywaxes or other binders, with amounts of up to 10% by weight being particularly expedient.
Füllstoffe können in den erfindungsgemäßen Desodorierungs- mitteln vorzugsweise in Mengen bis zu 30 % anwesend sein. Ein Beispiel für einen derartigen zweckmäßigen Füllstoff ist Natriumsulfat. Als weitere Bestandteile können die erfindungsgemäßen Desodorierungsmittel noch Parfümierungsmittel /gegebenenfalls andere übliche Zusatzstoffe, enthalten. Sofern Parfümierungsmittel anwesend sind, beträgt deren Menge vorzugsweise zwischen 0,5 bis 10 Gew.-%.Fillers can preferably be present in the deodorants according to the invention in amounts of up to 30%. An example of such a suitable filler is sodium sulfate. The deodorants according to the invention may also contain perfuming agents / optionally other customary additives as further constituents. If perfuming agents are present, their amount is preferably between 0.5 to 10% by weight.
Sind die erfindungsgemäßen Desodorierungsmittel als typische Luftreinigungsmittel bestimmt, so ist es vorteilhaft, wenn diese ausschließlich aus flüchtigen Stoffen bestehen, welche keinen Rückstand ergeben. In diesem Falle ist es also zweckmäßig, daß sie lediglich die Campherverbindung sowie gegebenenfalls ein Parfümierungsmittel enthalten.If the deodorants according to the invention are intended as typical air cleaning agents, it is advantageous if they consist exclusively of volatile substances which do not result in a residue. In this case it is therefore expedient that they contain only the camphor compound and optionally a perfuming agent.
Die erfindungsgemäßen Desodorierungsmittel können in an sich bekannter Weise hergestellt werden. Dafür stehen beispielsweise eine der folgenden drei Verfahren zur Verfügung:The deodorants according to the invention can be prepared in a manner known per se. For example, one of the following three methods is available:
Es können alle gewünschten Komponenten des Desodorierungs- mittels zunächst vermischt und danach zweckmäßig bei erhöhten Temperaturen, wie z.B. 50 bis 60°C homogenisiert werden. Aus dieser Mischung werden in entsprechenden handelsüblichen Vorrichtungen Formkörper durch Extrudieren erhalten.All desired components of the deodorant can first be mixed and then expediently at elevated temperatures, such as e.g. 50 to 60 ° C are homogenized. Moldings are obtained from this mixture in corresponding commercial devices by extrusion.
Eine andere Möglichkeit ist, die Komponenten so hoch zu erhitzen, daß eine Schmelze zumindest der Hauptbestandteile der Zusammensetzung vorliegt. Diese wird notwendigenfalls gründlich vermischt, um danach durch Ausgießen in eine Form und Abkühlen die Einzelstücke des Desodorierungsmittels zu erhalten. Schließlich ist es auch möglich, die Komponenten des Desodorierungsmittels zu mischen und die Mischung durch Formpressen zu entsprechenden handelsfähigen Formkörpern zu verarbeiten. Another possibility is to heat the components so high that there is a melt of at least the main components of the composition. If necessary, this is mixed thoroughly in order then to obtain the individual pieces of the deodorant by pouring them into a mold and cooling them. Finally, it is also possible to mix the components of the deodorizing agent and to process the mixture by compression molding into corresponding commercially available moldings.

