EP0134040B1 - Verfahren zum Zuführen von pulverförmigem Material in einem Kesselfeuerraum und Vorrichtung zum Durchführen dieses Verfahrens - Google Patents
Verfahren zum Zuführen von pulverförmigem Material in einem Kesselfeuerraum und Vorrichtung zum Durchführen dieses Verfahrens Download PDFInfo
- Publication number
- EP0134040B1 EP0134040B1 EP84110063A EP84110063A EP0134040B1 EP 0134040 B1 EP0134040 B1 EP 0134040B1 EP 84110063 A EP84110063 A EP 84110063A EP 84110063 A EP84110063 A EP 84110063A EP 0134040 B1 EP0134040 B1 EP 0134040B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hearth
- gas
- suspension
- powder material
- injecting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000002347 injection Methods 0.000 title claims description 19
- 239000007924 injection Substances 0.000 title claims description 19
- 238000002485 combustion reaction Methods 0.000 title claims description 7
- 239000000725 suspension Substances 0.000 claims abstract description 15
- 239000007787 solid Substances 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims abstract 12
- 239000002803 fossil fuel Substances 0.000 claims abstract 3
- 239000007789 gas Substances 0.000 claims description 23
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 16
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 16
- 239000004571 lime Substances 0.000 claims description 16
- 239000003245 coal Substances 0.000 claims description 4
- 239000012159 carrier gas Substances 0.000 claims description 3
- 239000003546 flue gas Substances 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
- 239000003517 fume Substances 0.000 description 6
- 150000008064 anhydrides Chemical class 0.000 description 4
- 239000004449 solid propellant Substances 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 3
- 235000012255 calcium oxide Nutrition 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- -1 alkali metal salt Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 239000003077 lignite Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 241000221988 Russula cyanoxantha Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J7/00—Arrangement of devices for supplying chemicals to fire
Definitions
- the present invention relates to a method for injecting a pulverulent material into a furnace of a fossil solid fuel boiler, in which the pulverulent material is suspended in a gas and then introduced into the furnace. It also extends to a device for implementing this method.
- the object of the present invention is to provide a method of injecting a pulverulent material into a boiler hearth which ensures better contact between the grains of pulverulent material and the combustion gases, and consequently improves the efficiency of the injection of pulverulent material, and in particular the percentage reduction in the sulfur dioxide and sulfuric anhydride contents in the flue gases at the outlet of the boiler in the case where the pulverulent material is an oxide or an alkaline earth or alkali metal salt capable of fixing these anhydrides to form a sulfate. It also aims to allow the injection of large quantities of pulverulent material and to ensure good dispersion of the latter in the hearth without significantly disturbing the operation of the boiler.
- the method according to the invention is characterized in that the pulverulent material is suspended in a low flow of gas, which is introduced into the hearth at low speed, and in that it is introduced into the hearth around or slightly below the suspending gas a flow of hot air or auxiliary hot gas of at least 1 kg per kg of material suspended in said gas, at a speed included at its outlet in the foyer between 30 and 70 m / s.
- the gas for suspending the pulverulent material is cold air.
- the gas loaded with pulverulent material is injected at several points around the edge of the fireplace.
- the hot air introduced into the hearth around or a little below the suspending gas is taken from the combustion air supply to the hearth.
- the gas loaded with pulverulent material is injected into the hearth at a level where the maximum temperature of the fumes is between 1000 ° and 1500 ° C.
- the injection points in the hearth are chosen so that the residence time of the pulverulent material in the hearth between its injection level and the level where the temperature of the fumes is reduced to 800 ° C. is sufficient for the pulverulent material react chemically.
- the invention further extends to a device for injecting pulverulent material into a hearth of a fossil solid fuel boiler, according to the above method, characterized in that it comprises at least one injection nozzle in the focal point of powdery material suspended in a low gas flow, and at least one injection nozzle with a higher flow of hot air or hot gas around or slightly below the gas injection nozzle carrier of the pulverulent material, at a flow rate of at least 1 kg per kg of material suspended in said carrier gas.
- the invention applies to boilers with fossil solid fuel, coal or lignite, whether these are introduced into the boiler in the pulverized state, in the granular state, on a grate or possibly using projectors, or are suspended there in a fluid bed.
- the pulverulent material can be an alkaline earth or alkaline oxide, or an alkaline earth or alkali metal salt, for example quicklime or slaked lime, limestone, magnesia, dolomite, its effect then being to react on the sulfurous and sulfuric anhydrides formed during the combustion of the solid fuel by forming a solid sulfate, and thereby reducing the content of the fumes in these anhydrides.
- an alkaline earth or alkaline oxide or an alkaline earth or alkali metal salt, for example quicklime or slaked lime, limestone, magnesia, dolomite, its effect then being to react on the sulfurous and sulfuric anhydrides formed during the combustion of the solid fuel by forming a solid sulfate, and thereby reducing the content of the fumes in these anhydrides.
- it can also be a material intended to modify the fusibility of the ashes, or more generally to influence the chemical reactions occurring in the hearth.
- the nozzle 1 is surrounded by the annular nozzle 4 of hot air, at a temperature of 250 ° to 320 ° C, taken from the combustion air circuit, the flow of which is adjustable by the flap 5.
