EP0137408A3 - Discoloration-resistant spandex fiber - Google Patents

Discoloration-resistant spandex fiber Download PDF

Info

Publication number
EP0137408A3
EP0137408A3 EP84111467A EP84111467A EP0137408A3 EP 0137408 A3 EP0137408 A3 EP 0137408A3 EP 84111467 A EP84111467 A EP 84111467A EP 84111467 A EP84111467 A EP 84111467A EP 0137408 A3 EP0137408 A3 EP 0137408A3
Authority
EP
European Patent Office
Prior art keywords
discoloration
spandex fiber
fiber
resistant spandex
resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84111467A
Other versions
EP0137408A2 (en
EP0137408B1 (en
Inventor
William Lewis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to AT84111467T priority Critical patent/ATE52111T1/en
Publication of EP0137408A2 publication Critical patent/EP0137408A2/en
Publication of EP0137408A3 publication Critical patent/EP0137408A3/en
Application granted granted Critical
Publication of EP0137408B1 publication Critical patent/EP0137408B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
    • C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Materials For Medical Uses (AREA)
  • Undergarments, Swaddling Clothes, Handkerchiefs Or Underwear Materials (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Increased resistance to discoloration induced by smog or heat is imparted to a spandex fiber by incorporating within the fiber a phenolic antioxidant and a dialkyl phenyl phosphite in which at least half of the alkyl groups are branched at the alpha position and the phenyl groups are unsubstituted or monoalkyl substituted.
EP84111467A 1983-09-26 1984-09-26 Discoloration-resistant spandex fiber Expired - Lifetime EP0137408B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT84111467T ATE52111T1 (en) 1983-09-26 1984-09-26 STAIN RESISTANT SPANDEX FIBER.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US535688 1983-09-26
US06/535,688 US4548975A (en) 1983-09-26 1983-09-26 Discoloration-resistant spandex fiber

Publications (3)

Publication Number Publication Date
EP0137408A2 EP0137408A2 (en) 1985-04-17
EP0137408A3 true EP0137408A3 (en) 1987-04-01
EP0137408B1 EP0137408B1 (en) 1990-04-18

Family

ID=24135345

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84111467A Expired - Lifetime EP0137408B1 (en) 1983-09-26 1984-09-26 Discoloration-resistant spandex fiber

Country Status (12)

Country Link
US (1) US4548975A (en)
EP (1) EP0137408B1 (en)
JP (1) JPS6094622A (en)
AT (1) ATE52111T1 (en)
BR (1) BR8404800A (en)
CA (1) CA1247776A (en)
DE (1) DE3481998D1 (en)
ES (1) ES536222A0 (en)
HK (1) HK65590A (en)
MX (1) MX159094A (en)
SG (1) SG42390G (en)
ZA (1) ZA847544B (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4871818A (en) * 1986-09-30 1989-10-03 E. I. Du Pont De Nemours And Company Polyester-based spandex filament
DE3637509A1 (en) * 1986-11-04 1988-05-05 Bayer Ag ELASTIC FIBERS STABILIZED AGAINST ENVIRONMENTAL INFLUENCES
US4798880A (en) * 1987-12-30 1989-01-17 E. I. Du Pont De Nemours And Company Spandex formed with a mixture of diamines
US5288779A (en) * 1991-10-31 1994-02-22 E. I. Du Pont De Nemours And Company Polyurethaneurea solutions and spandex therefrom
US5427854A (en) * 1994-03-14 1995-06-27 E. I. Du Pont De Nemours And Company Fibers containing polymer-coated inorganic particles
US5512369A (en) * 1994-03-14 1996-04-30 E. I. Du Pont De Nemours And Company Fibers containing polymer-coated inorganic particles
US5626960A (en) * 1995-09-07 1997-05-06 E. I. Du Pont De Nemours And Company Spandex containing a huntite and hydromagnesite additive
US6242558B1 (en) 1996-11-27 2001-06-05 Shell Oil Company Modified polytrimethylene terephthalate
US6093786A (en) * 1996-11-27 2000-07-25 Shell Oil Company Process for preparing polytrimethylene terephthalate
US6545074B1 (en) 1999-07-02 2003-04-08 Kolon Industries, Inc. Polyurethaneures elastic fiber, and a process of preparing the same
US6846866B2 (en) * 2001-06-05 2005-01-25 Invista North America S.A.R.L. Spandex containing a mixture of phenolic
US6664299B2 (en) 2002-02-14 2003-12-16 Dow Corning Corporation Masterbatch method for economically and efficiently producing soap dispersions in textile fluids for synthetic fiber treatment
US20030198809A1 (en) * 2002-04-18 2003-10-23 Hyosung Corporation Fluorescent elastic yarn and method for producing the same
US6720403B1 (en) * 2002-11-01 2004-04-13 E.I. Dupont De Nemours And Co. Polyurethaneurea and spandex comprising same
US20070174972A1 (en) * 2005-11-14 2007-08-02 Invista North America S.A R.I. Spandex having enhanced whiteness, and fabrics and garments comprising the same
WO2007120749A1 (en) * 2006-04-13 2007-10-25 Cytec Technology Corp. Stabilized spandex compositions
US20130033776A1 (en) 2011-08-05 2013-02-07 Harding Brett T Optical Element for Correcting Color Blindness
US8931930B2 (en) 2013-01-29 2015-01-13 Nitto Denko Corporation Optical element for correcting color blindness