Claims

P a t e n t a n s p r ü c h e Patent claims
1. Desodorierungsmittel, vorzugsweise zur Verwendung als Luftreinigungsmittel und in Toiletteneinrichtungen, dadurch gekennzeichnet, daß es eine Campherverbindung umfaßt.1. Deodorant, preferably for use as an air purifier and in toilet facilities, characterized in that it comprises a camphor compound.
2. Desodorierungsmittel nach Anspruch 1, dadurch gekennzeichnet, daß die CampherVerbindung Borneol, Isoborneoi, Camphen oder Campher ist.2. Deodorant according to claim 1, characterized in that the camphor compound is borneol, isoborneoi, camphene or camphor.
3. Desodorierungsmittel nach Anspruch 1 bis 2, dadurch gekennzeichnet, daß es in Form eines WC-EinsatzStückes oder eines Beckensteines vorliegt.3. Deodorant according to claim 1 or 2, characterized in that it is in the form of a toilet insert or a pool stone.
4. Desodorierungsmittel nach .Anspruch 3, dadurch gekennzeichnet, daß es die Campherverbindung in einem Anteil von 1 bis 50 Gew.-%, vorzugsweise 2 bis 10 Gew.-% enthält. 4. Deodorant according to .Anspruch 3, characterized in that it contains the camphor compound in a proportion of 1 to 50 wt .-%, preferably 2 to 10 wt .-%.
5. Desodorierungsmittel nach Anspruch 3 bis 4, dadurch gekennzeichnet, daß es mindestens ein Detergent, insbesondere aus der Gruppe der anionischen oder nicht-ionischen Detergenzien, vorzugsweise in einer Menge von 40 bis 50 Gew.-% enthält.5. Deodorant according to claim 3 to 4, characterized in that it contains at least one detergent, in particular from the group of anionic or non-ionic detergents, preferably in an amount of 40 to 50 wt .-%.
6. Desodorierungsmittel nach Anspruch 5, dadurch gekennzeichnet, daß es als Detergent Natriumalkylbenzolsulfonat, Natriumfettalkoholsulfat, Cocosfettsäure-monoethanolamid, ethoxylierte Oxoalkohole, ethoxylierte Fettalkohole bzw. Alkylphenoloxalkylate enthält.6. Deodorant according to claim 5, characterized in that it contains as detergent sodium alkylbenzenesulfonate, sodium fatty alcohol sulfate, coconut fatty acid monoethanolamide, ethoxylated oxo alcohols, ethoxylated fatty alcohols or alkylphenoloxyalkylates.
7. Desodorierungsmittel nach Anspruch 3 bis 6, dadurch gekenn- zeichnet, daß es Polywachse oder ein anderes Bindemittel, vorzugsweise in einer Menge bis zu 10 Gew.-% enthält.7. Deodorant according to claim 3 to 6, characterized in that it contains poly waxes or another binder, preferably in an amount up to 10 wt .-%.
8. Desodorierungsmittel nach Anspruch 3 bis 7, dadurch gekennzeichnet, daß es übliche Füllstoffe, vorzugsweise in einer Menge bis zu 30 Gew.-%, enthält.8. Deodorant according to claim 3 to 7, characterized in that it contains conventional fillers, preferably in an amount up to 30 wt .-%.
9. Desodorierungsmittel nach Anspruch 8, dadurch gekennzeichnet, daß es als Füllstoff Natriumsulfat enthält.9. Deodorant according to claim 8, characterized in that it contains sodium sulfate as a filler.
10. Desodorierungsmittel nach Anspruch 1 bis 2, dadurch gekenn- zeichnet, daß es in Form von Luftreinigungskörpern vorliegt.10. Deodorant according to claim 1 or 2, characterized in that it is in the form of air cleaning bodies.
11. Desodorierungsmittel nach Anspruch 1 bis 10, dadurch gekenn- zeichnet, daß es zusätzlich ein Parfümierungsmittel und/oder mindestens ein anderes übliches Zusatzmittel enthält.11. Deodorant according to claim 1 to 10, characterized in that it additionally contains a perfuming agent and / or at least one other conventional additive.
12. Desodorierungsmittel nach Anspruch 11, dadurch gekennzeichnet, daß das Parfümierungsmittel in einer Menge von 0,5 bis12. Deodorant according to claim 11, characterized in that the perfuming agent in an amount of 0.5 to
10 Gew.-% enthalten ist. 10 wt .-% is included.
EP19840903348 1983-09-05 1984-09-04 Deodorant Withdrawn EP0156833A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3331995 1983-09-05
DE19833331995 DE3331995A1 (en) 1983-09-05 1983-09-05 DEODORIZING AGENT

Publications (1)

Publication Number Publication Date
EP0156833A1 true EP0156833A1 (en) 1985-10-09

Family

ID=6208282

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19840903348 Withdrawn EP0156833A1 (en) 1983-09-05 1984-09-04 Deodorant

Country Status (4)

Country Link
EP (1) EP0156833A1 (en)
CH (1) CH664077A5 (en)
DE (1) DE3331995A1 (en)
WO (1) WO1985000980A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8417345D0 (en) * 1984-07-06 1984-08-08 Unilever Plc Para-dichlorobenzene-free lavatory cleansing blocks
DE3907555A1 (en) * 1989-03-09 1990-09-13 Hoechst Ag USE OF MONOTERPEN AS AN AIR IMPROVEMENT

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1016538A (en) * 1950-04-21 1952-11-14 Manufacturing process of disinfectant polish
FR1117379A (en) * 1955-01-10 1956-05-22 Rhodia Process for at least partial elimination of bad industrial odors
LU61504A1 (en) * 1970-08-12 1972-04-05
GB1428109A (en) * 1972-05-20 1976-03-17 Fisons Ltd Controlled release of volatile compounds
CH582003A5 (en) * 1972-07-12 1976-11-30 Ciba Geigy Ag
US4301043A (en) * 1976-12-25 1981-11-17 Idemitsu Kosan Company Limited Sublimable perfume compositions
CH623096A5 (en) * 1977-08-03 1981-05-15 Globol Werk Insert for a WC flushing cistern
DE3311642A1 (en) * 1983-02-11 1984-10-11 Dr. O. Martens & Co Nachf., 8021 Baierbrunn ODOR IMPROVERS, METHOD FOR THE PRODUCTION AND USE OF THE ODOR IMPROVERS

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO8500980A1 *

Also Published As

Publication number Publication date
WO1985000980A1 (en) 1985-03-14
CH664077A5 (en) 1988-02-15
DE3331995C2 (en) 1987-07-02
DE3331995A1 (en) 1985-03-21

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