- the annular vein d hot air surrounding the cold air stream loaded with lime ensures a distribution of lime throughout the cross section of the hearth, and in particular prevents the grains of lime from going down the hearth along its wall.
- the level 11 of the lime injectors in the cold air corresponds to a maximum smoke temperature of 1350 ° C.
- the height H separating this level from that of the steam superheaters 6, where the maximum temperature of the fumes is approximately 800 ° C., is such that the residence time of the lime particles in the boiler between these two levels is approximately 2 seconds, which allows them to react to a large extent with sulfurous and sulfuric anhydrides, without however being brought to a too high temperature which would cause their surface fusion and a decrease in their reactivity.
- the hot air to keep the lime in suspension enters the pipe at level 15, a little below the lime injection level.
- the pulverized charcoal burners are located at levels 12, 13 and 14, notably below the lime and hot air injectors.
- FIG. 13 shows the arrangement of the lime injectors 11A, 11B, 11C, 11D in horizontal cross section, in the corners of the hearth.
- the injectors could be arranged on two opposite faces of the hearth (for example front face and rear face) in the case of a hearth with frontal heating.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Glass Compositions (AREA)
- Crucibles And Fluidized-Bed Furnaces (AREA)
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT84110063T ATE34210T1 (de) | 1983-08-26 | 1984-08-23 | Verfahren zum zufuehren von pulverfoermigem material in einem kesselfeuerraum und vorrichtung zum durchfuehren dieses verfahrens. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8313779A FR2551184B1 (fr) | 1983-08-26 | 1983-08-26 | Procede d'injection d'un materiau pulverulent dans un foyer de chaudiere, et dispositif de mise en oeuvre de ce procede |
| FR8313779 | 1983-08-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0134040A1 EP0134040A1 (de) | 1985-03-13 |
| EP0134040B1 true EP0134040B1 (de) | 1988-05-11 |
Family
ID=9291833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP84110063A Expired EP0134040B1 (de) | 1983-08-26 | 1984-08-23 | Verfahren zum Zuführen von pulverförmigem Material in einem Kesselfeuerraum und Vorrichtung zum Durchführen dieses Verfahrens |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0134040B1 (de) |
| AT (1) | ATE34210T1 (de) |
| DE (1) | DE3471151D1 (de) |
| FR (1) | FR2551184B1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2583305B1 (fr) * | 1985-06-18 | 1989-10-27 | Fives Cail Babcock | Procede de desulfuration des gaz provenant du foyer d'une chaudiere et installation pour la mise en oeuvre de ce procede. |
| FR2583304B1 (fr) * | 1985-06-18 | 1989-12-22 | Fives Cail Babcock | Installation pour la desulfuration des gaz provenant du foyer d'une chaudiere. |
| US5027723A (en) * | 1986-07-14 | 1991-07-02 | Inland Steel Company | Method and apparatus for reducing sulfur dioxide content in flue gases |
| US5048431A (en) * | 1986-07-14 | 1991-09-17 | Inland Steel Company | Method and apparatus for reducing sulfur dioxide content in flue gases |
| US5246364A (en) * | 1986-07-14 | 1993-09-21 | Inland Steel Company | Method and apparatus for reducing sulfur dioxide content in flue gases |
| CA1309571C (en) * | 1986-07-14 | 1992-11-03 | Ronald R. Landreth | Method and apparatus for reducing sulfur dioxide content in flue gases |
| HU200361B (en) * | 1987-12-28 | 1990-05-28 | Gyoergy Vamos | Composition and process for reducing slagging of boiler furnaces and sulfur emission |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1601959B2 (de) * | 1968-03-09 | 1971-06-09 | Senft, Hugo, 4300 Essen | Vorrichtung zur zugabe von rauchgasseitig korrosionen verhin dernden staeuben oder aufgeschlaemmter staeuben |
| US3746498A (en) * | 1972-01-24 | 1973-07-17 | Combustion Eng | Reducing no{11 {11 emissions by additive injection |
| FR2349368A1 (fr) * | 1976-04-26 | 1977-11-25 | Charbonnages De France | Procede et dispositif d'introduction et de dispersion d'une matiere boueuse dans une enceinte |
| DE3133321A1 (de) * | 1980-09-05 | 1982-04-08 | Österreichische Draukraftwerke AG, 9020 Klagenfurt | "verfahren zur entschwefelung von kohlegefeuerten kraftwerken" |
-
1983
- 1983-08-26 FR FR8313779A patent/FR2551184B1/fr not_active Expired
-
1984
- 1984-08-23 EP EP84110063A patent/EP0134040B1/de not_active Expired
- 1984-08-23 DE DE8484110063T patent/DE3471151D1/de not_active Expired
- 1984-08-23 AT AT84110063T patent/ATE34210T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FR2551184B1 (fr) | 1985-10-11 |
| FR2551184A1 (fr) | 1985-03-01 |
| EP0134040A1 (de) | 1985-03-13 |
| ATE34210T1 (de) | 1988-05-15 |
| DE3471151D1 (en) | 1988-06-16 |
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