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB945479A (en) * 1959-05-05 1964-01-02 Gen Tire & Rubber Co Stabilized polyurethanes
US3386942A (en) * 1964-06-29 1968-06-04 Eastman Kodak Co Stabilization of non-yellowing segmented polyurethane copolymers of polymeric diols, functionally aliphatic diisocyanates and functionally aliphatic diamines
US3419524A (en) * 1965-01-04 1968-12-31 Weston Chemical Corp Polyphosphites as stabilizers for hydrocarbon polymers
DE1912179A1 (en) * 1968-03-11 1969-10-02 American Cyanamid Co Stabilized Polyurethane Elastomers
US3772218A (en) * 1971-10-12 1973-11-13 Scott Paper Co Flexible,open-cell,non-discoloring polyurethane foam
DE2231069A1 (en) * 1972-06-24 1974-01-03 Bayer Ag Polyurethane discolouration inhibitor - is trialkylphenol pref in synergic mixt with a phosphate/phosphine or sulphide ester

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3367996A (en) * 1964-06-22 1968-02-06 Nat Polychemicals Inc Phosphorus-containing polymers
US3373251A (en) * 1965-02-23 1968-03-12 Shure Bros Electrostatic transducer
US4228247A (en) * 1979-08-29 1980-10-14 Basf Wyandotte Corporation Stabilized polyoxyalkylene polyether polyol

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB945479A (en) * 1959-05-05 1964-01-02 Gen Tire & Rubber Co Stabilized polyurethanes
US3386942A (en) * 1964-06-29 1968-06-04 Eastman Kodak Co Stabilization of non-yellowing segmented polyurethane copolymers of polymeric diols, functionally aliphatic diisocyanates and functionally aliphatic diamines
US3419524A (en) * 1965-01-04 1968-12-31 Weston Chemical Corp Polyphosphites as stabilizers for hydrocarbon polymers
DE1912179A1 (en) * 1968-03-11 1969-10-02 American Cyanamid Co Stabilized Polyurethane Elastomers
US3772218A (en) * 1971-10-12 1973-11-13 Scott Paper Co Flexible,open-cell,non-discoloring polyurethane foam
DE2231069A1 (en) * 1972-06-24 1974-01-03 Bayer Ag Polyurethane discolouration inhibitor - is trialkylphenol pref in synergic mixt with a phosphate/phosphine or sulphide ester

Also Published As

Publication number Publication date
ZA847544B (en) 1986-05-28
ATE52111T1 (en) 1990-05-15
US4548975A (en) 1985-10-22
EP0137408A2 (en) 1985-04-17
HK65590A (en) 1990-08-31
EP0137408B1 (en) 1990-04-18
SG42390G (en) 1990-08-17
BR8404800A (en) 1985-08-13
DE3481998D1 (en) 1990-05-23
CA1247776A (en) 1988-12-28
MX159094A (en) 1989-04-14
ES8602975A1 (en) 1985-12-01
JPS6094622A (en) 1985-05-27
ES536222A0 (en) 1985-12-01

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